Academic literature on the topic 'Magnetic isotope effect'

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Journal articles on the topic "Magnetic isotope effect"

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Musich, О., A. Zubko, and О. Demyanуuk. "Isotopic effect of macro- and microelements in ecosystems." Balanced nature using, no. 4 (August 18, 2020): 132–38. http://dx.doi.org/10.33730/2310-4678.4.2020.226644.

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Isotopic effects occurring in living organisms due to metabolism are analyzed. The phenomenon of metabolism is considered in the classical sense as a combination of biochemical reactions (mainly enzyma­tic) that take place in the cells of living beings and provide the cleavage, synthesis and interconversion of complex compounds. The scope of use of natural isotopes is wide and diverse. Isotopes are carriers of information about the birth and transformation of molecules, and isotope fractionation is a chemical characteristic of a substance. Isotope metabolism consists in the intermolecular frac
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STEP, EUGENII N., VALERII F. TARASOV, and ANATOLII L. BUCHACHENKO. "Magnetic isotope effect." Nature 345, no. 6270 (1990): 25. http://dx.doi.org/10.1038/345025b0.

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Buchachenko, A. L. "Magnetic isotope effect." Theoretical and Experimental Chemistry 31, no. 3 (1995): 118–26. http://dx.doi.org/10.1007/bf00538783.

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Epov, Vladimir N. "Mechanisms of Oxidation-Reduction Reactions Can Be Predicted by the Magnetic Isotope Effect." Advances in Physical Chemistry 2011 (December 20, 2011): 1–7. http://dx.doi.org/10.1155/2011/450325.

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Magnetic isotope effect can cause mass-independent isotope fractionation, which can be used to predict the mechanisms of chemical reactions. In this critical paper, the isotope fractionation caused by magnetic isotope effect is used to understand detailed mechanisms of oxidation-reduction reactions for some previously published experimental data. Due to the rule that reactions are allowed for certain electron spin state, and forbidden for others, magnetic isotopes show chemical anomalies during these reactions due to the hyperfine interaction of the nuclear spin with the electron spin. It is d
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Norman, Michael. "A magnetic isotope effect." Nature Physics 2, no. 1 (2006): 19–20. http://dx.doi.org/10.1038/nphys201.

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Buchachenko, A. L. "The magnetic isotope effect." Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 39, no. 10 (1990): 2045–58. http://dx.doi.org/10.1007/bf01557733.

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Okazaki, Masaharu, Kazumi Toriyama, Keichi Nunome, Hachizo Muto, and Takeshi Shiga. "Two independent isotope effects and their magnetic field dependences in the photoreduction of menadione in deuterium labeled SDS micellar solutions. A spin trapping study." Canadian Journal of Chemistry 66, no. 8 (1988): 1832–35. http://dx.doi.org/10.1139/v88-296.

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Spin adduct yields in the photoreduction of menadione (2-methylnaphthoquinone) in isotope labeled micellar solutions were measured as functions of the external magnetic field. As surfactants, ordinary SDS, perdeuteriated SDS, and a mixture of the two were employed. In a mixed micellar solution, a normal isotope effect on the spin adduct yield was observed. On the other hand, in the pure micellar solutions with each of the former two surfactants, a reversed isotope effect was observed. These two apparent isotope effects depend on the external magnetic field and were separated into two independe
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Step, E. N., V. F. Tarasov, A. L. Buchachenko, V. I. Ustinov, and V. A. Grinenko. "Magnetic isotope effect of silicon." Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 37, no. 1 (1988): 186. http://dx.doi.org/10.1007/bf00962691.

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Letuta, A. S., and V. L. Berdinskii. "Magnetic isotope effect and chemical Zeno effect." Doklady Physical Chemistry 457, no. 2 (2014): 120–22. http://dx.doi.org/10.1134/s0012501614080028.

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Tarasov, V., N. D. Ghatlia, A. Buchachenko, and N. J. Turro. "Photostereoisomerization and the magnetic isotope effect." Journal of Physical Chemistry 95, no. 25 (1991): 10220–29. http://dx.doi.org/10.1021/j100178a002.

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Dissertations / Theses on the topic "Magnetic isotope effect"

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Ye, Quan-Lin, Hirofumi Yoshikawa, Shunji Bandow, and Kunio Awaga. "Green magnetite (Fe3O4): Unusual optical Mie scattering and magnetic isotropy of submicron-size hollow spheres." American Institite of Physics, 2009. http://hdl.handle.net/2237/12624.

