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Relevant bibliographies by topics / Limonene epoxide

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Journal articles

Academic literature on the topic 'Limonene epoxide'

Author: Grafiati

Published: 3 June 2025

Last updated: 1 August 2025

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Journal articles on the topic "Limonene epoxide"

1

Huang, Zi-Yi, Min-Ru Jiao, Xiu Gu, Zi-Ran Zhai, Jian-Qi Li, and Qing-Wei Zhang. "Asymmetric Synthesis of 1,2-Limonene Epoxides by Jacobsen Epoxidation." Pharmaceutical Fronts 03, no. 03 (2021): e113-e118. http://dx.doi.org/10.1055/s-0041-1740241.

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This study reported an asymmetric synthesis of 1,2-limonene epoxides. The absolute stereochemistry was controlled by a Jacobsen epoxidation of cis-1,2-limonene epoxide (with diastereomeric excess of 98%) and trans-1,2-limonene epoxide (with diastereomeric excess of 94%), which could be used as important raw materials for the preparation of related cannabinoid drugs.

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2

van der Werf, Mariët J., Karin M. Overkamp, and Jan A. M. de Bont. "Limonene-1,2-Epoxide Hydrolase fromRhodococcus erythropolis DCL14 Belongs to a Novel Class of Epoxide Hydrolases." Journal of Bacteriology 180, no. 19 (1998): 5052–57. http://dx.doi.org/10.1128/jb.180.19.5052-5057.1998.

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ABSTRACT An epoxide hydrolase from Rhodococcus erythropolisDCL14 catalyzes the hydrolysis of limonene-1,2-epoxide to limonene-1,2-diol. The enzyme is induced when R. erythropolis is grown on monoterpenes, reflecting its role in the limonene degradation pathway of this microorganism. Limonene-1,2-epoxide hydrolase was purified to homogeneity. It is a monomeric cytoplasmic enzyme of 17 kDa, and its N-terminal amino acid sequence was determined. No cofactor was required for activity of this colorless enzyme. Maximal enzyme activity was measured at pH 7 and 50°C. None of the tested inhibitors or m

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3

van der Werf, Mariët J., Henk J. Swarts, and Jan A. M. de Bont. "Rhodococcus erythropolis DCL14 Contains a Novel Degradation Pathway for Limonene." Applied and Environmental Microbiology 65, no. 5 (1999): 2092–102. http://dx.doi.org/10.1128/aem.65.5.2092-2102.1999.

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ABSTRACT Strain DCL14, which is able to grow on limonene as a sole source of carbon and energy, was isolated from a freshwater sediment sample. This organism was identified as a strain of Rhodococcus erythropolis by chemotaxonomic and genetic studies. R. erythropolis DCL14 also assimilated the terpenes limonene-1,2-epoxide, limonene-1,2-diol, carveol, carvone, and (−)-menthol, while perillyl alcohol was not utilized as a carbon and energy source. Induction tests with cells grown on limonene revealed that the oxygen consumption rates with limonene-1,2-epoxide, limonene-1,2-diol, 1-hydroxy-2-oxo

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4

Clerget, Mégane, Eric Gagnon, and Jerome P. Claverie. "Photopolymerization of Limonene Dioxide and Vegetable Oils as Biobased 3D-Printing Stereolithographic Formulation." Polymers 16, no. 7 (2024): 965. http://dx.doi.org/10.3390/polym16070965.

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Epoxidized vegetable oils and limonene dioxide, a bis-epoxide derived from the terpene limonene, are photo-copolymerized to yield highly crosslinked networks with high conversion of all epoxide groups at ambient temperature. However, the slow polymerization of such biobased formulation polymerizes is not compatible for a use in a commercial SLA 3D printer. Adding an acrylated epoxidized vegetable oil to the bis-epoxide leads to a decrease of curing time and an increase in LDO conversion to polymer. For example, in a 60:40 wt:wt mixture of LDO and epoxidized soybean oil, the conversions of both

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5

Fomenko, Vladislav V., Sergey S. Laev та Nariman F. Salakhutdinov. "Catalytic Epoxidation of 3-Carene and Limonene with Aqueous Hydrogen Peroxide, and Selective Synthesis of α-Pinene Epoxide from Turpentine". Catalysts 11, № 4 (2021): 436. http://dx.doi.org/10.3390/catal11040436.

