Academic literature on the topic 'Mechanism of iridium(III)'

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Journal articles on the topic "Mechanism of iridium(III)"

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B., Dharma Rao, Baby Nirmala N., and Vani P. "Kinetics and mechanism of iridium(III) catalysed oxidation of DL-methionine by alkaline hexacyanoferrate(III)." Journal of Indian Chemical Society Vol. 90, Mar 2013 (2013): 365–71. https://doi.org/10.5281/zenodo.5769719.

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Department of Inorganic and Analytical Chemistry, School of Chemistry, Andhra University, Visakhapatnam-530 003, Andhra Pradesh, India <em>E-mail</em> : vani_chem@rediffmail.com <em>Manuscript received online 07 April 2012, revised 04 May 2012, accepted 22 May 2012</em> Iridium(lll) catalysed oxidation of DL-methionine by hexacyanoferrate(III) was studied spectrophotometrically in aqueous alkaline medium at 30 &plusmn; 0.1 &deg;C&nbsp;at a constant ionic strength. A micro amount of iridium(III) was sufficient to catalyse the slow reaction between DL-methionine and hexacyanoferrate(III). The re
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Anjali, Goel, R. Verma G., and S. Singh H. "Kinetics and mechanism of iridium(III) chloride catalyzed oxidation of ethylene glycol and methyl glycol by hexacyanoferrate(III) in aqueous alkaline medium." Journal of Indian Chemical Society Vol. 79, Aug 2002 (2002): 665–67. https://doi.org/10.5281/zenodo.5843309.

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Department of Chemistry. Kanya Gurukul Mahavidhyalaya, Gurukul Kangri University, Jwalapur, Hardwar-249 407, India <em>E-mail : </em>dr_anjaligoel@rediffmail.com&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <em>Fax : </em>91-0133-452290 Chemistry Department, S. D. (P.G.) College, Muzaffernagar-251 001, India Chemical Laboratories, University of Allahabad, Allahabad-21 1 002, India <em>Manuscript received 28 July 2000, revised 27 September 2001. accepted 21 March 2002</em> The iridiurn(III) chloride catalyzed oxidation of ethylene glycol and me
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Shang, Xiaohong, Ning Wan, Deming Han, and Gang Zhang. "A theoretical study on the injection, transport, absorption and phosphorescence properties of heteroleptic iridium(iii) complexes with different ancillary ligands." Photochem. Photobiol. Sci. 13, no. 3 (2014): 574–82. http://dx.doi.org/10.1039/c3pp50394a.

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Pèrez-Miqueo, Jorge, Virginia San Nacianceno, F. Borja Urquiola, and Zoraida Freixa. "Revisiting the iridacycle-catalyzed hydrosilylation of enolizable imines." Catalysis Science & Technology 8, no. 24 (2018): 6316–29. http://dx.doi.org/10.1039/c8cy01236a.

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Cao, Jian-Jun, Cai-Ping Tan, Mu-He Chen, et al. "Targeting cancer cell metabolism with mitochondria-immobilized phosphorescent cyclometalated iridium(iii) complexes." Chemical Science 8, no. 1 (2017): 631–40. http://dx.doi.org/10.1039/c6sc02901a.

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He, Liang, Yi Li, Cai-Ping Tan, et al. "Cyclometalated iridium(iii) complexes as lysosome-targeted photodynamic anticancer and real-time tracking agents." Chemical Science 6, no. 10 (2015): 5409–18. http://dx.doi.org/10.1039/c5sc01955a.

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We report the rational design and photodynamic anticancer mechanism studies of iridium(iii) complexes with pH-responsive singlet oxygen (<sup>1</sup>O<sub>2</sub>) production and lysosome-specific imaging properties.
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Kim, Kye-Young, Richard T. Farley, and Kirk S. Schanze. "An Iridium(III) Complex that Exhibits Dual Mechanism Nonlinear Absorption." Journal of Physical Chemistry B 110, no. 35 (2006): 17302–4. http://dx.doi.org/10.1021/jp063916m.

