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1

Muradova, P. A. "MICROWAVE RADIATION STIMULATED REACTION OF ACYLATION OF DIETHYL-AMINE WITH M-TOLUIC ACID IN THE PRESENCE OF Zn-B-P/Al2O3/Al CATALYST." Azerbaijan Chemical Journal, no. 3 (September 22, 2022): 110–16. http://dx.doi.org/10.32737/0005-2531-2022-3-110-116.

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The paper presents the results of microwave synthesis of a Zn-B-P-oxide catalyst, which actively absorbs the energy of microwave radiation, applied to the surface of an aluminum-reinforced Al/γ-Al2O3 carrier, in order to further intensify the process of acylation of diethylamine with m-toluic acid to diethylamide m-toluic acid (DETA) under conditions of exposure to a microwave field. The results ob-tained demonstrate the possibility of realizing the process of acylation of diethylamine with m-toluic acid in a thermal regime, which is formed in the reaction zone due to the transformation of mic
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2

Trivedi, Mahendra Kumar, Alice Branton, Dahryn Trivedi, Gopal Nayak, Gunin Saikia, and Snehasis Jana. "Quantitative Determination of Isotopic Abundance Ratio of 13C, 2H, and 18O in Biofield Energy Treated Ortho and Meta Toluic Acid Isomers." American Journal of Applied Chemistry 3, no. 6 (2015): 217–23. https://doi.org/10.11648/j.ajac.20150306.17.

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O-Toluic acid (OTA) and m-toluic acid (MTA) are two isomers of toluic acid that act as an important organic intermediates, mostly used in medicines and pesticides. The aim of the study was to evaluate the impact of biofield energy treatment on isotopic abundance ratios of 2H/1H, 13C/12C, (PM+1)/PM and 18O/16O, (PM+2)/PM, in toluic acid isomers using gas chromatography-mass spectrometry (GC-MS). The OTA and MTA samples were divided into two parts: control and treated. The control sample remained as untreated, while the treated sample was further divided into four groups as T1, T2, T3, and T4. T
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3

Trivedi, Mahendra Kumar, Alice Branton, Dahryn Trivedi, Gopal Nayak, Gunin Saikia, and Snehasis Jana. "Quantitative Determination of Isotopic Abundance Ratio of 13C, 2H, and 18O in Biofield Energy Treated Ortho and Meta Toluic Acid Isomers." American Journal of Applied Chemistry 3, no. 6 (2015): 217–23. https://doi.org/10.5281/zenodo.192636.

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O-Toluic acid (OTA) and m-toluic acid (MTA) are two isomers of toluic acid that act as an important organic intermediates, mostly used in medicines and pesticides. The aim of the study was to evaluate the impact of biofield energy treatment on isotopic abundance ratios of 2H/1H, 13C/12C, (PM+1)/PM and 18O/16O, (PM+2)/PM, in toluic acid isomers using gas chromatography-mass spectrometry (GC-MS). The OTA and MTA samples were divided into two parts: control and treated. The control sample remained as untreated, while the treated sample was further divided into four groups as T1, T2
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4

Song, Yujun, Kathy T. Hart, and Kerry M. Dooley. "Waste-Reducing Catalytic Oxidation of m-Xylene to m-Toluic Acid." Catalysis Letters 146, no. 7 (2016): 1213–20. http://dx.doi.org/10.1007/s10562-016-1746-1.

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5

Jiang, Quan, Hai-Yang Hu, Can-Cheng Guo, Qiang Liu, Jian-Xin Song, and Qing-Hong Li. "Aerobic liquid-phase oxidation of p-xylene over metalloporphyrins." Journal of Porphyrins and Phthalocyanines 11, no. 07 (2007): 524–30. http://dx.doi.org/10.1142/s1088424607000618.

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The five metalloporphyrins ( T (p- Cl ) PPM , M = Fe , Mn , Co , Cu , Zn ) with different metal nuclei were synthesized, and their catalytic aerobic liquid-phase oxidations of p-xylene into p-toluic acid, p-toluic aldehyde and terephthalic acid using a low concentration of acetic acid as solvent without any halide additives, were studied. The p-xylene conversions and the oxidation product distributions were found to be affected by the structures and concentration of the metalloporphyrins as well as the reaction parameters such as time, temperature and air pressure. The formation of some interm
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6

Gómez, José María, Eduardo Díez, and Ignacio Bernabé. "Deoxygenation of m-toluic acid over hierarchical x zeolite." Catalysis Communications 78 (March 2016): 55–58. http://dx.doi.org/10.1016/j.catcom.2016.02.008.

