Relevant bibliographies by topics / Lithiation

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Academic literature on the topic 'Lithiation'

Author: Grafiati
Published: 4 June 2021
Last updated: 10 March 2023

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Journal articles on the topic "Lithiation"

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Bar, Sukanta, and Maxwell Israel Martin. "Regioselective Synthesis of 4-Bromo-3-formyl-N-phenyl-5-propylthiophene-2-carboxamide." Molbank 2021, no. 4 (2021): M1296. http://dx.doi.org/10.3390/m1296.

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We synthesized 4-bromo-3-formyl-N-phenyl-5-propylthiophene-2-carboxamide by using three successive direct lithiations and a bromination reaction starting from thiophene. All these lithiation reactions were carried out at −78 °C to RT over a period of 1 to 24 h based on the reactivity of electrophile. This is a four-step protocol starting from thiophene with an overall yield of 47%.
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Lee, Hyun-Jeong, Hong-Kyu Kim, Young-Woon Byeon, and Jae-Pyoung Ahn. "Elucidating in-Situ Lithiation Pathway of Si-C Composite Anode in Lithium Ion Battery." ECS Meeting Abstracts MA2022-01, no. 55 (2022): 2251. http://dx.doi.org/10.1149/ma2022-01552251mtgabs.

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Lithiation kinetics of a Si-C composite anode for high-capacity lithium-ion batteries were investigated through in-situ lithiation with electrochemical C-V measurements using a focused ion beam. Here, we found in the lithiation procedure that Li migrates sequentially into carbon (C), nanopores, and silicon (Si) in the Si-C composite. In the first lithiation step, Li was intercalated inside C particles while spreading over the surface of the C particles. The second lithiation process occurred through the filling of nanopores existing between electrode particles that consisted of the Si-C compos
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Lee, Seung-Eun, Hyung-Kyu Lim, and Sangheon Lee. "Ab Initio-Based Structural and Thermodynamic Aspects of the Electrochemical Lithiation of Silicon Nanoparticles." Catalysts 10, no. 1 (2019): 8. http://dx.doi.org/10.3390/catal10010008.

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We reported the theoretical understandings of the detailed structural and thermodynamic mechanism of the actual lithiation process of silicon nanoparticle systems based on atomistic simulation approaches. We found that the rearrangement of the Si bonding network is the key mechanism of the lithiation process, and that it is less frequently broken by lithiation in the smaller sizes of Si nanoparticles. The decreased lithiation ability of the Si nanoparticles results in the lithiation potential being significantly lower than that of crystalline silicon phases, which impedes the full usage of the
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Zheng, Jim P., Petru Andrei, Liming Jin, Junsheng Zheng, and Cunman Zhang. "Pre-Lithiation Strategies and Energy Density Theory of Lithium-Ion and Beyond Lithium-Ion Batteries." Journal of The Electrochemical Society 169, no. 4 (2022): 040532. http://dx.doi.org/10.1149/1945-7111/ac6540.

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Pre-lithiation is the most effective method to overcome the initial capacity loss of high-capacity electrodes and has the potential to be used in beyond-conventional lithium-ion batteries. In this article we focus on two types of pre-lithiation: the first type can be applied to batteries in which the cathode has been fully lithiated but the anode has a large initial capacity loss, such as batteries made with lithium metal oxide cathode and silicon-carbon anode. The second type can be applied to batteries in which both electrodes are initially lithium-free and suffer a loss of lithium during th
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Zhang, Kai, Erwin Hüger, Yong Li, Harald Schmidt, and Fuqian Yang. "Invited: Review and Stress Analysis on the Lithiation Onset of Amorphous Silicon Films." Batteries 9, no. 2 (2023): 105. http://dx.doi.org/10.3390/batteries9020105.

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This work aims to review and understand the behavior of the electrochemical lithiation onset of amorphous silicon (a-Si) films as electrochemically active material for new generation lithium-ion batteries. The article includes (i) a review on the lithiation onset of silicon films and (ii) a mechanochemical model with numerical results on the depth-resolved mechanical stress during the lithiation onset of silicon films. Recent experimental studies have revealed that the electrochemical lithiation onset of a-Si films involves the formation of a Li-poor phase (Li0.3Si alloy) and the propagation o
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Smith, Keith, Gamal El-Hiti, and Mohammed Alshammari. "Unravelling Factors Affecting Directed Lithiation of Acylamino­aromatics." Synthesis 50, no. 18 (2018): 3634–52. http://dx.doi.org/10.1055/s-0036-1591954.

