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Journal articles on the topic 'Low temperature matrix-isolation'

Author: Grafiati

Published: 24 April 2022

Last updated: 30 July 2025

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1

NAKATA, Munetaka. "Application of Low-Temperature Matrix-Isolation Infrared Spectroscopy to Carbon Clusters." Hyomen Kagaku 14, no. 4 (1993): 215–21. http://dx.doi.org/10.1380/jsssj.14.215.

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2

Bugalho, Susana C. S., Ermelinda M. S. Maçôas, M. Lurdes S. Cristiano, and Rui Fausto. "Low temperature matrix-isolation and solid state vibrational spectra of tetrazole." Physical Chemistry Chemical Physics 3, no. 17 (2001): 3541–47. http://dx.doi.org/10.1039/b103344c.

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3

Coleman, W. M., and Bert M. Gordon. "Examination of the Matrix Isolation Fourier Transform Infrared Spectra of Organic Compounds: Part VI." Applied Spectroscopy 42, no. 1 (1988): 101–8. http://dx.doi.org/10.1366/0003702884428545.

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Matrix isolation Fourier transform spectral evidence is presented that documents the isolation of rotational isomers in an argon matrix. The spectral evidence is based on the presence of split carbonyl absorption bands in the spectra of selected derivatives of methyl acetate which do not vary in intensity with changes in the matrix-to-eluate ratios. The results compare very favorably with FT-IR data on the identical compounds obtained in the vapor phase. The low temperature of the matrix isolation experiment (10 K) allows for the observance of rotational isomers not seen at the high temperatur

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4

Chattopadhyay, Nitin, Igor Reva, Leszek Lapinski, Rui Fausto, Luis G. Arnaut та Sebastião J. Formosinho. "Photoisomerization ofp-(Dimethylamino)-β-chlorostyrene: A Low Temperature Matrix Isolation FTIR Study". Journal of Physical Chemistry A 106, № 15 (2002): 3722–26. http://dx.doi.org/10.1021/jp013715c.

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5

Ryazantsev, Sergey V., Daniil A. Tyurin, Kirill B. Nuzhdin, Vladimir I. Feldman, and Leonid Khriachtchev. "The HKrCCH⋯CO2 complex: an ab initio and matrix-isolation study." Physical Chemistry Chemical Physics 21, no. 7 (2019): 3656–61. http://dx.doi.org/10.1039/c8cp04327b.

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6

TAKAYANAGI, MASAO. "Applications of the Low-Temperature Rare-Gas Matrix-Isolation Technique to Dye Molecules." Journal of the Spectroscopical Society of Japan 48, no. 3 (1999): 115–16. http://dx.doi.org/10.5111/bunkou.48.115.

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7

Lopes, Susy, Andrea Gómez-Zavaglia та Rui Fausto. "Matrix isolation and low temperature solid state FTIR spectroscopic study of α-furil". Phys. Chem. Chem. Phys. 8, № 15 (2006): 1794–806. http://dx.doi.org/10.1039/b516164a.

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8

Saenko, Elizaveta V., and Vladimir I. Feldman. "Radiation-induced transformations of methanol molecules in low-temperature solids: a matrix isolation study." Physical Chemistry Chemical Physics 18, no. 47 (2016): 32503–13. http://dx.doi.org/10.1039/c6cp06082j.

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9

Toumi, A., N. Piétri, and I. Couturier-Tamburelli. "Infrared study of matrix-isolated ethyl cyanide: simulation of the photochemistry in the atmosphere of Titan." Physical Chemistry Chemical Physics 17, no. 45 (2015): 30352–63. http://dx.doi.org/10.1039/c5cp03616j.

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10

Agarwal, U. P., A. J. Barnes, and W. J. Orville-Thomas. "Hydrogen sulphide – halogen complexes studied by matrix isolation vibrational spectroscopy." Canadian Journal of Chemistry 63, no. 7 (1985): 1705–7. http://dx.doi.org/10.1139/v85-286.