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7

Redasani, Vivekkumar K., Amol B. Shinde, and Sanjay J. Surana. "Anti-Inflammatory and Gastroprotective Evaluation of Prodrugs of Piroxicam." Ulcers 2014 (August 26, 2014): 1–4. http://dx.doi.org/10.1155/2014/729754.

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Therapeutically potential prodrugs of piroxicam were synthesized by effective masking of enolic hydroxyl group through generation of ester congeners. The reaction facilitated using N,N′-dicyclohexylcarbodiimide coupled with acetic acid, benzoic acid, p-toluic acid, m-toluic acid, and cinnamic acid. Synthesized prodrugs were characterized for confirmation of the said structures. The modification of piroxicam showed better anti-inflammatory activity as evoked by all prodrugs. Interestingly, compound 3e, cinnamic acid ester prodrug, depicted 75 percent inhibition of rat paw edema as compared to 5
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8

Ali, Tammar, Thorsten Heidelberg, and Rusnah Hussen. "Base-Induced Cyclization of Derivatives of Bispropargylated Acetic Acid to m-Toluic Acid." Synlett 26, no. 10 (2015): 1361–64. http://dx.doi.org/10.1055/s-0034-1380513.

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9

Tao, Bao, Zhipeng Sheng, Weiping Luo, Xiaoxiao Sheng, and Qinbo Wang. "Measurement and correlation for solubilities of isophthalic acid and m-toluic acid in binary acetic acid + water and acetic acid + m-xylene solvent mixtures." Journal of Molecular Liquids 262 (July 2018): 549–55. http://dx.doi.org/10.1016/j.molliq.2018.04.086.

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10

Shen, Chi-Yen, and Shuming Tong Wang. "Fabrication of Proton-Exchanged High-Index $\bf LiNbO_{3}$ Waveguides Using m-Toluic Acid." Japanese Journal of Applied Physics 35, Part 2, No. 10B (1996): L1333—L1335. http://dx.doi.org/10.1143/jjap.35.l1333.

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11

Zhukovetska, O. M., O. M. Guzenko, and D. V. Snigur. "LOW TEMPERATURE ANALYTICAL CLOUD POINT EXTRACTION. 1: PROTOLYTIC PROPERTIES OF ACIDIC EXTRACTION INITIATORS IN ORGANIZED MEDIA." Odesa National University Herald. Chemistry 28, no. 3(86) (2023): 62–71. http://dx.doi.org/10.18524/2304-0947.2023.3(86).297826.

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Cloud point extraction is a powerful tool for the analytical preconcentration of trace amounts of analytes. The standard cloud point extraction procedure requires prolonged heating of the solution, which is not always appropriate in the case of thermally unstable analytes or analytical forms and significantly limits the capabilities of the method. One of the ways to modify cloud point extraction is to find approaches to intensifying the process of analytical concentration. The main disadvantage of cloud point extraction is the need for thermal, ultrasonic, infrared or any other initiation of t
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12

Balachandran, V., T. Karthick, S. Perumal, and A. Nataraj. "Vibrational spectroscopic studies, molecular orbital calculations and chemical reactivity of 6-nitro-m-toluic acid." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 92 (June 2012): 137–47. http://dx.doi.org/10.1016/j.saa.2012.02.048.

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13

U., Arvind, and Kumar Sanjay. "Non-specific solvent effects on proton transfer equilibrium between toluic acids and carbinol base of crystal violet." Journal of Indian Chemical Society Vol. 87, Mar 2010 (2010): 361–63. https://doi.org/10.5281/zenodo.5779115.

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Department of Chemistry, Rajendra College, Chapra-841 301, Bihar, India Department of Chemistry, Jagdam College, Chapra-841 301, Bihar, India <em>Manuscript received 27 April 2009, accepted 20 August 2009</em> Acid-base reactions In apolar aprotic media provide a sufficiently close measure of intrinsic acid/base strengths. A study on reaction equilibria between <em>o</em>- and m-methyl benzoic: (toluic) acids with&nbsp;the carbinol base of crystal violet in five apolar aprotic solvents of similar Kirkwood polarity function (\(\in\) - 1)/(2\(\in\)+ 1) and significantly different Dimroth Reichar
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14

Godin, Simon, Pawel Kubica, Anthony Ranchou-Peyruse, et al. "An LC-MS/MS Method for a Comprehensive Determination of Metabolites of BTEX Anaerobic Degradation in Bacterial Cultures and Groundwater." Water 12, no. 7 (2020): 1869. http://dx.doi.org/10.3390/w12071869.

