Journal articles on the topic 'Low-dimensional magnetic oxide'

Purpose The purpose of this paper is to investigate the coupled effect of magnetic field and radiation on convective heat transfer of low electrically conductive dielectric oxide melt. Design/methodology/approach The 3D Navier–Stokes equations are formulated using the vector potential-vorticity formulation and solved using the finite volume method (FVM). The radiative heat transfer equation is discretized using the FTnFVM method. A code was written using FORTRAN language. Findings The obtained numerical results are focused on the effect of the different parameters on the heat transfer and the flow structure with a special interest on the 3D transvers flow. It is found that the flow is developing in inner spirals and the magnetic field intensifies this 3D character. The radiation acts mainly at the core of the enclosure and causes the apparition of the merging phenomenon near the front and back walls. Originality/value The effect of magnetic field on convective heat transfer of highly electrically conductive fluids has been intensively studied. Reciprocally, the case of a fluid with low electrical conductivity is not so much investigated, especially when it is coupled with the effect of radiation. These two effects are studied in this paper for the case of a low-conductive LiNbO3 oxide melt.

Engineering magnetic anisotropy in two-dimensional systems has enormous scientific and technological implications. The uniaxial anisotropy universally exhibited by two-dimensional magnets has only two stable spin directions, demanding 180° spin switching between states. We demonstrate a previously unobserved eightfold anisotropy in magnetic SrRuO3 monolayers by inducing a spin reorientation in (SrRuO3)1/(SrTiO3)N superlattices, in which the magnetic easy axis of Ru spins is transformed from uniaxial 〈001〉 direction (N < 3) to eightfold 〈111〉 directions (N ≥ 3). This eightfold anisotropy enables 71° and 109° spin switching in SrRuO3 monolayers, analogous to 71° and 109° polarization switching in ferroelectric BiFeO3. First-principle calculations reveal that increasing the SrTiO3 layer thickness induces an emergent correlation-driven orbital ordering, tuning spin-orbit interactions and reorienting the SrRuO3 monolayer easy axis. Our work demonstrates that correlation effects can be exploited to substantially change spin-orbit interactions, stabilizing unprecedented properties in two-dimensional magnets and opening rich opportunities for low-power, multistate device applications.

Interfaces between correlated oxides are attracting great interest. Electron correlations give rise to novel forms of couplings between electronic ground states at both sides of the interface. The bonding discontinuity at the interface between magnetic and nonmagnetic oxides is at the origin of a form of low dimensional magnetism in the otherwise nonmagnetic material. Its origin is the splitting of its bands due to the hybridization with the exchange split bands of the magnetic material. This induced magnetism could find interesting functionalities in devices with operation controlled by the interface such as tunnel or field effect devices of interest in spintronics.

A brief introduction is presented on transition metal oxide bronzes and their relationship to the phosphate tungsten bronzes; the latter compounds are the major focus of this review. The phosphate tungsten bronzes (PTB) are a new class of quasi-low-dimensional materials which exhibit charge density wave (CDW) instabilities. The growth of single crystals and investigation of the physical properties including the temperature dependence of the electrical resistivity and magnetic susceptibility on oriented single crystals are discussed for selected members of the major families in the PTB’s. Correlation of the physical measurement data with structural properties, X-ray diffraction data and results of the theoretical band structure calculations are also presented.

Do charge modulations compete with electron pairing in high-temperature copper oxide superconductors? We investigated this question by suppressing superconductivity in a stripe-ordered cuprate compound at low temperature with high magnetic fields. With increasing field, loss of three-dimensional superconducting order is followed by reentrant two-dimensional superconductivity and then an ultraquantum metal phase. Circumstantial evidence suggests that the latter state is bosonic and associated with the charge stripes. These results provide experimental support to the theoretical perspective that local segregation of doped holes and antiferromagnetic spin correlations underlies the electron-pairing mechanism in cuprates.

We review the modeling of silicon MOS devices in the 10–300 K temperature range with an emphasis on the specifics of low-temperature operation. Recently developed one-dimensional models of long-channel transistors are discussed in connection with experimental determination and verification of the effective channel mobility in a wide temperature range. We also present analytical pseudo-two-dimensional models of short-channel devices which have been proposed for potential use in circuit simulators. Several one-, two-, and three-dimensional numerical models are discussed in order to gain insight into the more subtle details of the low-temperature device physics of MOS transistors and capacitors. Particular attention is paid to freezeout effects which, depending on the device design and the ambient temperature range, may or may not be important for actual device operation. The numerical models are applied to study the characteristic time scale of freezeout transients in the space-charge regions of silicon devices, to the analysis and suppression of delayed turn-off in MOS transistors with compensated channel, and to the temperature dependence of three-dimensional effects in short-channel, narrow-channel MOSFETs.