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Infrared spectra are reported of mixtures of hydrogen sulphide with chlorine or bromine in low-temperature argon or nitrogen matrices. The H2S … Cl2 and H2S … Br2 complexes were identified from the perturbed halogen stretching vibration. Absorptions due to the corresponding hydrogen halides provided evidence that reaction was occurring between the hydrogen sulphide and halogen (despite the use of a twin-jet deposition), and other reaction products were tentatively identified from the observed absorptions.

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11

Komaguchi, Kenji. "8 Low-temperature Matrix-isolation ESR Technique and Radiolysis of Methane in Solid Ar." RADIOISOTOPES 66, no. 10 (2017): 459–67. http://dx.doi.org/10.3769/radioisotopes.66.459.

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12

Travers, Michael J., Erika L. Eldenburg, and Julanna V. Gilbert. "Low-Temperature Matrix Isolation Studies of BCl(N3)2: Infrared Spectra and Photolysis Processes." Journal of Physical Chemistry A 103, no. 48 (1999): 9661–68. http://dx.doi.org/10.1021/jp991898l.

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13

Gómez-Zavaglia, A., and R. Fausto. "Matrix-isolation and solid state low temperature FT-IR study of 2,3-butanedione (diacetyl)." Journal of Molecular Structure 661-662 (December 2003): 195–208. http://dx.doi.org/10.1016/j.molstruc.2003.06.003.

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14

Smyrnova, Daryna, та Stepan Stepanian. "Low Temperature Matrix Isolation IR-Spectroscopy and Quantum Chemical Study of β-Alanine Structure". Biophysical Journal 102, № 3 (2012): 596a. http://dx.doi.org/10.1016/j.bpj.2011.11.3248.

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15

Sieber, Klaus, JÖRg Ohlmann, and JÜRgen Hüttermann. "Matrix-Isolation of Free Radicals from Purines and Derivatives in Aqueous Low Temperature Glasses." Free Radical Research Communications 6, no. 2-3 (1989): 95–96. http://dx.doi.org/10.3109/10715768909073437.

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16

Soares, Maria I. L., Cláudio M. Nunes, Clara S. B. Gomes, Teresa M. V. D. Pinho e Melo, and Rui Fausto. "Conformational behaviour, photochemistry and flash vacuum pyrolysis of a 2-(1H-tetrazol-1-yl)thiophene." New Journal of Chemistry 41, no. 24 (2017): 15581–89. http://dx.doi.org/10.1039/c7nj02775c.

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The conformational and photochemical behaviour of a 2-(1H-tetrazol-1-yl)thiophene was studied using low-temperature matrix isolation infrared spectroscopy and theoretical calculations. FVP of 2-(1H-tetrazol-1-yl)thiophene afforded new thieno-fused heterocycles.

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17

Hayashi, Masazumi, Rintaro Ichihara, Nobuyuki Akai, and Munetaka Nakata. "Photoreaction of 2-chlorothiophenol studied by low-temperature matrix-isolation IR spectroscopy with DFT calculation." Journal of Molecular Structure 1244 (November 2021): 130909. http://dx.doi.org/10.1016/j.molstruc.2021.130909.

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18

Johnson, Lisa A., Samantha A. Sturgis, Ismail A. Al-Jihad, Bing Liu, and Julanna V. Gilbert. "Low-Temperature Matrix Isolation and Photolysis of BCl2N3: Spectroscopic Identification of the Photolysis Product ClBNCl." Journal of Physical Chemistry A 103, no. 6 (1999): 686–90. http://dx.doi.org/10.1021/jp9836574.

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19

Knudsen, R., O. Sala, and Y. Hase. "A low temperature matrix isolation infrared study of acetamides. I. Acetamide and some deuterated derivatives." Journal of Molecular Structure 321, no. 3 (1994): 187–95. http://dx.doi.org/10.1016/0022-2860(93)07964-x.

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20

Knudsen, R., O. Sala, and Y. Hase. "A low temperature matrix isolation infrared study of acetamides. II. Thioacetamide and some deuterated derivatives." Journal of Molecular Structure 321, no. 3 (1994): 197–203. http://dx.doi.org/10.1016/0022-2860(93)07965-y.

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21

Mohaček-Grošev, Vlasta. "Low Temperature Raman Spectroscopy of Tetrahydrofuran: Phonon Spectra Compared to Matrix Isolation Spectra in Air." Crystals 14, no. 5 (2024): 468. http://dx.doi.org/10.3390/cryst14050468.

