Dissertations / Theses on the topic 'Macro-composite'
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Hills, Zachary Patrick. "Using Macro-Fiber Composite Actuators for Aquatic Locomotion." Thesis, Virginia Tech, 2010. http://hdl.handle.net/10919/42818.
Full textMaster of Science
Lloyd, Justin Michael. "Electrical Properties of Macro-Fiber Composite Actuators and Sensors." Thesis, Virginia Tech, 2004. http://hdl.handle.net/10919/10013.
Full textMaster of Science
THIEN, ANDREW B. "PIPELINE STRUCTURAL HEALTH MONITORING USING MACRO-FIBER COMPOSITE ACTIVE SENSORS." University of Cincinnati / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1140799131.
Full textBilgen, Onur. "Macro Fiber Composite Actuated Unmanned Air Vehicles: Design, Development, and Testing." Thesis, Virginia Tech, 2007. http://hdl.handle.net/10919/33117.
Full textMaster of Science
Stiltner, Brandon Chase. "Macro Fiber Composite Actuated Control Surfaces with Applications Toward Ducted Fan Vehicles." Thesis, Virginia Tech, 2011. http://hdl.handle.net/10919/34441.
Full text
To achieve morphing, a piezoelectric device known as Macro Fiber Composites is used. These devices are embedded in the skin of the vehicles control surface, and when actuated, they cause the control surface to increase or decrease camber. This thesis describes experiments that were performed to investigate the performance of this type of actuator. Specifically, the actuation bandwidth of these devices is presented and compared to a servo. Results show that the morphing control surfaces can actuate at frequencies twice as high as a servo.
Master of Science
Njuguna, James A. K. "Micro- and macro-mechanical properties of aerospace composite structures and their dynamic behaviour." Thesis, City University London, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.440734.
Full textHaig, Alexander George. "The use of macro fiber composite transducers for ultrasonic guided wave based inspection." Thesis, Brunel University, 2013. http://bura.brunel.ac.uk/handle/2438/12840.
Full textRosatti, Lyric Michael. "Fatigue performance of macro-fiber piezoelectric composite actuator with respect to variable beam geometry." Thesis, Montana State University, 2012. http://etd.lib.montana.edu/etd/2012/rosatti/RosattiL1212.pdf.
Full textRubenking, Samuel Kim. "Dual Mode Macro Fiber Composite-Actuated Morphing Tip Feathers for Controlling Small Unmanned Aircraft." Thesis, Virginia Tech, 2017. http://hdl.handle.net/10919/78433.
Full textMaster of Science
Williams, Robert Brett. "Nonlinear Mechanical and Actuation Characterization of Piezoceramic Fiber Composites." Diss., Virginia Tech, 1999. http://hdl.handle.net/10919/11141.
Full textPh. D.
Sodano, Henry Angelo. "Macro-Fiber Composites for Sensing, Actuation and Power Generation." Thesis, Virginia Tech, 2003. http://hdl.handle.net/10919/34289.
Full textMaster of Science
Hamilton, Bruce Howard. "Study of damage evolutions in composite plates subjected to bending loads using micro-macro analysis." Thesis, Monterey, Calif. : Springfield, Va. : Naval Postgraduate School ; Available from National Technical Information Service, 1994. http://handle.dtic.mil/100.2/ADA288523.
Full textCalard, Vincent. "APPROCHES STATISTIQUES - PROBABILISTES DU COMPORTEMENT MÉCANIQUE DES COMPOSITES À MATRICE CÉRAMIQUE." Phd thesis, Université Sciences et Technologies - Bordeaux I, 1998. http://tel.archives-ouvertes.fr/tel-00003071.
Full textVarghese, Ronnie Paul. "MEMS Technologies for Energy Harvesting and Sensing." Diss., Virginia Tech, 2013. http://hdl.handle.net/10919/51619.
Full textPh. D.
Gustafson, Eric Andrew. "Design, Simulation, and Wind Tunnel Verication of a Morphing Airfoil." Thesis, Virginia Tech, 2011. http://hdl.handle.net/10919/33663.
