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Dissertations / Theses on the topic 'Macrocyclic Schiff base'

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Published: 5 June 2025

Last updated: 1 August 2025

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1

Najera, Blanca A. "Schiff base macrocyclic ligands and their complexes." Thesis, University of Sheffield, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.301827.

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2

Archibald, Stephen James. "Complexes of tripodal and macrocyclic Schiff base ligands." Thesis, University of Edinburgh, 1995. http://hdl.handle.net/1842/14781.

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The synthesis, structures and physical properties of tripodal and macrocyclic Schiff base ligands and their complexes are described. All ligands are synthesised by the condensation of amines with 2,6-diformyl- or 2,6-diacetyl-phenols. The synthesis of a novel dodecadentate tripodal Schiff base ligand, L<SUP>1</SUP>H<SUB>3</SUB>, is described. Reaction of L<SUP>1</SUP>H<SUB>3</SUB> with Ln(ClO<SUB>4</SUB>)<SUB>3</SUB> where Ln=La, Pr gives complexes of the form [Ln(L<SUP>1</SUP>H<SUB>3</SUB>)(H<SUB>2</SUB>O)](CIO<SUB>4</SUB>)<SUB>3</SUB> and where Ln=Y, [Y(L<SUP>1</SUP>H<SUB>3</SUB>)](CIO<SUB>4

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3

Leeland, James William. "Macrocyclic 'Pacman' complexes for secondary coordination sphere control." Thesis, University of Edinburgh, 2011. http://hdl.handle.net/1842/8740.

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The work presented in this Thesis describes the design, synthesis and reactivity of a symmetric and various asymmetric Schiff-base macrocycles that are capable of forming a wedge-shaped “Pacman” conformation upon metal binding. Chapter One introduces catalysts for small molecule transformation as well as transition metal complexes of pyrrole-containing macrocycles. Further to this, Pacman systems, including previous work from Love and co-workers, and complexes capable of secondary coordination-sphere control will be discussed. Chapter Two details the design and synthesis of two asymmetric macr

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4

Cheng, Wing-kin. "Synthesis, reactivities, and electrochemistry of osmium complexes with macrocyclic tertiary amine and multianionic amide and schiff-base ligands /." [Hong Kong : University of Hong Kong], 1989. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12374118.

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5

Chan, Ka-ho, and 陳嘉豪. "Ruthenium-N-heterocyclic carbene and ruthenium acetylide complexes supported by macrocyclic porphyrin or tetradentate schiff base ligands : synthesis, structure and catalytic applications." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2015. http://hdl.handle.net/10722/211130.

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6

Liang, Hongze. "Synthesis, crystal structures and spectroscopic properties of mono- and bi-metallic Schiff-base complexes ; Synthesis of polydentate and macrocyclic phosphine ligands, and their reactivities towards transition and lanthanide metal ions." HKBU Institutional Repository, 2001. http://repository.hkbu.edu.hk/etd_ra/294.

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7

Boden, Britta Nicole. "Investigations of highly conjugated macrocycles and polymers for aggregation and chemical sensing." Thesis, University of British Columbia, 2007. http://hdl.handle.net/2429/269.

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With the goal of developing Schiff base macrocycles with conjugation extended over multiple aromatic rings, new phenanthrene and triphenylene-containing bis(salicylates) were synthesized. A convenient route to 3,6,9,10-tetraalkoxy-2,7-diiodophenanthrene was developed. This compound has been found to be a useful precursor for Pd-catalyzed cross-coupling reactions. Macrocycles were synthesized by Schiff base condensation of the phenanthrene and triphenylene precursors. Reaction of smaller phenanthrene and triphenylene bis(salicylates) with 1,2-dialkoxy-4,5-phenylenediamine afforded macrocycles

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8

Marrs, Deborah Jane. "Macrocycles, macrobicycles : a study." Thesis, Open University, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.257447.

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9

Black, Daniel. "Studies on binuclear Schiff-base compartmental ligand complexes." Thesis, University of Nottingham, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.363560.