In this work, n-ZnO/p-Si heterojunction was investigated using two-dimensional numerical simulation. The effect of Zinc Oxide thickness, carrier concentration in Zinc Oxide layer, minority carrier lifetime of bulk Silicon and the interface states density on electrical properties were studied in dark and under illumination conditions. This study aimed to optimize these parameters in order to obtain n-ZnO/p-Si solar cell with high conversion efficiency and low cost. The simulation was carried out by Atlas silvaco software. As results, a very low saturation current Is, low series resistance Rs, an ideality factor n between 1 and 1.5 were obtained for optimal charge carrier concentrations in the range [5 × 1019–5 × 1021 cm−3] and a thickness of Zinc Oxide between 0.6 and 2 µm. Moreover, a photovoltaic conversion efficiency of 24.75% was achieved without interfacial defect, which decreases to 5.49% for an interface defect density of 5 × 1014 cm−2.

This work presents a one-dimensional magnetic chip composed of a hybrid magnetosensor and a readout circuit, which were fabricated with 0.18 μm 1P6M CMOS technology. The proposed magnetosensor includes a polysilicon cross-shaped Hall plate and two separated metal-oxide semiconductor field-effect transistors (MOSFETs) to sense the magnetic induction perpendicular to the chip surface. The readout circuit, which comprises a current-to-voltage converter, a low-pass filter, and an instrumentation amplifier, is designed to amplify the output Hall voltage with a gain of 43 dB. Furthermore, a SPICE macro model is proposed to predict the sensor’s performance in advance and to ensure sufficient comprehension of the magnetic mechanism of the proposed magnetosensor. Both simulated and measured results verify the correctness and flexibility of the proposed SPICE macro model. Measurements reveal that the maximum output Hall voltage VH, the optimum current-related magnetosensitivity SRI, the optimum voltage-related magnetosensitivity SRV, the averaged nonlinearity error NLE, and the relative bias current Ibias are 4.381 mV, 520.5 V/A·T, 40.04 V/V·T, 7.19%, and 200 μA, respectively, for the proposed 1-D magnetic chip with a readout circuit of 43 dB. The averaged NLE is small at high magnetic inductions of ±30 mT, whereas it is large at low magnetic inductions of ±30 G.

Much of the insight into the low temperature behaviour of two-dimensional quantum antiferromagnets has been recently obtained by extensive Monte Carlo. These models are relevant in the study of the magnetic behaviour of high Tc compounds containing copper-oxide layers. While of little technical importance, the physical properties of these models are certainly important for the understanding of the new type of behaviour that leads to superconductivity under certain conditions.

Multifunctional magnetic nanomaterials displaying high specific loss power (SLP) and high imaging sensitivity with good spatial resolution are highly desired in image-guided cancer therapy. Currently, commercial nanoparticles do not sufficiently provide such multifunctionality. For example, Resovist® has good image resolution but with a low SLP, whereas BNF® has a high SLP value with very low image resolution. In this study, hydrophilic magnesium iron oxide@tetramethyl ammonium hydroxide nanoparticles were prepared in two steps. First, hydrophobic magnesium iron oxide nanoparticles were fabricated using a thermal decomposition technique, followed by coating with tetramethyl ammonium hydroxide. The synthesized nanoparticles were characterized using XRD, DLS, TEM, zeta potential, UV-Vis spectroscopy, and VSM. The hyperthermia and imaging properties of the prepared nanoparticles were investigated and compared to the commercial nanoparticles. One-dimensional magnetic particle imaging indicated the good imaging resolution of our nanoparticles. Under the application of a magnetic field of frequency 614.4 kHz and strength 9.5 kA/m, nanoparticles generated heat with an SLP of 216.18 W/g, which is much higher than that of BNF (14 W/g). Thus, the prepared nanoparticles show promise as a novel dual-functional magnetic nanomaterial, enabling both high performance for hyperthermia and imaging functionality for diagnostic and therapeutic processes.

A fully functional Si photonics and 65-nm complementary metal-oxide semiconductor (CMOS) heterogeneous three-dimensional (3-D) integration is demonstrated for the first time in a 300-mm production environment. Direct oxide wafer bonding was developed to eliminate voids between silicon on insulator photonics and bulk Si CMOS wafers. A via-last, Cu through-oxide via 3-D integration was developed for low capacitance electrical connections with no impact on the CMOS performance. The 3-D yield approaching 100% was demonstrated on &gt;20,000 via chains.

AbstractThe interface between the oxide insulators LaAlO3 and SrTiO3 (LAO/STO) hosts a two-dimensional electron gas. The combination of interfacial conductivity and superconductivity at ultra-low temperatures with the physical phenomena of the oxide parent materials has fueled extensive research in the field since its discovery in 2004. Scanning superconducting quantum interference device (SQUID) measurements have shown that structural domain walls, formed below 105 K, modulate the current flow at the interface and recently revealed weak magnetic signals along the same domain structure. Here we use scanning SQUID to investigate the temperature dependence of different electronic properties of the LAO/STO interface. We find correlation between magnetism and conductivity, which are both spatially modulated on the domain structure. This data suggests a possible relation between the populations of electrons participating in each order.