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Zhang, Cheng, Shang-Hai Lai, Hui-Hui Yang, et al. "Photoinduced ROS regulation of apoptosis and mechanism studies of iridium(iii) complex against SGC-7901 cells." RSC Advances 7, no. 29 (2017): 17752–62. http://dx.doi.org/10.1039/c7ra00732a.

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A new iridium(iii) complex, Ir(ppy)<sub>2</sub>(FBPIP)]PF<sub>6</sub> (Ir-1), was synthesized and characterized. The anticancer activity of the complex was investigated by cytotoxicity in vitro, apoptosis, cell invasion, autophagy, cell cycle arrest and western blot.
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Tellers, David M., and Robert G. Bergman. "Mechanistic study of ligand substitution processes in TpIr(III) complexes." Canadian Journal of Chemistry 79, no. 5-6 (2001): 525–28. http://dx.doi.org/10.1139/v00-162.

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The synthesis of the cationic hydridotris(pyrazolyl)borate iridium(III) complex [Tp(PMe3)IrMe(ClCH2Cl)][BArf] (2-CH2Cl2) is reported. Spectroscopic characterization of 2-CH2Cl2 in CH2Cl2 solution indicates that exchange of bound CH2Cl2 with free CH2Cl2 is slow on the NMR time scale. Under 50 atm (1 atm = 101.325 kPa) of N2, the CH2Cl2 in 2-CH2Cl2 is displaced by N2 to yield [Tp(PMe3)IrMe(N2)][BArf] (2-N2). The stronger nucleophile CH3CN reacts rapidly with 2-CH2Cl2 to produce [Tp(PMe3)IrMe(NCCH3)][BArf] (4). A kinetic study was performed on CH2Cl2 substitution in 2-CH2Cl2 by CD3CN. The data ar
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Novohradsky, Vojtech, Zhe Liu, Marie Vojtiskova, Peter J. Sadler, Viktor Brabec, and Jana Kasparkova. "Mechanism of cellular accumulation of an iridium(iii) pentamethylcyclopentadienyl anticancer complex containing a C,N-chelating ligand." Metallomics 6, no. 3 (2014): 682–90. http://dx.doi.org/10.1039/c3mt00341h.

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A new antitumor iridium complex [(η<sup>5</sup>-Cp*)(Ir)(bq)Cl] (Cp* = pentamethylcyclopentadienyl, bq = 7,8-benzoquinoline) and conventional cisplatin have contrasting mechanisms of accumulation in ovarian cancer cells.
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Dissertations / Theses on the topic "Mechanism of iridium(III)"

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Tu, Jing. "Exploiting an unexpected reactivity of cyclometalated iridium dimers for the direct synthesis of [Ir(C^N)2(O^CN)] complexes." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2022.

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Here we present the exploitation of the mechanism of the unexpected reactivity of μ-dichloro-bridged dimeric complex with formula [Ir(C^N)2Cl2] for the direct synthesis of [Ir(C^N)2(OC^N)] complexes (named JTG). JTG is an octahedral iridium complex with three cyclometalating ligands in meridional structure, where C^N indicates 2-phenylpyridyl and OC^N indicates that a oxygen is inserted between carbon from the 2-phenylpyridyl and center iridium ion. A series of synthesis conditions were investigated to understand the formation of the JTG. During the research process, the formation of meridiona
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Talwar, Dinesh. "Hydrogenation and dehydrogenation with cyclometalated iridium (III) complexes." Thesis, University of Liverpool, 2014. http://livrepository.liverpool.ac.uk/2003856/.

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The selective hydrogenation and dehydrogenation of organic molecules is a fundamentally challenging and an attractive transformation for both, industry and academia. However, catalysts capable of undergoing both transformations under environmentally benign conditions are rare. In this thesis, our contribution to the development of a “universal” catalyst capable of achieving both hydrogenation and dehydrogenation of a wide range of organic compounds under mild conditions is presented. A general introduction covering the recent developments in the area of transfer hydrogenation of C=X (X = O, N)
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Karpin, George W. "Synthesis and Antimicrobial Activity of Half-Sandwich Ir(III), Rh(III), and Co(III) Complexes." Diss., Virginia Tech, 2017. http://hdl.handle.net/10919/79414.