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Flores, Gonzalez Jessica. "Isotopic Enrichments of lanthanide based single molecule magnets." Thesis, Rennes 1, 2019. http://www.theses.fr/2019REN1S064.

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Les matériaux moléculaires, et plus précisément ceux à base d’ions lanthanides, ont été largement étudiés pour leur utilisation dans différentes applications, dont le stockage de l’information ou l’ordinateur quantique. Cet intérêt s’explique du fait que des systèmes contenant des ions lanthanides donnent lieu à une large anisotropie et une bistabilité magnétiques d‘origine purement moléculaire. Durant les vingt-cinq dernières années, beaucoup d’articles ont été publiés dans lesquels les composés à base de ces ions montraient une relaxation lente de leur aimantation et une hystérèse magnétique
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Engelbrecht, Leon de Villiers. "A study of isotope-effects in the high-resolution 195Pt NMR spectra of octahedral complexes of the type [PtCl6-n(OH)n]2-, n = 0-6, in water." Thesis, Stellenbosch : Stellenbosch University, 2013. http://hdl.handle.net/10019.1/80186.

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Thesis (MSc)--Stellenbosch University, 2013.<br>ENGLISH ABSTRACT: The high-resolution 195Pt NMR signals (128.8 MHz) of most of the octahedral mixed-ligand Pt(IV) complexes in the series [PtCl6-n(OH)n]2-, n = 0-6, have been recorded in aqueous solutions at 293 K. These signals show characteristic 35/37Cl isotope-induced fine structure that results from the presence of several isotopologues in samples with a natural chlorine isotope distribution; each 37Cl isotope incorporated into the Pt coordination sphere of one of these complexes affords a fixed upfield (low frequency) isotope shift of betwe
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Davis, John Christopher. "Understanding the origin of 35/37Cl and 16/18O isotope effects on 195Pt and 103Rh NMR nuclear shielding in selected Pt(IV) and Rh(III) complexes : a DFT study." Thesis, Stellenbosch : Stellenbosch University, 2013. http://hdl.handle.net/10019.1/95484.

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Nibart, Vincent. "Projet PIAFE : transport d'ions exotiques de basse énergie sur longue distance." Université Joseph Fourier (Grenoble), 1996. http://www.theses.fr/1996GRE10019.

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Le projet piafe consiste a produire des noyaux riches en neutrons par fission au sein d'une cible d'uranium placee pres du cur du reacteur de l'institut laue langevin, puis de transporter les produits de fission sous forme monochargee et a basse energie (inferieure a 30 kev) sur une distance de 400 m jusqu'au complexe accelerateur sara de l'institut des sciences nucleaires de grenoble. Une solution originale de guidage ayant ete proposee, l'objectif de cette these est de prouver la faisabilite d'un tel transport. Pour ceci, on s'est attache a etudier les effets sur le faisceau des defauts d'al
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Aissani, Sarra. "Résonance quadrupolaire de l'azote-14 : amélioration de la qualité spectrale et effet d'un champ magnétique statique de faible amplitude." Thesis, Université de Lorraine, 2014. http://www.theses.fr/2014LORR0069/document.

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La Résonance Quadrupolaire Nucléaire (RQN) est une technique spectroscopique appliquée à l’état solide et qui ne nécessite aucun champ magnétique statique contrairement à la Résonance Magnétique Nucléaire (RMN). Elle permet de détecter, les molécules qui contiennent un noyau quadrupolaire (tel que l'azote-14). La RQN de l’azote-14 suscite un intérêt particulier car elle s'avère utile dans la détection de drogues et d’explosifs, qui contiennent, pour la plupart, des molécules azotées. Cette thèse porte en premier lieu sur l’amélioration de la qualité spectrale en résonance quadrupolaire (RQN) d
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Lording, William James. "A deeper understanding of the Diels–Alder reaction." Phd thesis, 2010. http://hdl.handle.net/1885/11776.

