Academic literature on the topic 'MADIX controlled radical polymerization'

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Journal articles on the topic "MADIX controlled radical polymerization"

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Etchenausia, Laura, Abdel Khoukh, Elise Deniau Lejeune, and Maud Save. "RAFT/MADIX emulsion copolymerization of vinyl acetate and N-vinylcaprolactam: towards waterborne physically crosslinked thermoresponsive particles." Polymer Chemistry 8, no. 14 (2017): 2244–56. http://dx.doi.org/10.1039/c7py00221a.

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Destarac, Mathias, Wojciech Bzducha, Daniel Taton, Isabelle Gauthier-Gillaizeau, and Samir Z. Zard. "Xanthates as Chain-Transfer Agents in Controlled Radical Polymerization (MADIX): Structural Effect of the O-Alkyl Group." Macromolecular Rapid Communications 23, no. 17 (2002): 1049–54. http://dx.doi.org/10.1002/marc.200290002.

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Destarac, Mathias, Juliette Ruchmann-Sternchuss, Eric Van Gramberen, Xavier Vila та Samir Z. Zard. "α-Amido Trifluoromethyl Xanthates: A New Class of RAFT/MADIX Agents". Molecules 29, № 10 (2024): 2174. http://dx.doi.org/10.3390/molecules29102174.

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Xanthates have long been described as poor RAFT/MADIX agents for styrene polymerization. Through the determination of chain transfer constants to xanthates, this work demonstrated beneficial capto-dative substituent effects for the leaving group of a new series of α-amido trifluoromethyl xanthates, with the best effect observed with trifluoroacetyl group. The previously observed Z-group activation with a O-trifluoroethyl group compared to the O-ethyl counterpart was quantitatively established with Cex = 2.7 (3–4 fold increase) using the SEC peak resolution method. This study further confirmed
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Seiler, Lucie, Julien Loiseau, Frédéric Leising, Pascal Boustingorry, Simon Harrisson, and Mathias Destarac. "Acceleration and improved control of aqueous RAFT/MADIX polymerization of vinylphosphonic acid in the presence of alkali hydroxides." Polymer Chemistry 8, no. 25 (2017): 3825–32. http://dx.doi.org/10.1039/c7py00747g.

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Wang, Pucheng, Jingwen Dai, Lei Liu, Qibao Dong, Hu Wang та Ruke Bai. "Synthesis and properties of a well-defined copolymer of chlorotrifluoroethylene and N-vinylpyrrolidone by xanthate-mediated radical copolymerization under 60Co γ-ray irradiation". Polym. Chem. 5, № 21 (2014): 6358–64. http://dx.doi.org/10.1039/c4py00902a.

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Theis, Alexander, Thomas P. Davis, Martina H. Stenzel, and Christopher Barner-Kowollik. "Probing the reaction kinetics of vinyl acetate free radical polymerization via living free radical polymerization (MADIX)." Polymer 47, no. 4 (2006): 999–1010. http://dx.doi.org/10.1016/j.polymer.2005.12.054.

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Zard, Samir Z. "The Genesis of the Reversible Radical Addition–Fragmentation–Transfer of Thiocarbonylthio Derivatives from the Barton–McCombie Deoxygenation: A Brief Account and Some Mechanistic Observations." Australian Journal of Chemistry 59, no. 10 (2006): 663. http://dx.doi.org/10.1071/ch06263.

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The observations and reasoning leading to the discovery of the degenerative transfer of xanthates and related thiocarbonylthio derivatives are briefly described. A few synthetic applications are presented, and the consequences on the emergence of the RAFT and MADIX polymerization technologies as well as some mechanistic aspects are briefly discussed.
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Matyjaszewski, Krzysztof. "Controlled radical polymerization." Current Opinion in Solid State and Materials Science 1, no. 6 (1996): 769–76. http://dx.doi.org/10.1016/s1359-0286(96)80101-x.

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Gaynor, Scott, Dorota Greszta, Daniela Mardare, Mircea Teodorescu, and Krzysztof Matyjaszewski. "Controlled Radical Polymerization." Journal of Macromolecular Science, Part A 31, no. 11 (1994): 1561–78. http://dx.doi.org/10.1080/10601329408545868.