Graphene was attended widely in recent years because of its excellent performance in electrical, mechanical, optical and magnetic applications. X-ray photoelectron spectroscopy (XPS) is commonly used tools for studying the chemical binding state, chemical modification, heteroatom dopants and quantitative chemical composition of graphene. In this work, XPS characterization of graphene films, obtained through reduction and then thermal treatment of graphene oxide films, was studied. The XPS of the graphene films are performed by direct testing, Ar+ etching, and direct peeling of the surface layer. The result shows that for graphene film, direct peeling is a simple and easy to use low-cost treatment, which can also be extended to XPS testing of other two-dimensional (2D) materials.

Due to its high sensitivity, low price and fast response speed, gas sensors based on metal oxide nanomate-rials have attracted many researchers to modify and explore the materials. First, pure indium oxide (In2O3) nanotubes (NTs)/porous NTs (PNTs) and Ho doped In2O3 NTs/PNTs are prepared by electrospinning and calcination. Then, based on the prepared nanomaterials, the 6-channel sensor array is obtained and used in the electronic nose sensing system for wine product identification. The system obtains the frequency signals of different liquor products by means of 6-channel sensor array, analyzes the extracted electronic signal characteristic information by means of ordinary least squares, and introduces the pattern recognition method of moving average and linear discriminant to identify liquor products. In the experiment, compared with pure In2O3 NTs sensor, pure In2O3 PNTs sensor has higher sensitivity to 100 ppm ethanol gas, and the sensitivity is further improved after mixing Ho. Among them, 6 mol% Ho + In2O3 PNTs have the highest sensitivity and the shortest response time; based on the electronic nose system composed of prepared nanomaterial sensor array, frequency signals of different Wu Liang Ye wines are collected. With the extension of acquisition time, the corresponding frequency first decreases and then becomes stable; the extracted liquor characteristic signal is projected into two-dimensional space and three-dimensional space. The results show that the pattern recognition system based on this method can extract the characteristic signals of liquor products and distinguish them.

Environmental contextRemediation of wastewater containing polycyclic aromatic hydrocarbons and metals is essential to limit adverse effects on the environment and human health. Using a simple precipitation method, we prepared porous magnetic MgO hybrids for use as a material for removing pollutants from wastewater. The material showed excellent removal performance for 12 polycyclic aromatic hydrocarbons and cadmium ions, and thus has potential applications in wastewater treatment. AbstractHierarchical porous magnetic MgO hybrids (Fe3O4/MgO) are controllably synthesised based on a facile precipitation process. The resulting material displays a three-dimensional architecture with nest-like morphology, large surface area (135.2m2 g−1) and uniform mesochannels (5–35nm). The adsorption equilibrium data of target polycyclic aromatic hydrocarbons (PAHs) on Fe3O4/MgO sorbents are described by the Langmuir isotherm model. The composites show a strong tendency for the removal of PAHs owing to their porous structure that possesses an excellent affinity for PAHs. Under the optimal conditions, a removal of more than 70% is achieved for 12 PAHs. The materials also exhibit a good removal ability of cadmium (Cd2+) from water with fast adsorption (&lt;5min) and high removal percentage (&gt;80%). Moreover, the composites possess sufficient magnetism for separation. To demonstrate the performance of the sorbents, Fe3O4/MgO is exposed to aqueous samples spiked with low concentrations of PAHs and Cd2+. In almost all cases, the composites are superior to the commercially available sorbents as well as un-functionalised Fe3O4 nanoparticles. Therefore, this work provides a promising approach for the simultaneous removal of PAHs and Cd2+ from water using multifunctional MgO microspheres.

Rechargeable zinc–air batteries are deemed as the most feasible alternative to replace lithium–ion batteries in various applications. Among battery components, separators play a crucial role in the commercial realization of rechargeable zinc–air batteries, especially from the viewpoint of preventing zincate (Zn(OH)42−) ion crossover from the zinc anode to the air cathode. In this study, a new hydroxide exchange membrane for zinc–air batteries was synthesized using poly (2,6-dimethyl-1,4-phenylene oxide) (PPO) as the base polymer. PPO was quaternized using three tertiary amines, including trimethylamine (TMA), 1-methylpyrolidine (MPY), and 1-methylimidazole (MIM), and casted into separator films. The successful synthesis process was confirmed by proton nuclear magnetic resonance and Fourier-transform infrared spectroscopy, while their thermal stability was examined using thermogravimetric analysis. Besides, their water/electrolyte absorption capacity and dimensional change, induced by the electrolyte uptake, were studied. Ionic conductivity of PPO–TMA, PPO–MPY, and PPO–MIM was determined using electrochemical impedance spectroscopy to be 0.17, 0.16, and 0.003 mS/cm, respectively. Zincate crossover evaluation tests revealed very low zincate diffusion coefficient of 1.13 × 10−8, and 0.28 × 10−8 cm2/min for PPO–TMA, and PPO–MPY, respectively. Moreover, galvanostatic discharge performance of the primary batteries assembled using PPO–TMA and PPO–MPY as initial battery tests showed a high specific discharge capacity and specific power of ~800 mAh/gZn and 1000 mWh/gZn, respectively. Low zincate crossover and high discharge capacity of these separator membranes makes them potential materials to be used in zinc–air batteries.

