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1

PIETRZAK, TOMASZ K., IRENA GORZKOWSKA, JAN L. NOWIŃSKI, JERZY E. GARBARCZYK, and MAREK WASIUCIONEK. "PREPARATION OF TRIPHYLITE-LIKE GLASSES AND NANOMATERIALS IN THE LiFePO4-V2O5 SYSTEM AND STUDY ON THEIR ELECTRICAL CONDUCTIVITY." Functional Materials Letters 04, no. 02 (2011): 143–45. http://dx.doi.org/10.1142/s1793604711001750.

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Research on lithium iron phosphates is stimulated by their application as cathodes in Li -ion rechargeable batteries. The aim of this study was to enhance its initially poor electronic conductivity. A thermal nanocrystallization is applied to lithium-iron-phosphate and lithium-vanadium-iron-phosphates materials resulting in a significant increase of the electronic conductivity of the latter (almost 10-6 S/cm). The obtained nanomaterial exhibits very good thermal stability (up to 625°C), the activation energy 0.51 eV and moderate electronic conductivity at the room temperature, which is, howeve
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2

Naranje, S. M., and S. V. Moharil. "Thermoluminescence in Lithium Phosphates." physica status solidi (a) 165, no. 2 (1998): 489–94. http://dx.doi.org/10.1002/(sici)1521-396x(199802)165:2<489::aid-pssa489>3.0.co;2-t.

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3

Galogaža, V. M., E. A. Prodan, V. A. Sotnikova-Yuzhik, G. V. Peslyak, and L. Obradović. "Thermal transformations of lithium phosphates." Journal of Thermal Analysis 31, no. 4 (1986): 897–909. http://dx.doi.org/10.1007/bf01913560.

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4

Liu, Yayuan, Haotian Wang, Dingchang Lin, et al. "Electrochemical tuning of olivine-type lithium transition-metal phosphates as efficient water oxidation catalysts." Energy & Environmental Science 8, no. 6 (2015): 1719–24. http://dx.doi.org/10.1039/c5ee01290b.

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5

Bakenov, Zhumabay, and Izumi Taniguchi. "LiMnPO4 Olivine as a Cathode for Lithium Batteries." Open Materials Science Journal 5, no. 1 (2011): 222–27. http://dx.doi.org/10.2174/1874088x01105010222.

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The olivine structured mixed lithium-transition metal phosphates LiMPO4 (M = Fe, Mn, Co) have attracted tremendous attention of many research teams worldwide as a promising cathode materials for lithium batteries. Among them, lithium manganese phosphate LiMnPO4 is the most promising considering its high theoretical capacity and operating voltage, low cost and environmental safety. Various techniques were applied to prepare this perspective cathode for lithium batteries. The solution based synthetic routes such as spray pyrolysis, precipitation, sol-gel, hydrothermal and polyol synthesis allow
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6

Huang, E. M., and T. C. Detwiler. "The effects of lithium on platelet phosphoinositide metabolism." Biochemical Journal 236, no. 3 (1986): 895–901. http://dx.doi.org/10.1042/bj2360895.

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The effects on phosphoinositide metabolism of preincubation of platelets for 90 min with 10 mM-Li+ were studied. Measurements were made of [32P]phosphate-labelled phosphoinositides and of [3H]inositol-labelled inositol mono-, bis- and tris-phosphate (InsP, InsP2 and InsP3). Li+ had no effect on the basal radioactivity in the phosphoinositides or in InsP2 or InsP3, but it caused a 1.8-fold increase in the basal radioactivity in InsP. Li+ caused a 4-, 3- and 2-fold enhanced thrombin-induced accumulation of label in InsP, InsP2 and InsP3 respectively. Although the elevated labelling of InsP2 and
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7

Huang, H., T. Faulkner, J. Barker, and M. Y. Saidi. "Lithium metal phosphates, power and automotive applications." Journal of Power Sources 189, no. 1 (2009): 748–51. http://dx.doi.org/10.1016/j.jpowsour.2008.08.024.