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The conformation of tetrahydrofuran (THF) molecules in vapor has been the subject of considerable computational and experimental studies, the most recent by Park and Kwon stated that the difference between the most stable, twisted C2 conformer and the bent Cs conformer is 17 ± 15 cm−1. Because of low symmetry, all modes from both conformers are allowed in the Raman and infrared spectra. In 1982, Aleksanyan and Antipov observed the emergence of two Raman bands at 249 and 303 cm−1 at 20 K, while only one band at 293 cm−1 was present in solid THF at 142. They assigned the 249 cm−1 band to the res

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22

Fetzer, John C., W. R. Biggs, and Maximilian Zander. "Notizen: The Preparation and Purification of Perhydrocoronene for Use as a Spectroscopic Matrix." Zeitschrift für Naturforschung A 46, no. 3 (1991): 291–92. http://dx.doi.org/10.1515/zna-1991-0313.

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Abstract Perhydrocoronene has recently been studied as a matrix in low and high temperature luminescence spectroscopy of aromatic compounds. Perhydrocoronene has been found to be a by-product formed during the catalytic hydrocracking of a petroleum feedstock. The isolation and purification of spectroscopy grade perhydrocoronene is described in detail

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23

Sıdır, İsa, Susy Lopes, Timur Nikitin, Yadigar Gülseven Sıdır, and Rui Fausto. "Infrared Spectroscopy and Photochemistry of Ethyl Maltol in Low-Temperature Argon Matrix." Spectroscopy Journal 2, no. 4 (2024): 188–205. http://dx.doi.org/10.3390/spectroscj2040013.

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Ethyl maltol was investigated using matrix isolation infrared spectroscopy and DFT calculations. In an argon matrix (14.5 K), the compound was found to exist in a single conformer (form I), characterized by an intramolecular hydrogen bond with an estimated energy of ~17 kJ mol−1. The IR spectrum of this conformer was assigned, and the molecule’s potential energy landscape was explored to understand the relative stability and isomerization dynamics of the conformers. Upon annealing the matrix to 41.5 K, ethyl maltol was found to predominantly aggregate into a centrosymmetric dimer (2× conformer

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24

Nishiya, Teruhiko, Noboru Hirota, Hisanori Shinohara, and Nobuyuki Nishi. "Identification of ammonia clusters in low-temperature matrixes using the FTIR short-pulsed matrix isolation technique." Journal of Physical Chemistry 89, no. 11 (1985): 2260–64. http://dx.doi.org/10.1021/j100257a022.

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25

Nishino, Satoshi, and Munetaka Nakata. "Intramolecular Hydrogen Atom Tunneling in 2-Chlorobenzoic Acid Studied by Low-Temperature Matrix-Isolation Infrared Spectroscopy." Journal of Physical Chemistry A 111, no. 30 (2007): 7041–47. http://dx.doi.org/10.1021/jp0717600.

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26

Travers, Michael J., Erika L. Eldenburg, and Julanna V. Gilbert. "ChemInform Abstract: Low-Temperature Matrix Isolation Studies of BCl(N3)2: Infrared Spectra and Photolysis Processes." ChemInform 31, no. 8 (2010): no. http://dx.doi.org/10.1002/chin.200008002.

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27

Miyazaki, Jun, Hiroshi Takiyama, and Munetaka Nakata. "Isocyano compounds newly recognized in photochemical reaction of thiazole: matrix-isolation FT-IR and theoretical studies." RSC Advances 7, no. 9 (2017): 4960–74. http://dx.doi.org/10.1039/c6ra27496j.

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UV-induced photoreactions of thiazole isolated in low-temperature argon matrices have been investigated, leading to the conclusion that photoproducts identified newly, including three kind isocyano compounds, are produced by ring-opening reaction.

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28

Miyazaki, Yasunori, Yoshiya Inokuchi, Nobuyuki Akai, and Takayuki Ebata. "Direct Spectroscopic Evidence of Photoisomerization in para-Methoxy Methylcinnamate Revealed by Low-Temperature Matrix-Isolation FTIR Spectroscopy." Journal of Physical Chemistry Letters 6, no. 7 (2015): 1134–39. http://dx.doi.org/10.1021/acs.jpclett.5b00203.