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BTEX (benzene, toluene, ethylbenzene, and the different xylene isomers), known for carcinogenic and neurotoxic effects, are common environmental contaminants. The first step for the development of the bioremediation technologies is the detection of intense microbial degradation in contaminated waters in the quest for the most active bacterial strains. This requires the multispecies analysis for BTEX metabolites which are considered as markers of microbial degradation. A direct (50 µL injection) HPLC–electrospray MS/MS analytical method was developed for the simultaneous analysis of 11 BTEX met
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15

Potapenko, E. V., and I. P. Isaenko. "Catalytic oxidation of m-xylene by ozone in the liquid phase." Voprosy Khimii i Khimicheskoi Tekhnologii, no. 1 (March 2023): 82–88. http://dx.doi.org/10.32434/0321-4095-2023-146-1-82-88.

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This work reports the selective oxidation of m-xylene by ozone in the liquid phase. It is established that the main direction of the reaction is the destruction of the aromatic system when ozone interacts with m-xylene. It is shown that the selective oxidation of m-xylene by ozone occurs at the temperature of 200С in the system Mn(II)–СН3СООН–Н2SO4 with the yield of 3-toluic acid equal to 75–78%. 3-toluyl alcohol and 3-toluyl aldehyde are formed as intermediate oxidation products. At the deeper stages of the reaction, after complete consumption of m-xylene, the following oxidation products of
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16

Yao, Jun, and Alan M. Lambowitz. "Gene Targeting in Gram-Negative Bacteria by Use of a Mobile Group II Intron (“Targetron”) Expressed from a Broad-Host-Range Vector." Applied and Environmental Microbiology 73, no. 8 (2007): 2735–43. http://dx.doi.org/10.1128/aem.02829-06.

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ABSTRACT Mobile group II introns (“targetrons”) can be programmed for insertion into virtually any desired DNA target with high frequency and specificity. Here, we show that targetrons expressed via an m-toluic acid-inducible promoter from a broad-host-range vector containing an RK2 minireplicon can be used for efficient gene targeting in a variety of gram-negative bacteria, including Escherichia coli, Pseudomonas aeruginosa, and Agrobacterium tumefaciens. Targetrons expressed from donor plasmids introduced by electroporation or conjugation yielded targeted disruptions at frequencies of 1 to 5
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17

Liu, Shiu-Mei, and Wei-Chiung Chi. "Effects of the Headspace Gas Composition on Anaerobic Biotransformation ofo-,m-, andp-Toluic Acid in Sediment Slurries." Journal of Environmental Science and Health, Part A 38, no. 6 (2003): 1099–113. http://dx.doi.org/10.1081/ese-120019867.

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18

Lyu, Quanming, Wenbo Zhang, Weizhen Sun, Zhimei Xu, and Ling Zhao. "Determination and correlation of solubility and dissolution thermodynamics of m-toluic acid and isophthalic acid in binary (water plus ethanoic acid) solvent mixtures." Canadian Journal of Chemical Engineering 96, no. 8 (2018): 1814–19. http://dx.doi.org/10.1002/cjce.23107.

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19

Onyeke, Zamena Zion, Oladotun Paul Bolade, and Feyisayo Victoria Adams. "Optimization of the Removal of Naphthenic Acids from Crude Oil via Catalytic Esterification." Key Engineering Materials 917 (April 13, 2022): 241–49. http://dx.doi.org/10.4028/p-085907.

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This study was carried out to ascertain the optimum parameters for maximum total acid number (TAN) reduction via catalytic esterification using chicken eggshell ash as catalyst. A central composite design (CCD) was created to optimize TAN reduction by varying temperature and catalyst weight %. The chicken eggshell ash was calcined and reactivated in a furnace at 900 °C for an hour. An oil solution (referred to as synthetic solution) of diesel was adulterated with the organic acid m-toluic which served as a representation for highly acidic oil. Titration using alcoholic potassium hydroxide (KOH
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20

Zhai, Xiang-Sheng, Yue-Qing Zheng, Jian-Li Lin, and Wei Xu. "Four new dinuclear uranyl complexes based on p - and m -toluic acid: Syntheses, structures, luminescent and photocatalytic properties." Inorganica Chimica Acta 423 (November 2014): 1–10. http://dx.doi.org/10.1016/j.ica.2014.07.040.