Full textMaster of Science
Kuppuswamy, Anand. "Theoretical and experimental analysis of strain concentration around a broken fiber using the macro-composite technique." Thesis, This resource online, 1996. http://scholar.lib.vt.edu/theses/available/etd-09182008-063050/.
Full textMedeiros, Ricardo de. "Desenvolvimento de uma metodologia computacional para determinar coeficientes efetivos de compósitos inteligentes." Universidade de São Paulo, 2012. http://www.teses.usp.br/teses/disponiveis/18/18148/tde-23072012-143759/.
Full textThis work presents the development a numerical methodology to determine the mechanical properties of active macro composites (AFC - Active Fiber Composite, or MFC - Macro Fiber Composite), combining the concept of Representative Elementary Volume (REV) with the Finite Element Method (FEM). In the first instance, the theoretical framework associated with the numerical approach employed is presented. Later, numerical models based on unit cell are applied to predict the effective material coefficients of the transversely isotropic piezoelectric composite with circular cross section fibers. Finally, numerical results obtained by the proposed methodology are compared to other methods reported in the literature. It appears that the results are very similar to the literature results for square and hexagonal arrangement of fibers with circular geometry, in which case, it was compared numerical with analytical results calculated by Asymptotic Homogenization Method (AHM). After that, the methodology is applied to determine the effective coefficients for square and hexagonal array with square fiber geometry. Employing different fiber volume fractions, it follows that the results obtained by the proposed methodology were compared to analytical results calculated by the Uniform Field Method (UFM). After assessing the potential and limitations of the methodology, either directly, through analytical results, the evaluation took place in the indirect approach. Then, dynamic analyses were performed in order to compare the Frequency Response Functions (FRFs) determined by experimental tests with computational results. Thus, it was used a cantilever beam aluminum structure, which were bonded two piezoelectric patches, one to carry the excitement of the structure and the second to perform the data acquisition. The effective properties determined by the proposed methodology were applied for the dominium established by the piezoelectric patches. The results showed, again, the potential of the proposed methodology. Therefore, the numerical methodology is not only a good alternative for the calculation of effective coefficients of smart composite, but also a tool for the design of smart structures monitored by piezoelectric materials.
Bilgen, Onur. "Aerodynamic and Electromechanical Design, Modeling and Implementation Of Piezocomposite Airfoils." Diss., Virginia Tech, 2010. http://hdl.handle.net/10919/28665.
Full textPh. D.
Siron, Olivier. "Approche micro-macro du comportement mécanique et de la rupture d'un composite carbone-carbone à architecture fibreuse multidirectionnelle." Bordeaux 1, 1996. http://www.theses.fr/1996BOR10609.
Full textLang, Jr Joseph Reagle. "Characterization of Oscillatory Lift in MFC Airfoils." Thesis, Virginia Tech, 2014. http://hdl.handle.net/10919/50935.
Full textMaster of Science
Butrym, Brad A. "Crack Detection in Aluminum Structures." Thesis, Virginia Tech, 2010. http://hdl.handle.net/10919/32276.
Full textMaster of Science
Wojtowicz, Maria. "Macro composites for crushing - additive manufacturing of hard phase : Development and testing of macro composites for crushing purposes." Thesis, Uppsala universitet, Tillämpad materialvetenskap, 2021. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-447459.
Full textAl, Haji Ghazwan. "Towards a Road Safety Development Index (RSDI) : Development of an International Index to Measure Road Safety Performance." Licentiate thesis, Linköping : Department of Science and Technology, Linköping University, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-2989.
Full textZinck, Philippe Gérard Jean-François. "De la caractérisation micromécanique du vieillissement hydrothermique des interphases polyépoxyde - fibre de verre au comportement du composite unidirectionnel relations entre les échelles micro et macro /." Villeurbanne : Doc'INSA, 2000. http://docinsa.insa-lyon.fr/these/pont.php?id=zinck.