We report on a GaN metal-oxide-semiconductor high electron mobility transistor (MOS-HEMT) using atomic layer deposition (ALD) Al 2 O 3 film as a gate dielectric and for surface passivation simultaneously. Compared to the conventional AlGaN/GaN HEMT of the same design, six order of magnitude smaller gate leakage current and tripled drain current at forward gate bias demonstrate the effectiveness of ALD Al 2 O 3 as a gate dielectric. The high transconductance and high effective two-dimensional electron mobility verify the high-quality of Al 2 O 3/ AlGaN interface with low interface trap density. The Al 2 O 3 passivation effect is also studied by sheet resistance measurement and short pulse drain characterization.

The technology progress and increasing high density demand have driven the nonvolatile memory devices into nanometer scale region. There is an urgent need of new materials to address the high programming voltage and current leakage problems in the current flash memory devices. As one of the most important nanomaterials with excellent mechanical and electronic properties, carbon nanotube has been explored for various nonvolatile memory applications. While earlier proposals of "bucky shuttle" memories and nanoelectromechanical memories remain as concepts due to fabrication difficulty, recent studies have experimentally demonstrated various prototypes of nonvolatile memory cells based on nanotube field-effect-transistor and discrete charge storage bits, which include nano-floating gate memory cells using metal nanocrystals, oxide-nitride-oxide memory stack, and more simpler trap-in-oxide memory devices. Despite of the very limited research results, distinct advantages of high charging efficiency at low operation voltage has been demonstrated. Single-electron charging effect has been observed in the nanotube memory device with quantum dot floating gates. The good memory performance even with primitive memory cells is attributed to the excellent electrostatic coupling of the unique one-dimensional nanotube channel with the floating gate and the control gate, which gives extraordinary charge sensibility and high current injection efficiency. Further improvement is expected on the retention time at room temperature and programming speed if the most advanced fabrication technology were used to make the nanotube based memory cells.

The authors of the present paper sought to conduct a numerical study on the convection heat transfer, along with the radiation and entropy generation (EGE) of a nanofluids (NFs) in a two and three-dimensional square enclosure, by using the FVM. The enclosure contained a high-temperature blade in the form of a vertical elliptical quadrant in the lower corner of the enclosure. The right edge of the enclosure was kept at low temperature, while the other edges were insulated. The enclosure was subjected to a magnetic field (MGF) and could be adjusted to different angles. In this research, two laboratory relationships dependent on temperature and volume fraction were used to simulate thermal conductivity and viscosity. The variables of this problem were Ra, Ha, RAP, nanoparticle (NP) volume fraction, blade aspect ratio, enclosure angles, and MGF. Evaluating the effects of these variables on heat transfer rate (HTR), EGE, and Be revealed that increasing the Ra and reducing the Ha could increase the HTR and EGE. On the other hand, adding radiation HTR to the enclosure increased the overall HTR. Moreover, an augmentation of the volume fraction of magnesium oxide NPs led to an increased amount of HTR and EGE. Furthermore, any changes to the MGF and the enclosure angle imposed various effects on the HTR. The results indicated that an augmentation of the size of the blade increased and then decreased the HTR and the generated entropy. Finally, increasing the blade always increased the Be.