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The Diels-Alder reaction was discovered in 1928 and has become the most efficient and practical method for the synthesis of six-membered carbocyclic and heterocyclic rings. This thesis comprises three chapters of results and discussion with the Diels-Alder reaction as a theme. Chapter 2 details an investigation of endo:exo selectivity in the Diels-Alder reactions of 1,3-butadiene. Chapter 3 explores aspects of the intramolecular Diels-Alder reactions of some substituted 1,3,8-nonatrienes, and Chapter 4 describes the domino Diels-Alder reactions of 1,4-diiodo-1,3-butadiene. The Diels-Ald
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Zeng, Fan-Wei. "The Effects of Land Use and Human Activities on Carbon Cycling in Texas Rivers." Thesis, 2011. http://hdl.handle.net/1911/62285.

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I investigated how land use and human activities affect the sources and cycling of carbon (C) in subtropical rivers. Annually rivers receive a large amount of terrestrial C, process a portion of this C and return it to the atmosphere as CO2. The rest is transported to the ocean. Land use and human activities can affect the sources and fate of terrestrial C in rivers. However, studies on these effects are limited, especially in the humid subtropics. I combined measurements of the partial pressure of dissolved CO2 (pCO2), C isotopes (13C and 14C) and solid-state 13C nuclear magnetic resonance (N
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Books on the topic "Magnetic isotope effect"

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Salikhov, Kev M. Magnetic Isotope Effect in Radical Reactions. Springer Vienna, 1996. http://dx.doi.org/10.1007/978-3-7091-6569-0.

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Buchachenko, A. L. Magnetic isotope effect in chemistry and biochemistry. Nova Science Publishers, 2009.

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Salikhov, K. M. Magnetic isotope effect in radical reactions: An introduction. Springer, 1996.

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1946-, Berger Stefan, ed. Isotope effects in NMR spectroscopy. Springer-Verlag, 1990.

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Zech, Damian. A magnetization study of cuprate superconductors: I. Oxygen isotope effect in YBa₂Cu₃O[subscript x]; II. Anisotropic magnetic properties of single crystalline Y₂Ba₄Cu₈O₁₆ and Bi₂Sr₂CaCu₂O[subscript 8+delta]. [s.n.], 1995.

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Born, R. Ab initio calculations of conformational effects on ¹³C NMR spectra of amorphous polymers. Springer, 1997.

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Salikhov, Kev M. Magnetic Isotope Effect in Radical Reactions. Island Press, 1996.

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Salikhov, Kev M. Magnetic Isotope Effect in Radical Reactions: An Introduction. Springer London, Limited, 2012.

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Buchachenko, Anatoly. Magnetic Isotope Effects in Chemistry and Biochemistry. Wiley & Sons, Incorporated, John, 2009.

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Glazov, M. M. Spin Resonance. Oxford University Press, 2018. http://dx.doi.org/10.1093/oso/9780198807308.003.0003.

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This chapter is devoted to one of key phenomena in the field of spin physics, namely, resonant absorption of electromagnetic waves under conditions where the Zeeman splitting of spin levels in magnetic field is equal to photon energy. This method is particularly important for identification of nuclear spin effects, because resonance spectra provide fingerprints of different involved spin species and make it possible to distinguish different nuclear isotopes. As discussed in this chapter the nuclear magnetic resonance provides also an access to local magnetic fields acting on nuclear spins. The
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Book chapters on the topic "Magnetic isotope effect"

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Salikhov, Kev M. "Magnetic isotope effect in the presence of external magnetic fields." In Magnetic Isotope Effect in Radical Reactions. Springer Vienna, 1996. http://dx.doi.org/10.1007/978-3-7091-6569-0_4.

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Salikhov, Kev M. "Theoretical description of magnetic isotope effect in the Earth’s magnetic field." In Magnetic Isotope Effect in Radical Reactions. Springer Vienna, 1996. http://dx.doi.org/10.1007/978-3-7091-6569-0_3.

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Salikhov, Kev M. "Experimental evidences of magnetic isotope effect." In Magnetic Isotope Effect in Radical Reactions. Springer Vienna, 1996. http://dx.doi.org/10.1007/978-3-7091-6569-0_5.

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Salikhov, Kev M. "Introduction." In Magnetic Isotope Effect in Radical Reactions. Springer Vienna, 1996. http://dx.doi.org/10.1007/978-3-7091-6569-0_1.

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Salikhov, Kev M. "Main concepts of the theory of magnetic isotope effect." In Magnetic Isotope Effect in Radical Reactions. Springer Vienna, 1996. http://dx.doi.org/10.1007/978-3-7091-6569-0_2.

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Salikhov, Kev M. "Some perspectives." In Magnetic Isotope Effect in Radical Reactions. Springer Vienna, 1996. http://dx.doi.org/10.1007/978-3-7091-6569-0_6.