Full textZinck, Philippe. "De la caractérisation micromécanique du vieillissement hydrothermique des interphases polyépoxyde - fibre de verre au comportement du composite unidirectionnel : relations entre les échelles micro et macro." Lyon, INSA, 1999. http://theses.insa-lyon.fr/publication/1999ISAL0108/these.pdf.
Full textDurability of fibre reinforced polymer composites has been of great interest all along the last three decates. While the degradation processes of each component have been well characterised, predicting the long term behaviour of such materials still remain difficult dur to the poor knowledge of the long term behaviour of the interfacial zones. By performing mechanical testing on unidirectional epoxy/glass fibres composites before and after hydrothermal treatment, a post-condensation of the interphases is evidenced and explained through the inorganic-organic character of these zones. The influence of the nature of the components (comonomers, fibre surface treatment) on the behaviour of the interfacial zones is further investigated using micromechanical characterisation. The microbond technique is applied to the study of the influence of fiber surface treatment while the single fibre fragmentation test is more suitable to investigate the chemical nature of theepoxy matrix. The latter is performed at temperatures near the glass transition temperature of the matrix in order to enhance its elongation at break. Relating microcomposites behaviour to that of the bulk materials by considering degradation mechanisms at the different scales, residual stresses but also the specific properties of polymeric microdroplets, we show that the main factors governing the interface durability are the weight gain of the matrix at equilibrium, the sizing formulation (in particular the presence of filmformer) and in a lesser extent the diameter of the fibre used as reinforcement. It is finally emphasised that the development of composites materials for use in hostile environment can be envisaged by the design of interphases based on the chemistry of hybrid organic-inorganic materials
Padoin, Eduardo. "Otimização topológica de cascas compostas laminadas com atuador piezelétrico para o controle de vibrações." reponame:Biblioteca Digital de Teses e Dissertações da UFRGS, 2014. http://hdl.handle.net/10183/115273.
Full textThis work presents a topologic optimization methodology of piezoelectric actuators in laminated composite structures with the objective of controlling external perturbation induced by structural vibrations. The Linear Quadratic Regulator (LQR) and Linear Quadratic Gaussian (LQG) optimal control techniques are used. The states are estimated through of the full order state observers, using the Kalman filter to the observer gain matrix. The topology optimization is formulated to find the optimum localization of the Macro Fiber Composite (MFC) active piezoelectric patch, determining the most advantageous location of the MFC, through of the maximization of the controllability index. For the structural model, this work proposes a simplified MFC/structure interaction model. It is assumed that the MFC is one of the orthotropic material layers which has an initial strain arising from the application of an electric potential; this strain acts on the remainder of the structure. This way, modeling the electromechanical interaction between the piezoelectric material and the electric field is unnecessary because this effect is considered analytically. Both the stiffness and the mass of the MFC are taken into account in the structural model. Numerical results show that proposed MFC-structure interaction model presents good agreement with experiments and numerical simulations of models that uses the electromechanical effect. Actuator location optimization results show that the technique implemented improves the structural vibration damping. The response simulations to an unit step force allows to conclude that the control strategy using the LQG controller presents better performance in terms of settling time, overshoot, damping and control signal energy when compared to the LQR controller.
Musaramthota, Vishal. "Prediction of Fracture Toughness and Durability of Adhesively Bonded Composite Joints with Undesirable Bonding Conditions." FIU Digital Commons, 2015. http://digitalcommons.fiu.edu/etd/2513.
Full textŽůrová, Marcela. "Příprava MDF kompozitů se zvýšenou odolností proti vlhkosti." Master's thesis, Vysoké učení technické v Brně. Fakulta chemická, 2015. http://www.nusl.cz/ntk/nusl-217160.
Full textBeguinel, Johanna. "Interfacial adhesion in continuous fiber reinforced thermoplastic composites : from micro-scale to macro-scale." Thesis, Lyon, 2016. http://www.theses.fr/2016LYSEI051.
