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Dissertations / Theses on the topic 'Liquid-liquid extraction'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Lee, Jonathan George Malcolm. "Liquid-liquid extraction in centrifugal fields." Thesis, University of Newcastle Upon Tyne, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.336273.

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2

Hindocha, Ravinder K. "Liquid-liquid extraction with long wavelength fluorescence detection." Thesis, Loughborough University, 1994. https://dspace.lboro.ac.uk/2134/31792.

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Long wavelength fluorophores, methylene blue, Rhodamine 800, 3,3'diethyloxacarbocyanine iodide (DODC) and 1, 1',3,3,3' ,3' -hexamethylindotricarbocyanine perchlorate (HIDTCP) were investigated as probes to quantify drugs after liquid-liquid extraction. Fluorescence measurements in the long wavelength region (550-1000nm) are a recent development in photoluminescence spectroscopy and offer many advantages compared with conventional measurements which are made in the ultraviolet and visible spectral regions. These include, reduced background fluorescence in the presence of biological materials; r

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3

Brodkorb, M. "Multicomponent and contamination effects in liquid-liquid extraction." Thesis, University of Bradford, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.504892.

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4

Jildeh, Hanin [Verfasser]. "Liquid-Liquid Extraction Columns: Parameter Estimation / Hanin Jildeh." München : Verlag Dr. Hut, 2015. http://d-nb.info/107976903X/34.

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5

Solanki, A. S. "Homogeneous liquid-liquid extraction using consolute point systems." Thesis, University of Bradford, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.384269.

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6

Atalla, Abdo Mena. "Study of the liquid-liquid extraction of gallium." Thesis, University of Hertfordshire, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.315652.

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7

Schuur, Boelo. "Enantioselective liquid-liquid extraction in centrifugal contactor separators." [S.l. : [Groningen : s.n.] ; University Library Groningen] [Host], 2008. http://irs.ub.rug.nl/ppn/.

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8

Zgonnik, Viacheslav. "Elle & il : enantioselective liquid-liquid extraction and ionic liquids." Toulouse 3, 2011. http://thesesups.ups-tlse.fr/1297/.

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L'extraction liquide-liquide énantiosélective (ELLE) consiste en l'extraction d'un énantiomère à partir d'un mélange racémique par transfert entre deux phases liquides. Cette technologie est très prometteuse pour l'obtention des composés énantiopurs et devient l'objet d'une forte attention les dernières années grâce au développement de l'équipement approprié qui permet de réduire le temps et le prix de la séparation des énantiomères. L'objectif essentiel pour l'introduction d'ELLE dans le monde industriel est la découverte d'hôtes chiraux fiables, peu chers, durables, sélectifs et applicables

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9

Holbach, Marcus Alexander [Verfasser]. "Enantioselective Liquid-Liquid Extraction in Process Intensified Extraction Columns / Marcus Alexander Holbach." München : Verlag Dr. Hut, 2015. http://d-nb.info/1079768823/34.

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10

Hewitson, Peter. "Intermittent counter-current extraction : a new continuous dynamic liquid-liquid extraction methodology." Thesis, Brunel University, 2014. http://bura.brunel.ac.uk/handle/2438/13900.

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For the pharmaceutical industry, the manufacture of high value pharmaceuticals from natural products, chemical synthetic routes or fermentation processes all require intensive downstream processing steps to produce a pure final product. A small footprint liquid-liquid processing method would help to reduce the capital cost and process development time of this downstream processing. In this thesis, it is hypothesised that continuous liquid-liquid extraction can be achieved using a standard hydrodynamic counter-current chromatography (CCC) instrument by switching the flow of the liquid phases be

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11

Kuhn, Jay C. "Experimental design for the study of extraction efficiencies of the continuous liquid-liquid extractor." Master's thesis, This resource online, 1991. http://scholar.lib.vt.edu/theses/available/etd-01202010-020253/.

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12

Otu, Emmanuel Ogbonna. "Liquid-liquid extraction studies of the rare earth elements." Thesis, University of Ottawa (Canada), 1990. http://hdl.handle.net/10393/5804.