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21

Vecht, S. E., M. W. Platt, Z. Er-El, and I. Goldberg. "The growth of Pseudomonas putida on m-toluic acid and on toluene in batch and in chemostat cultures." Applied Microbiology and Biotechnology 27, no. 5-6 (1988): 587–92. http://dx.doi.org/10.1007/bf00451637.

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22

Huang, Yangyi, Yuning Zhang, Haoran Liu, and Weiping Luo. "Measurement and Correlation of Solubilities of Isophthalic Acid and m-Toluic Acid in Different Organic Solvents from 287.65 to 347.45 K." Journal of Chemical & Engineering Data 67, no. 1 (2021): 231–44. http://dx.doi.org/10.1021/acs.jced.1c00670.

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23

Huang, Yangyi, Yuning Zhang, Haoran Liu, and Weiping Luo. "Correction to “Measurement and Correlation for Solubilities of Isophthalic Acid and m-Toluic Acid in Different Organic Solvents from 287.65 to 347.45 K”." Journal of Chemical & Engineering Data 67, no. 4 (2022): 1025–26. http://dx.doi.org/10.1021/acs.jced.2c00135.

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24

Muradova, Peri. "Effect of Microwave Radiation on the Development of a Porous Aluminum Carrier of the Active Mass of Catalysts in Heterogeneous Catalytic Reactions." Catalysis Research 02, no. 03 (2022): 1–13. http://dx.doi.org/10.21926/cr.2203030.

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In this study, we prepared a fine-grained, aluminum-reinforced alumina support matrix of the active mass of catalysts, which showed activity in heterogeneous catalytic reactions stimulated by electromagnetic radiation in the microwave range. The support absorbed microwave radiation of 2.45 GHz. We compared the textural characteristics of samples of Аl/Аl&lt;sub&gt;2&lt;/sub&gt;О&lt;sub&gt;3 &lt;/sub&gt;supports obtained by conventional heat treatment to those synthesized by heat treatment in a microwave field. We found several advantages of heat treating potential supports of the active mass b
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25

Muradova, P. A., S. M. Zulfugarova, V. F. Tret’yakov, R. M. Talyshinskii, N. M. Gasankulieva та Yu N. Litvishkov. "Acid Properties of the Surface of Zn–B–P/γ-Al2O3/Al Catalysts and Their Activity in Microwave-Stimulated Reaction of Diethylamine Acylation with m-Toluic Acid". Petroleum Chemistry 57, № 12 (2017): 1081–87. http://dx.doi.org/10.1134/s096554411712009x.

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26

He, Xiaojun, Ze Tan, Qinbo Wang, and Yinchuan Pei. "Study on the Solubilities of Mononitro-Substituted Products of Nitration of m-Toluic Acid in Several Solvents at Temperatures between 297.65 and 351.75 K." Journal of Chemical & Engineering Data 62, no. 10 (2017): 3360–67. http://dx.doi.org/10.1021/acs.jced.7b00431.

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27

Mochizuki, Tomoki, Kimitaka Kawamura, Kazuma Aoki, and Nobuo Sugimoto. "Long-range atmospheric transport of volatile monocarboxylic acids with Asian dust over a high mountain snow site, central Japan." Atmospheric Chemistry and Physics 16, no. 22 (2016): 14621–33. http://dx.doi.org/10.5194/acp-16-14621-2016.

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Abstract. To understand the long-range transport of monocarboxylic acids from the Asian continent to the Japanese islands, we collected snowpack samples from a pit sequence (depth ca. 6 m) at the Murodo-Daira snowfield near the summit of Mt. Tateyama, central Japan, in 2009 and 2011. Snow samples (n = 16) were analyzed for normal (C1–C10), branched chain (iC4–iC6), aromatic (benzoic and toluic acid isomers), and hydroxyl (glycolic and lactic) monocarboxylic acids, together with inorganic ions and dissolved organic carbon (DOC). Acetic acid (C2) was found to be a dominant species (average 125 n
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28

Hajji, K. Tawfiki, F. Lépine, J. G. Bisaillon, and R. Beaudet. "Simultaneous removal of phenol, ortho- and para-cresol by mixed anaerobic consortia." Canadian Journal of Microbiology 45, no. 4 (1999): 318–25. http://dx.doi.org/10.1139/w99-003.

