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Journal articles on the topic 'Linear alpha olefin'

Author: Grafiati

Published: 4 June 2021

Last updated: 19 February 2022

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1

Golub, F. S., V. A. Bolotov, and V. N. Parmon. "Modern trends in the processing of linear alpha olefins to technologically important products. Part 2." Kataliz v promyshlennosti 20, no. 6 (2020): 456–72. http://dx.doi.org/10.18412/1816-0387-2020-6-456-472.

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This review is a continuation of the first part, which considered modern trends in the processing of linear alpha olefins to (co)polymers of ethylene, anionic and non-ionic surfactants. Important directions in LAO processing are briefly described: alkylation leading to the formation of linear alkylbenzenes, oligomerization of alpha olefins to poly alpha olefins, sulfation yielding alpha olefin sulfonates, and other bulky processes.

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2

Suri, Sushil K., Manmohan S. Thakur, and Satish Bhardwaj. "The mixed surfactant system of linear alkylbenzene sulfonate and alpha olefin sulfonate." Journal of the American Oil Chemists’ Society 70, no. 1 (1993): 59–64. http://dx.doi.org/10.1007/bf02545368.

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3

du Toit, Jean I., Percy van der Gryp, Monique M. Loock, et al. "Industrial viability of homogeneous olefin metathesis: Beneficiation of linear alpha olefins with the diphenyl-substituted pyridinyl alcoholato ruthenium carbene precatalyst." Catalysis Today 275 (October 2016): 191–200. http://dx.doi.org/10.1016/j.cattod.2015.12.004.

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4

Kalyon, Dilhan M., Dong-Woo Yu, and Francis H. Moy. "Rheology and processing of linear low density polyethylene resins as affected by alpha-olefin comonomers." Polymer Engineering and Science 28, no. 23 (1988): 1542–50. http://dx.doi.org/10.1002/pen.760282304.

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5

Carre´, D. J., P. D. Fleischauer, C. G. Kalogeras, and H. D. Marten. "Comparison of Lubricant Performance in an Oscillating Spacecraft Mechanism." Journal of Tribology 113, no. 2 (1991): 308–12. http://dx.doi.org/10.1115/1.2920621.

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A life test of lubricants for the R2 shaft bearings of a spacecraft oscillating scanner mechanism was performed under simulated orbital conditions. The lubricant originally used in the application, a chloroarylalkylsiloxane (CAS) oil, and a linear perfluoropolyalkylether (PFPE) oil failed in less than 2500 hr of operation. A poly-alpha-olefin (PAO) oil has been running for more than 11,000 hr without any indication of lubricant or system degradation. The performances of the oils are discussed in terms of the boundary lubrication conditions of the test.

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6

Niu, Ruixia, Daqiang Wang, Biao Long, et al. "Salinity tolerance, adsorption, and emulsification properties of nonylphenol alkyl sulphonates derived from bi-component linear alpha olefin." Canadian Journal of Chemical Engineering 95, no. 11 (2017): 2073–77. http://dx.doi.org/10.1002/cjce.22836.

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7

Kalyon, Dilhan M., and Francis H. Moy. "Ultimate properties of blown films of linear low density polyethylene resins as affected by alpha-olefin comonomers." Polymer Engineering and Science 28, no. 23 (1988): 1551–58. http://dx.doi.org/10.1002/pen.760282305.

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8

Kissin, Y. V. "Co-oligomerization of ethylene and higher linear alpha olefins. II. Olefin reactivities in various reaction steps of co-oligomerization with nickel ylide-based system." Journal of Polymer Science Part A: Polymer Chemistry 27, no. 2 (1989): 623–37. http://dx.doi.org/10.1002/pola.1989.080270221.

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9

Ramachandrarao, Bojja, Kottari Naresh, Ashoutosh Panday, and Nettem Venkateswarlu Choudary. "A Rapid Py‐GC/MS Study for Linear Alpha Olefin Production from Fast Pyrolysis of Wax and Waste Polyethylene." ChemistrySelect 4, no. 45 (2019): 13245–49. http://dx.doi.org/10.1002/slct.201903371.