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Bertin, Denis, and Bernard Boutevin. "Controlled radical polymerization." Polymer Bulletin 37, no. 3 (1996): 337–44. http://dx.doi.org/10.1007/bf00318066.

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Dissertations / Theses on the topic "MADIX controlled radical polymerization"

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Simms, Ryan W. "Living/controlled Polymerization Conducted in Aqueous Based Systems." Thesis, Kingston, Ont. : [s.n.], 2007. http://hdl.handle.net/1974/700.

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Miguel-Arricau, Sophie. "Corrélation structure/propriété de polymères à base d'acrylamide pour des applications en récupération assistée des hydrocarbures (RAH)." Electronic Thesis or Diss., Pau, 2022. https://theses.hal.science/tel-04010751.

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La connaissance des propriétés physico-chimiques des solutions de polymères utilisées en récupération assistée des hydrocarbures (RAH) est essentielle pour une bonne efficience du procédé. Ces travaux avaient pour but de conforter et enrichir un modèle de viscosité universelle dépendant du paramètre de recouvrement C[η] qui permet de prendre en compte l'occupation du milieu par les chaînes macromoléculaires (concentration d'enchevêtrement critique, C*, régimes dilué et semi-dilué). Les effets des microstructures, de la taille et de la composition des polymères ont été étudiés via la synthèse d
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Wang, Aileen Ruiling Zhu Shiping. "Diffusion-controlled atom transfer radical polymerization." *McMaster only, 2005.

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Mochizuki, Shuto. "Controlled radical polymerization in designed porous materials." Kyoto University, 2019. http://hdl.handle.net/2433/242535.

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Qi, Genggeng. "Unconventional radical miniemulsion polymerization." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2008. http://hdl.handle.net/1853/26547.

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Thesis (Ph.D)--Chemical Engineering, Georgia Institute of Technology, 2009.<br>Committee Chair: Jones, Christopher W.; Committee Chair: Schork, F. Joseph; Committee Member: Koros, William J.; Committee Member: Lyon, Andrew; Committee Member: Nenes, Athanasios. Part of the SMARTech Electronic Thesis and Dissertation Collection.
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Yin, Meizhen. "Synthesis and controlled radical polymerization of multifunctional monomers." Doctoral thesis, Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2004. http://nbn-resolving.de/urn:nbn:de:swb:14-1091453146703-47835.

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Multifunctional monomers on the basis of acryl- and methacryl derivatives were synthesized and different protective groups were used. After polymerization the protective groups were removed by different methods. Various initiators for the NMP of the monomers were synthesized and the reaction conditions were optimized. The results showed that NMP was not a suitable method for multifunctional acryl- and methacryl derivatives to achieve well-defined homopolymers, although it was successful for control of polymerization of styrene and block copolymerization of multifunctional acryl- and methacryl
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Heredia, Karina Lynn. "Synthesis of polymer bioconjugates using controlled radical polymerization." Diss., Restricted to subscribing institutions, 2008. http://proquest.umi.com/pqdweb?did=1583873071&sid=37&Fmt=2&clientId=1564&RQT=309&VName=PQD.

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Minaux, Eric. "Controlled radical polymerization at pressures up to 2000 bar." Doctoral thesis, [S.l.] : [s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=962677035.

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Carlmark, Anna. "Complex Macromolecular Architectures by Atom Transfer Radical Polymerization." Doctoral thesis, KTH, Fibre and Polymer Technology, 2004. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3740.

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<p>Controlled radical polymerization has proven to be a viableroute to obtain polymers with narrow polydispersities (PDI's)and controlled molecular weights under simple reactionconditions. It also offers control over the chain-]ends of thesynthesized polymer. Atom transfer radical polymerization(ATRP) is the most studied and utilized of these techniques. Inthis study ATRP has been utilized as a tool to obtain differentcomplex macromolecular structures.</p><p>In order to elaborate a system for which a multitude ofchains can polymerize in a controlled manner and in closeproximity to one another,
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Aksakal, Resat. "Functional polymers via Cu-mediated radical polymerization." Thesis, Queen Mary, University of London, 2018. http://qmro.qmul.ac.uk/xmlui/handle/123456789/36215.