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8

Ma, Weihua, Wei Si, Wei Wu, and Qin Zhong. "Structures and Catalytic Properties of Lithium Phosphates." Catalysis Letters 141, no. 7 (2011): 1032–36. http://dx.doi.org/10.1007/s10562-011-0597-z.

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9

Lesnyak, V. V., and N. S. Slobodyanik. "Crystallization of molybdenum and lithium double phosphates." Theoretical and Experimental Chemistry 35, no. 6 (1999): 338–42. http://dx.doi.org/10.1007/bf02522793.

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10

Novikova, Svetlana A., Sergei A. Yaroslavtsev, Vyacheslav S. Rusakov, Tatyana L. Kulova, Alexander M. Skundin, and Andrei B. Yaroslavtsev. "Lithium intercalation and deintercalation into lithium–iron phosphates doped with cobalt." Mendeleev Communications 23, no. 5 (2013): 251–52. http://dx.doi.org/10.1016/j.mencom.2013.09.003.

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11

Shintani, Ryo, Ayase Ohzono, and Kentaro Shirota. "Phosphinative cyclopropanation of allyl phosphates with lithium phosphides." Chemical Communications 56, no. 79 (2020): 11851–54. http://dx.doi.org/10.1039/d0cc04854b.

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A new cyclopropanation reaction of allyl phosphates with lithium phosphides has been developed to give cyclopropylphosphines, and high selectivity toward cyclopropanation has been realized by conducting the reaction in the presence of HMPA.
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12

Dixon, J. F., and L. E. Hokin. "Lithium stimulates accumulation of second-messenger inositol 1,4,5-trisphosphate and other inositol phosphates in mouse pancreatic minilobules without inositol supplementation." Biochemical Journal 304, no. 1 (1994): 251–58. http://dx.doi.org/10.1042/bj3040251.

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Previous studies showed that lithium, beginning at therapeutic plasma concentrations in the treatment of manic depression, increased the accumulation of second-messenger inositol 1,4,5-trisphosphate [Ins(1,4,5)P3] in cerebral cortex slices of guinea pig and rhesus monkey [Lee, Dixon, Reichman, Moummi, Los and Hokin (1992) Biochem. J. 282, 377-385; Dixon, Lee, Los and Hokin (1992) J. Neurochem. 59, 2332-2335; Dixon, Los and Hokin (1994) Proc. Natl. Acad. Sci. U.S.A. 91, 8358-8362]. These studies have now been extended to a peripheral tissue, mouse pancreatic minilobules. In the presence of carb
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13

Yin, Shih-Chieh, Hiltrud Grondey, Pierre Strobel, Huan Huang, and Linda F. Nazar. "Charge Ordering in Lithium Vanadium Phosphates: Electrode Materials for Lithium-Ion Batteries." Journal of the American Chemical Society 125, no. 2 (2003): 326–27. http://dx.doi.org/10.1021/ja028973h.

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14

Davis, J. S., L. L. Weakland, L. A. West, and R. V. Farese. "Luteinizing hormone stimulates the formation of inositol trisphosphate and cyclic AMP in rat granulosa cells. Evidence for phospholipase C generated second messengers in the action of luteinizing hormone." Biochemical Journal 238, no. 2 (1986): 597–604. http://dx.doi.org/10.1042/bj2380597.

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The following studies were conducted to determine whether luteinizing hormone (LH), a hormone which increases cellular levels of cyclic AMP, also provokes increases in ‘second messengers’ derived from inositol lipid metabolism (i.e. inositol phosphates and diacylglycerol). Rat granulosa cells isolated from mature Graafian follicles were prelabelled for 3 h with myo-[2-3H]inositol. LH provoked rapid (5 min) and sustained (up to 60 min) increases in the levels of inositol mono-, bis, and trisphosphates (IP, IP2 and IP3, respectively). Time course studies revealed that IP3 was formed more rapidly
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15

Suzuki, Takahito, Naoto Hayakawa, Kazuyoshi Uematsu, Kenji Toda, and Mineo Sato. "Single Crystal Growth of Lithium Ion Conductive Phosphates." Key Engineering Materials 181-182 (May 2000): 183–86. http://dx.doi.org/10.4028/www.scientific.net/kem.181-182.183.