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Ureas, pivalamides, and carbamates are widely used as directing metalation groups (DMGs) due to their good directing ability, low cost, ease of access, and ease of removal. Lithiation of substituted benzenes having such directing metalation groups using various alkyllithiums in anhydrous solvent at low temperature provides the corresponding lithium intermediates, but lithiation may take place at various sites. Reactions of the lithium reagents obtained in situ with various electrophiles give the corresponding derivatives, typically substituted at the site(s) where initial lithiation occurred,
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Patel, Premji, and John A. Joule. "Lithiation of pyridones." Journal of the Chemical Society, Chemical Communications, no. 15 (1985): 1021. http://dx.doi.org/10.1039/c39850001021.

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Schönherr, Kay, Markus Pöthe, Benjamin Schumm, Holger Althues, Christoph Leyens, and Stefan Kaskel. "Tailored Pre-Lithiation Using Melt-Deposited Lithium Thin Films." Batteries 9, no. 1 (2023): 53. http://dx.doi.org/10.3390/batteries9010053.

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The user demands lithium-ion batteries in mobile applications, and electric vehicles request steady improvement in terms of capacity and cycle life. This study shows one way to compensate for capacity losses due to SEI formation during the first cycles. A fast and simple approach of electrolyte-free direct-contact pre-lithiation leads to targeted degrees of pre-lithiation for graphite electrodes. It uses tailor-made lithium thin films with 1–5 µm lithium films produced by lithium melt deposition as a lithium source. These pre-lithiated graphite electrodes show 6.5% capacity increase after the
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Guo, Z. P., Z. W. Zhao, H. K. Liu, and S. X. Dou. "Electrochemical lithiation and de-lithiation of MWNT–Sn/SnNi nanocomposites." Carbon 43, no. 7 (2005): 1392–99. http://dx.doi.org/10.1016/j.carbon.2005.01.008.

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Chen, W. "Electrochemical lithiation and de-lithiation of carbon nanotube-Sn2Sb nanocomposites." Electrochemistry Communications 4, no. 3 (2002): 260–65. http://dx.doi.org/10.1016/s1388-2481(02)00268-0.

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Dissertations / Theses on the topic "Lithiation"

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Hegazy, Amany Saber. "Directed lithiation of substituted benzylamines." Thesis, Cardiff University, 2009. http://orca.cf.ac.uk/54873/.

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CHAPTER SIX Chapter six describes a lithiation procedure that allows the production of 3-substituted isoindolin-l-ones in high yields in only one step via lithiation of various substituted N-benzyl-MN-dimethylureas with /-BuLi (3.3 mole equivalents) in THF at 0 °C followed by reactions with various electrophiles. The procedure has been proven to be simple, efficient and general.
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PERROTEY, ANNE. "Substitution nucleophile et lithiation d'arenetricarbonylchrome." Paris 6, 1996. http://www.theses.fr/1996PA066325.

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Dans la premiere partie de ce travail, nous avons etudie la regioselectivite de l'addition d'anions stabilises de nitriles ou d'esters sur le complexe de la benzophenone et de ses derives dans le but de synthetiser un precurseur du ketoprofene. Nous avons ensuite envisage une autre voie de synthese du ketoprofene: une substitution nucleophile ipso d'un atome d'halogene. Dans un premier temps, nous avons etudie la regioselectivite de la lithiation du complexe de la benzophenone protegee par un acetal (premiere etape avant l'halogenation). Dans la deuxieme partie, nous avons tente de lithier dia
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Lefranc, Julien. "Lithiation chemistry of vinyl ureas." Thesis, University of Manchester, 2011. https://www.research.manchester.ac.uk/portal/en/theses/lithiation-chemistry-of-vinyl-ureas(b559b2b8-744e-4dbe-87ee-4a5fef7d3443).html.

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The construction of tertiary alkylamines is a synthetic challenge exacerbated by the poor electrophilicity of imines. Due to the presence of this kind of building block in a large number of bioactive molecules, the development of new strategies to synthesise the quaternary carbon centre is essential. This thesis describes the work carried out on the rearrangement of lithiated vinyl ureas in order to form α-tertiary amines. The first part presents how vinyl ureas were synthesised, using the reaction between an imine and an aryl isocyanate. The development of one-pot process allows the synthesis
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Haxell, Thomas Francis Nelson. "Asymmetric lithiation-substitution of imidazolidines and pyrrolidines." Thesis, University of Exeter, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.249066.

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Li, Xiabing. "Synthesis of substituted tetrahydroisoquinolines using lithiation-substitution." Thesis, University of Sheffield, 2014. http://etheses.whiterose.ac.uk/6431/.

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Gilday, J. P. "Regiocontrol in the lithiation of tricarbonylarenechromium(0) complexes." Thesis, Imperial College London, 1986. http://hdl.handle.net/10044/1/38014.