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This work reports the investigation of Cu-mediated polymerization systems and its limits, in order to obtain functional branched polymers, in particular star-shaped and graft-shaped polymers. A novel initiator structure has allowed developing a new approach to synthesise sequence controlled multiblock star polymers via Cu-mediated reversible deactivation radical polymerization (RDRP) in water. This technique allows the preparation of pentablock star shaped polymers in just under 90 minutes of reaction time. The obtained polymers had a good agreement between theoretical and experimental molecul
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Books on the topic "MADIX controlled radical polymerization"

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Matyjaszewski, Krzysztof, ed. Controlled Radical Polymerization. American Chemical Society, 1998. http://dx.doi.org/10.1021/bk-1998-0685.

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K, Matyjaszewski, American Chemical Society. Division of Polymer Chemistry., and American Chemical Society Meeting, eds. Controlled radical polymerization. American Chemical Society, 1998.

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Matyjaszewski, Krzysztof, ed. Controlled/Living Radical Polymerization. American Chemical Society, 2006. http://dx.doi.org/10.1021/bk-2006-0944.

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Matyjaszewski, Krzysztof, ed. Controlled/Living Radical Polymerization. American Chemical Society, 2000. http://dx.doi.org/10.1021/bk-2000-0768.

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Matyjaszewski, Krzysztof, Brent S. Sumerlin, Nicolay V. Tsarevsky, and John Chiefari, eds. Controlled Radical Polymerization: Mechanisms. American Chemical Society, 2015. http://dx.doi.org/10.1021/bk-2015-1187.

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Matyjaszewski, Krzysztof, Brent S. Sumerlin, Nicolay V. Tsarevsky, and John Chiefari, eds. Controlled Radical Polymerization: Materials. American Chemical Society, 2015. http://dx.doi.org/10.1021/bk-2015-1188.

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Tsarevsky, Nicolay V., and Brent S. Sumerlin, eds. Fundamentals of Controlled/Living Radical Polymerization. Royal Society of Chemistry, 2013. http://dx.doi.org/10.1039/9781849737425.

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Matyjaszewski, Krzysztof, ed. Advances in Controlled/Living Radical Polymerization. American Chemical Society, 2003. http://dx.doi.org/10.1021/bk-2003-0854.

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K, Matyjaszewski, American Chemical Society. Division of Polymer Chemistry, and American Chemical Society Meeting, eds. Advances in controlled/living radical polymerization. American Chemical Society, 2003.

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Matyjaszewski, Krzysztof, ed. Controlled/Living Radical Polymerization: Progress in ATRP. American Chemical Society, 2009. http://dx.doi.org/10.1021/bk-2009-1023.

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Book chapters on the topic "MADIX controlled radical polymerization"

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Ambade, Ashootosh V. "Controlled Radical Polymerization." In Metal-Catalyzed Polymerization. CRC Press, 2017. http://dx.doi.org/10.1201/9781315153919-5.

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Reynaud, Stéphanie, and Bruno Grassl. "Microwave-Assisted Controlled Radical Polymerization." In Microwave-assisted Polymer Synthesis. Springer International Publishing, 2014. http://dx.doi.org/10.1007/12_2014_302.

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Spanswick, James, and Bernard Pike. "Opportunities in Controlled Radical Polymerization." In ACS Symposium Series. American Chemical Society, 2009. http://dx.doi.org/10.1021/bk-2009-1023.ch026.

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Lefay, Catherine, and Julien Nicolas. "Controlled/Living Radical Polymerization in Aqueous Miniemulsion." In Miniemulsion Polymerization Technology. John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470922354.ch7.

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Flores, Joel D., Brooks A. Abel, DeeDee Smith, and Charles L. McCormick. "Stimuli-Responsive Polymers Via Controlled Radical Polymerization." In Monitoring Polymerization Reactions. John Wiley & Sons, 2014. http://dx.doi.org/10.1002/9781118733813.ch3.

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Khabibullin, Amir, Erlita Mastan, Krzysztof Matyjaszewski, and Shiping Zhu. "Surface-Initiated Atom Transfer Radical Polymerization." In Controlled Radical Polymerization at and from Solid Surfaces. Springer International Publishing, 2015. http://dx.doi.org/10.1007/12_2015_311.

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Tang, Huadong, Maciej Radosz, and Youqing Shen. "Controlled/"Living" Radical Polymerization of Vinyl Acetate." In ACS Symposium Series. American Chemical Society, 2009. http://dx.doi.org/10.1021/bk-2009-1023.ch010.