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16

Patoux, Sébastien, and Christian Masquelier. "Lithium Insertion into Titanium Phosphates, Silicates, and Sulfates." Chemistry of Materials 14, no. 12 (2002): 5057–68. http://dx.doi.org/10.1021/cm0201798.

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17

Ermilova, M. M., N. V. Orekhova, E. Yu Mironova, et al. "Methanol transformations on framework lithium zirconium vanadate phosphates." Russian Journal of Inorganic Chemistry 61, no. 8 (2016): 940–45. http://dx.doi.org/10.1134/s0036023616080076.

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18

Islam, M. Saiful, Robert Dominko, Christian Masquelier, Chutchamon Sirisopanaporn, A. Robert Armstrong, and Peter G. Bruce. "Silicate cathodes for lithium batteries: alternatives to phosphates?" Journal of Materials Chemistry 21, no. 27 (2011): 9811. http://dx.doi.org/10.1039/c1jm10312a.

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19

Yazdani, Sajad, Raana Kashfi-Sadabad, Mayra Daniela Morales-Acosta, et al. "Thermal transport in phase-stabilized lithium zirconate phosphates." Applied Physics Letters 117, no. 1 (2020): 011903. http://dx.doi.org/10.1063/5.0013716.

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20

Wilcke, S. L., Y. J. Lee, E. J. Cairns, and J. A. Reimer. "Covalency Measurements via NMR in Lithium Metal Phosphates." Applied Magnetic Resonance 32, no. 4 (2007): 547–63. http://dx.doi.org/10.1007/s00723-007-0032-1.

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21

Mauger, A., K. Zaghib, F. Gendron, and C. M. Julien. "Small magnetic polaron effect in lithium iron phosphates." Ionics 14, no. 3 (2007): 209–14. http://dx.doi.org/10.1007/s11581-007-0182-z.

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22

Ait Salah, A., P. Jozwiak, K. Zaghib, et al. "FTIR features of lithium-iron phosphates as electrode materials for rechargeable lithium batteries." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 65, no. 5 (2006): 1007–13. http://dx.doi.org/10.1016/j.saa.2006.01.019.

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23

Novikova, Svetlana A., Sergei A. Yaroslavtsev, Vyacheslav S. Rusakov, Tatyana L. Kulova, Alexander M. Skundin, and Andrei B. Yaroslavtsev. "ChemInform Abstract: Lithium Intercalation and Deintercalation into Lithium-Iron Phosphates Doped with Cobalt." ChemInform 45, no. 3 (2014): no. http://dx.doi.org/10.1002/chin.201403017.

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24

Strutynska, N., А. Spivak, R. Kuzmin, and M. Slobodyanik. "SYNTHESIS, INVESTIGATION AND CONDUCTIVE PROPERTIES OF ALLUAUDITE-RELATED PHASES." Bulletin of Taras Shevchenko National University of Kyiv. Chemistry, no. 1 (57) (2020): 6–9. http://dx.doi.org/10.17721/1728-2209.2020.1(57).1.

