Academic literature on the topic 'Ligands Metal complexes Electrochemistry'

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Journal articles on the topic "Ligands Metal complexes Electrochemistry"

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Ioachim, Elena, and Garry S. Hanan. "Spectroscopy and electrochemistry of new 6,6′-disubstituted-4,4′-bipyrimidine molybdenum(0) and tungsten(0) tetracarbonyl complexes." Canadian Journal of Chemistry 83, no. 8 (2005): 1114–19. http://dx.doi.org/10.1139/v05-127.

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A new family of tetracarbonyl molybdenum(0) and tungsten(0) complexes based on new 6,6′-disubstituted-4,4′-bipyrimidine ligands was synthesized and characterized. The visible region of the absorption spectrum of each complex is dominated by a metal-to-ligand charge transfer band significantly lower in energy than the corresponding transition in 2,2′-bipyridine tetracarbonyl metal complexes. The 6,6′-substituents create a larger π-electronic system in the substituted bipyrimidines and are consequently better π acceptors than even the parent 4,4′-bipyrimidine. The absorption bands are shifted ba
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Journal, Baghdad Science. "Ligand reduction in variously substituted cerium (IV) tetrakis acetylacetone complexes by electrochemistry technique." Baghdad Science Journal 5, no. 2 (2008): 278–84. http://dx.doi.org/10.21123/bsj.5.2.278-284.

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In this work, substantial evidence was obtained for ligand reduction in cerium tetrakis acac complexes. Also, this ligand reduction of a negatively charged ligand proved to depend far less on the nature central metal than neutral ligands does. It is supposed that in Mz(acac)z complexes the charge is distributed evenly over the whole molecule. In this work these complexes were prepared and characterized by IR and CHN analysis to indicate the purities of these complexes. The electrochemistry techniques were shown as obtained for ligand reduction. This research was carried out at School of Chemis
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Thompson, Laurence K. "2004 Alcan Award LectureFrom dinuclear to triakontahexanuclear complexes — Adventures in supramolecular coordination chemistry." Canadian Journal of Chemistry 83, no. 2 (2005): 77–92. http://dx.doi.org/10.1139/v04-173.

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Polynuclear coordination complexes result from the interplay between the arrangement of the binding sites of a ligand, and their donor content, and the coordination preferences of the metal ion involved. Rational control of the ligand properties, such as denticity, geometry, and size, can lead to large, and sometimes predictable, polynuclear assemblies. This Alcan Award Lecture highlights our "adventures" with polynucleating ligands over the last 25 years, with examples ranging from simple dinucleating to more exotic high-denticity ligands. Complexes with nuclearities ranging from 2 to 36 have
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Kim, Jee Eon, Justin A. Bogart, Patrick J. Carroll, and Eric J. Schelter. "Rare Earth Metal Complexes of Bidentate Nitroxide Ligands: Synthesis and Electrochemistry." Inorganic Chemistry 55, no. 2 (2015): 775–84. http://dx.doi.org/10.1021/acs.inorgchem.5b02236.

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Yaman, Ș. Özalp, A. M. Önal, and H. Isci. "Electrochemistry of Acetate-, Carbonate-, Sulfate-, and Dihydrogenphosphate-Bridged Dirhodium(II) Complexes." Zeitschrift für Naturforschung B 58, no. 6 (2003): 563–70. http://dx.doi.org/10.1515/znb-2003-0612.

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Complexes, [Rh2(B-B)4L2]n (B-B = CH3COD2 , L = CH3CN, H2O, Cl-, Br-, SCN-; B-B = CO2-3 , SO2-4 , H2PO4̄, L =H2O, Cl-, Br-, SCN-) were prepared and their cyclic voltammograms (CV) and electronic absorption spectra were measured in solution. The CV of the complexes exhibits a reversible one-electron transfer from a metal-based orbital. Constant potential electrolysis at the oxidation peak potential of [Rh2(O2CCH3)4(NCCH3)2] in acetonitrile yielded [Rh2(O2CCH3)4(NCCH3)2]+, a mixed valent Rh(II)DRh(III) cation complex. The formation of the mixed valent complex was monitored by measuring electronic
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Loukova, Galina V., and Vladimir V. Strelets. "A Review on Molecular Electrochemistry of Metallocene Dichloride and Dimethyl Complexes of Group 4 Metals: Redox Properties and Relation with Optical Ligand-to-Metal Charge Transfer Transitions." Collection of Czechoslovak Chemical Communications 66, no. 2 (2001): 185–206. http://dx.doi.org/10.1135/cccc20010185.