In recent years, many attempts have been made to improve the sensory properties of SnO2, including design of sensors based on one-dimensional nanostructures of this material, such as nanofibers, nanotubes or nanowires. One of the simpler methods of producing one-dimensional tin oxide nanomaterials is to combine the electrospinning method with a sol-gel process. The purpose of this work was to produce SnO2 nanowires using a hybrid electrospinning method combined with a heat treatment process at the temperature of 600 °C and to analyze the morphology and structure of the one-dimensional nanomaterial produced in this way. Analysis of the morphology of composite one-dimensional tin oxide nanostructures showed that smooth, homogeneous and crystalline nanowires were obtained. Full Text: PDF ReferencesN. Dharmaraj, C.H. Kim, K.W. Kim, H.Y. Kim, E.K. Suh, "Spectral studies of SnO2 nanofibres prepared by electrospinning method", Spectrochim. Acta - Part A Mol. Biomol. Spectrosc. 64, (2006) CrossRef N. Gao, H.Y. Li, W. Zhang, Y. Zhang, Y. Zeng, H. Zhixiang, ... & H. Liu, "QCM-based humidity sensor and sensing properties employing colloidal SnO2 nanowires", Sens. Actuators B Chem. 293, (2019), 129-135. CrossRef W. Ge, Y. Chang, V. Natarajan, Z. Feng, J. Zhan, X. Ma, "In2O3-SnO2 hybrid porous nanostructures delivering enhanced formaldehyde sensing performance", J.Alloys and Comp. 746, (2018) CrossRef M. Zhang, Y. Zhen, F. Sun, C. Xu, "Hydrothermally synthesized SnO2-graphene composites for H2 sensing at low operating temperature", Mater. Sci. Eng. B. 209, (2016), 37-44. CrossRef Y. Zhang, X. He, J. Li, Z. Miao, F. Huang, "Fabrication and ethanol-sensing properties of micro gas sensor based on electrospun SnO2 nanofibers", Sens. Actuators B Chem. 132, (2008), 67-73. CrossRef W.Q. Li, S.Y. Ma, J. Luo, Y.Z. Mao, L. Cheng, D.J. Gengzang, X.L. Xu, S H. Yan, "Synthesis of hollow SnO2 nanobelts and their application in acetone sensor", Mater. Lett. 132, (2014), 338-341. CrossRef E. Mudra, I. Shepa, O. Milkovic, Z. Dankova, A. Kovalcikova, A. Annusova, E. Majkova, J. Dusza, "Effect of iron doping on the properties of SnO2 nano/microfibers", Appl. Surf. Sci. 480, (2019), 876-881. CrossRef P. Mohanapriya, H. Segawa, K. Watanabe, K. Watanabe, S. Samitsu, T.S. Natarajan, N.V. Jaya, N. Ohashi, "Enhanced ethanol-gas sensing performance of Ce-doped SnO2 hollow nanofibers prepared by electrospinning", Sens. Actuators B Chem. 188, (2013), 872-878. CrossRef W.Q. Li, S.Y. Ma, Y.F. Li, X.B. Li, C.Y. Wang, X.H. Yang, L. Cheng, Y.Z. Mao, J. Luo, D.J. Gengzang, G.X. Wan, X.L. Xu, "Preparation of Pr-doped SnO2 hollow nanofibers by electrospinning method and their gas sensing properties", J.Alloys and Comp. 605, (2014), 80-88. CrossRef X.H. Xu, S.Y. Ma, X.L. Xu, T. Han, S.T. Pei, Y. Tie, P.F. Cao, W.W. Liu, B.J. Wang, R. Zhang, J.L. Zhang, "Ultra-sensitive glycol sensing performance with rapid-recovery based on heterostructured ZnO-SnO2 hollow nanotube", Mater. Lett, 273, (2020), 127967. CrossRef F. Li, X. Gao, R. Wang, T. Zhang, G. Lu, Sens. "Study on TiO2-SnO2 core-shell heterostructure nanofibers with different work function and its application in gas sensor", Actuators B Chem, 248, (2017), 812-819. CrossRef S. Bai, W. Guo, J. Sun, J. Li, Y. Tian, A. Chen, R. Luo, D. Li, "Synthesis of SnO2–CuO heterojunction using electrospinning and application in detecting of CO", Sens Actuators B Chem, 226, (2016), 96-103. CrossRef H. Du, P.J. Yao, Y. Sun, J. Wang, H. Wang, N. Yu, "Electrospinning Hetero-Nanofibers In2O3/SnO2 of Homotype Heterojunction with High Gas Sensing Activity", Sensors, 17, (2017), 1822. CrossRef X. Wang, H. Fan, P. Ren, "Electrospinning derived hollow SnO2 microtubes with highly photocatalytic property", Catal. Commun. 31, (2013), 37-41. CrossRef L. Cheng, S.Y. Ma, T.T. Wang, X.B. Li, J. Luo, W.Q. Li, Y.Z. Mao, D.J Gengzang, "Synthesis and characterization of SnO2 hollow nanofibers by electrospinning for ethanol sensing properties", Mater. Lett. 131, (2014), 23-26. CrossRef P.H. Phuoc, C.M. Hung, N.V. Toan, N.V. Duy, N.D. Hoa, N.V. Hieu, "One-step fabrication of SnO2 porous nanofiber gas sensors for sub-ppm H2S detection", Sens. Actuators A Phys. 303, (2020), 111722. CrossRef A.E. Deniz, H.A. Vural, B. Ortac, T. Uyar, "Gold nanoparticle/polymer nanofibrous composites by laser ablation and electrospinning", Matter. Lett. 65, (2011), 2941-2943. CrossRef S. Sagadevan, J. Podder, "Investigation on Structural, Surface Morphological and Dielectric Properties of Zn-doped SnO2 Nanoparticles", Mater. Res. 19, (2016), 420-425. CrossRef

Physiological events related to oxygen concentration gradients provide valuable information to determine the state of metabolizing biological cells. The existing oxygen sensing methods (i.e., optical photoluminescence, magnetic resonance, and scanning electrochemical) are well-established and optimized for existing in vitro analyses. However, such methods also present various limitations in resolution, real-time sensing performance, complexity, and costs. An electrochemical imaging system with an integrated microelectrode array (MEA) would offer attractive means of measuring oxygen consumption rate (OCR) based on the cell’s two-dimensional (2D) oxygen concentration gradient. This paper presents an application of an electrochemical sensor platform with a custom-designed complementary-metal-oxide-semiconductor (CMOS)-based microchip and its Pt-coated surface MEA. The high-density MEA provides 16,064 individual electrochemical pixels that cover a 3.6 mm × 3.6 mm area. Utilizing the three-electrode configuration, the system is capable of imaging low oxygen concentration (18.3 µM, 0.58 mg/L, or 13.8 mmHg) at 27.5 µm spatial resolution and up to 4 Hz temporal resolution. In vitro oxygen imaging experiments were performed to analyze bovine cumulus-oocytes-complexes cells OCR and oxygen flux density. The integration of a microfluidic system allows proper bio-sample handling and delivery to the MEA surface for imaging. Finally, the imaging results are processed and presented as 2D heatmaps, representing the dissolved oxygen concentration in the immediate proximity of the MEA. This paper provides the results of real-time 2D imaging of OCR of live cells/tissues to gain spatial and temporal dynamics of target cell metabolism.