Full textThe present study was initiated by the development of a new processing route, i.e. latex-dip impregnation, for thermoplastic (TP) acrylic semi-finished materials. The composites resulting from thermocompression of TPREG I plies were studied by focusing of interfacial adhesion. Indeed the fiber/matrix interface governs the stress transfer from matrix to fibers. Thus, a multi-scale analysis of acrylic matrix/fiber interfaces was conducted by considering microcomposites, as models for fiber-based composites, and unidirectional (UD)macro-composites. The study displayed various types of sized glass and carbon fibers. On one hand, the correlation between thermodynamic adhesion and practical adhesion, resulting from micromechanical testing, is discussed by highlighting the role of the physico-chemistry of the created interphase. Wetting and thermodynamical adhesion are driven by the polarity of the film former of the sizing. On the other hand, in-plane shear modulus values from off-axis tensile test results on UD composites are consistent with the quantitative analyses of the interfacial shear strength obtained from microcomposites. More specifically, both tests have enabled a differentiation of interface properties based on the fiber sizing nature for glass and carbon fiber-reinforced (micro-)composites. The study of overall mechanical and interface properties of glass and carbon fiber/acrylic composites revealed the need for tailoring interfacial adhesion. Modifications of the matrix led to successful increases of interfacial adhesion in glass fiber/acrylic composites. An additional hygrothermal ageing study evidenced a significant loss of interfacial shear strength at micro-scale which was not observed for UD composites. The results of this study are a first step towards a database of relevant interface properties of structural TP composites. Finally, the analyses of interfaces/phases at different scales demonstrate the importance of a multi-scale approach to tailor the final properties of composite parts
Wang, Jie. "Simulation macro-méso de la mise en forme de renforts tissés interlocks." Thesis, Lyon, 2019. http://www.theses.fr/2019LYSEI075.
Full textThe forming stage in the RTM process is crucial because it strongly influences the mechanical behavior of composites in service. In order to better predict the appearance of possible defects of composite materials, numerical simulations are increasingly developed taking into account the duration and the cost of experiences. Deformations and orientations of yarns at the mesoscopic scale are essential to simulate the resin flow in the stage of injection. Given the number of elements and their complex interactions, it is difficult to conduct the shaping simulations for the entire reinforcement at this mesoscopic scale. This present thesis consists in developing a multiscale method that allows linking the macroscopic simulations of reinforcements and the mesoscopic modellings of RVE (representative volume element) during the forming process. Firstly, the numerical simulations for three different woven reinforcements at the macroscopic scale are carried out using an anisotropic hyperelastic constitutive law, by the finite element method with a dynamic explicit scheme. Then, the geometrical modelling of RVE at the mesoscopic scale are reconstituted based on the tomographic images. The mesoscopic displacement-deformation fields of woven reinforcements are determined from the macroscopic results and the position of the yarns. In order to take into consideration sliding effects of yarns, two approaches of mesoscopic simulations of RVE are developed. Finally, the mesoscopic numerical results are compared with the experimental results
Kaymak, Yalcin. "A Composite Frame/joint Super Element For Structures Strengthened By Externally Bonded Steel/frp Plates." Master's thesis, METU, 2003. http://etd.lib.metu.edu.tr/upload/1052547/index.pdf.
Full textPallon, Love. "Polyethylene/metal oxide nanocomposites for electrical insulation in future HVDC-cables : probing properties from nano to macro." Doctoral thesis, KTH, Polymera material, 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-193591.