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Emphasis is given to redox, photophysical, and photochemical properties of homologous bent metallocenes of group 4 transition metals. Comparative analysis of a variety of electron-transfer induced transformations and ligand-to-metal charge-transfer excited states is performed for bent metallocene complexes upon systematic variation of the identity of the metal ion (Ti, Zr or Hf), ancillary π- and monodentate σ- (Cl, Me) ligands. For such organometallic π-complexes, linear correlations exist between energies of optical and redox HOMO-to-LUMO electron transitions. It is suggested that combinatio
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Kulkarni, Naveen V., M. P. Sathisha, Srinivasa Budagumpi, Gurunath S. Kurdekar, and Vidyanand K. Revankar. "Binuclear transition metal complexes of bicompartmental SNO donor ligands: synthesis, characterization, and electrochemistry." Journal of Coordination Chemistry 63, no. 8 (2010): 1451–61. http://dx.doi.org/10.1080/00958971003770405.

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Denisovich, L. I., S. M. Peregudova, and Yu N. Novikov. "Electrochemical properties of transition metal complexes with C60 and C70 fullerne ligands (review)." Russian Journal of Electrochemistry 46, no. 1 (2010): 1–17. http://dx.doi.org/10.1134/s1023193510010015.

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Lucas, C. Robert, and Shuang Liu. "Thiophenophane metal complexes IV. Effects from ligand changes outside the coordination sphere." Canadian Journal of Chemistry 74, no. 11 (1996): 2340–48. http://dx.doi.org/10.1139/v96-261.

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Preparation of two thiophenophane polythioether macrocycles and 11 of their complexes of Cu(I), Cu(II), Ag(I), and Pd(II) is described. The single crystal X-ray structure of [(CuBr)2(L1)x is reported: space group Pcma, a = 8.7120(6), b = 10.7791(5), c = 12.0929(5) Å, Z = 2, Rf = 0.052, Rw = 0.036 for 521 reflections. Variable-temperature magnetic susceptibility measurements for [(CuCl2)2(L1)] and [(CuCl2)2(L2)] reveal weak antiferromagnetic and weak ferromagnetic coupling, respectively. Cyclic voltammograms of these compounds display two unequal waves in acetonitrile solvent but only one in ni
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Chahma, M'hamed, Daniel JT Myles, and Robin G. Hicks. "Synthesis, characterization, and coordination chemistry of phosphines with ethylenedioxythiophene substituents." Canadian Journal of Chemistry 83, no. 2 (2005): 150–55. http://dx.doi.org/10.1139/v05-004.

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The preparation of several new phosphines bearing one or more 3,4-ethylenedioxythiophene (EDOT) units as substituents linked at the 2-thienyl position is described. The phosphines were prepared by reaction of lithiated EDOT intermediates with appropriate chlorophosphines to afford (3,4-ethylenedioxy-2-thienyl)diphenylphosphine (1), (bis(3,4-ethylenedioxy-2-thienyl)phenylphosphine (2), tris(3,4-ethylenedioxy-2-thienyl)phosphine (3), 2,5-bis(diphenylphosphino)-3,4-ethylenedioxythiophene (4), and 2-diphenylphosphino-5-mesitylthio-3,4-ethylenedioxythiophene (5). Molybdenum carbonyl complexes of co
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Dissertations / Theses on the topic "Ligands Metal complexes Electrochemistry"

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Foster, Keith A. "Preparative, structural, and electrochemical investigation of metal complexes of tetraazamacrocyclic ligands containing tertiary amine donors." Diss., Georgia Institute of Technology, 1986. http://hdl.handle.net/1853/30370.

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Smith, Mark Edward. "Molecular wires : syntheses, electrochemistry and properties of metal complexes containing carbon chains /." Title page, contents and abstract only, 2002. http://web4.library.adelaide.edu.au/theses/09PH/09phs654.pdf.