In recent times, ab initio density functional theory has emerged as a powerful tool for making the connection between models and materials. Insulating transition metal oxides with a small spin forms a fascinating class of strongly correlated systems that exhibit spin-gap states, spin–charge separation, quantum criticality, superconductivity, etc. The coupling between spin, charge, and orbital degrees of freedom makes the chemical insights equally important to the strong correlation effects. In this review, we establish the usefulness of ab initio tools within the framework of the N-th order muffin orbital (NMTO)-downfolding technique in the identification of a spin model of insulating oxides with small spins. The applicability of the method has been demonstrated by drawing on examples from a large number of cases from the cuprate, vanadate, and nickelate families. The method was found to be efficient in terms of the characterization of underlying spin models that account for the measured magnetic data and provide predictions for future experiments.

The magnetic-field–tuned superconductor-to-insulator transition was studied in a hybrid system of superconducting indium islands, deposited on an indium oxide (InOx) thin film, which exhibits global superconductivity at low magnetic fields. Vacuum annealing was used to tune the conductivity of the InOx film, thereby tuning the inergrain coupling and the nature of the transition. The hybrid system exhibits a “giant” magnetoresistance above the magnetic-field–tuned superconductor-to-insulator transition (H-SIT), with critical behavior similar to that of uniform InOx films but at much lower magnetic fields, that manifests the duality between Cooper pairs and vortices. A key feature of this hybrid system is the separation between the quantum criticality and the onset of nonequilibrium behavior.

Studies of spin-resolved electron momentum densities involve the measurement of the so-called magnetic Compton profile. This is a one-dimensional projection of the electron momentum distribution of only those electrons that contribute to the spin moment of a sample. The technique is applicable to ferri- and ferromagnetic materials. Since electrons originating from different atomic orbitals have specific momentum densities, it is often possible to determine the origin of the magnetism present. Typically, interpretation requires the use of electronic structure calculations using molecular orbital and band structure approaches. The profile is obtained experimentally via the inelastic "Compton" scattering of high energy X-rays. For the experiments discussed here, the high energy beamlines at the ESRF and SPring-8 synchrotron X-ray sources were used, where we have a cryomagnet which can provide a sample environment with applied magnetic fields up to 9 Tesla, at temperatures from 1.3K to 600K. In this talk, we discuss our combined experimental and theoretical study of the spin density of the low-dimensional frustrated metamagnet Ca3Co2O6. The spin moment, measured using magnetic Compton scattering, confirms the existence of a large unquenched Co orbital moment (1.310.1 μB). With regards to the orbital occupation, we have performed molecular orbital calculations on the active trigonal CoO6cluster in order to determine which Co 3d orbitals are responsible for the observed electronic and magnetic behaviour and the observed orbital moment, and revealing the existence a oxygen spin moment of approximately 0.9 μB. Electronic structure calculations with a Hubbard U energy term give Compton profiles which are in good agreement with our experimental data. The magnetic Compton profile exhibits oscillations, which are well described, and their frequency in momentum space corresponds to the real-space inter-cobalt site bond length.

Two carboxylate-bridged one-dimensional chain complexes, {[MnII(MeOH)2][FeIII(L)2]2}n (1) and {[MnII(DMF)2][MnIII(L)2]2·DMF}n (2) [H2L = ((2-carboxyphenyl)azo)-benzaldoxime], containing a low-spin [FeIII(L)2]− or [MnIII(L)2]− unit were synthesized. Magnetic measurements show that the adjacent high-spin MnII and low-spin MIII ions display weak antiferromagnetic coupling via the syn–anti carboxyl bridges, with J = −0.066(2) cm−1 for complex 1 and J = −0.274(2) cm−1 for complex 2.

Abstract Defects exist ubiquitously in crystal materials, and usually exhibit a very different nature from the bulk matrix. Hence, their presence can have significant impacts on the properties of devices. Although it is well accepted that the properties of defects are determined by their unique atomic environments, the precise knowledge of such relationships is far from clear for most oxides because of the complexity of defects and difficulties in characterization. Here, we fabricate a 36.8° SrRuO3 grain boundary of which the transport measurements show a spin-valve magnetoresistance. We identify its atomic arrangement, including oxygen, using scanning transmission electron microscopy and spectroscopy. Based on the as-obtained atomic structure, the density functional theory calculations suggest that the spin-valve magnetoresistance occurs because of dramatically reduced magnetic moments at the boundary. The ability to manipulate magnetic properties at the nanometer scale via defect control allows new strategies to design magnetic/electronic devices with low-dimensional magnetic order.