Full textNanokompositer av polyeten och metalloxidpartiklar anses vara möjliga material att använda i morgondagens isolationshölje till högspänningskablar för likström. För att nå en transmissionsspänning på 1 MV behövs isolationsmaterial som i jämförelse med dagens polyeten har lägre elektrisk ledningsförmåga, högre styrka mot elektriskt genomslag och som kan kontrollera ansamling av rymdladdningar. De senaste årens forskning har visat att kompositer av polyeten med nanopartiklar av metalloxider har potential att nå dessa egenskaper. I det här arbetet har kompositer av polyeten och nanopartiklar av MgO för elektrisk isolation producerats och karaktäriserats. Nanopartiklar av MgO har framställts från en vattenbaserad utfällning med efterföljande calcinering, vilket resulterade i polykristallina partiklar med en mycket stor specifik ytarea (167m2 g-1). MgO-nanopartiklarna ytmodifierades i n-heptan genom att kovalent binda oktyl(trietoxi)silan och oktadekyl(trimetoxi)silan till partiklarna för att skapa en hydrofob och skyddande yta. Extrudering av de ytmodifierade MgO nanopartiklarna tillsammans med polyeten resulterade i en utmärkt dispergering med jämnt fördelad partiklar i hela kompositen, vilket ska jämföras med de omodifierade partiklarna som till stor utsträckning bildade agglomerat i polymeren. Alla kompositer med låg fyllnadsgrad (1–3 vikt% MgO) visade upp till 100 gånger lägre elektrisk konduktivitet jämfört med värdet för ofylld polyeten. Vid högre koncentrationer av omodifierade MgO förbättrades inte de isolerande egenskaperna på grund av för stor andel agglomerat, medan kompositerna med de ytmodifierade fyllmedlen som var väl dispergerade behöll en kraftig reducerad elektrisk konduktivitet upp till 9 vikt% fyllnadshalt. Den minsta interaktionsradien för MgO-nanopartiklarna för att minska den elektriska konduktiviten i kompositerna fastställdes med bildanalys och simuleringar till ca 800 nm. Den teoretiskt beräknade interaktionsradien kompletterades med observation av en experimentell interaktionsradie genom att mäta laddningsfördelningen över en Al2O3-nanopartikle i en polyetenfilm med intermodulation (frekvens-mixning) elektrostatisk kraftmikroskop (ImEFM), vilket är en ny AFM-metod för att mäta ytpotentialer. Genom att lägga på en spänning på AFM-kantilevern kunde det visualiseras hur laddningar, både injicerades och extraherades, från nanopartiklarna men inte från polyeten. Det tolkades som att extra energinivåer skapades på och runt nanopartiklarna som fungerar för att fånga in laddningar, ekvivalent med den gängse tolkningen att nanopartiklar introducera extra elektronfällor i den polymera matrisen i nanokompositer. Nanotomografi användes för att avbilda elektriska träd i tre dimensioner. Avbildningen av det elektriska trädet visade att tillväxten av trädet hade skett genom bildning av håligheter framför den framväxande trädstrukturen. Håligheterna leder till försvagning av materialet framför det propagerande trädet och förenklar på det sättet fortsatt tillväxt. Bildningen av håligheter framför trädstrukturen uppvisar en analogi till propagering av sprickor vid mekanisk belastning, i enlighet med Griffiths koncept.
QC 20161006
Kader, Ammar. "Caractérisation et modélisation électromagnétique de multimatériaux composites : application aux structures automobiles." Thesis, Bordeaux, 2015. http://www.theses.fr/2015BORD0056.
Full textThe main concern of this thesis is the characterization of the impacts of some composite materials on the main electromagnetic compatibility issues in a vehicle. The surface models of the dielectric materials are validated by confronting their simulated and measured permittivity. The surface model of the studied conductive material is validated by confronting it to a wire model and by measuring and simulating the S parameters on a structure constituted by such a material. It appears in both cases of dielectric and conductive composite materials that the surface impedance modeling technique gives a good description of the materials. The analysis of the effects of these materials on the EMC issues within a vehicle is done by use of a demonstrator representing the car body. The different equipment and harnesses embedded in a vehicle are represented in the demonstrator by some wires and monopoles. The evaluation of the impact of the composite materials on the EMC issues is done by measuring and simulating the different couplings within the demonstrator and between the demonstrator and a test antenna. The analysis of the different couplings confirms that the surface impedance material modeling approach describes well the materials under test. Concerning the impact of the composite materials on the EMC issues at a vehicle level, this analysis fulfills two main results. The first one concerns the dielectric materials. Indeed the use of these materials increases the different coupling by a value varying between at least 5 dB to 30 dB. The second conclusion concerns the use of conductive composite materials. It appears that they have no effect on the different couplings in comparison to the full steel structure
Karavelić, Emir. "Stochastic Galerkin finite element method in application to identification problems for failure models parameters in heterogeneous materials." Thesis, Compiègne, 2019. http://www.theses.fr/2019COMP2501.