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29

Johnson, Lisa A., Samantha A. Sturgis, Ismail A. Al-Jihad, Bing Liu, and Julanna V. Gilbert. "ChemInform Abstract: Low-Temperature Matrix Isolation and Photolysis of BCl2N3: Spectroscopic Identification of the Photolysis Product ClBNCl." ChemInform 30, no. 20 (2010): no. http://dx.doi.org/10.1002/chin.199920015.

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30

Volkova, Vera V., Leonid E. Gusel'nikov, and Gerhard Zimmermann. "Low-temperature matrix-isolation infrared spectroscopy — a method to characterize reactive species from low-pressure pyrolysis of hydrocarbons for mechanistic elucidations." Journal of Analytical and Applied Pyrolysis 23, no. 3 (1992): 265–86. http://dx.doi.org/10.1016/0165-2370(92)80021-d.

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31

Chandra, Swaroop, B. Suryaprasad, N. Ramanathan та K. Sundararajan. "Dominance of unique P⋯π phosphorus bonding with π donors: evidence using matrix isolation infrared spectroscopy and computational methodology". Physical Chemistry Chemical Physics 22, № 36 (2020): 20771–91. http://dx.doi.org/10.1039/d0cp02880k.

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32

Yalpani, Mohamed, and E. Klotzbücher. "Transformations in Thin Solid Layers: The Reversible Polymerization-Depolymerization of 2,6-Di-n-propyl- 1,3,5,7-tetraoxa-2,6-dibora-4,8-octalindiones at Low Temperatures." Zeitschrift für Naturforschung B 40, no. 2 (1985): 222–28. http://dx.doi.org/10.1515/znb-1985-0213.

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The course of Aggregation of molecules of the title compound (1b) through different, spectroscopically discernible and chemically identifiable forms of associations could be followed by matrix isolation and thin film infrared and UV-visible spectroscopy. It was found that molecules of 1b in thin films form clusters which at low temperatures interact weakly, probably through the carbonyl oxygens of one and the boron atoms of the neighbouring molecules. On warming to 260 K this association gradually takes the form of more defined chelate bonds, probably with ordered three-dimensional intermolecu

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33

Akai, Nobuyuki, Satoshi Kudoh, Masao Takayanagi, and Munetaka Nakata. "Photoreaction mechanisms of 2-bromophenols studied by low-temperature matrix-isolation infrared spectroscopy and density-functional-theory calculation." Chemical Physics Letters 363, no. 5-6 (2002): 591–97. http://dx.doi.org/10.1016/s0009-2614(02)01294-0.

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34

Fausto, Rui, Ermelinda M. S. Maçôas, and A. Kulbida. "Structure elucidation and photochemistry of substituted carboxylic compounds by low temperature matrix-isolation and solid state vibrational spectroscopy." Journal of Molecular Structure 480-481 (May 1999): 83–99. http://dx.doi.org/10.1016/s0022-2860(98)00654-1.

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35

Nakata, Munetaka. "Dynamics of Molecules and Clusters Studied by Low-Temperature Matrix-Isolation Infrared Spectroscopy and Density-Functional-Theory Calculations." Bulletin of the Chemical Society of Japan 75, no. 6 (2002): 1173–89. http://dx.doi.org/10.1246/bcsj.75.1173.

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36

Minatoyama, Misaki, Nobuyuki Akai, Emi Yamada та ін. "Degradation mechanism of γ-irradiated polytetrafluoroethylene (PTFE) powder by low-temperature matrix-isolation infrared spectroscopy and chemiluminescence spectroscopy". Polymer Journal 48, № 6 (2016): 697–702. http://dx.doi.org/10.1038/pj.2015.139.

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37

KNUDSEN, R., O. SALA, and Y. HASE. "ChemInform Abstract: A Low Temperature Matrix Isolation Infrared Study of Acetamides. Part 1. Acetamide and Some Deuterated Derivatives." ChemInform 25, no. 40 (2010): no. http://dx.doi.org/10.1002/chin.199440038.