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10

Niu, R. X., J. Y. He, B. Long, et al. "Adsorption, wetting, foaming, and emulsification properties of mixtures of nonylphenol dodecyl sulfonate based on linear alpha-olefin and heavy alkyl benzene sulfonate." Journal of Dispersion Science and Technology 39, no. 8 (2017): 1108–14. http://dx.doi.org/10.1080/01932691.2017.1383267.

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11

Sousan, Sinan, Swastika Regmi, and Yoo Min Park. "Laboratory Evaluation of Low-Cost Optical Particle Counters for Environmental and Occupational Exposures." Sensors 21, no. 12 (2021): 4146. http://dx.doi.org/10.3390/s21124146.

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Low-cost optical particle counters effectively measure particulate matter (PM) mass concentrations once calibrated. Sensor calibration can be established by deriving a linear regression model by performing side-by-side measurements with a reference instrument. However, calibration differences between environmental and occupational settings have not been demonstrated. This study evaluated four commercially available, low-cost PM sensors (OPC-N3, SPS30, AirBeam2, and PMS A003) in both settings. The mass concentrations of three aerosols (salt, Arizona road dust, and Poly-alpha-olefin-4 oil) were measured and compared with a reference instrument. OPC-N3 and SPS30 were highly correlated (r = 0.99) with the reference instrument for all aerosol types in environmental settings. In occupational settings, SPS30, AirBeam2, and PMS A003 exhibited high correlation (>0.96), but the OPC-N3 correlation varied (r = 0.88–1.00). Response significantly (p < 0.001) varied between environmental and occupational settings for most particle sizes and aerosol types. Biases varied by particle size and aerosol type. SPS30 and OPC-N3 exhibited low bias for environmental settings, but all of the sensors showed a high bias for occupational settings. For intra-instrumental precision, SPS30 exhibited high precision for salt for both settings compared to the other low-cost sensors and aerosol types. These findings suggest that SPS30 and OPC-N3 can provide a reasonable estimate of PM mass concentrations if calibrated differently for environmental and occupational settings using site-specific calibration factors.

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12

Jonathan, Alvin, Nathaniel M. Eagan, David L. Bruns, et al. "Ethylene oligomerization into linear olefins over cobalt oxide on carbon catalyst." Catalysis Science & Technology 11, no. 10 (2021): 3599–608. http://dx.doi.org/10.1039/d1cy00207d.

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13

Bekmukhamedov, Giyjaz E., Aleksandr V. Sukhov, Aidar M. Kuchkaev, and Dmitry G. Yakhvarov. "Ni-Based Complexes in Selective Ethylene Oligomerization Processes." Catalysts 10, no. 5 (2020): 498. http://dx.doi.org/10.3390/catal10050498.

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Linear alpha-olefins are widely used in the petrochemical industry and the world demand for these compounds increases annually. At present, the main method for producing linear alpha-olefins is the homogeneous catalytic ethylene oligomerization. This review presents modern nickel catalysts for this process, mainly systems for obtaining of one of the most demanded oligomer—1-butene—which is used for the production of linear low density polyethylene (LLDPE) and high density polyethylene (HDPE). The dependence of the catalytic performance on the composition and the structure of the used activated complexes, the electronic and coordination states of the nickel center was considered.

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14

McClelland, Daniel J., Bo-Xun Wang, William T. Cordell, et al. "Renewable linear alpha-olefins by base-catalyzed dehydration of biologically-derived fatty alcohols." Green Chemistry 23, no. 12 (2021): 4338–54. http://dx.doi.org/10.1039/d1gc00243k.

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15

Nobbs, James D., Atanas K. Tomov, Craig T. Young, Andrew J. P. White, and George J. P. Britovsek. "From alternating to selective distributions in chromium-catalysed ethylene oligomerisation with asymmetric BIMA ligands." Catalysis Science & Technology 8, no. 5 (2018): 1314–21. http://dx.doi.org/10.1039/c7cy01896g.

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The oligomerisation of ethylene with chromium-based catalysts containing asymmetric BIMA (bis(benzimidazole)methylamine) ligands produces linear alpha olefins (LAOs) that follow an alternating distribution.