Full textThis thesis deals with the localized failure for structures built of heterogeneous composite material, such as concrete, at two different scale. These two scale are latter connected through the stochastic upscaling, where any information obtained at meso-scale are used as prior knowledge at macro-scale. At meso scale, lattice model is used to represent the multi-phase structure of concrete, namely cement and aggregates. The beam element represented by 3D Timoshenko beam embedded with strong discontinuities ensures complete mesh independency of crack propagation. Geometry of aggregate size is taken in agreement with EMPA and Fuller curve while Poisson distribution is used for spatial distribution. Material properties of each phase is obtained with Gaussian distribution which takes into account the Interface Transition Zone (ITZ) through the weakening of concrete. At macro scale multisurface plasticity model is chosen that takes into account both the contribution of a strain hardening with non-associative flow rule as well as a strain softening model components for full set of different 3D failure modes. The plasticity model is represented with Drucker-Prager yield criterion, with similar plastic potential function governing hardening behavior while strain softening behavior is represented with St. Venant criterion. The identification procedure for macro-scale model is perfomed in sequential way. Due to the fact that all ingredients of macro-scale model have physical interpretation we made calibration of material parameters relevant to particular stage. This approach is latter used for model reduction from meso-scale model to macro-scale model where all scales are considered as uncertain and probability computation is performed. When we are modeling homogeneous material each unknown parameter of reduced model is modeled as a random variable while for heterogeneous material, these material parameters are described as random fields. In order to make appropriate discretizations we choose p-method mesh refinement over probability domain and h-method over spatial domain. The forward model outputs are constructed by using Stochastic Galerkin method providing outputs more quickly the the full forward model. The probabilistic procedure of identification is performed with two different methods based on Bayes’s theorem that allows incorporating new observation generated in a particular loading program. The first method Markov Chain Monte Carlo (MCMC) is identified as updating the measure, whereas the second method Polynomial Chaos Kalman Filter (PceKF) is updating the measurable function. The implementation aspects of presented models are given in full detail as well as their validation throughthe numerical examples against the experimental results or against the benchmarks available from literature
Lin, Sheng Yi, and 林勝義. "Flutter Modes Control of Plates Using Macro-Fiber-Composite Actuators." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/91645950411304446352.
Full text大葉大學
機械與自動化工程學系
100
The purpose of this study is to reduce the flutter vibrational modes of plates using Macro Fiber Composite (MFC) actuators. To achieve this goal and avoid causing structural damage in any vibration mode, the additional damping and external shunt circuits are added to consume the energy when the bending and twisting mode vibrations occur. In this study, three control techniques are utilized. The first is active control method, a velocity-feedback system with a laser displacement meter, a low-pass filter, a voltage amplifier and MFC actuators is applied to reduce vibration. The second is passive control method, the MFC actuators, R-shunt and RL-shunt are constructed to consume the vibrational energy resulting in vibration attenuation. The last is the hybrid control method which combines with active and passive control methods. Finally, the results of three techniques are compared in order to realize the performance in flutter attenuation. Key Words : Plates, MFC actuators, Shunt circuits, Flutter reduction, Hybrid control.
Yao-QingPeng and 彭耀慶. "Improvement of Hydrophobicity and Macro-scale Tribological Performance of HPMC composite films with stearic acid." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/myt58f.