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This thesis is directed towards the study of the solvent extraction behaviour of the lanthanides and aluminium, bismuth, calcium and zinc whose radii and/or charges are similar to those of the REE. A brief review of the fundamentals and classification of extraction systems and of extractants is presented in Chapter 1. Chapters 2 and 3 are reviews of the properties and uses of the lanthanides and solvent extraction using phosphonate and sulphonate extractants, respectively. Chapter 4 deals with experimental procedures, results, discussions and conclusions. The extraction of zinc (II), calcium (

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13

Barker, Michael H. "Electrochemistry at liquid/liquid interfaces for metal ion extraction." Thesis, University of Liverpool, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.367192.

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The aim of this project was to produce a selective extraction system for the separation of precious metal ions from waste electrolyte streams utilising liquid/liquid electrochemical techniques. During the course of this project the work partitioned into three different aspects of charge transfer: electron transfer, ion transfer and membrane studies. Some fundamental physicochemical properties of liquid/liquid systems were explored. For electron transfer reactions the dependence of the rate of electron transfer on supporting electrolyte concentration in the organic phase for the water/1,2-DCE i

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14

Mohd-Setapar, Siti H. "Reverse micelle liquid-liquid extraction of a pharmaceutical product." Thesis, Loughborough University, 2008. https://dspace.lboro.ac.uk/2134/36143.

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Reverse micelle extraction has received considerable attention in recent years due to its ability to selectively solubilise solutes from an aqueous phase, and in the case of biomolecules to maintain their biological activities, This thesis reports the results from studies on the extraction of penicillin G from aqueous solution (forward extraction) and from the reverse micelle to a new aqueous solution (backward extraction), The extraction is influenced by the initial penicillin G concentration, the salt type and concentration in the aqueous phase, pH, and surfactant concentration. The results

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15

Tucker, Kate Louise. "Heavy metal extraction using advanced liquid-liquid style partitioning systems." Thesis, University of Manchester, 2015. https://www.research.manchester.ac.uk/portal/en/theses/heavy-metal-extraction-using-advanced-liquid--liquid-style-partitioning-systems(6a238cb4-94cf-4fa8-bffe-d1a1b70adaa6).html.

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Understanding the behaviour of heavy metals involved in the nuclear fuel cycle is of paramount importance to the reprocessing and storage of spent nuclear fuel. These studies have attempted to obtain a greater understanding of the fundamental chemistry of these systems, by investigating extraction performance and speciation in current (PUREX) and proposed (GANEX) extraction processes. Various complexes have been shown to exist in the post-extracted organic fraction of the systems analysed. For Zr(IV), U(VI) and Np(VI) separated from aqueous nitric and hydrochloric using TBP, the complexes [Zr(

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16

Pinheiro, Regiane Silva. "Study of liquid-liquid extraction for methyl biodiesel purification process." Universidade Federal do CearÃ, 2013. http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=14103.

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CoordenaÃÃo de AperfeÃoamento de Pessoal de NÃvel Superior<br>In the process of purification of biodiesel is of extreme importance washing methyl or ethyl ester rich- phase, since in conventional processes there is a great amount of water. During the washing is extracted primarily excess alcohol. Composition data for the washing process of biodiesel is still scarce in the literature and the study of liquid-liquid equilibrium provides the means to develop equipment and to optimize the extraction processes. Thus the main goal of this work is to determine equilibrium data for three different tern

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17

Desouky, Osman Abd El-Naby. "Liquid-liquid extraction of rare earth elements from sulfuric acid." Thesis, University of Leeds, 2006. http://etheses.whiterose.ac.uk/638/.

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This thesis is concerned with the liquid-liquid extraction and separation of Y, Ce, La, binary mixtures, and ternary mixtures as well as synthesis of novel amide ligands for the extraction of rare earth elements. Chapter I is the general introduction of the practical process and applications of solvent extraction and its theory. It describes systems involving compound formation, ion-association and solvation as well as solvent loading capacity, dispersion and coalescence. The aims of this thesis are also presented. Chapter 2 presents an introduction to yttrium chemistry and recent developments

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18

Hanif, Mohammed. "Mass transfer studies in solvent extraction." Thesis, Teesside University, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.328022.