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16

Chatterjee, Anamitra, Sondre H. Hopen Eliasson, Karl W. Törnroos, and Vidar R. Jensen. "Palladium Precatalysts for Decarbonylative Dehydration of Fatty Acids to Linear Alpha Olefins." ACS Catalysis 6, no. 11 (2016): 7784–89. http://dx.doi.org/10.1021/acscatal.6b02460.

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17

Kuhlmann, S., P. Wasserscheid, K. Blann, J. T. Dixon, and D. H. Morgan. "Tri- and Tetramerisation of Ethylene: On-purpose Routes to Linear Alpha Olefins." Chemie Ingenieur Technik 78, no. 9 (2006): 1266. http://dx.doi.org/10.1002/cite.200650025.

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18

van der Klis, Frits, Jérôme Le Nôtre, Rolf Blaauw, Jacco van Haveren, and Daan S. van Es. "Renewable linear alpha olefins by selective ethenolysis of decarboxylated unsaturated fatty acids." European Journal of Lipid Science and Technology 114, no. 8 (2012): 911–18. http://dx.doi.org/10.1002/ejlt.201200024.

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19

Philippoff, W., and E. G. M. Tornqvist. "Rheo-optical behavior of isotactic and linear atactic poly-alpha-olefins in solution." Journal of Polymer Science Part C: Polymer Symposia 23, no. 2 (2007): 881–89. http://dx.doi.org/10.1002/polc.5070230243.

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20

Eliasson, Sondre, Anamitra Chatterjee, Giovanni Occhipinti, and Vidar Jensen. "The Mechanism of Rh-Catalyzed Transformation of Fatty Acids to Linear Alpha olefins." Inorganics 5, no. 4 (2017): 87. http://dx.doi.org/10.3390/inorganics5040087.

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21

Gatiyatullina, L. Ya, M. D. Sayakhov, and Z. G. Latypova. "Photocolorimetric determination of zirconium microcontent in the products of linear alpha-olefins production." Industrial laboratory. Diagnostics of materials 84, no. 6 (2018): 18–22. http://dx.doi.org/10.26896/1028-6861-2018-84-6-18-22.

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Analytical control of the technological process of linear alpha-olefins (LAO) production using a zirconium carboxylate based catalyst according to α-SABLIN technology calls for determination of the residual zirconium in the solvent when washing equipment, in the reaction products and wastewater, the purity of which is strictly regulated. Features of photocolorimetric determination of zirconium impurities with different complexing agents are considered and sensitivity of the determination with iron, aluminum, nickel and chromium present is estimated by comparing the values of the «sensitivity index» (by E. Sendel) and «specific absorption» (by Z. Marchenko). The reaction of complex formation with arsenazo III in 9 – 10 M HCl is used for determination of zirconium in the LAO production related products. The resulting colored complex exhibits the maximum light absorption at a wavelength of 670 nm. The measured content ranges from 0.100 to 100 mg/kg, 103-fold amounts of Ni2+, Fe3+, Al3+ and 400-fold amounts of Cr3+ do not interfere with the determination. The method of additives is used to eliminate the interfering effect of the acidity of the medium. It is shown that the developed technique provides a satisfactory level of the reproducibility and correctness of the results for analytical control of LAO production.

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22

Tembe, Gopal L., and Marayil Ravindranathan. "Oligomerization of ethylene to linear .alpha.-olefins by a titanium aryl oxide-alkylaluminum catalyst." Industrial & Engineering Chemistry Research 30, no. 10 (1991): 2247–52. http://dx.doi.org/10.1021/ie00058a002.

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23

Liu, Yiyang, Kelly E. Kim, Myles B. Herbert, Alexey Fedorov, Robert H. Grubbs, and Brian M. Stoltz. "Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins." Advanced Synthesis & Catalysis 356, no. 1 (2014): 130–36. http://dx.doi.org/10.1002/adsc.201301109.

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24

Golub, F. S., V. A. Bolotov, and V. N. Parmon. "Modern trends in the processing of linear alpha olefins to technologically important products. Part 1." Kataliz v promyshlennosti 20, no. 6 (2020): 433–55. http://dx.doi.org/10.18412/1816-0387-2020-6-433-455.