Full text國立成功大學
機械工程學系
105
To improve hydrophobicity and tribology performance of HPMC films, two different methods to produce SA/HPMC composite films, namely blending and coating have been studied in this research. Contact angle test was used to characterize the hydrophobicity of surfaces; pin-on-disk, 3D profiler and SEM images of worn surface of samples were used for tribological performance analysis. Experiment results and analysis show that WCA of blending films decrease as SA content increases due to larger surface roughness, whereas the WCA of coating films increase as SA content increases due to the surface geometry effect and hydrophobic nature of SA petal-like crystals on the surface of coating films. As to tribological properties, with addition of SA, tribological performance of blending and coating films was improved effectively, and the dominant wear mechanism of SA/HPMC composites have also be demonstrated to be formation and development of SA third bodies with appropriate size and shape during wear process. By this research, applications of HPMC films as packaging and coating materials have been strengthened, and the mechanisms of stearic acid improving hydrophobicity and tribological performance were decrypted as well, which provides a valuable reference for the design of similar cellulose derivatives/fatty acids composites.
Chen, Kuan-Lin, and 陳冠霖. "Functionalization of multi-walled carbon nanotubes with macro-cyclic carbodiimide into poly-acylurea for composite applications." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/51931363088571123426.
Full text國立中興大學
化學工程學系所
98
We have carried out a successful chemical functionalization on multi-walled carbon nanotube (MW-CNT) through addition of marcocyclic carbodimides (MC-CDI) onto the carboxylic groups of CNT as a means for its dispersion promotion in organic media. In the meantime, the formed ringed acylurea groups attached to the modified CNT also can serve as latent reactive groups capable of crosslinking polymers in formation of composites with chemically bonding to CNT. In the study, the pristine MW-CNT was first treated with 8 N of nitric acid at 110oC for 3 hours for introducing anchoring carboxylic groups on the CNT walls. Then, MC-CDIs with molecular weights of 496 and 1,004 were mixed with the carboxylic acid bearing MW-CNT at 60 oC in formation of the ringed-acylurea on CNT. The ringed-acylurea functionalized CNT was found to disperse readily in most organic solvents of polar and medium-polar solvents to form homogenous solutions for six months without precipitation. The acylurea functionalized CNTs could also be blended into polymeric solutions. Upon heating at 180 oC or above, isocyanate groups was generated on CNT through ring-opening reactions of the acylurea groups in indicating that the acylurea functionalized CNT can serve as blocked-isocyanate crosslinkers for curing polymeric systems. In order to demonstrate crosslinking potentials, the ringed-acylurea modified CNTs were blended individually with two hydroxyl containing polymer systems, a polyacrylate co-plymer of 7,070 molecular weights and a typical elastomeric polyurethane of about 60,000 molecular weight. The physically blended mixtures were heated to 180 to 200 oC for the curing tests. It was observed that homogenous CNT composites were made both in physically blended and heat-treated CNT composites. Moreover, great enhancements of thermal and mechanical properties were observed at three weight percent addition of the functionalized CNTs. It was observed that the degree of enhancement is more prominent in all those composites which have been fully cured. Although the selection of the polymer systems and curing conditions are still needed for further optimization, our functionalization and demonstration of blocked-isocyanate chemistry on CNT surfaces shown by the ringed-acylurea groups appear to be novel and useful for future CNT composite applications.
Xiao-NingTsai and 蔡孝寧. "Study on Preparation of Stable HPMC Composite Solution with Metal/Oxide Nanoparticle by Steric Stabilization and Load Capacity, Macro-scale Tribological Behavior of Composite Films." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/v3n3cm.