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Zverev, V. M. "Magnetoelasticity and Isotope Effect in Ferromagnets." In Itinerant Electron Magnetism: Fluctuation Effects. Springer Netherlands, 1998. http://dx.doi.org/10.1007/978-94-011-5080-4_15.

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Risley, J. M., and R. L. van Etten. "Properties and Chemical Applications of 18O Isotope Shifts in 13C and 15N Nuclear Magnetic Resonance Spectroscopy." In Isotope Effects in NMR Spectroscopy. Springer Berlin Heidelberg, 1990. http://dx.doi.org/10.1007/978-3-642-74835-6_3.

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Raynes, W. T. "Effects of Isotopic Substitution and Temperature on Nuclear Magnetic Shielding." In Nuclear Magnetic Shieldings and Molecular Structure. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1652-7_21.

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Kresin, Vladimir Z., Sergei G. Ovchinnikov, and Stuart A. Wolf. "Properties: Spectroscopy." In Superconducting State. Oxford University Press, 2021. http://dx.doi.org/10.1093/oso/9780198845331.003.0003.

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This chapter focuses on the spectroscopy of the superconducting state. Various manifestations of macroscopic quantisation are described, including flux quantisation, the Josephson effect, vortices, and the Little–Parks effect. The Ginzburg–Landau theory and its microscopic derivation are presented. An interesting new direction, the search for the lossless ground current state, undergoes an intensive development. If the electronic density of states contains several peaks, it manifests as a multigap structure. Impurity scattering and, especially, the pair-breaking effect can drastically affect t
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Conference papers on the topic "Magnetic isotope effect"

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Niki, Hideaki, and Iwao Kitazima. "Magnetic field effect on laser isotope separation of gadolinium and zirconium." In Advanced High-Power Lasers and Applications, edited by Kunioki Mima, Gerald L. Kulcinski, and William J. Hogan. SPIE, 2000. http://dx.doi.org/10.1117/12.375112.

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Yu, U., Yu V. Skrvpnyk, and B. I. Min. "Isotope effects in charge ordered colossal magnetoresistive (CMR) manganites." In IEEE International Magnetics Conference. IEEE, 1999. http://dx.doi.org/10.1109/intmag.1999.837974.

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Travis, J. C., J. D. Fassett, and L. J. Moore. "Thermal vaporization resonance ionization mass spectrometry." In OSA Annual Meeting. Optica Publishing Group, 1985. http://dx.doi.org/10.1364/oam.1985.tha1.

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The combination of the ionization efficiency and elemental selectivity of resonance ionization spectroscopy with the isotopic discrimination of mass spectrometry is known as resonance ionization mass spectrometry or RIMS. Much of the normal gestation period of any new analytical method can be circumvented by combining the new laser-ionization source with the time-tested technology of thermal ionization isotope-dilution mass spectrometry (IDMS). Use of a pulsed frequency-doubled tunable laser system provides broad access across the periodic table, with only infrequent (predictable and correctab
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Fleury, P. A., and K. B. Lyons. "Light scattering from spin and electronic excitations in Tc superconductors." In OSA Annual Meeting. Optica Publishing Group, 1988. http://dx.doi.org/10.1364/oam.1988.tuj2.

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The high-temperature superconductors now fall into several structural and compositional classes. However, they all are oxides of copper, show little or no isotope effect, are relatively poor metals in their normal state, have very low carrier densities, and are closely related in composition to compounds which exhibit magnetic order. All of these attributes, together of course with the very high values of Tc, strongly suggest that the heretofore very successful microscopic theory of superconductivity based on the electron-photon interaction is inadequate here. Alternative theories have now app
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Sharova, Y. S., and D. S. Shidlovski. "Numerical study of radiatively cooling partially ionized plasma expansion in neutral environment." In 8th International Congress on Energy Fluxes and Radiation Effects. Crossref, 2022. http://dx.doi.org/10.56761/efre2022.s2-p-033502.