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19

Zaidi, Muthana Getan Mohammed. "Methodology of synthesis and selection of solvents for liquid-liquid extraction." Thesis, University of Manchester, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.333314.

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20

Oloidi, Jimmy O. "A study of liquid-liquid extraction in a sieve plate column." Thesis, Aston University, 1987. http://publications.aston.ac.uk/10226/.

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The literature relating to sieve plate liquid extraction columns and relevant hydrodynamic phenomena have been surveyed. Mass transfer characteristics during drop formation, rise and coalescence, and related models were also reviewed. Important design parameters i.e. flooding, dispersed phase hold-up, drop size distribution, mean drop size, coalescence/flocculation zone height beneath a plate and jetting phenomena were investigated under non-mass transfer and mass transfer conditions in a 0.45m diameter, 2.3m high sieve plate column. This column had provision for four different plate designs,

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21

Boey, Sek Chew. "Citric acid extraction by liquid membranes." Thesis, Imperial College London, 1989. http://hdl.handle.net/10044/1/47363.

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22

Wächtler, Timo [Verfasser]. "Numerical Simulation of Turbulent Dispersions in Liquid-Liquid Extraction Columns / Timo Wächtler." München : Verlag Dr. Hut, 2014. http://d-nb.info/1055863168/34.

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23

Tizvar, Roza. "Investigation of liquid-liquid extraction process for separation of glycerol and biodiesel." Thesis, University of Ottawa (Canada), 2007. http://hdl.handle.net/10393/27490.

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Biodiesel is a sustainable and environmentally friendly source of energy which is now being used as an alternative for fossil fuels worldwide. Glycerol is the main by-product of biodiesel produced via transesterification and must be removed from biodiesel according to the ASTM Standard D-6751-02. This purification has usually been carried out with liquid-liquid extraction with water as a solvent for glycerol. In commonly-used alkali-catalyzed transesterification of waste cooking oil, the use of large quantities of water alone, as extraction solvent, results in formation of soaps, then emulsion

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24

Watts, Frank. "The effect of electrical potential on mass transfer in liquid-liquid extraction." Diss., Georgia Institute of Technology, 1990. http://hdl.handle.net/1853/10283.

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25

Göklen, Kent Emir. "Liquid-liquid extraction of biopolymers : selective solubilization of proteins in reverse micelles." Thesis, Massachusetts Institute of Technology, 1986. http://hdl.handle.net/1721.1/15103.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemical Engineering, 1986.<br>MICROFICHE COPY AVAILABLE IN ARCHIVES AND SCIENCE.<br>Bibliography: leaves 297-308.<br>by Kent Emir Göklen.<br>Ph.D.

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26

Wächtler, Timo Frederik [Verfasser]. "Numerical Simulation of Turbulent Dispersions in Liquid-Liquid Extraction Columns / Timo Wächtler." München : Verlag Dr. Hut, 2014. http://d-nb.info/1055863168/34.

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27

Slaymaker, Elizabeth Ann. "Effects of surface active agents on drop size in liquid-liquid systems." Thesis, Georgia Institute of Technology, 1985. http://hdl.handle.net/1853/10260.

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28

Kanel, Jeffrey Scott. "Effects of some interfacial phenomena on mass transfer in agitated liquid-liquid dispersions." Diss., Georgia Institute of Technology, 1990. http://hdl.handle.net/1853/11257.

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29

Bahmanyar, Hossein. "Drop breakage and mass transfer phenomena in a rotating disc contactor." Thesis, University of Bradford, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.253321.

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30

Luechau, Frank. "Process considerations for the recovery of bio-nanoparticulates in polymer-salt aqueous two-phase systems." Thesis, University of Birmingham, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.289385.