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Thesis (Ph.D.)--University of Adelaide, Dept. of Chemistry, 2002.<br>"September 2002" Includes as appendix: a list of publications by the author arising from this work; and, copies of some published journal articles. Includes bibliographical references.
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Mohamed, Nuralli. "Electrochemical studies of monosubstituted squarate ligands and its transition metal and lanthanide complexes." Thesis, University of the Western Cape, 2008. http://etd.uwc.ac.za/index.php?module=etd&action=viewtitle&id=gen8Srv25Nme4_9818_1263431045.

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<p>The study introduces and puts forward Sector Policing as a model to expand community Policing and to broaden the scope of crime prevention. It also demonstrates how Sector Policing can be utilised to decentralise policing and deepen community participation.</p>
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Yohannes, Desta Yonas. "Synthesis and electrochemistry of biodegradable ligands - iminodiglutaric acid and iminoglutaricsuccinic acid - and their complexes with selected metal ions (Zn²⁺, Cd²⁺, Cu²⁺)." Thesis, Stellenbosch : Stellenbosch University, 2004. http://hdl.handle.net/10019.1/50112.

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Thesis (MSc)--Stellenbosch University, 2004.<br>ENGLISH ABSTRACT: Two new potentially biodegradable aminopolycarboxylic acid ligands, iminodiglutaric acid tetra sodium salt (IDG-4Na) and iminoglutaricsuccinic acid tetra sodium salt (IGS- 4Na), were synthesized in reasonably good yield and purity. The commercially unavailable precursor for the two ligands, ethyl p-aminoglutarate, was synthesised in high yield and purity, and together with the two ligands were fully characterized by means of melting point measurements and various spectrometric techniques CH-NMR, 13C-NMR, MS and IR). For
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Brown, Douglas J. "Heteroleptic paddlewheel complexes and molecular assemblies of dimolybdenum and ditungsten a study of electronic and structural control /." Columbus, Ohio : Ohio State University, 2006. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1150289057.

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Lengkeek, Nigel Andrew. "Functional cage-amine complexes : polymerisable metallomonomers and multi-cage complexes." University of Western Australia. School of Biomedical, Biomolecular and Chemical Sciences, 2008. http://theses.library.uwa.edu.au/adt-WU2008.0138.

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[Truncated abstract] Chapter 1 provides an introduction to the 'sarcophagine' class of ligands and the field of metallopolymers. The synthesis, stereochemistry, physical properties and functionalisation of 'sarcophagines' and their metal complexes are discussed. A brief overview of the burgeoning field of metallopolymers is given with specific mention of the synthetic routes to pendant metallopolymers, and how these could be employed to prepared cage amine containing metallopolymers. Chapter 2 deals with the synthesis, characterisation and reactivity of cinnamylamino and styrylamido derivative
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Weiß, Daniel Traugott [Verfasser], Fritz E. [Akademischer Betreuer] Kühn, and Richard W. [Akademischer Betreuer] Fischer. "Influence of Open Chain, Tetradentate NHC and NHC/Pyridine Hybrid Ligands on the Coordination and Electrochemistry of Late Transition Metal Complexes / Daniel Traugott Weiß. Betreuer: Fritz E. Kühn. Gutachter: Fritz E. Kühn ; Richard W. Fischer." München : Universitätsbibliothek der TU München, 2015. http://d-nb.info/1079974563/34.

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Hicks, Owen Michael. "Complexes of redox-active cyanomanganese ligands." Thesis, University of Bristol, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.390377.

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Rajan, Siji. "Synthesis and complexes of bridging heterocyclic ligands." Thesis, University of Canterbury. Chemistry, 2014. http://hdl.handle.net/10092/9948.

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Ligand–mediated coupling between metal centres is of fundamental importance in inorganic and materials chemistry. Bridging ligands involving azo groups as coordinating π–acceptors can yield complexes with interesting properties. This thesis describes the synthesis of a series of N–heterocyclic compounds containing the azo functionality, designed for potential coordination to the metal through the azo nitrogen and a N–heterocyclic ring. The azo ligands are divided into four categories; ligands based on azobispyridines, ligands containing pyrimidine and fused aromatic azine groups and ligands
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Cheung, Wai Man. "Transition metal complexes with dichalcogenoimidodiphosphinate ligands /." View abstract or full-text, 2007. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202007%20CHEUNG.