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This dissertation describes the synthesis and antimicrobial use of a series of half-sandwich Ir(III), Rh(III), Co(III) amino acid and ethylenediamine complexes. This investigation focuses on the formulation (ηn-arene)M(L)X, (L = ethylenediamine or α-amino carboxylate), (M= Ir, Rh, Ru, Co). Arene, Ligand and metal center variations were designed to tailor antimicrobial activity specific for each organism studied (Staphylococcus aureus or Mycobacteria). Each of the D/L-amino acids formed a diasteromeric complex with chiral centers on both the metal center and amino acid ligand. The unique chira
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Weigand, Stefan. "Metallierung von Pyridylmetallocenen durch Platin(II), Gold(III), Quecksilber(II) und Iridium(III)." Diss., Ludwig-Maximilians-Universität München, 2013. http://nbn-resolving.de/urn:nbn:de:bvb:19-166074.

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Leung, Ka Ho. "Oligonucleotide-based lunimescent detection platform utilizing iridium (III) complexes." HKBU Institutional Repository, 2015. https://repository.hkbu.edu.hk/etd_oa/163.

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Luminescent transition metal complexes have arisen as viable alternatives to organic dyes for sensory applications due to their notable advantages. This thesis aimed to synthesize different kinds of Ir(III) complexes, explore their interactions with DNAs and investigate their application for the construction of label-free oligonucleotide-based sensing platforms. A series of Ir(III) complexes incorporating a variety of C^N and N^N donor ligands were synthesized and were shown to exhibit G-quadruplex-selective binding properties via emission titration, UV/vis titration, fluorescence resonance en
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Wang, Modi. "The application of iridium(iii) complexes in luminescent sensing." HKBU Institutional Repository, 2016. http://repository.hkbu.edu.hk/etd_oa/296.

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Luminescent transition metal complexes have arisen as viable alternatives to organic dyes for sensory applications due to their notable advantages. This thesis aimed to synthesize different kinds of iridium(III) complexes as chemosensors and G-quadruplex probes for the detection of metal ions, small molecules, proteins and DNA to demonstrate the versatility of iridium(III) complex in luminescence sensing. Iridium(III) complex chemosensors were synthesized and developed for the detection of Cu2+ and cysteine. The iridium(III) complex plays the role of the "signaling unit", which transduces the
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Brown, Loren. "Rapid Synthesis, Characterization, and Catalytic Function of Rhodium(III) and Iridium(III) Chloro-bridged Dimers." Diss., Virginia Tech, 2019. http://hdl.handle.net/10919/89732.

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Rh(III) and Ir(III) dimeric complexes with tunable cyclopentadienyl (Cp) rings have proven versatile for both catalysis and as synthetic precursors. An efficient microwave method to synthesize Rh(III) and Ir(III) dimeric complexes [(η5-ring)MCl]2(μ2-Cl)2, (where (η5-ring)MCl = (η5-Me4C5R)Rh(III)Cl or (η5-Me4C5R)Ir(III)Cl) was developed. A modular design for the substituted cyclopentadienes HC5Me4R was based on Grignard reactions of 2,3,4,5-tetramethylcyclopent-2-en-1-one (R = alkyl, 12 examples; R = aryl, 3 examples) or by SNAr reactions of potassium tetramethylcyclopentadienide with perfluoro
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Bhangu, Kiran. "Synthesis and reactivity of terminal phosphido complexes of iridium(III)." Thesis, University of British Columbia, 1987. http://hdl.handle.net/2429/26168.