The purpose of this paper was to detect and separate the cluster intensity provided by Iron oxide nanoparticles (IO-NPs), in the MRI images, to investigate the drug delivery effectiveness. IO-NPs were attached to the macrophages and inserted into the eye of the inflamed mouse’s calf. The low resolution of MRI and the tiny dimension of the IO-NPs made the situation challenging. IO-NPs serve as a marker, due to their strong intensity in the MRI, enabling us to follow the track of the macrophages. An image processing procedure was developed to estimate the position and the amount of IO-NPs spreading inside the inflamed mouse leg. A fuzzy Clustering algorithm was adopted to select the region of interest (ROI). A 3D model of the femoral region was used for the detection and then the extraction IO-NPs in the MRI images. The results achieved prove the effectiveness of the proposed method to improve the control process of targeted drug delivered. It helps in optimizing the treatment and opens a promising novel research axis for nanomedicine applications.

We extend the BSC theory to the strong electron-phonon (magnon) coupling limit. We show that the formation of small polarons and bipolarons provides a number of new physical phenomena both in the normal and superconducting states and explains low-energy physics of high-Tc superconductors. Both lattice and spin (bi)polarons are discussed. A highly nonadiabatic motion of bipolarons leads to a unique physical nature of (bi)polaronic superconductivity, making it totally different from that of the BCS one, including its wellknown strong-coupling generalization. The maximum attainable Tc is estimated to be in the region of the transition from the Fermi-liquid to a charged Bose-liquid. Some evidence for 2e bosons is given from NMR, neutron scattering, near-infrared absorption, Hall effect, resistivity, thermal conductivity, and critical magnetic fields of high-Tc oxides. An infinite thermal conductivity of two-dimensional charged bosons is predicted below Tc. The insulator-metal transition and ARPES in copper oxides are also discussed. The proposed theory is not restricted by low dimensionality and might be applied to cubic oxides like BaPbBiO and to alkali-doped C 60.

Nanomedicine targeted drug delivery is one of the emerging techniques for diagnosis and treatment of complex diseases. Medical image processing of High-Resolution Magnetic Resonance Imaging (HR-MRI), when combined with iron oxide nanoparticles (IO-NPs), provides a precious tool to monitor diagnosis and treatment processes. The challenge is to detect the nanoparticles inside the HR-MRI images. This is due to the low resolution of the images and the small size of the nanoparticles. In this paper, we study the drug delivery efficiency using a mouse with an inflamed calf, with IO-NPs attached to the therapeutic drug and injected into the mouse's eye. Our aim is to know how much of the drug injected will reach the inflamed region of the calf. A high-resolution MRI system was used to take images of the inflamed calf region. Knowing that iron oxide has a strong magnetic intensity on MRI images, image processing techniques were used to identify the location and quantity of IO-NPs attached to the drug. By knowing the location and quantity of IO-NPs we can estimate the quantity of drug delivered to the region of interest. In our project, K-mean algorithm, an automatic clustering algorithm was used to detect the iron oxide NPs in the MRI images. This then extracts them from the 3D model of the femoral region of interest. Extraction of NPs permits an estimation of the number of NPs clustered in the region and furthermore estimates the quantity of the drug delivered to the region of interest. The results obtained of nanoparticle detection and extraction seem to be a promising way to estimate the amount of delivered drug to a targeted area.

Magnets based on metal oxides have been important for hundreds of years. Magnetite, Fe3O4, Co-doped γ-Fe2O3, and CrO2 are important examples. The oxide (O2-) bridge between the magnetic metal ions has filled p orbitals (Figure 1a) that provide the pathway for strong spin coupling. Albeit with twice as many atoms, cyanide (C≡N−) can bridge between two metal ions via its pair of empty antibonding orbitals (Figure 1b) and filled nonbonding orbitals. Even prior to a detailed understanding of either their composition or structure, magnetic ordering of several cyanide complexes, although at low temperature, was noted. The differing atoms at each end of the cyanide ion have different binding affinities to metal ions, and simple coordination compounds, for example, [FeII(CN)6]2− (ferrocyanide), with alkali cations can easily be made. Replacement of the alkali cations with transition-metal cations affords insoluble materials, for example FeIII4[FeII(CN)6]3 (Prussian blue). Prussian blue has been used as a pigment and as an electrochromic and electrocatalyst material. The structure of Prussian blue was elucidated to be cubic (isotropic) with ⟶FeII⟵C≡N⟶FeIII⟵N≡C⟶FeII⟵ linkages along all three crystallographic directions (Figure 2). The FeII … FeIII separation is ∼5 Å. However, based on the composition, this is an idealized structure, as one FeII site per unit cell is missing. Water fills the vacant sites as well as the channels present in the structure. Due to the structural defects, it has been a challenge to grow single crystals.