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Barker, Graeme. "New lithiation methodologies to 2-substituted nitrogen heterocycles." Thesis, University of York, 2011. http://etheses.whiterose.ac.uk/1549/.

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This thesis describes the development of methodologies for lithiation-trapping and lithiation-arylation of N-Boc heterocycles in the position α to nitrogen as well as in situ infra-red spectroscopic monitoring of lithiation reactions and the application of lithiation-arylation in total synthesis. Chapter 2 details the use of in situ infra-red spectroscopy to monitor the lithiation of N-Boc pyrrolidine, N-Boc piperidine, N-Boc homopiperidine, an N-Boc acetal piperidine, N-Boc-Nʹ-benzyl piperazine, N-Boc-Nʹ-i-Pr imidazolidine and an O-alkyl carbamate in diethyl ether using s-BuLi and the diamine
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Zapico, Julian. "New approaches to the α-functionalisation of N-heterocycles." Thesis, University of Bristol, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.271831.

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Condon, Brian D. "Stereoselective bond formation via lithiation of asymmetric acyclic sulfides." Diss., Georgia Institute of Technology, 1989. http://hdl.handle.net/1853/29911.

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Herbert, Simon Anthony. "Oxazoline directed lithiation of Calix[4]arene and Ferrocene." Thesis, Stellenbosch : Stellenbosch University, 2011. http://hdl.handle.net/10019.1/17867.

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Thesis (PhD)--Stellenbosch University, 2011.<br>ENGLISH ABSTRACT: The use of chiral oxazoline directed lithiation provides a highly diastereoselective (up to >99% de) route to meta functionalised inherently chiral calixarenes. This methodology can be used on both the butylated and debutylated calixarene systems and is tolerant of a wide range of different electrophillic quenches allowing access to a structurally diverse range of inherently chiral metafunctionalised calixarenes. The oxazoline directing group can be removed via hydrolysis, generating a range of functionalised calixarene car
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Books on the topic "Lithiation"

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Lue, Ping. Some new strategies of direction, protection, and activation in lithiation chemistry. 1990.

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Book chapters on the topic "Lithiation"

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Kühne, Matthias. "Lithiation Studies." In Springer Theses. Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-030-02366-9_4.

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Leonori, Daniele, and Varinder K. Aggarwal. "Reagent-Controlled Lithiation–Borylation." In Synthesis and Application of Organoboron Compounds. Springer International Publishing, 2015. http://dx.doi.org/10.1007/978-3-319-13054-5_9.

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Fan, Feifei, and Ting Zhu. "Modeling of Lithiation in Silicon Electrodes." In Multiscale Materials Modeling for Nanomechanics. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-33480-6_16.

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Azzena, Ugo, and Luisa Pisano. "Reductive Lithiation and Multilithiated Compounds in Synthesis." In Lithium Compounds in Organic Synthesis. Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527667512.ch12.

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Semmelhack, Martin F., and Anatoly Chlenov. "(Arene)Cr(CO)3 Complexes: Arene Lithiation/Reaction with Electrophiles." In Topics in Organometallic Chemistry. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/b94490.

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Hoppe, Dieter, Felix Marr, and Markus Brüggemann. "Enantioselective Synthesis by Lithiation Adjacent to Oxygen and Electrophile Incorporation." In Organolithiums in Enantioselective Synthesis. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/3-540-36117-0_4.

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Beak, Peter, Timothy A. Johnson, Dwight D. Kim, and Sung H. Lim. "Enantioselective Synthesis by Lithiation Adjacent to Nitrogen and Electrophile Incorporation." In Organolithiums in Enantioselective Synthesis. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/3-540-36117-0_5.

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Hodgson, David M., Katsuhiko Tomooka, and Emmanuel Gras. "Enantioselective Synthesis by Lithiation Adjacent to Oxygen and Subsequent Rearrangement." In Organolithiums in Enantioselective Synthesis. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/3-540-36117-0_7.

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Clayden, Jonathan. "Enantioselective Synthesis by Lithiation to Generate Planar or Axial Chirality." In Organolithiums in Enantioselective Synthesis. Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/3-540-36117-0_8.

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Cosandey, F., J. F. Al-Sharab, F. Badway, and G. G. Amatucci. "HRTEM Imaging and EELS Spectroscopy of Lithiation Process in Fefx:C Nanocomposites." In Ceramic Transactions Series. John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9781118407189.ch12.

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Conference papers on the topic "Lithiation"

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Zheng, Zhuoyuan, Yanwen Xu, Bo Chen, and Pingfeng Wang. "Gaussian Process Based Crack Initiation Modeling for Design of Battery Anode Materials." In ASME 2019 International Design Engineering Technical Conferences and Computers and Information in Engineering Conference. American Society of Mechanical Engineers, 2019. http://dx.doi.org/10.1115/detc2019-97547.