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Complex oxide phosphates Na1.5Co1.5Fe1.5(PO4)3, Na1.75Co1.75Fe1.25(PO4)3, Na2Co2Fe(PO4)3 and Li0.25Na1.75Co2Fe(PO4)3, belonging to the alluaudite structural type (monoclinic system, space group C2/c) were synthesized by the melting method with further annealing of the homogenous glasses at a temperature 600°C. According to powder X-ray diffraction data the partial substitution of sodium cations by lithium cations in the initial phosphate matrix Na2Co2Fe(PO4)3 led to decreasing of lattice parameters for Li0.25Na1.75Co2Fe(PO4)3 (a = 11.7572(3) Å, b = 12.4528(4) Å, c = 6.4416(2) Å and β = 113.911
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25

Yang, Shoufeng, Yanning Song, Peter Y. Zavalij, and M. Stanley Whittingham. "Reactivity, stability and electrochemical behavior of lithium iron phosphates." Electrochemistry Communications 4, no. 3 (2002): 239–44. http://dx.doi.org/10.1016/s1388-2481(01)00298-3.

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26

Lepley, N. D., and N. A. W. Holzwarth. "Computer Modeling of Crystalline Electrolytes: Lithium Thiophosphates and Phosphates." Journal of The Electrochemical Society 159, no. 5 (2012): A538—A547. http://dx.doi.org/10.1149/2.jes113225.

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27

Garrigou-Lagrange, C., M. Ouchetto, and B. Elouadi. "Infrared spectra of vitreous lithium and cadmium mixed phosphates." Canadian Journal of Chemistry 63, no. 7 (1985): 1436–46. http://dx.doi.org/10.1139/v85-247.

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Infrared reflection spectra of vitreous phosphates (1 − x − χ)Li2O − xCdO − χ P2O5 are analysed in relation to the conformation when it is known. The evolution of the spectra with the different constituents is studied and the oxide forming-character of CdO is discussed.
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28

Lepley, Nicholas, and Natalie Holzwarth. "Computer Modeling of Crystalline Electrolytes - Lithium Thiophosphates and Phosphates." ECS Transactions 35, no. 14 (2019): 39–51. http://dx.doi.org/10.1149/1.3644902.

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29

Shiga, Tohru, Yuichi Kato, Hiroki Kondo, and Chika-aki Okuda. "Self-extinguishing electrolytes using fluorinated alkyl phosphates for lithium batteries." Journal of Materials Chemistry A 5, no. 10 (2017): 5156–62. http://dx.doi.org/10.1039/c6ta09915g.

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30

Cai, Gan, Zhenguo Wu, Tao Luo, et al. "3D hierarchical rose-like Ni2P@rGO assembled from interconnected nanoflakes as anode for lithium ion batteries." RSC Advances 10, no. 7 (2020): 3936–45. http://dx.doi.org/10.1039/c9ra10729k.

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In recent years, anode materials of transition metal phosphates (TMPs) for lithium ion batteries have drawn a vast amount of attention, due to their high theoretical capacity and comparatively low intercalation potentials vs. Li/Li<sup>+</sup>.
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31

Koleva, Violeta, Ekaterina Zhecheva, and Radostina Stoyanova. "Ordered Olivine-Type Lithium-Cobalt and Lithium-Nickel Phosphates Prepared by a New Precursor Method." European Journal of Inorganic Chemistry 2010, no. 26 (2010): 4091–99. http://dx.doi.org/10.1002/ejic.201000400.

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32

Penazzi, N., M. Arrabito, M. Piana, S. Bodoardo, S. Panero, and I. Amadei. "Mixed lithium phosphates as cathode materials for Li-Ion cells." Journal of the European Ceramic Society 24, no. 6 (2004): 1381–84. http://dx.doi.org/10.1016/s0955-2219(03)00568-5.

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33

Julien, C. M., K. Zaghib, Atmane Ait Salah, Alain Mauger, and Francois Gendron. "Electronic and Magnetic Properties of Carbon-Coated Lithium Iron Phosphates." ECS Transactions 1, no. 14 (2019): 1–8. http://dx.doi.org/10.1149/1.2214604.

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34

Wohlfahrt-Mehrens, Margret. "Advanced Positive Materials for Lithium-Ion-Batteries: Oxides and Phosphates." Zeitschrift für anorganische und allgemeine Chemie 638, no. 10 (2012): 1547. http://dx.doi.org/10.1002/zaac.201202001.

