Academic literature on the topic 'Mannich condensation reaction, polybenzoxazine synthesis, characterization'

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Journal articles on the topic "Mannich condensation reaction, polybenzoxazine synthesis, characterization"

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Journal, Baghdad Science. "Synthesis and Characterization of Some New Benzimidazole Derivatives." Baghdad Science Journal 13, no. 1 (2016): 82–88. http://dx.doi.org/10.21123/bsj.13.1.82-88.

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In this paper the new starting material 2-(5-chloro-1H-benzo[d]imidazole-2-yl) aniline (1) was synthesized by the condensation reaction of 4-chloro-o-phenylenediamine and anthranilic acid .The new Mannich base derivatives were synthesized using formaldehyde and different secondary amines to synthesize a new set of benzimidazole derivatives(2-5). Also, the new Schiff-base derivatives (6-10) were synthesized from the reaction of compound (1) with various aromatic aldehydes and the closure-ring was done successfully using mercapto acetic acid to get the new thiazolidine derivatives(11-12).These n
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2

Rani, V. E., and L. K. Ravindranath. "Synthesis, Characterization and Antimicrobial Evaluation of Novel Mannich Bases Containing Pyrazole-5-One Phosphonates." Open Pharmaceutical Sciences Journal 3, no. 1 (2016): 49–55. http://dx.doi.org/10.2174/1874844901603010049.

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Background: Newly synthesised compounds of phosphonates were prepared by condensation of diethylphosphate with imine which undergoes a reaction of mannich bases with pyrazole containing schiffs base. The base was prepared by condensation of aldehyde with primary amine. These newly synthesised derivatives were characterised by spectral analysis. Objective: Mannich bases are very important to synthesize wide variety of natural products and pharmaceuticals. Method: Thin Layer Chromatography was performed on aluminum sheet of silica gel 60F254, E-Merk, Germany using iodine as visualizing agent. IR
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Rohimi, Nurfatin Farhanah, Rasidi Roslan, Nurjannah Salim, Siti Noor Hidayah Mustapha, Sarani Zakaria, and Chin Hua Chia. "Lignin-Based Polybenzoxazine Derived from Empty Fruit Bunch Fibers with Good Thermal and Mechanical Properties." Materials Science Forum 981 (March 2020): 121–26. http://dx.doi.org/10.4028/www.scientific.net/msf.981.121.

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In this study, a renewable phenolic component was synthesized using empty fruit bunch fibers via microwave-assisted liquefaction known as Liquefied Empty Fruit Bunch (LEFB). LEFB can be used as phenolic derivative to replace petroleum-based phenol as it contains aromatic group in lignin that can be used as starting materials to synthesis polybenzoxazine resins. A Lignin-based benzoxazine (L-PBz) has been synthesized using a solventless approach from the reaction of LEFB, furfurylamine as the amine component and paraformaldehyde via Mannich condensation reaction. Two different ratios of LEFB:fu
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4

Sharma, Piush, and Charanjeet Singh. "Synthesis, characterization and biological evaluation of some novel N-Mannich bases of heterocyclic 1,3,4-thiadiazole." Journal of Drug Delivery and Therapeutics 9, no. 4-A (2019): 220–28. http://dx.doi.org/10.22270/jddt.v9i4-a.3332.

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A series of some novel N-Mannich bases of heterocyclic 1,3,4-thiadiazole were synthesized through the condensation reaction of 1,3,4-thiadiazole containing a aromatic secondary amine, aromatic aldehydes and cyclic compounds employing Mannich reaction and using conventional synthesis. All the synthesized compounds were obtained in the range of 57.41-83.3 % yield. The structures of synthesized compounds were confirmed by UV, IR, 1H NMR spectroscopy. the essential structural features responsible for interaction with receptor site are established within a suggested pharmacophore. The in vitro anti
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5

Abdulghani, Ahlam J., and Nada M. Abbas. "Synthesis Characterization and Biological Activity Study of New Schiff and Mannich Bases and Some Metal Complexes Derived from Isatin and Dithiooxamide." Bioinorganic Chemistry and Applications 2011 (2011): 1–15. http://dx.doi.org/10.1155/2011/706262.

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Two new Schiff and Mannich bases, namely, 1-Morpholinomethyl-3(1′ -N-dithiooxamide)iminoisatin (LIH) and 1-diphenylaminomethyl-3-1′-N-dithiooxamide)iminoisatin (LIIH), were prepared from condensation reaction of new Schiff base 3-(1′-N-dithiooxamide)iminoisatin (SBH) with morpholine or diphenylamine respectively in presence of formaldehyde . The structures were characterized by IR,1HNMR, mass spectrometry, and CHN analyses. Metal complexes of the two ligands were synthesized, and their structures were characterized by elemental analyses, atomic absorption, IR and UV-visible spectra, molar cond
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Nkurunziza, Jean Baptiste, Pierre Dukuziyaturemye, Edith Musabwa, and Balakrishna Kalluraya. "Facile Synthesis, Characterization and in Silico Docking Studies of Novel Thiazolidine-2,4-Dione-Based Mannich Base Bearing Furan/Thiophene Moiety as Promising Anti-Inflammatory Agents." Rwanda Journal of Engineering, Science, Technology and Environment 4, no. 1 (2021). http://dx.doi.org/10.4314/rjeste.v4i1.5.

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Mannich bases are compounds bearing a β-amino carbonyl moiety. They are formed in the Mannich reaction that consists of an amino alkylation of an acidic proton placed next to a carbonyl functional group by formaldehyde and a primary or secondary amine. Mannich base products are known for their curative properties such as anti-inflammatory, antibacterial, anticancer, antifungal, anthelmintic, anticonvulsant, analgesic, anti-HIV, antipsychotic, antiviral, and antimalarial activities. Further, thiazolidinedione derivatives have shown to be efficacious in inflammatory diseases as wide-ranging as p
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Dissertations / Theses on the topic "Mannich condensation reaction, polybenzoxazine synthesis, characterization"

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Efe, Tugba. "Synthesis And Characterization Of Polybenzoxazine." Master's thesis, METU, 2009. http://etd.lib.metu.edu.tr/upload/2/12610346/index.pdf.

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A new method for polybenzoxazine synthesis was developed and carried out throughout this work. Bisphenol-A, hexamethylenediamine, and paraformaldehyde were reacted through Mannich condensation reaction forming polybenzoxazine precursors. The reaction was followed by Gel Permeation Chromatography (GPC) as a molecular weight determination method in order to decide the end of reaction. The synthesized product, polybenzoxazine precursors, was polymerized thermally. Polybenzoxazine precursors were also characterized by using spectroscopic methods, 1H-NMR and FTIR, giving an approximation to structu
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