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31

Dowling, Irena C. "Rate of cobalt extraction by D2EHPA from aqueous forming drops : cobalt extraction from aqueous forming drops by di-2-ethylhexylphosphoric acid is studied by flow injection analysis and a computer program is used to calculate mass transfer coefficients. F." Thesis, University of Bradford, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.236490.

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A study of the extraction of cobalt II ions from an aqueous growing drop into a continuous medium of di-2-ethylhexylphosphoric acid (D2EHPA) is made. The apparatus for this technique is described and a flow injection analysis method for measuring the cobalt remaining in the aqueous phase has been developed. In this study the feed concentration of cobalt has varied between 8.48 x 10-3 and 16.97 x 10-3 mole 9-1. The D2EHPA held in n-heptane, has been altered between 0.143 and 2.41 mole P. Also, pH has been adjusted between 3.10 and 4.44. The principal temperature applied to this study was 25 ±0.

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32

Savastano, Cesar Alberto. "Interfacial phenomena and rate processes in the extraction of nickel by mixed reagents." Thesis, Imperial College London, 1988. http://hdl.handle.net/10044/1/47247.

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33

Hussain, A. A. "The behaviour of single drops in pulsed perforated plate liquid-liquid extraction columns." Thesis, University of Bradford, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.373226.

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34

Saeed, Muhammad Tariq. "Application of kinetic models to the design of liquid-liquid extraction spray columns." Thesis, Imperial College London, 1989. http://hdl.handle.net/10044/1/47638.

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35

Chen, Fu-Yih Jeffrey. "Characterization of the liquid-liquid interface and its influence on metal extraction processes." Diss., The University of Arizona, 1994. http://hdl.handle.net/10150/186977.

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8-Mercaptoquinoline (QSH) exhibited substantial interfacial activity in its neutral form. The interfacial activity of QSH may stem from its zwitterionic form QH⁺S⁻. The interfacial activities of Ni-HPMBP system are in the order Ni(PMBP)₂ > PMBP⁻ > HPMBP. The interfacial rate constant of formation reaction is 4 times greater than the bulk value. The bulk and interfacial rate constants for dissociation reaction of Ni(PMBP)₂ are essentially the same. The centrifugal partition chromatography (CPC) inefficiency as measured by the quantity channel equivalent of a theoretical plate (CETP), reflects t

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36

Young, Christi Lynn Patton. "Solute separabilities in solvent gas-rich liquid-liquid-vapor systems topographical and molecular consideration /." Access abstract and link to full text, 1993. http://0-wwwlib.umi.com.library.utulsa.edu/dissertations/fullcit/9313535.

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37

Thompson, Peter G. "Liquid collection efficiencies after supercritical fluid extraction." Thesis, Virginia Tech, 1994. http://hdl.handle.net/10919/44469.

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The design of any supercritical fluid extraction (SFE) experiment should break down into two parts: 1) removal of the analytes of interest from the bulk matrix and 2) deposition of those analytes in a user friendly manner for further studies (spectroscopy or chromatography). While great attention has been paid to the extraction of analytes, less attention has been paid for their efficient collection after extraction. Currently solid phase trapping and liquid trapping are available for off-line collection of analytes after SFE. A polarity test mix consisting of acetophenone, <i>N,N</i>-dimethy

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38

Barakat, Salem Ahmad Salem. "Spectroscopic and flow-injection studies of some novel ion-pair reactions." Thesis, Queen's University Belfast, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.317545.

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39

Stoffers, Martin [Verfasser]. "Liquid-Liquid Extraction of n-Butanol from Aqueous Solutions Using Ionic Liquids / Martin Stoffers." München : Verlag Dr. Hut, 2014. http://d-nb.info/1055863524/34.

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40

Yang, Ningsheng. "Hydrodynamic and mass transfer characteristics of air-assisted multistage screen liquid-liquid extraction column." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp03/MQ31663.pdf.

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41

Bastani, Daryoush. "Liquid-liquid extraction column performance evaluation for two column diameters and two chemical systems." Thesis, University of Manchester, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.333252.