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Linear alpha olefins (LAO) form a class of chemical compounds that are used in the production of highly marketable products, such as plasticizers, synthetic lubricants, surfactants and (co)polymers with the improved operating characteristics. Since the annual world consumption of LAO derivatives is growing, specialists from research institutes, universities and industrial laboratories become involved in LAO processing. The analysis of scientific literature published in recent ten years revealed the absence of general reviews devoted to LAO processing. This review considers modern trends in the processing of LAO, which contain four and more carbon atoms, to technologically important derivatives. General information on the main products obtained by LAO processing, methods of their production and application fields is reported. The existing technological processes used to obtain LAO derivatives as well as the catalysts employed in the processes are briefly described. The review presents modern trends in LAO processing and promising ways for enhancing the available technologies, particularly the development of new types of catalysts. Authors of the review make no pretence to a comprehensive or detailed presentation of the material; the main aim was to give a general idea of the main directions in LAO processing, the catalysts used in such processes, and the advanced approaches to their improvement.

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25

Vaganov, R. A., N. V. Deryagina, and F. A. Buryukin. "Extraction Octene-1 and Decene-1 from C8+ Fraction by Production of Linear Alpha- Olefins." Journal of Siberian Federal University. Chemistry 8, no. 3 (2015): 327–35. http://dx.doi.org/10.17516/1998-2836-2015-8-3-327-335.

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26

Wang, Dong, Sikander H. Hakim, David Martin Alonso, and James A. Dumesic. "A highly selective route to linear alpha olefins from biomass-derived lactones and unsaturated acids." Chemical Communications 49, no. 63 (2013): 7040. http://dx.doi.org/10.1039/c3cc43587c.

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27

Chen, Qianqian, Danfeng Wang, Yu Gu, et al. "Techno-economic evaluation of CO2-rich natural gas dry reforming for linear alpha olefins production." Energy Conversion and Management 205 (February 2020): 112348. http://dx.doi.org/10.1016/j.enconman.2019.112348.

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28

Golub’, F. S., V. A. Bolotov, and V. N. Parmon. "Modern Trends in the Processing of Linear Alpha Olefins into Technologically Important Products: Part I." Catalysis in Industry 13, no. 2 (2021): 168–86. http://dx.doi.org/10.1134/s2070050421020069.

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29

Bekmukhamedov, Giyjaz E., Aleksandr V. Sukhov, Aidar M. Kuchkaev, et al. "Electrochemical Synthesis of Zirconium Pre-Catalysts for Homogeneous Ethylene Oligomerization." Catalysts 9, no. 12 (2019): 1059. http://dx.doi.org/10.3390/catal9121059.

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The catalytic activity of electrochemically synthesized zirconium carboxylates was studied in the process of ethylene oligomerization. Zirconium carboxylates were electrochemically synthesized directly from metallic zirconium and corresponding carboxylic acids (acetic, octanoic and lauric). A comprehensive study (element analysis, nuclear magnetic resonance (NMR) and infrared (IR) spectroscopy, powder X-ray diffraction (PXRD)) of the synthesized zirconium carboxylates showed that these species contain bidentate carboxylate moieties. It was shown that obtained zirconium carboxylates, in combination with Et3Al2Cl3 (Al/Zr = 20), have a moderate activity of (7.6–9.9) × 103 molC2H4⋅molZr−1⋅h−1 in terms of ethylene oligomerization (at T = 80 °C, p = 20 bar), leading to even-numbered C4–C10 linear alpha-olefins.

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30

Liu, Yiyang, Kelly E. Kim, Myles B. Herbert, Alexey Fedorov, Robert H. Grubbs, and Brian M. Stoltz. "ChemInform Abstract: Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins." ChemInform 45, no. 31 (2014): no. http://dx.doi.org/10.1002/chin.201431049.

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31

Guo, Lisheng, Yu Cui, Hangjie Li, et al. "Selective formation of linear-alpha olefins (LAOs) by CO2 hydrogenation over bimetallic Fe/Co-Y catalyst." Catalysis Communications 130 (October 2019): 105759. http://dx.doi.org/10.1016/j.catcom.2019.105759.

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32

Kissin, Y. V. "Co-oligomerization of ethylene and higher linear alpha olefins. I. Co-oligomerization with the sulfonated nickel ylide-based catalytic system." Journal of Polymer Science Part A: Polymer Chemistry 27, no. 2 (1989): 605–21. http://dx.doi.org/10.1002/pola.1989.080270220.