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35

Barpanda, Prabeer, Nadir Recham, Karim Djellab, Adrien Boulineau, Michel Armand, and Jean-Marie Tarascon. "Ionothermal Synthesis and Electrochemical Characterization of Nanostructured Lithium Manganese Phosphates." ECS Transactions 25, no. 14 (2019): 1–7. http://dx.doi.org/10.1149/1.3301805.

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36

Marincaş, Alexandru-Horaţiu, and Petru Ilea. "Enhancing Lithium Manganese Oxide Electrochemical Behavior by Doping and Surface Modifications." Coatings 11, no. 4 (2021): 456. http://dx.doi.org/10.3390/coatings11040456.

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Lithium manganese oxide is regarded as a capable cathode material for lithium-ion batteries, but it suffers from relative low conductivity, manganese dissolution in electrolyte and structural distortion from cubic to tetragonal during elevated temperature tests. This review covers a comprehensive study about the main directions taken into consideration to supress the drawbacks of lithium manganese oxide: structure doping and surface modification by coating. Regarding the doping of LiMn2O4, several perspectives are studied, which include doping with single or multiple cations, only anions and c
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37

Islam, M. Saiful. "Recent atomistic modelling studies of energy materials: batteries included." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 368, no. 1923 (2010): 3255–67. http://dx.doi.org/10.1098/rsta.2010.0070.

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Advances in functional materials for energy conversion and storage technologies are crucial in addressing the global challenge of green sustainable energy. This article aims to demonstrate the valuable role that modern modelling techniques now play in providing deeper fundamental insight into novel materials for rechargeable lithium batteries and solid oxide fuel cells. Recent work is illustrated by studies on important topical materials encompassing transition-metal phosphates and silicates for lithium battery electrodes, and apatite-type silicates for fuel cell electrolytes.
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38

Shao, Lianyi, Jie Shu, Yuanhao Tang, et al. "Phase diagram and electrochemical behavior of lithium sodium vanadium phosphates cathode materials for lithium ion batteries." Ceramics International 41, no. 3 (2015): 5164–71. http://dx.doi.org/10.1016/j.ceramint.2014.11.152.

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39

Kellerman, D. G., A. P. Tyutyunnik, N. I. Medvedeva, et al. "New Li–Mg phosphates with a 3D framework: experimental and ab initio calculations." Dalton Transactions 49, no. 29 (2020): 10069–83. http://dx.doi.org/10.1039/d0dt01963a.

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40

Mo, Xiang Yin, Xiao San Feng, Yi Ding, and Cai Rong Kang. "Carbon-Coated, Bismuth-Substituted, Lithium Iron Phosphate as Cathode Material for Lithium Secondary Batteries." Advanced Materials Research 739 (August 2013): 21–25. http://dx.doi.org/10.4028/www.scientific.net/amr.739.21.

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Carbon-coated, bismuth-doped, lithium iron phosphates, LiFe1xBixPO4(0x0.05), have been synthesized by a solid-state reaction method. From the optimization, the carbon-coated LiFe0.95Bi0.05PO4phase showed superior performances in terms of phase purity and high discharge capacity. The structural, morphological, and electrochemical properties were studied and compared to carbon-coated, LiFePO4. The Li/LiFe0.95Bi0.05PO4with carbon coating cell delivered an initial discharge capacity of 145 mAh/g and was 30 mAh/g higher than the Li/LiFePO4with carbon coating cell. Cyclic voltammetry revealed excell
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41

Zhang, Yin, Jose A. Alarco, Jawahar Y. Nerkar, et al. "Spectroscopic Evidence of Surface Li-Depletion of Lithium Transition-Metal Phosphates." ACS Applied Energy Materials 3, no. 3 (2020): 2856–66. http://dx.doi.org/10.1021/acsaem.9b02489.