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The epoxidation of turpentine (technical α-pinene), 3-carene, and limonene with aqueous hydrogen peroxide was studied in a new catalytic system employing manganese sulfate, salicylic acid, sodium bicarbonate, and acetonitrile, as a polar solvent. The proposed approach makes it possible to carry out a “chemical separation” of turpentine components, yielding valuable individual derivatives of monoterpenes without the need to isolate individual monoterpene reagents. Specific methods have been developed for the production of α-pinene epoxide, 3-carene epoxide, limonene diepoxide, as well as for tw

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6

Setzer, William N. "A Computational Examination of the Uncatalyzed Meinwald Rearrangement of Monoterpene Epoxides." Natural Product Communications 11, no. 9 (2016): 1934578X1601100. http://dx.doi.org/10.1177/1934578x1601100901.

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Epoxides are relatively reactive compounds and may undergo decomposition or rearrangement reactions at elevated temperatures, and gas chromatographic analysis of essential oils may cause thermal decomposition or rearrangement of epoxide components at gas chromatographic temperatures. Density functional theory (DFT) calculations were carried out using the B3LYP functional at the 6-311++G**//6-31G* level of theory on the Meinwald rearrangements of α-pinene oxide (two different mechanisms leading to trans-pinocamphone and α-campholenal), cis-limonene oxide (leading to trans-dihydrocarvone), trans

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7

El Hammoumi, M. M., L. Ait Said, A. El Bachiri, and M. Khoukhi. "Kinetic Separation of cis-and trans-Limonene Epoxide: Reaction of Diastereomeric Mixture of Limonene Oxides with Secondary Amine and Carbamate." Asian Journal of Chemistry 33, no. 11 (2021): 2667–70. http://dx.doi.org/10.14233/ajchem.2021.23379.

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A simple kinetic separation of (1:1) diastereomeric mixture of limonene oxides was used to purify cis-and trans-diastereomers of (R)-(+)-limonene oxide. The epoxide ring of trans-isomer was selectively opened by (R)-N-methyl-(α-methyl-benzyl)amine. This secondary nucleophilic amine left cis-limonene oxide largely unreacted and was obtained up to 90% yield. In a diverse way, (R)-N-(α-methylbenzyl) ethyl carbamate, selectively catalyze hydrolysis of cis-limonene oxide to 1,2-limonene diol leaving trans-limonene oxide largely unreacted. The unreacted trans-limonene oxide was recovered in up to 75

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8

Sevalho, Elison de Souza, Elissandro Fonseca Dos Banhos, Antonia Queiroz Lima De Souza, and Afonso Duarte Leão De Souza. "Evaluation of the biotransformation of R-(+)-limonene to aroma compounds by Pestalotiopsis versicolor LabMicrA-478 isolated of Euterpe oleracea Martius." DELOS: DESARROLLO LOCAL SOSTENIBLE 16, no. 42 (2023): 75–85. http://dx.doi.org/10.55905/rdelosv16.n42-007.

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Fungal biotransformation is a pertinent strategy to overcome difficulties and problems arising from chemical synthesis and direct extraction from nature. This biotechnological approach is a relevant strategy to obtain high-added-value aroma compounds under environmentally friendly conditions. In order to understand the effect of an amazon endophytic fungus on the monoterpene substrate, this research work aims to investigate the biotransformation using cells cultivated of Pestalotiopsis versicolor LabMicrA-478 with R-(+)-limonene as a sole carbon and energy source. The main products of the limo

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9

Shafiezadeh, Fatemeh, Ali Javid, Rahele Zhiani, and Sadegh Allameh. "Ho₃Fe₅O₁₂ nanoparticles immobilized on FPS for production of a biopolymer from CO₂ and limonene epoxide." RSC Advances 14, no. 50 (2024): 37431–37. http://dx.doi.org/10.1039/d4ra05285d.

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Ho3Fe5O12@FPS was synthesized for the first time using an advanced and environmentally friendly method. Subsequently, Ho3Fe5O12@FPS was used as a long-lasting and reusable adsorbent for the reaction of carbon dioxide with limonene epoxide.

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10

Ait Said, Lyazid, Mohamed Merouane El Hammoumi, Chaimaa El Haimer, Abdelhadi El Bachiri та Mostafa Khoukhi. "Synthesis of limonene β-amino alcohol from (R)-(+)-α-methylbenzylamine and (+)-limonene 1,2-epoxide". Journal of Molecular Structure 1241 (жовтень 2021): 130691. http://dx.doi.org/10.1016/j.molstruc.2021.130691.

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