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10

Edwards, David Ryan. "Towards liquid crystalline [3 + 3] Schiff-base macrocycles." Thesis, University of British Columbia, 2007. http://hdl.handle.net/2429/31612.

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Conjugated Schiff-base macrocycles are interesting compounds of interest as platforms for catalysis, the preparation of novel synthetic ion channels and potentially as porous or tubular discotic liquid crystals. The preparation of organic macrocycles is typically low yielding, with polymerization competing with cyclization; the use of imines derived from the condensation of an aldehyde and an amine provides a means by which to conduct cyclizations under thermodynamic control and thereby improve yields. The use of difunctional aldehydes and amines allows for the formation of macrocycles in high

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11

Provençal, Alexandre. "Synthetic strategies for self-assembled schiff-base macrocycles." Thesis, University of British Columbia, 2009. http://hdl.handle.net/2429/6048.

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Schiff-base macrocycles have interesting properties that could be used in new materials such as chemical sensors, catalysts and discotic liquid crystals. Triangular [3+3] Schiff-base macrocycles, for example, have been extensively studied in the MacLachlan group. However, few examples of [4+4] Schiff-base macrocycles have been reported. A square [4+4] Schiff-base macrocycle requires a precursor with the appropriate geometry such as compound 18. Synthesis of compound 18, however, proved to be problematic because of the formation of isomers, poor solubility and low yields. To avoid these issues,

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12

Chen, Zhengyu. "Disparate symmetries in head-to-tail Schiff-base macrocycles." Thesis, University of British Columbia, 2017. http://hdl.handle.net/2429/60618.

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Two new Schiff-base macrocycles (called campestarenes) with 5-fold symmetry were prepared with bulky triphenylsilyl and triisopropylsilyl substituents. A single crystal structure of one campestarene showed an almost flat conformation of campestarenes are in their extreme enol-imine form. Tautomerization within the campestarene between the enol-imine and keto-enamine form was investigated by variable-temperature NMR and UV-vis spectroscopy. It was found that the molecule displays strong solvent- and temperature-dependent tautomerization that leads to large changes in color. These results were

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13

Gallant, Amanda Jane. "New [3+3] Schiff-base macrocycles and their complexes." Thesis, University of British Columbia, 2006. http://hdl.handle.net/2429/30870.

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A series of conjugated [3+3] Schiff-base macrocycles containing both a central crown ether-like pocket and three tetradentate N[sub 2]O[sub 2] binding sites were prepared and investigated. The formation mechanism was investigated through the synthesis and study of macrocycle fragments. Further understanding of the macrocycle conformations and dynamics was obtained through computational studies. A monoreduced macrocycle where one of the six imines has been reduced was obtained as a by-product of macrocycle formation. Reactivity studies and deuterium labeling investigations revealed that

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14

Connolly, Emma Anne. "Macrocycles as platforms for mono-and dinuclear calcium chemistry." Thesis, University of Edinburgh, 2017. http://hdl.handle.net/1842/25879.

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This thesis presents the design and structure of a number of Schiff-base pyrrole macrocycles, their use in the formation of mono- and dinuclear calcium complexes, and reactions with various alkali- and transition metals to form mixed-metal clusters. Chapter One introduces the range of Schiff-base macrocycles with tuneable properties for various synthetic applications. Previously reported complexes of various s-, d- and f-block metals in these macrocyclic frameworks are also discussed. Research into calcium chemistry is reviewed, both in catalysis of synthetic organic processes, and in syntheti

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15

Hunter, Mary Josephine. "Encapsulated metal ions : mononuclear complexes of Schiff-base macrocycles and cryptands." Thesis, Open University, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.277902.

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16

Bowman, Gary Raymond, University of Western Sydney, of Science Technology and Environment College, and of Science Food and Horticulture School. "Studies of Titanium(IV)complexes of mixed nitrogen and oxygen donor macrocycles and related schiff base ligands." THESIS_CSTE_SFH_Bowman_G.xml, 2002. http://handle.uws.edu.au:8081/1959.7/410.