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Books on the topic "Ligands Metal complexes Electrochemistry"

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Survila, Arvydas. Electrochemistry of Metal Complexes. Wiley-VCH Verlag GmbH & Co. KGaA, 2015. http://dx.doi.org/10.1002/9783527691241.

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Buchler, J. W., ed. Metal Complexes with Tetrapyrrole Ligands II. Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/3-540-52899-7.

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Buchler, Johann Walter, ed. Metal Complexes with Tetrapyrrole Ligands I. Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/bfb0036788.

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Zagal, Jose H., and Fethi Bedioui, eds. Electrochemistry of N4 Macrocyclic Metal Complexes. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-31332-0.

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Zagal, Jose H., and Fethi Bedioui, eds. Electrochemistry of N4 Macrocyclic Metal Complexes. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-31172-2.

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Lane, H. P. Transition metal complexes of group fifteen donor ligands. UMIST, 1994.

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Chauvin, Remi, and Yves Canac, eds. Transition Metal Complexes of Neutral eta1-Carbon Ligands. Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-04722-0.

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Hawkins, Ian Michael. New transition metal complexes containing phosphine and sulphur ligands. University of East Anglia, 1988.

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Transition metal complexes of neutral [Eta]1-carbon ligands. Springer Verlag, 2010.

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Kawaguchi, Shinʼichi. Variety in coordination modes of ligands in metal complexes. Springer-Verlag, 1988.

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Book chapters on the topic "Ligands Metal complexes Electrochemistry"

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Martell, Arthur E., and Robert D. Hancock. "Chelating Ligands." In Metal Complexes in Aqueous Solutions. Springer US, 1996. http://dx.doi.org/10.1007/978-1-4899-1486-6_3.

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Guerchais, Véronique, and Hubert Le Bozec. "Metal Complexes Featuring Photochromic Ligands." In Topics in Organometallic Chemistry. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-642-01866-4_6.

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Dzhardimalieva, Gulzhian I., and Igor E. Uflyand. "Metal Complexes with Polymer Chelating Ligands." In Chemistry of Polymeric Metal Chelates. Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-56024-3_3.

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Yamada, Jun-ichi, and Toyonari Sugimoto. "TTFs as Ligands of Metal Complexes." In TTF Chemistry. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-662-10630-3_7.

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Cotton, F. A., and C. M. Lukehart. "Transition Metal Complexes Containing Carbenoid Ligands." In Progress in Inorganic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470166178.ch3.

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Liu, Chen-Wei, and J. Derek Woollins. "Metal Complexes Containing P-Se Ligands." In Selenium and Tellurium Chemistry. Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/978-3-642-20699-3_13.

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McGuinness, David S. "Cr Complexes of Nitrogen Donor Ligands for Olefin Oligomerisation and Polymerisation." In Catalysis by Metal Complexes. Springer Netherlands, 2011. http://dx.doi.org/10.1007/978-90-481-3815-9_1.

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Mayr, A. "The Role of Nucleophiles and Electrophiles in Coupling Reactions of Alkylidyne Ligands." In Transition Metal Carbyne Complexes. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4_25.

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Lungwitz, B., and A. C. Filippou. "Electron-Rich Tungsten Aminocarbyne Complexes with Cp* Ligands Synthesis and Protonation Reactions." In Transition Metal Carbyne Complexes. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4_28.

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Trifonov, Alexander A. "Rare-Earth Metal Complexes Supported by Nitrogen-Containing Ligands in Olefin Polymerization." In Catalysis by Metal Complexes. Springer Netherlands, 2011. http://dx.doi.org/10.1007/978-90-481-3815-9_3.

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Conference papers on the topic "Ligands Metal complexes Electrochemistry"

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Ayadi, A., K. El Korchi, D. Guichaoua, S. Taboukhat, and A. El-Ghayoury. "Azo-Based Ligands and Metal Complexes for NLO Applications." In 2019 21st International Conference on Transparent Optical Networks (ICTON). IEEE, 2019. http://dx.doi.org/10.1109/icton.2019.8840333.

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Palopoli, Stephen F., and Thomas B. Brill. "Synthesis And Thermolysis Of Metal Complexes Containing Energetic Ligands." In 1988 Los Angeles Symposium--O-E/LASE '88, edited by Joseph Flanagan. SPIE, 1988. http://dx.doi.org/10.1117/12.943744.

