Academic literature on the topic 'Mahidol University Organophosphorus Compounds'

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Journal articles on the topic "Mahidol University Organophosphorus Compounds"

1

Zykova, A. "Synthesis and Structure of Aryl Phosphorus Compounds." Bulletin of the South Ural State University series "Chemistry" 12, no. 4 (2020): 5–50. http://dx.doi.org/10.14529/chem200401.

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Based on an analysis of the literature published from the late 20th century to the beginning of the 21st century, methods for the synthesis of some complex tetraorganylphosphonium salts are systematized and described, along with the features of the chemical transformations of pentaphenylphosphorus, which was first obtained in 1953. The tetraorganylphosphonium salts were known much earlier, however, the features of the synthesis of transition metal complexes, which are usually obtained from tetraorganylphosphorus halides and metal halides, have not been sufficiently studied. The present review is devoted to the discussion of these topics, since the famous Wittig Reaction is associated with aryl phosphorus compounds, which allows synthesizing alkenes of a given structure, and derivatives of transition metals rightfully occupy a special place among catalysts of various chemical processes. The continuation of these classical studies in the field of chemistry of organoelemental compounds takes place at one of the leading universities in Russia - South Ural State University in the laboratory of chemistry of organoelemental compounds at the Faculty of Chemistry. This article aims at familiarizing the reader with the achievements of Professor V.V. Sharutin and his students in the field of organophosphorus compounds. The main attention is paid to the reactions of pentaphenylphosphorus and its derivatives, as well as methods for the synthesis of ionic complexes of silver, gold, copper, titanium, zirconium, hafnium, ruthenium, osmium, cobalt, rhodium, iridium, palladium and platinum with tetraorganylphosphonium cations. The structural features of the described compounds and the possibility of using transition metal complexes in some catalytic reactions are described.
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2

Quin, Louis D. "The Chemistry of Functional Groups, Vol. 4: The Chemistry of Organophosphorus Compounds Edited by F. R. Hartley (Cranfield University). John Wiley & Sons, Inc. New York, NY. 1996. xiv + 945 pp. 15 × 22.5 cm. $375.00. ISBN 0-471-95706-2." Journal of Natural Products 60, no. 3 (1997): 323. http://dx.doi.org/10.1021/np960621z.

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3

McClure, Cynthia K. "The Chemistry of Organophosphorus Compounds. Volume 4. Ter- and Quinquevalent Phosphorus Acids and their Derivatives. The Chemistry of Functional Group Series Edited by Frank R. Hartley (Cranfield University, Cranfield, U.K.). Wiley: New York. 1996. xiv + 995 pp. $375.00. ISBN 0-471-95706-2." Journal of the American Chemical Society 119, no. 15 (1997): 3639–40. http://dx.doi.org/10.1021/ja965683q.

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Dissertations / Theses on the topic "Mahidol University Organophosphorus Compounds"

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Le, Ngoc Hung Juntra Karbwang Laothavorn. "Clinical pharmacology of artemisinin compounds in multidrug resistant falciparum malaria /." Abstract, 1999. http://mulinet3.li.mahidol.ac.th/thesis/2542/42E-LeNgocHung.pdf.

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Narayan, Urja Vidya. "Synthesis and characterization of phosphorous containing macromolecular polyether compounds." Scholarly Commons, 2006. https://scholarlycommons.pacific.edu/uop_etds/640.

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A radioisotope of rubidium, 82Rb is used in positron emission tomography. Neutral crown ethers and cryptands have been studied as carrier ligands for Rb+ but exhibit low ion carrying capacity and high toxicity. The present study involved investigating a lariat ether containing an ionizable phosphoryl moiety and a lipophilic sidearm. This kind of molecule is expected to be ionized at physiological pH. It should be able to form neutral complexes with Rb+ and may be able to cross the blood-brain barrier. Molecular modeling of crown ether-alkali metal cation complexes indicates that a macrocycle containing more than 18 but less than 21 atoms can incorporate Rb+ ion in its cavity. Molecular modeling of some of the complexes of phospho-lariat ethers with rubidium using the Spartan'02 software package revealed that a lariat ether containing 20 member macrocycle will probably form the most stable complex with Rb+ion. Also, it was thought that more flexibility could be imparted to the macrocycle if it contains propyleneoxy units instead of ethyleneoxy units which form most crown ethers. Molecular modeling of two phospho-lariat ethers with 16 and 20 membered rings revealed that 20 membered macrocycle may be a better choice due to the side arm's participation in the complexation with Rb+ to a greater extent. Molecular modeling was used to find the bond angles and bond distances in this molecule. The synthesis to obtain ionizable phospho-bipodands was performed using subsequent benzylation, phosphorylation and hydrogenation steps. The characterization of products was done using HPLC, NMR and ESI-MS techniques. The synthetic scheme used was demonstrated to be plausible and could be used to obtain ionizable phoshobipodands. Extraction using solid phase anion exchange columns proved to be a good clean up procedure for obtaining pure bipodand. This bipodand could be used as a precursor for synthesizing an ionizable 20 membered lariat ether.
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Nillos, Mae Grace Gareza. "Stereoselectivity in modern-use chiral pesticides enantiomer-specific ecotoxicological assessment of chiral organophosprus, Fipronil and Pyrethroid insecticides /." Diss., UC access only, 2009. http://proquest.umi.com/pqdweb?index=144&did=1871875461&SrchMode=1&sid=1&Fmt=7&retrieveGroup=0&VType=PQD&VInst=PROD&RQT=309&VName=PQD&TS=1270494617&clientId=48051.

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4

Johnson, Frank Orlando. "Behavioral outcomes and molecular marker modulation during learning and memory formation following developmental exposure to organophoshorus insecticides." Diss., Mississippi State : Mississippi State University, 2007. http://library.msstate.edu/etd/show.asp?etd=etd-03122009-143101.

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O'Hair, Richard Alfred John. "Studies in gas phase ion chemistry : a thesis presented for the degree of Doctor of Science in the Faculty of Science of the University of Adelaide /." Title page, table of contents and summary only, 2004. http://web4.library.adelaide.edu.au/theses/09SD/09sdo362.pdf.

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