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This work investigated the use of large tetradentate mixed nitrogen and oxygen donor macrocycles as potential ligands for titanium(IV).These large ligands are capable of encapsulating the metal ion, thereby protecting it from reacting further. In addition, titanium complexes of this type had not been reported previously.Molecular modelling was utilised to evaluate and predict the coordinating potential of the macrocycles investigated.An alternative synthetic strategy was needed to achieve coordination complexes with titanium. This involved the use of a benzene based solvent system and rigorous

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17

Kulmaczewski, Rafal. "Mechanisms of formation of pseudocalixarene Schiff base macrocycles investigated by ESI-MS." Thesis, Loughborough University, 2011. https://dspace.lboro.ac.uk/2134/9130.

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Starting from 4-substituted phenols, three dialdehydes were synthesised as Schiff base pseudocalixarene macrocyclic precursors. Two of the dialdehydes, 2,2'methylene-bis- [(6-hydroxymethyl)-4-methylphenol] and 2,2'-methylene-bis-[(6-hydroxymethyl)-4- phenylphenol] were structurally characterised. For the phenyl substituted compound condensation with 1,3-diaminopropan-2-ol, with transition metal ions as template, was investigated and a series of dinuclear complexes was synthesised and characterised by IR, FAB-MS and elemental analysis. The analytical data implied that the complexes have the sam

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18

Bahron, H. "Characterization of new metal complexes of Schiff bases and macrocyclic ligands and some mononitrosyl derivatives." Thesis, University of Surrey, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.240159.

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19

Pankhurst, James Richard. "Complexes of Schiff-base macrocycles and donor-expanded dipyrrins for catalysis and uranyl reduction." Thesis, University of Edinburgh, 2018. http://hdl.handle.net/1842/28887.

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The modern world faces a number of challenges related to energy and the environment. Atmospheric levels of carbon dioxide have now surpassed the 400 ppm mark due to the burning of fossil fuels, yet despite its abundance and potential use as a C1 feedstock for value-added products, there are both thermodynamic and kinetic barriers associated with the strong carbon-oxygen bonds that preclude its widespread deployment in industry. Nuclear energy is an alternative power source that reduces carbon emissions by billions of tonnes each year, but there are widespread concerns regarding the treatment o

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20

Hui, Joseph. "Construction of nanofibers from supramolecular self-assembly of Schiff-base macrocycles and metal salphen complexes." Thesis, University of British Columbia, 2010. http://hdl.handle.net/2429/29485.

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The work described in this thesis mainly covers the investigations of a series of conjugated Schiff-base macrocycles and metal salphen complexes. These compounds self-assemble into supramolecular structures through electrostatic or metal-ligand interactions, and their morphologies were studied by electron microscopy and atomic force microscopy. The Schiff-base macrocycles can bind alkali metal and ammonium cations into their crown-ether interior, leading to the formation of one-dimensional columns that can further organize into nanofibers with hierarchical organization. However, when macrocycl

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21

Lingga, Novalina. "Syntheses and structural studies of polynuclear copper (II) complexes of Schiff-base macrocycles and related ligands." Thesis, University of Canterbury. Chemistry, 1996. http://hdl.handle.net/10092/7315.

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Two diimine-diamine ligands derived from the [2+1] template condensation of 1,3-diaminopropane with 2,6-diformyl-4-R-phenol [R = Me, (L¹)-; R = tBu, (L⁸)-], have been isolated as their dicopper(II) hydroxo-bridged complex cations. The ring-closure condensation reaction of the dicopper complex cation of (L¹)- with 2,5-diformylfuran produced a new asymmetric tetraimine macrocycle, (L³)- as the methoxo-, hydroxo- and ethoxo-bridged dicopper(II) complexes. The hydroxo- and ethoxo-bridged dicopper(II) complexes of (L³)- were isolated from the recrystallisation of the methoxo-bridged analogue using

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22

Bowman, G. R. "Studies of titanium (IV) complexes of mixed nitrogen and oxygen donor macrocycles and related Schiff base ligands /." View thesis, 2002. http://library.uws.edu.au/adt-NUWS/public/adt-NUWS20030721.114851/index.html.