Full text國立成功大學
機械工程學系
106
Hydroxypropyl methylcellulose (HPMC) is a kind of biopolymer with the character-istics of biodegradability, environment friendly, great mechanical properties and tribological properties. Therefore, it is suitable to develop as substituted materials of plastic. However, HPMC deforms easily when it bears the loading, causing real con-tact area and the adhesive force between HPMC and counter(AISI52100) increase, so that the HPMC film is easily damaged due to adhesive wear, and leading to lose efficacy on wear resistance. Hence, nanoparticles(NPs) Al, Cu, Al2O3, CuO have been used as fillers, by means of procedure, nano- suspension with dispersant (Span80) were prepared, and mixed with HPMC solution to prepare composite solu-tions and composite films. The study examined the basic properties (quality analysis, thickness, surface roughness, morphology), load capacity and macro-scale tribologi-cal behaviors. Results showed that Span80 could provide steric stabilization, and dispersed the NPs effectively in suspension. After suspension mixed with HPMC so-lution, HPMC made composite solution more stable. The load capacity of composite film remarkably enhanced, especially Cu/HPMC composite film. In terms of tribo-logical behaviors, the NPs Al and Cu occur deformation after wear test of low load-ing, the wear resistances had rose. Spherical CuO and sphere-like Al2O3 occurred rolling effect as third-body at interface during the test, so that the coefficient of fric-tion and wear rate decreased significantly. Since HPMC is soluble in water and or-ganic solvents (ethanol, and so on), the composite solution could be separated into additive and solution easily by appropriate pore size of filters, preventing pollution and recycling limited resources.
(5929553), Ernesto Camarena. "Multiscale Continuum Modeling of Piezoelectric Smart Structures." Thesis, 2019.
Find full textFirst, the Mechanics of Structure Genome (MSG) was extended to provide a rigorous analytical homogenization method. The MFC was idealized to consist of a stack of homogeneous layers where some of the layers were homogenized with existing rules of mixtures. For the analytical model, the electrical behavior caused by the interdigitated electrodes (IDEs) was approximated with uniform poling and uniform electrodes. All other assumptions on the field variables were avoided; thus an exact solution for a stack of homogeneous layers was found with MSG. In doing so, it was proved that in any such multi-layered composite, the in-plane strains and the transverse stresses are equal in each layer and the in-plane electric fields and transverse electric displacement are constant between the electrodes. Using this knowledge, a hybrid rule of mixtures was developed to homogenize the entire MFC layup so as to obtain the complete set of effective device properties. Since various assumptions were avoided and since the property set is now complete, it is expected that greater energy equivalence between reality and the homogenized model has been made possible. The derivation clarified what the electrical behavior of a homogenized solid with internal electrodes should be—an issue that has not been well understood. The behavior was verified by large-scale FE models of an isolated MFC patch.
Increased geometrical fidelity for homogenization was achieved with an FE-based RVE analysis that accounted for finite-thickness effects. The presented theory also rectifies numerous issues in the literature with the use of the periodic boundary conditions. The procedure was first developed without regard to the internal electrodes (ie a homogenization of the active layer). At this level, the boundary conditions were shown to satisfy a piezoelectric macrohomogeneity condition. The methodology was then applied to the full MFC layup, and modifications were implemented so that both types of MFC electrodes would be accounted for. The IDE case considered nonuniform poling and electric fields, but fully poled material was assumed. The inherent challenges associated with these nonuniformities are explored, and a solution is proposed. Based on the homogenization boundary conditions, a dehomogenization procedure was proposed that enables the recovery of local fields. The RVE analysis results for the effective properties revealed that the homogenization procedure yields an unsymmetric constitutive relation; which suggests that the MFC cannot be homogenized as rigorously as expected. Nonetheless, the obtained properties were verified to yield favorable results when compared to a large-scale 3D FE model.
As a final test of the obtained effective properties, large-scale 3D FE models of MFCs acting in a static unimorph configuration were considered. The most critical case to test was the smallest MFC available. Since none of the homogenized models account for the passive MFC regions that surround the piezoelectric fiber array, some of the test models were constructed with and without the passive regions. Studying the deflection of the host substrate revealed that ignoring the passive area in smaller MFCs can overpredict the response by up to 20%. Satisfactory agreement between the homogenized models and a direct numerical simulation were obtained with a larger MFC (about a 5% difference for the tip deflection). Furthermore, the uniform polarization assumption (in the analytical model) for the IDE case was found to be inadequate. Lastly, the recovery of the local fields was found to need improvement.
Farhad, Siamak. "Performance Simulation of Planar Solid Oxide Fuel Cells." Thesis, 2011. http://hdl.handle.net/10012/6252.
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