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Plasma physics is a vast area of physics, which includes both fundamental aspects, such as, for example, astrophysics, and more applied ones: new compact plasma accelerators, compact powerful sources of X-ray and gamma radiation, new promising, practically inexhaustible sources of clean energy due to controlled thermonuclear fusion, compact ion sources for cancer therapy and isotope sources for nuclear medicine. Currently, studies of non-stationary and non-equilibrium processes in pulsed plasma created under the influence of high-intensity energy flows on matter are topical. Energy flows of mu
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Muncaci, S., S. Boboia, and I. Ardelean. "The effect of diffusion in internal gradients on nuclear magnetic resonance transverse relaxation measurements." In PROCESSES IN ISOTOPES AND MOLECULES (PIM 2013). AIP, 2013. http://dx.doi.org/10.1063/1.4833712.

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Hults, Malcolm, J. Czerwinska, and J. Heldt. "Electric quadrupole admixture in mixed forbidden lines of Sb I." In OSA Annual Meeting. Optica Publishing Group, 1987. http://dx.doi.org/10.1364/oam.1987.wf2.

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There are two forbidden spectral lines of neutral antimony (Sb I) in the visible range which are mixtures of magnetic dipole (MD) and electric quadrupole (EQ) radiation. Their Zeeman effect was studied previously to determine the relative intensities of these two types of radiation by using separated isotopes (121 and 123) and observing in both parallel and perpendicular directions to the magnetic field.1 Observation of interference between MD and EQ allows the determination of relative percentages of the two types of radiation in the line. A new computer simulation technique, recently develop
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Ciambella, Jacopo, and David C. Stanier. "Orientation Effects in Short Fibre-Reinforced Elastomers." In ASME 2014 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2014. http://dx.doi.org/10.1115/imece2014-40430.

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The large strain behaviour of a short fibre-reinforced composite is studied through numerical simulations. The reinforcing fibres yield the macroscopic response transversely isotropic which is indeed the case of many reinforcements currently used in composites: short carbon fibres, cellulose whiskers, carbon nanotubes. As a result of the analysis, it is shown that the reorientation of the fibres that takes place at large strain has a significant effect on the overall material response by changing the axis of isotropy. This behaviour can be adequately described by using a transversely isotropic
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Voss, D. F., K. A. Bunding, M. Nagumo, and L. S. Goldberg. "Second Harmonic Generation Studies of Adsorption and Reorientation at Electrode Surfaces." In Microphysics of Surfaces, Beams, and Adsorbates. Optica Publishing Group, 1985. http://dx.doi.org/10.1364/msba.1985.wa3.

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Second harmonic generation at surfaces (SSHG) has recently been the subject of increasing interest among researchers who require a probe of interfacial phenomena that is both surface-specific and can be utilized in condensed phase studies (see [1] and references therein). SSHG belongs to a larger class of second order nonlinear optical processes that includes optical rectification, sum and difference frequency mixing, and the Pockles effect, all of which are symmetry forbidden in isotropic media (at least in the electric dipole approximation [1]). At an interface between dissimilar media the i
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Al-Za’Al, Mohammad, Harold C. Miller, and John W. Farley. "High resolution spectroscopic studies of the negative molecular ion NH− using a color-center laser." In International Laser Science Conference. Optica Publishing Group, 1986. http://dx.doi.org/10.1364/ils.1986.tul4.

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We have performed high-resolution spectroscopic measurements on the negative molecular ion NH−. The infrared beam of a Burleigh FCL-20 color-center laser overlaps a parallel mass-selected 3-keV ion beam and induces vibrational-rotational transitions. The laser-excited ionic state autodetaches, yielding a fast (keV) collinear neutral NH, which is detected by secondary electron emission. Resonances are observed by scanning the ion velocity with fixed laser frequency. Our results more than quadruple the number of high-precision measurements in this system. Our results include the important Q and
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Reports on the topic "Magnetic isotope effect"

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Elling, John. Use of the Magnetic Isotope Effect for Silicon Isotopomer Chemical Separation. Office of Scientific and Technical Information (OSTI), 2021. http://dx.doi.org/10.2172/1772293.

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Turro, N. J. Photoreaction in microscopic reactions: Novel methods for the utilization of magnetic effects on chemical reactivity and isotope separation. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/6491112.

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Turro, N. J. Towards a quantitative approach to the utilization of magnetic effects as a means of isotopic enrichment. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/5225222.

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Turro, N. J. Towards a quantitative approach to the utilization of magnetic effects as a means of isotopic enrichment. [Progress report, January 1, 1989--April 1, 1992]. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/10152133.

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(Utilization of magnetic effects as a means of isotopic enrichment). Office of Scientific and Technical Information (OSTI), 1989. http://dx.doi.org/10.2172/5553867.

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