Since the discovery, research on iron-based superconductivity (SC) has become one of the main streams in condensed matter physics [1]. The interplay between structure, magnetism and SC is one of most intriguing subjects of this field. The common structural feature is the presence of square planar sheets of Fe atoms coordinated tetrahedrally by pnictogens or chalcogens. They have been, at the early stage, realized in the ZrCuSiAs (1111), ThCr2Si2 (122), anti-PbO (11) and Cu2Sb (111) structures. To gain further insight into the mechanism of the SC and variation of magnetic orders, investigation of Fe-based compounds with a separate spatial dimension is important. This is because the dimensionality should influence magnetism and can control itinerancy of electrons by changing Fermi surface topology. As spin ladders in copper oxides shed a new light on the mechanism of SC, a study on an analogue with ladder geometry among Fe-based compounds is highly desired. Here we report our recent studies of iron-based ladder compounds AFe2X3 (A = K, Rb, Cs, Ba; X = S, Se, Te) [2,3]. Crystal structure is novel, comprising of FeX4 tetrahedra with channels which host A atoms, and four-fold coordinated Fe2+ ions form two-leg ladder geometry. Unlike most of parent compounds of the Fe-based SCs, the ladder compounds are insulating down to the lowest measured temperature. Through bulk properties and neutron diffraction measurements, a variety of magnetic structures and low dimensional characteristics were elucidated. These would provide a clue of the SC realized in a separate dimension systems. The description of theory that accounts for the observed magnetic structures will be also presented.

This article provides the review of the medical use of pH- and temperature-sensitive polymer hydrogels. Such polymers are characterised by their thermal and pH sensitivity in aqueous solutions at the functioning temperature of living organisms and can react to the slightest changes in environmental conditions. Due to these properties, they are called stimuli-sensitive polymers. This response to an external stimulus occurs due to the amphiphilicity (diphilicity) of these (co)polymers. The term hydrogels includes several concepts of macrogels and microgels. Microgels, unlike macrogels, are polymer particles dispersed in a liquid and are nano- or micro-objects. The review presents studies reflecting the main methods of obtainingsuch polymeric materials, including precipitation polymerisation, as the main, simplest, and most accessible method for mini-emulsion polymerisation, microfluidics, and layer-by-layer adsorption of polyelectrolytes. Such systems will undoubtedly be promising for use in biotechnology and medicine due to the fact that they are liquid-swollen particles capable of binding and carrying various low to high molecular weight substances. It is also important that slight heating and cooling or a slight change in the pH of the medium shifts the system from a homogeneous to a heterogeneous state and vice versa. This providesthe opportunity to use these polymers as a means of targeted drug delivery, thereby reducing the negative effect of toxic substances used for treatment on the entire body and directing the action to a specific point. In addition, such polymers can be used to create smart coatings of implanted materials, as well as an artificial matrix for cell and tissue regeneration, contributing to a significant increase in the survival rate and regeneration rate of cells and tissues. References 1. Gisser K. R. C., Geselbracht M. J., Cappellari A.,Hunsberger L., Ellis A. B., Perepezko J., et al. 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AbstractWe have examined the novel heteroepitaxy of magnetic oxide thin films on ultra-smooth sapphire substrates by laser MBE for fabrication of low-dimensional structures. Employing the atomically controlled substrate surfaces with atomic steps and terraces, we demonstrate the deposition of magnetic oxide nanowires (~0.5 nm high and ~20 nm wide) and nanodots of (Mn, Zn) ferrite, Fe3O4 and NiO.

AbstractVery few materials show large magnetoresistance (MR) under a low magnetic field at room temperature, which causes the barrier to the development of magnetic field sensors for detecting low-level electromagnetic radiation in real- time. Here, a hybrid reduced graphene oxide (rGO)-based magnetic field sensor is produced by in situ deposition of FeCo nanoparticles (NPs) on reduced graphene oxide (rGO). Special quantum magnetoresistance (MR) of the hybrid rGO is observed, which unveils that Abrikosov’s quantum model for layered materials can occur in hybrid rGO; meanwhile, the MR value can be tunable by adjusting the particle density of FeCo NPs on rGO nanosheets. Very high MR value up to 21.02 ± 5.74% at 10 kOe at room temperature is achieved, and the average increasing rate of resistance per kOe is up to 0.9282 Ω kOe−1. In this paper, we demonstrate that the hybrid rGO-based magnetic field sensor can be embedded in a wireless system for real-time detection of low-level electromagnetic radiation caused by a working mobile phone. We believe that the two-dimensional nanomaterials with controllable MR can be integrated with a wireless system for the future connected society.

AbstractMany experiments investigating magnetic-field tuned superconductor-insulator transition (H-SIT) often exhibit low-temperature resistance saturation, which is interpreted as an anomalous metallic phase emerging from a ‘failed superconductor’, thus challenging conventional theory. Here we study a random granular array of indium islands grown on a gateable layer of indium-oxide. By tuning the intergrain couplings, we reveal a wide range of magnetic fields where resistance saturation is observed, under conditions of careful electromagnetic filtering and within a wide range of linear response. Exposure to external broadband noise or microwave radiation is shown to strengthen the tendency of superconductivity, where at low field a global superconducting phase is restored. Increasing magnetic field unveils an ‘avoided H-SIT’ that exhibits granularity-induced logarithmic divergence of the resistance/conductance above/below that transition, pointing to possible vestiges of the original emergent duality observed in a true H-SIT. We conclude that anomalous metallic phase is intimately associated with inherent inhomogeneities, exhibiting robust behavior at attainable temperatures for strongly granular two-dimensional systems.