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Sahraoui, Bouchta, Konstantinos Iliopoulos, and Abdelkrim El-Ghayoury. "NLO investigations of electroactive ligands and of their electroactive metal complexes." In 2013 15th International Conference on Transparent Optical Networks (ICTON). IEEE, 2013. http://dx.doi.org/10.1109/icton.2013.6602961.

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Gale, David C., Gary M. Gray, and Christopher M. Lawson. "Nonlinear optical properties of metal-organic complexes with phosphorous-donor ligands." In Optical Science, Engineering and Instrumentation '97, edited by Christopher M. Lawson. SPIE, 1997. http://dx.doi.org/10.1117/12.284168.

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Gude, Lourdes, Katerina Duskova, Sara Sierra, María-José Fernández, and Antonio Lorente. "Synthesis of 2,2'-bipyridine metal complexes as potential G-quadruplex DNA ligands." In XVth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2011. http://dx.doi.org/10.1135/css201112330.

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Dhindsa, Ajaib S., Allan E. Underhill, Stephen N. Oliver, and Stephen V. Kershaw. "Third-order NLO properties of metal complexes containing delocalized oxygen or sulphur donor ligands and mixed oxygen and sulphur donor ligands." In SPIE's 1995 International Symposium on Optical Science, Engineering, and Instrumentation, edited by Carl M. Lampert, Satyen K. Deb, and Claes-Goeran Granqvist. SPIE, 1995. http://dx.doi.org/10.1117/12.217353.

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Jaya, NM, NH Ismail, ALM Low, et al. "Schiff base ligands derived from phenylenediamine and its metal complexes as enhancer against two mechanisms of antibiotic resistance." In 67th International Congress and Annual Meeting of the Society for Medicinal Plant and Natural Product Research (GA) in cooperation with the French Society of Pharmacognosy AFERP. © Georg Thieme Verlag KG, 2019. http://dx.doi.org/10.1055/s-0039-3400408.

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Záliš, S., R. S. Winter, M. Linseis, et al. "DFT modeling of Spectral and Redox Properties of Di-and Tetranuclear Ruthenium Transition Metal Complexes with Bridging Ligands." In COMPUTATIONAL METHODS IN SCIENCE AND ENGINEERING: Advances in Computational Science: Lectures presented at the International Conference on Computational Methods in Sciences and Engineering 2008 (ICCMSE 2008). AIP, 2009. http://dx.doi.org/10.1063/1.3225297.

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Tobysheva, P. D., L. A. Khamidullina, I. S. Puzyrev, and A. V. Pestov. "Biological activity of complexes based on polycarbonyl ligands: assessment of the mode of action using molecular docking." In 2nd International Scientific Conference "Plants and Microbes: the Future of Biotechnology". PLAMIC2020 Organizing committee, 2020. http://dx.doi.org/10.28983/plamic2020.249.

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Romero, María J., Sandra Fernández-Fariña, Luis M. González-Barcia, Rosa Pedrido, Ana M. González-Noya, and Marcelino Maneiro. "Synthesis of two asymmetric half-salen imine-type ligands as precursors of polynuclear metal complexes." In The 21st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2017. http://dx.doi.org/10.3390/ecsoc-21-04752.

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Reports on the topic "Ligands Metal complexes Electrochemistry"

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Rakowski-DuBois, Mary C. Aspects of C-H Activation in Metal Complexes Containing Sulfur Ligands. Office of Scientific and Technical Information (OSTI), 2004. http://dx.doi.org/10.2172/833244.

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Reynolds, Michael. Transition Metal Complexes of Cr, Mo, W and Mn Containing η1(S)-2,5-Dimethylthiophene, Benzothiophene and Dibenzothiophene Ligands. Office of Scientific and Technical Information (OSTI), 2000. http://dx.doi.org/10.2172/764616.

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Kubas, G. J., J. Eckert, and X. L. Luo. Binding of hydrocarbons and other extremely weak ligands to transition metal complexes that coordinate hydrogen: Investigation of cis-interactions and delocalized bonding involving sigma bonds. Office of Scientific and Technical Information (OSTI), 1997. http://dx.doi.org/10.2172/505275.

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