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38

KNUDSEN, R., O. SALA, and Y. HASE. "ChemInform Abstract: A Low Temperature Matrix Isolation Infrared Study of Acetamides. Part 2. Thioacetamide and Some Deuterated Derivatives." ChemInform 25, no. 40 (2010): no. http://dx.doi.org/10.1002/chin.199440039.

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39

Koizumi, Yoshiko, Shu Seki, Anjali Acharya, Akinori Saeki, and Seiichi Tagawa. "Delocalization of Positive and Negative Charge Carriers on Oligo- and Poly-fluorenes Studied by Low-Temperature Matrix Isolation Technique." Chemistry Letters 33, no. 10 (2004): 1290–91. http://dx.doi.org/10.1246/cl.2004.1290.

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40

Velasco-Cuervo, Isabel C., Erika D. Lemos-Micolta, Ingrid E. Madera-Sierra, et al. "Impact of Aging and Low Temperatures on the Mechanical Properties of Low-Cost Seismic Isolator Prototypes." Buildings 15, no. 13 (2025): 2238. https://doi.org/10.3390/buildings15132238.

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Seismic isolation systems are an effective passive protection strategy that decouples structures from ground motion. Their performance depends heavily on the elastomeric materials used, which must retain mechanical integrity under environmental stressors. In recent years, low-cost isolators made from natural and recycled rubber have gained attention as an affordable solution for protecting low-rise buildings in seismic-prone developing regions, particularly due to their environmental benefits and ease of installation. However, their long-term performance under real environmental conditions rem

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41

Kugel, Roger W., and Bruce S. Ault. "Infrared Matrix-Isolation and Theoretical Studies of the Reactions of Bis(benzene)chromium with Ozone." Molecules 29, no. 15 (2024): 3583. http://dx.doi.org/10.3390/molecules29153583.

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Reactions of bis(benzene)chromium (Bz2Cr) and ozone (O3) were studied using low-temperature argon matrix-isolation infrared spectroscopy with supporting DFT calculations. When Bz2Cr and O3 were co-deposited, they reacted upon matrix deposition to produce two new prominent peaks in the infrared spectrum at 431 cm−1 and 792 cm−1. These peaks increased upon annealing the matrix to 35 K and decreased upon UV irradiation at λ = 254 nm. The oxygen-18 and mixed oxygen-16,18 isotopic shift pattern of the peak at 792 cm−1 is consistent with the antisymmetric stretch of a symmetric ozonide species. DFT

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42

VOLKOVA, V. V., L. E. GUSEL'NIKOV, and G. ZIMMERMANN. "ChemInform Abstract: Low-Temperature Matrix-Isolation Infrared Spectroscopy - A Method to Characterize Reactive Species from Low-Pressure Pyrolysis of Hydrocarbons for Mechanistic Elucidations." ChemInform 24, no. 11 (2010): no. http://dx.doi.org/10.1002/chin.199311345.

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43

Coleman, W. M., and Bert M. Gordon. "Examinations of the Matrix Isolation Fourier Transform Infrared Spectra of Organic Compounds: Part XVI." Applied Spectroscopy 43, no. 6 (1989): 1008–16. http://dx.doi.org/10.1366/0003702894203895.

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Information concerning the matrix isolation Fourier transform infrared spectra of a series of alkanes, esters, lactones, lactams, phenols, alcohols, amides, alkenes, and ketones is presented. A comparison between the characteristics of the spectra in two matrices (argon and xenon) as well as in the absence of any matrix (bare gold disk) is drawn. The impact of these matrices on the characteristics of the IR spectra is compared with the impact observed when spectra are gathered in the vapor phase as well as the condensed phase/solid state. For the majority of compounds studied, the major absorp

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44

Wentrup, Curt, and David Kvaskoff. "1,5-(1,7)-Biradicals and Nitrenes Formed by Ring Opening of Hetarylnitrenes." Australian Journal of Chemistry 66, no. 3 (2013): 286. http://dx.doi.org/10.1071/ch12502.