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Two different anerobic consortia, one removing phenol and ortho- (o-) cresol and the other removing para- (p-) cresol, were cultivated in serum bottles using whey as cosubstrate substitute for proteose peptone. Phenol and p-cresol removal with the phenol-removing consortium were the same with 0.0125% (w/v) whey as with 0.05% proteose peptone. For the other consortium, 8 days were required to decrease the p-cresol concentration from 35 to 2 mg/L with 0.025% whey, while 35 days were required to achieve a similar removal with 0.5% proteose peptone. The two consortia were mixed and cultivated with
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29

Hasanguliyeva, Nargalam M., Ninel V. Shakunova, and Yuriy N. Litvishkov. "Microwave Solid-Phase Synthesis of Ni-Co Ferrites and their Activities in Liquid-Phase Oxidation of m-Xylene." EURASIAN JOURNAL OF CHEMISTRY, August 2, 2024. http://dx.doi.org/10.31489/2959-0663/3-24-1.

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In this paper, the activity of mono- and di-substituted cobalt and nickel ferrites prepared by microwave solid-phase synthesis was studied in the reaction of liquid-phase oxidation of m-xylene to m-toluic acid. It was established that among the tested samples, the di-substituted ferrites of spinel structure with the composition of Ni0,6Co0,4Fe2O4 have the shortest induction period and the highest initial rate of oxygen absorption. In order to clarify the role of the active surface of the Ni0.6Co0.4Fe2O4 catalyst and the volumetric conversions of m‑xylene in the nucleation stage of primary xyly
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30

Mahendra, Trivedi, Branton Alice, Trivedi Dahryn, and Nayak Gopal. "Quantitative Determination of Isotopic Abundance Ratio of 13C, 2H, and 18O in Biofield Energy Treated Ortho and Meta Toluic Acid Isomers." Science Publishing Group, December 21, 2015. https://doi.org/10.5281/zenodo.813685.

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O-Toluic acid (OTA) and m-toluic acid (MTA) are two isomers of toluic acid that act as an important organic intermediates, mostly used in medicines and pesticides. The aim of the study was to evaluate the impact of biofield energy treatment on isotopic abundance ratios of 2H/1H, 13C/12C, (PM+1)/PM and 18O/16O, (PM+2)/PM, in toluic acid isomers using gas chromatography-mass spectrometry (GC-MS). The OTA and MTA samples were divided into two parts: control and treated. The control sample remained as untreated, while the treated sample was further divided into four groups as T1, T2, T3, and T4. T
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31

Trivedi, Mahendra Kumar, Alice Branton, Dahryn Trivedi, Gopal Nayak, Ragini Singh, and Snehasis Jana. "Physical, Thermal and Spectroscopic Characterization of m-Toluic Acid: an Impact of Biofield Treatment." Biochemistry & Pharmacology: Open Access 4, no. 4 (2015). https://doi.org/10.4172/2167-0501.1000178.

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m-toluic acid (MTA) is widely used in manufacturing of dyes, pharmaceuticals, polymer stabilizers, and insect repellents. The aim of present study was to evaluate the impact of biofield treatment on physical, thermal and spectroscopic properties of MTA. MTA sample was divided into two groups that served as treated and control. The treated group received Mr. Trivedi&rsquo;s biofield treatment. Subsequently, the control and treated samples were evaluated using X-ray diffraction (XRD), surface area analyser, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Fourier transf
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32

Trivedi, Mahendra Kumar, Alice Branton, Dahryn Trivedi, Gopal Nayak, Ragini Singh, and Snehasis Jana. "Physical, Thermal and Spectroscopic Characterization of m-Toluic Acid: an Impact of Biofield Treatment." Biochemistry & Pharmacology: Open Access 4, no. 4 (2015). https://doi.org/10.5281/zenodo.181721.