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33

AL-JARALLAH, A. M., J. A. ANABTAWI, M. A. B. SIDDIQUI, A. M. AITANI, and A. W. AL-SA'DOUN. "ChemInform Abstract: Ethylene Dimerization and Oligomerization to 1-Butene and Linear . alpha.-Olefins. A Review of Catalytic Systems and Processes." ChemInform 23, no. 39 (2010): no. http://dx.doi.org/10.1002/chin.199239323.

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34

Park, Ji Chan, Sanha Jang, Geun Bae Rhim, et al. "A durable nanocatalyst of potassium-doped iron-carbide/alumina for significant production of linear alpha olefins via Fischer-Tropsch synthesis." Applied Catalysis A: General 564 (August 2018): 190–98. http://dx.doi.org/10.1016/j.apcata.2018.07.037.

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35

Favis, D. V. "The inverse gaussian density function as applied to the ziegler-natta catalysis in the oligomerization of ethylene to linear alpha-olefins." Canadian Journal of Chemical Engineering 66, no. 5 (1988): 792–801. http://dx.doi.org/10.1002/cjce.5450660513.

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36

Vallada, Douglas Da Silva, Carlos Alberto Mendes Moraes, and Paulo Ricardo Santos da Silva. "Thermal pyrolysis of LDPE and LLDPE films in post-consumer packaging." Revista Eletrônica em Gestão, Educação e Tecnologia Ambiental 24 (December 4, 2020): e23. http://dx.doi.org/10.5902/2236117062698.

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Thermoplastics are increasingly present in the daily life of society in the most varied applications. Among the thermoplastics, polyethylene is the one that presents the higher volume of worldwide production and consumption. However, a large part of its applications are for products with a short shelf life, especially the food packaging sector. This way, they become expressive constituents in the composition of urban solid waste, leading to large quantities often being deposited in landfills. Pyrolysis appears as a technology for recycling plastic waste, allowing the recovery of the monomers that originated it. Through this thermochemical process, the waste is converted into three different products: oil or, in some cases wax, non-condensable gases, and a solid fraction named char. Thus, the goal of this study is to contribute for the development of pyrolysis as a technology for the final treatment of low-density polyethylene (LDPE) and linear low-density polyethylene (LLDPE) waste from post-consumer packaging, through the analysis of the influence of the pyrolysis temperature in the chemical composition of the oil produced, as well as the discussion of possible applications. For this purpose, the waste was initially characterized through analyses of attenuated total reflectance Fourier-transform infrared spectroscopy (ATR-FTIR), thermogravimetry (TGA), differential scanning calorimetry (DSC), and X-ray fluorescence (XRF). The characterization experiments showed that the plastic waste is constituted of 4.07% ash, 0.52% fixed carbon, and 95.54% volatile matter, showing its great potential to produce pyrolytic oil. Thermal degradation of the waste initiated at around 410°C and continued through about 530°C, with maximum rate of thermal degradation at about 488°C. The pyrolysis process was carried out with 50g samples of post-consumer LDPE and LLDPE, previously agglutinated, with particle size ranging from 0.001mm to 4mm, in a horizontal quartz reactor, with an inert atmosphere of N2, heating rate of 10°C/min, and residence time of 30 minutes. The experiments were conducted with experimental temperatures of 500°C and 700°C, in order to verify the influence of the temperature in the chemical composition of the oil obtained in the process. The analysis of the oil collected at 500°C by infrared spectroscopy revealed a specter similar to the one of commercial diesel. Through gas chromatography coupled with mass spectrometry, it was verified a composition constituted mostly by olefins (44%), from 8 to 35 carbon atoms, followed by paraffins (23.8%), and cycloparaffins (10%). There was also a considerable percentage of alpha-olefins, important for the petrochemical industry, and a percentage of aromatic compounds on a trace level. By varying the temperature to 700°C, an increase in the level of aromatic compounds to 16.6% occurred, accompanied by a decrease in the percentage of olefins, paraffins, and cycloparaffins. The oils obtained in both temperatures have potential for application in steam cracking or conventional catalytic cracking processes to obtain the raw materials of the petrochemical industry.