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Abstract Silicon-based anode is one of the promising candidates for the next generation lithium ion batteries (LIBs) to achieve high power/energy density. However, the major drawback limiting the practical application of Si anode is that Si experiences significant volume change during its lithiation/de-lithiation cycles, which induces high stress and causes degradation and pulverization of the anode. This study focuses on the crack initiation performances of Si anode during the de-lithiation process. A multi-physics based finite element (FE) model is built to simulate the electrochemical proce
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Yus, Miguel, Rosario Torregrosa, and Isidro Pastor. "Isoprene-mediated lithiation of chiral N-alkylimidazoles." In The 11th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2007. http://dx.doi.org/10.3390/ecsoc-11-01302.

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Adams, Jacob N., Logan J. Ausderau, and George J. Nelson. "Structural Changes in Alloy Anodes for Li-Ion Batteries." In ASME 2018 12th International Conference on Energy Sustainability collocated with the ASME 2018 Power Conference and the ASME 2018 Nuclear Forum. American Society of Mechanical Engineers, 2018. http://dx.doi.org/10.1115/es2018-7539.

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Tin (Sn) alloy electrodes show great potential for advancing battery performance due to the high capacity of tin. To realize this potential, the volumetric expansion during the lithiation process must be mitigated. One means of mitigating volumetric expansion of tin is to alloy it with copper to create Cu6Sn5. Such alloy electrodes retain some of the high capacity of tin, while attempting to accommodate volumetric changes with the addition of the malleable copper. Lithiation and delithiation tests were conducted with the Cu6Sn5 pellet electrodes to produce microstructural changes at the electr
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Yus, M., J. Almena, E. Alonso, et al. "Functionalized Organolithium Compounds Through an Arene-Catalyzed Lithiation." In The 1st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 1997. http://dx.doi.org/10.3390/ecsoc-1-02003.

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Nadimpalli, Siva P. V., and Rajasekhar Tripuraneni. "Stress Response of Germanium Electrodes During Lithiation/Delithiation Cycling." In ASME 2015 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2015. http://dx.doi.org/10.1115/imece2015-50958.

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An in situ study of stress evolution of germanium as a lithium-ion battery electrode material is presented. Thin films of germanium are cycled in a half-cell configuration with lithium metal foil as counter/reference electrode, with 1M lithium hexafluorophosphate in ethylene carbonate, diethylene carbonate, dimethyl carbonate solution (1:1:1, wt. %) as electrolyte. Real-time stress evolution in the germanium thin-film electrodes during electrochemical lithiation and delithiation is measured by monitoring the substrate curvature using the multi-beam optical sensing method. Germanium thin film u
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Zheng, Zhuoyuan, Zheng Liu, Pingfeng Wang, and Yumeng Li. "Design of Three-Dimensional Bi-Continuous Silicon Based Electrode Materials for High Energy Density Batteries." In ASME 2022 International Design Engineering Technical Conferences and Computers and Information in Engineering Conference. American Society of Mechanical Engineers, 2022. http://dx.doi.org/10.1115/detc2022-89652.

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Abstract Silicon-based anode is a promising candidate for next generation lithium-ion batteries (LIBs) with improved energy and power density. However, the practical application of Si anode is hindered by their major reliability issue that Si experiences significant volume change during its lithiation/delithiation cycles, leading to high stress, degradation, and pulverization of the anode. With the development of advanced electrode fabrication technologies, structured Si anodes with delicately designed architectures have been proposed. This study focuses on five triply periodic minimal surface
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Liu, H. Y., C. H. Hu, and S. Q. Wu. "Ab initio study on the lithiation mechanism of Mg2Si electrode." In Environment (ICMREE). IEEE, 2011. http://dx.doi.org/10.1109/icmree.2011.5930901.

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Zheng, Zhuoyuan, Bo Chen, Yashraj Gurumukhi, et al. "Surrogate Model Assisted Design of Silicon Anode Considering Lithiation Induced Stresses." In 2019 IEEE International Reliability Physics Symposium (IRPS). IEEE, 2019. http://dx.doi.org/10.1109/irps.2019.8720601.

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Ashrit, Pandurang V. "Structure-dependent electrochromic behavior of WO3 thin films under dry lithiation." In SPIE's International Symposium on Optical Science, Engineering, and Instrumentation, edited by Carl M. Lampert and Claes-Goeran Granqvist. SPIE, 1999. http://dx.doi.org/10.1117/12.367567.

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Yus, Miguel, Abdeslam Abou, and Francisco Foubelo. "Chemoselective lithiation of 6-chloro-1-halohex-1-ynes with lithium/naphthalene." In The 10th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2006. http://dx.doi.org/10.3390/ecsoc-10-01400.

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