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m-toluic acid (MTA) is widely used in manufacturing of dyes, pharmaceuticals, polymer stabilizers, and insect repellents. The aim of present study was to evaluate the impact of biofield treatment on physical, thermal and spectroscopic properties of MTA. MTA sample was divided into two groups that served as treated and control. The treated group received Mr. Trivedi&rsquo;s biofield treatment. Subsequently, the control and treated samples were evaluated using X-ray diffraction (XRD), surface area analyser, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Fourier transf
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33

Pham, Duc Thinh, Van Thu Nguyen, Binh Duong Vu, and Dinh Chau Phan. "A New Method for the Synthesis of N, N-Diethyl-m-Methylbenzamide from m-Toluic Acid and Diethylamine Using 1,1'-Carbonyl-di-(1,2,4-triazole) (CDT) as Coupling Agent." Letters in Organic Chemistry 18 (November 19, 2021). http://dx.doi.org/10.2174/1570178618666211119121227.

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: A new, simple method for the synthesis of N, N-dietyl-m-methylbenzamide (DEET) from m-toluic acid and diethylamine using 1,1'-carbonyl-di-(1,2,4-triazole) (CDT) as a coupling agent has been performed. The basic principles of activated carbonyls have been explored with the ability to prepare new amides easily. All reaction by-products are water-soluble as well as removed by filtration, the reaction could be purified easily in an aqueous solution by liquid-liquid extraction, and the product DEET was high purity. This experimental efficiency is about 94-95%, purity (HPLC): 97-98%.
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34

Branton, Alice. "Physical, Thermal and Spectroscopic Characterization of m-Toluic Acid: an Impact of Biofield Treatment." August 6, 2015. https://doi.org/10.5281/zenodo.167211.

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m-toluic acid (MTA) is widely used in manufacturing of dyes, pharmaceuticals, polymer stabilizers, and insect repellents. The aim of present study was to evaluate the impact of biofield treatment on physical, thermal and spectroscopic properties of MTA. MTA sample was divided into two groups that served as treated and control. The treated group received Mr. Trivedi’s biofield treatment. Subsequently, the control and treated samples were evaluated using X-ray diffraction (XRD), surface area analyser, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Fourier transform in
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35

Trivedi, Mahendra Kumar. "Physical, Thermal and Spectroscopic Characterization of m-Toluic Acid: an Impact of Biofield Treatment." Biochemistry & Pharmacology: Open Access 04, no. 04 (2015). http://dx.doi.org/10.4172/2167-0501.1000178.

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36

Chen, Jian, Mei Dong, Wenjing Shi, et al. "Solubility of Isophthalic Acid and m-Toluic Acid in Eight Monobasic Alcohols: Experimental Measurements and Thermodynamic Modeling." Journal of Chemical & Engineering Data, August 8, 2023. http://dx.doi.org/10.1021/acs.jced.3c00237.

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37

Linker, Torsten, and Tobias Krüger-Braunert. "One‐Pot Synthesis of 1,3‐Cyclohexadienes by Birch Reduction in the Presence of Carbonyl Compounds." Angewandte Chemie International Edition, May 13, 2024. http://dx.doi.org/10.1002/anie.202407568.

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Birch reductions are well‐known transformations of arenes, applied for large scale synthesis of 1,4‐cyclohexadienes. Herein, we describe first reactions of benzoic acids in the presence of carbonyl compounds, affording aldol products in moderate to high yields. Alkyl aldehydes give the expected nonconjugated dienes by reaction at the α‐position. Interestingly, the intermediately formed enolate attacks aryl aldehydes and ketones from its γ‐position, which can be explained by steric hindrance. This opens the door for the one‐pot synthesis of 1,3‐cyclohexadienes, which are not accessible by class
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38

Linker, Torsten, and Tobias Krüger-Braunert. "One‐Pot Synthesis of 1,3‐Cyclohexadienes by Birch Reduction in the Presence of Carbonyl Compounds." Angewandte Chemie, May 13, 2024. http://dx.doi.org/10.1002/ange.202407568.

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Birch reductions are well‐known transformations of arenes, applied for large scale synthesis of 1,4‐cyclohexadienes. Herein, we describe first reactions of benzoic acids in the presence of carbonyl compounds, affording aldol products in moderate to high yields. Alkyl aldehydes give the expected nonconjugated dienes by reaction at the α‐position. Interestingly, the intermediately formed enolate attacks aryl aldehydes and ketones from its γ‐position, which can be explained by steric hindrance. This opens the door for the one‐pot synthesis of 1,3‐cyclohexadienes, which are not accessible by class
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