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37

"Shell considers US linear alpha-olefin expansion." Focus on Surfactants 2013, no. 5 (2013): 2. http://dx.doi.org/10.1016/s1351-4210(13)70093-3.

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38

"5554777 Catalyst for the preparation of linear carbon monoxide/alpha-olefin copolymers." Journal of Molecular Catalysis A: Chemical 120, no. 1-3 (1997): 296. http://dx.doi.org/10.1016/s1381-1169(97)80089-1.

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39

"5565547 Catalyst for the preparation of linear carbon monoxide/alpha-olefin copolymers." Journal of Molecular Catalysis A: Chemical 124, no. 2-3 (1997): 177–78. http://dx.doi.org/10.1016/s1381-1169(97)80230-0.

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40

Lee, Jin Hee, Hack-Keun Lee, Kwangsoo Kim, et al. "Unravelling the K-promotion effect in a highly active and stable Fe5C2 nanoparticle for catalytic linear alpha-olefin production." Materials Advances, 2021. http://dx.doi.org/10.1039/d0ma00920b.

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C5−C13 linear alpha() olefins (LAOs) are high-value-added chemicals acknowledged by industry. However, using catalysts to elevate the activity and selectivity of LAOs remains a major challenge for Fischer–Tropsch synthesis (FTS)....

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41

"Linear alpha-olefins." Focus on Surfactants 2003, no. 5 (2003): 2. http://dx.doi.org/10.1016/s1351-4210(03)00505-5.

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42

"Linear alkylbenzene/alpha-olefins." Focus on Surfactants 2015, no. 6 (2015): 2. http://dx.doi.org/10.1016/j.fos.2015.06.002.

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43

"Linear alpha olefins patent for IPCL." Focus on Surfactants 2002, no. 3 (2002): 3. http://dx.doi.org/10.1016/s1351-4210(02)80075-0.

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44

"Spolana closes linear alpha-olefins unit." Focus on Surfactants 2003, no. 9 (2003): 2. http://dx.doi.org/10.1016/s1351-4210(03)00906-5.

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45

"Global linear alpha-olefins market 2019–2024." Focus on Surfactants 2019, no. 4 (2019): 2. http://dx.doi.org/10.1016/j.fos.2019.05.003.

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46

"Profile of linear alpha-olefins in the US." Focus on Surfactants 2005, no. 4 (2005): 2. http://dx.doi.org/10.1016/s1351-4210(05)70695-8.

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47

"SABIC and Linde announce successful commercialization of linear alpha-olefins." Focus on Surfactants 2010, no. 1 (2010): 2. http://dx.doi.org/10.1016/s1351-4210(10)70002-0.

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48

"First application of a new process for producing linear alpha-olefins." Focus on Surfactants 2005, no. 4 (2005): 2. http://dx.doi.org/10.1016/s1351-4210(05)70694-6.

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49

"Idemitsu, Mitsui plan US linear alpha-olefins complex and sign agreement with Dow." Focus on Surfactants 2013, no. 6 (2013): 2. http://dx.doi.org/10.1016/s1351-4210(13)70123-9.

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50

Bawareth, Bander. "Membranes Separation of 2-Ethyl Hexyl Amine/1-Decene." Jurnal Teknologi 69, no. 9 (2014). http://dx.doi.org/10.11113/jt.v69.3392.

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1-Decene is a valuable product in linear alpha olefins plants that is contaminated with 2-EHA (2-ethyl hexyl amine). Using organic solvent nanofiltration membranes for this separation is quite challengeable. A membrane has to be a chemically stable in this environment with reasonable and stable separation factor. This paper shows that Teflon AF 2400 and cellulose acetate produced interesting results in 1-decene/2-EHA separation. The separation factor of Teflon AF 2400 is 3 with a stable permeance of 1.1x10-2 L/(m2·h·bar). Likewise, cellulose acetate gave 2-EHA/1-decene separation factor of 2 with a lower permeance of 3.67x10-3 L/(m2·h·bar). A series of hydrophilic membranes were tested but they did not give any separation due to high degree of swelling of 2-EHA with these polymers. The large swelling causes the membrane to lose its diffusivity selectivity because of an increase in the polymer's chain mobility.

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