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Matyjaszewski, Krzysztof. "Overview: Fundamentals of Controlled/Living Radical Polymerization." In ACS Symposium Series. American Chemical Society, 1998. http://dx.doi.org/10.1021/bk-1998-0685.ch001.

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Phan, Trang N. T., Jacques Jestin, and Didier Gigmes. "Nitroxide-Mediated Polymerization from Surfaces." In Controlled Radical Polymerization at and from Solid Surfaces. Springer International Publishing, 2015. http://dx.doi.org/10.1007/12_2015_317.

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Cenacchi-Pereira, Ana, Eliana Grant, Franck D’Agosto, Muriel Lansalot, and Elodie Bourgeat-Lami. "Encapsulation with the Use of Controlled Radical Polymerization." In Encyclopedia of Polymeric Nanomaterials. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-36199-9_347-1.

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Conference papers on the topic "MADIX controlled radical polymerization"

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Liu, Rui, Xi Chen, and Antonios Armaou. "Accelerated Process Modelling for Light-Mediated Controlled Radical Polymerization." In The 35th European Symposium on Computer Aided Process Engineering. PSE Press, 2025. https://doi.org/10.69997/sct.128107.

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Mathematical modelling and simulation are pivotal components in process systems engineering. Focusing on polymerization process systems, identifying microscopic properties of polymers is highly sought after for advancing kinetic comprehension and facilitating industrial applications. Among various computational methods predicting polymeric properties microscopically, kinetic Monte Carlo (kMC) offers a stochastic framework to characterize individual polymer chains and track dynamic system evolution, providing mechanistic insights into complex polymerization kinetics. In this study, an accuratel
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Yoshida, Jun-ichi, and Aiichiro Nagaki. "Flash Chemistry - Fast Chemical Synthesis in Micro Flow Systems." In ASME 2009 7th International Conference on Nanochannels, Microchannels, and Minichannels. ASMEDC, 2009. http://dx.doi.org/10.1115/icnmm2009-82157.

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Flash chemistry is a field of chemical synthesis where extremely fast reactions are conducted in a highly controlled manner. A key element of flash chemistry is the control of extremely fast reactions to obtain the desired products selectively. For extremely fast reactions, kinetics often cannot be used because of the lack of homogeneity of the reaction environment when they are conducted in conventional reactors such as flasks. Fast micromixing by virtue of short diffusion path solves such problems. Fast reactions are usually highly exothermic, and heat removal is an important factor in contr
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Jian, Guoqing, Ashok Santra, Hasmukh A. Patel, and Ahmet Atilgan. "A Novel Star Polymer based Fluid Loss Control Additive for Non-Aqueous Drilling Fluids." In SPE International Conference on Oilfield Chemistry. SPE, 2023. http://dx.doi.org/10.2118/213791-ms.

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Abstract Non-aqueous fluids (NAF) are considered as efficient and reliable drilling fluid systems for challenging wellbore conditions, such as high-temperature drilling operations. NAFs require fluid loss control additives to reduce filtration loss into the formation with minimum filter cake thickness. Polymer developed in this work demonstrated exceptional properties such as high dispersibility, good thermal stability and low plastic viscosity, when compared with traditional natural and synthetic-based fluid loss control additives (e.g., gilsonite). We have utilized a synthetic molecular opti
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Reports on the topic "MADIX controlled radical polymerization"

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Matyjaszewski, K., S. Gaynor, D. Greszta, D. Mardare, and T. Shigemoto. Unimolecular and Bimoleculare Exchange Reactiions in Controlled Radical Polymerization. Defense Technical Information Center, 1995. http://dx.doi.org/10.21236/ada295862.

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Hu, S., J. H. Malpert, X. Yang, and D. C. Neckers. Exploring Chromophore Tethered Aminoethers as Potential Photoinitiators for Controlled Radical Polymerization. Defense Technical Information Center, 1999. http://dx.doi.org/10.21236/ada370961.

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Matyjaszewski, Krzysztof. The Importance of Exchange Reactions in Controlled/Living Radical Polymerization in the Presence of Alkoxyamines and Transition Metals. Defense Technical Information Center, 1996. http://dx.doi.org/10.21236/ada309796.

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