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42

YAMASHITA, TETSUYA, HIROYUKI NARIAI, and ITARU MOTOOKA. "THE THERMAL BEHAVIOR OF THE BINARY SYSTEMS OF LITHIUM-POTASSIUM PHOSPHATES." Phosphorus Research Bulletin 5 (1995): 65–70. http://dx.doi.org/10.3363/prb1992.5.0_65.

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43

Deniard, P., A. M. Dulac, X. Rocquefelte, et al. "High potential positive materials for lithium-ion batteries: transition metal phosphates." Journal of Physics and Chemistry of Solids 65, no. 2-3 (2004): 229–33. http://dx.doi.org/10.1016/j.jpcs.2003.10.019.

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44

Maslanski, J., L. Leshko, and W. Busa. "Lithium-sensitive production of inositol phosphates during amphibian embryonic mesoderm induction." Science 256, no. 5054 (1992): 243–45. http://dx.doi.org/10.1126/science.1314424.

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45

Whittingham, M. Stanley, Yanning Song, Samuel Lutta, Peter Y. Zavalij, and Natasha A. Chernova. "Some transition metal (oxy)phosphates and vanadium oxides for lithium batteries." Journal of Materials Chemistry 15, no. 33 (2005): 3362. http://dx.doi.org/10.1039/b501961c.

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46

Yiu, Y. M., Songlan Yang, Dongniu Wang, Xueliang Sun, and T. K. Sham. "Ab-initio Calculation of the XANES of Lithium Phosphates and LiFePO4." Journal of Physics: Conference Series 430 (April 22, 2013): 012014. http://dx.doi.org/10.1088/1742-6596/430/1/012014.

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47

Menzel, Jennifer, Hannah Schultz, Vadim Kraft, Juan Pablo Badillo, Martin Winter, and Sascha Nowak. "Quantification of ionic organo(fluoro)phosphates in decomposed lithium battery electrolytes." RSC Advances 7, no. 62 (2017): 39314–24. http://dx.doi.org/10.1039/c7ra07486g.

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48

Saiful Islam, M., and Peter R. Slater. "Solid-State Materials for Clean Energy: Insights from Atomic-Scale Modeling." MRS Bulletin 34, no. 12 (2009): 935–41. http://dx.doi.org/10.1557/mrs2009.216.

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AbstractFundamental advances in solid-state ionics for energy conversion and storage are crucial in addressing the global challenge of cleaner energy sources. This review aims to demonstrate the valuable role that modern computational techniques now play in providing deeper fundamental insight into materials for solid oxide fuel cells and rechargeable lithium batteries. The scope of contemporary work is illustrated by studies on topical materials encompassing perovskite-type proton conductors, gallium oxides with tetrahedral moieties, apatite-type silicates, and lithium iron phosphates. Key fu
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49

Castro, Laurent, Nicolas Penin, Dany Carlier, et al. "Crystal structure of a new lithium iron vanadate." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C1101. http://dx.doi.org/10.1107/s2053273314088986.

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Iron vanadates and phosphates have been widely explored [1-2] as possible electrode material for Li-ion batteries. In the goal of finding new materials, our approach was to consider existing materials and to investigate the flexibility of their network for possible substitutions. Among the different materials containing iron and vanadium, Cu3Fe4(XO4)6 (X = P, V) are isostructural to Fe7(PO4)6. Lafontaine et al. [3] discussed the structural relationships between β-Cu3Fe4(VO4)6 and several other vanadates, phosphates and molybdates of general formula AxBy(VO4)6. The interesting network flexibili
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50

TAKAHASHI, Hiroaki, Takao OI, and Morikazu HOSOE. "Lithium Isotope Selectivity of Semicrystalline Titanium Phosphates with Rapid Ion Exchange Rate." Journal of Ion Exchange 14, Supplement (2003): 385–88. http://dx.doi.org/10.5182/jaie.14.supplement_385.

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