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42

Dietz, Mark L. "The role of the interface in the kinetics and mechanism of liquid-liquid extraction." Diss., The University of Arizona, 1989. http://hdl.handle.net/10150/184800.

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When solutions of various metal 8-quinolinolates or beta-diketonates in an organic solvent were contacted with an aqueous phase and vigorously stirred to generate a large interfacial area, a reversible decrease in the organic phase concentration of the complex was observed. The magnitude of this decrease varied with interfacial area, solvent, temperature, and the nature and concentration of the complex. Analysis of the phenomenon using the Langmuir isotherm showed that the concentration change may be explained by adsorption of significant quantities of the complexes at the increased liquid-liq

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43

Chamupathi, Virittamulla Gamage. "Role of the interface in metal solvent extraction kinetics." Diss., The University of Arizona, 1987. http://hdl.handle.net/10150/184256.

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Interfacially active reagents are utilized in metal solvent extraction processes and it is therefore important to understand the role of the liquid-liquid interface in the study of the kinetics and equilibria of extraction. The diffusion problems encountered in the traditional apparatus were overcome by using a high speed stirring apparatus. The microporous teflon membrane phase separator permitted more accurate measurements of interfacial areas, characterization of extraction kinetics of metal chelates, and a greater understanding of the phase separation mechanism. In contrast to the neutral

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44

Ashrafizadeh, Seyed Nezameddin. "Solvent extraction and liquid membrane separation of rhodium." Thesis, McGill University, 1996. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=37698.

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The aim of this work was to develop a viable solvent-extraction based system for the separation of rhodium (Rh) from aqueous chloride solutions. Ultimately, two different systems were developed. Kelex 100, a commercially available derivative of 8-hydroxyquinoline, was used as the extractant reagent in both of these systems. One of the systems involved the supported liquid membrane (SLM) extraction of Rh. In this system a very thin microporous "Gore-Tex" polymer sheet, impregnated with an organic solution of Kelex 100, served as the SLM. The other system involved the conversion of the chlorocom

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45

Tungkananuruk, Nipon. "Extraction ion-pair complexes using solid-liquid systems." Thesis, Queen's University Belfast, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.317121.

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46

McDaniel, Lori Heldreth. "Investigation of Liquid Trapping Following Supercritical Fluid Extraction." Diss., Virginia Tech, 1999. http://hdl.handle.net/10919/29121.

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Supercritical fluid extraction (SFE) is an alternative to traditional extractions with organic solvents. SFE consists of removing the analyte(s) from the matrix, solubilizing them, moving the analyte(s) into the bulk fluid, and sweeping the fluid containing the analyte(s) out of the extraction vessel. As the fluid leaves the extraction vessel, decompression of the fluid occurs, changing its volume and temperature which can lead to analyte loss. This work focussed on the trapping process with the restrictor immersed in a liquid after SFE. Experiments compared the effects of trapping paramete

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47

Nedungadi, Kishore. "On the performance of a liquid-liquid extraction column packed with Sulzer SMV static mixers /." [S.l.] : [s.n.], 1991. http://e-collection.ethbib.ethz.ch/show?type=diss&nr=9406.

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48

Attarakih, Menwer. "Solution methodologies for the population balance equations describing the hydrodynamics of liquid-liquid extraction contactors." [S.l. : s.n.], 2004. http://deposit.ddb.de/cgi-bin/dokserv?idn=971873631.

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49

Grundl, Gabriel [Verfasser], and Werner [Akademischer Betreuer] Kunz. "Influence of electrolytes on liquid-liquid equilibria for extraction processes / Gabriel Grundl ; Betreuer: Werner Kunz." Regensburg : Universitätsbibliothek Regensburg, 2021. http://d-nb.info/1228213178/34.

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50

Pursell, Mark Robert. "The effect of fermentation broth components and added compounds on mass transfer during liquid-liquid extraction." Thesis, Imperial College London, 2002. http://hdl.handle.net/10044/1/8501.

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