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Several aromatic and heteroaromatic nitrenes and carbenes undergo photochemical and sometimes also thermal ring opening. Depending on benz-annelation, the ring-opened species may have the character of either nitrenes (for α-annelation) or 1,5-(1,7-)-biradicals (for β-annelation). Both types have been observed, and they are clearly distinguished by their characteristic electron spin resonance spectra. In addition, ring opening of hetarylnitrenes to nitrile ylides can be observed whenever there is a meta-relationship between a ring nitrogen atom and the nitrene (or carbene) centre. The factors g

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45

Sundararajan, K., and N. Ramanathan. "Dimethoxymethane–Hydrogen Chloride Interaction: Gas Phase versus Low-Temperature Behavior Studied Using Matrix Isolation Infrared and Density Functional Theory Methods." Journal of Physical Chemistry A 117, no. 11 (2013): 2347–57. http://dx.doi.org/10.1021/jp400332v.

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46

Futami, Yoshisuke, Maisy Lim Siaw Chin, Satoshi Kudoh, Masao Takayanagi, and Munetaka Nakata. "Conformations of nitro-substituted spiropyran and merocyanine studied by low-temperature matrix-isolation infrared spectroscopy and density-functional-theory calculation." Chemical Physics Letters 370, no. 3-4 (2003): 460–68. http://dx.doi.org/10.1016/s0009-2614(03)00136-2.

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47

Tarczay, György, Karolina Haupa, and Yuan-Pern Lee. "On the correlation of the abundances of HNCO and NH2CHO: Advantages of solid para-H2 to study astrochemical H-atom addition and abstraction reactions." Proceedings of the International Astronomical Union 15, S350 (2019): 394–96. http://dx.doi.org/10.1017/s1743921319008378.

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AbstractIn dense interstellar clouds that are shielded from high-energy radiation (e.g., UV photons or cosmic rays), H-atom addition and abstraction reactions that take place on grain surfaces play principal roles in the synthesis or decomposition of complex organic molecules (COMs). These reactions are extensively investigated with laboratory experiments by bombarding astrophysical analogue ices with a beam of low-temperature H atoms. Here we demonstrate that, although 2-4 K solid para-H2 does not represent a typical environment of the surface of interstellar grains, para-H2 matrix isolation

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48

Akai, Nobuyuki, Satoshi Kudoh, and Munetaka Nakata. "Lowest excited triplet states of 1,2- and 1,4-dicyanobenzenes by low-temperature matrix-isolation infrared spectroscopy and density-functional-theory calculation." Chemical Physics Letters 371, no. 5-6 (2003): 655–61. http://dx.doi.org/10.1016/s0009-2614(03)00329-4.

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49

Leboucher, Heloïse, Joëlle Mascetti, Christian Aupetit, Jennifer A. Noble, and Aude Simon. "Water Clusters in Interaction with Corannulene in a Rare Gas Matrix: Structures, Stability and IR Spectra." Photochem 2, no. 2 (2022): 237–62. http://dx.doi.org/10.3390/photochem2020018.

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The interaction of polycyclic aromatic hydrocarbons (PAHs) with water is of paramount importance in atmospheric and astrophysical contexts. We report here a combined theoretical and experimental study of corannulene-water interactions in low temperature matrices and of the matrix’s influence on the photoreactivity of corannulene with water. The theoretical study was performed using a mixed density functional based tight binding/force field approach to describe the corannulene-water clusters trapped in an argon matrix, together with Born-Oppenheimer molecular dynamics to determine finite-temper

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50

Falcony, Ciro, Denise Estrada-Wiese, Jessica De Anda, Oscar Pérez-Díaz, and Mariano Aceves-Mijares. "Low temperature (<700 °C) SiO₂ and Si-rich SiO₂ films: Short review." Journal of Vacuum Science & Technology B 41, no. 3 (2023): 030801. http://dx.doi.org/10.1116/6.0002531.

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SiO2 layers deposited at temperatures (lower than 700 °C) have attracted a great deal of attention for a large variety of applications, since they can be used for dielectric isolation, a needed approach for multilayer, multifunctional coatings that exhibit two or more properties simultaneously. A similar phenomenon occurred with Si-rich SiO2, a two-phase material in which excess silicon, introduced during the deposition process of the films, forms a Si inclusion phase uniformly embedded in a SiO2 matrix, modifying its optical and electrical characteristics. In this short review, the synthesis

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