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23

Tamgho, Ingrid-Suzy. "Synthesis of Ligands and Macrocycles Based on 1,3-Diiminoisoindoline and Study of New Highly Fluorescent and Symmetric Pyrrole-BF₂ Chromophores." University of Akron / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=akron1412163224.

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24

Lidster, Jon. "Design and synthesis of new metallo-organic complexes and their evaluation as anti-cancer agents : synthesis, characterisation and biological evaluation of novel, late first row transition metal Schiff base complexes, as anti-cancer metallopharmaceuticals." Thesis, University of Bradford, 2011. http://hdl.handle.net/10454/5679.

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This work is concerned with the design and synthesis of the cheap, late first row transition metal complexes of Schiff base ligand systems. The prepared complexes readily afford systematic variation in order to probe potency and understand the role of metal, chelating ligands and anionic ligands when carrying out their cytotoxic effect. This study has lead to a better understanding of the action of these classes of complex and will be used to direct the design of new anti-cancer metallopharmaceuticals going forward. This thesis details the synthesis of a library of Schiff base macroacyclic lig

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25

Devoille, Aline M. J. "New cofacial binuclear complexes for the oxygen reduction reaction and selective anion binding." Thesis, University of Edinburgh, 2011. http://hdl.handle.net/1842/9963.

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This thesis describes the design, synthesis and reactivity of bimetallic complexes of doubly-pillared Schiff-base calixpyrrole ligands. Chapter One introduces the oxygen reduction reaction in light of the global energy scenario at present and in the future. Compounds and materials known to catalyse this reaction are discussed, with particular focus on transition metal complexes of pyrrole-containing macrocycles and the ability of these compounds to act as catalysts in redox reactions. Chapter Two describes the design and synthesis of several of the macrocyclic ligands developed during this pro

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26

Akerman, Kate J. "Structural, physical and biological studies of gold (lll) bis(pyrrolide-imine) Schiff base macrocyclic and pseudomacrocyclic complexes : targeted chemotherapeutic agents." Thesis, 2013. http://hdl.handle.net/10413/10975.

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27

Hui, Joseph. "Conjugated Schiff-base macrocycles and their metal complexes." Thesis, 2004. http://hdl.handle.net/2429/15276.

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The [3+3] Schiff-base macrocycles (37-40) were obtained by reacting 3,6- diformyl-l,2-dihydroxybenzene (31) and 4,5-diamino-l,2-dialkoxybenzene (33-36). The resulting macrocycles were characterized by ¹H and ¹³C NMR spectroscopy, IR spectroscopy, UV-Vis spectroscopy, ESI mass spectrometry, DSC and POM. The macrocycles with long alkoxy substituents have the potential to exhibit liquid crystallinity; however, no mesomorphic characteristics were observed. Macrocycle 37 was metallated with most of the first-row transition metals. The metal-containing [3+3] Schiff-base macrocycles (47-53) were char

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28

Bowman, Gary R. "Studies of Titanium(IV)complexes of mixed nitrogen and oxygen donor macrocycles and related schiff base ligands." Thesis, 2002. http://handle.uws.edu.au:8081/1959.7/410.

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This work investigated the use of large tetradentate mixed nitrogen and oxygen donor macrocycles as potential ligands for titanium(IV).These large ligands are capable of encapsulating the metal ion, thereby protecting it from reacting further. In addition, titanium complexes of this type had not been reported previously.Molecular modelling was utilised to evaluate and predict the coordinating potential of the macrocycles investigated.An alternative synthetic strategy was needed to achieve coordination complexes with titanium. This involved the use of a benzene based solvent system and rigorous

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29

Katsiaouni, Stamatia. "Neuartige Pyrrol/Pyrazol-Bausteine für die Synthese von Hybrid-Makrozyklen, azyklischen Ligandsystemen und bimetallischen Komplexen." Doctoral thesis, 2007. http://hdl.handle.net/11858/00-1735-0000-0006-ACA0-A.

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