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The iridium(III) methyl dlarylphosphido complexes, Ir(CH₃)(PR₂)-[N(SiMe₂CH₂PPh₂)₂] (2a: R = phenyl, 2b: R = meta-tolyl), have been successfully prepared by transmetalation of the iridium(III) methyl iodide complex, Ir(CH₃)(I)[N(SiMe₂CH₂PPh₂)₂], with the corresponding lithium diarylphosphide. Based primarily on a nuclear Overhauser effect difference experiment, these complexes are assigned a stereochemistry intermediate between square pyramidal and trigonal bipyramidal forms. The pyramidal geometry at the phosphido ligand is evident from the ³¹P{¹H} NMR spectral data. The complex 2a affords a
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Tian, Nan [Verfasser]. "Phosphorescent iridium(III) complexes, copolymers and their applications / Nan Tian." Wuppertal : Universitätsbibliothek Wuppertal, 2012. http://d-nb.info/1025663772/34.

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Bettington, Sylvia. "The synthesis and photophysical studies of cyclometalated iridium(III) complexes." Thesis, Durham University, 2003. http://etheses.dur.ac.uk/1295/.

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In 1985, fac-Ir(ppy)3 was characterised as the first triply ortho-metalated iridium(III) species. This bright yellow solid exhibits green phosphorescent emission. Since then, numerous related iridium(III) complexes of the formula Ir(L)3 and Ir(L)2acac have been synthesised utilising ligands such as 2-phenylpyridine (ppy), 4-(2-pyridyl)benzaldehyde (fppy), benzo[h]-quinoline (bzq) and 2-(2-thienyl)pyridine (thpy), to name, but a few. These complexes give rise to tuneable emission wavelengths via ligand modification and also exhibit electroluminescence allowing them to be used as phosphorescent
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Books on the topic "Mechanism of iridium(III)"

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Zysman-Colman, Eli, ed. Iridium(III) in Optoelectronic and Photonics Applications. John Wiley & Sons, Ltd, 2017. http://dx.doi.org/10.1002/9781119007166.

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Beran, Jaroslav, Martin Bílek, Miroslav Václavík, and Petr Žabka, eds. Advances in Mechanism Design III. Springer International Publishing, 2022. http://dx.doi.org/10.1007/978-3-030-83594-1.

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R, Stein Matthew, and Society of Photo-optical Instrumentation Engineers., eds. Telemanipulator and telepresence technologies III: 18-19 November 1996, Boston, Massachusetts. SPIE, 1996.

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Ratner, Lee. Mechanism of cytotoxicity of the AIDS virus, HTLV-III/LAV: Annual report. Washington University, 1988.

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Ratner, Lee. Mechanism of cytotoxicity of the AIDS virus, HTLV-III/LAV: Annual report. Washington University, 1994.

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Bellouard, Yves. Optomechatronic actuators and manipulation III: 8-10 October 2007, Lausanne, Switzerland. Edited by Society of Photo-optical Instrumentation Engineers, École polytechnique fédérale de Lausanne, France. Commissariat à l'énergie atomique. Laboratoire d'intégration des systèmes et des technologies, and Fondation suisse pour la recherche en microtechnique. SPIE, 2007.

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Klüglein, Nicole. Bacterial Fe(III) reduction and Fe(II) oxidation: Relevance for magnetite formation in the environment and the mechanism of nitrate-dependent Fe(II) oxidation. s.n.], 2014.

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Baillairgé, Charles P. Florent. The human mechanism the most marvelous ... to be read by C. Baillairgé before Section III of the Royal Society of Canada at its May meeting, 1901. s.n., 1995.

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Pocsatko, Cirstina. Iridium(I)- und Iridium(III)-(Ether-phosphan)-Komplexe: Cyclovoltammetrische Untersuchungen. 1993.

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Zysman-Colman, Eli. Iridium(III) in Optoelectronic and Photonics Applications. Wiley & Sons, Limited, John, 2017.

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Book chapters on the topic "Mechanism of iridium(III)"

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Ford, P. C. "Of Rhodium(III) and Iridium(III)." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145302.ch73.

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Williams, J. A. Gareth. "Multinuclear Iridium Complexes." In Iridium(III) in Optoelectronic and Photonics Applications. John Wiley & Sons, Ltd, 2017. http://dx.doi.org/10.1002/9781119007166.ch2.

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Laird, Sarah E., and Conor F. Hogan. "Electrochemiluminescence of Iridium Complexes." In Iridium(III) in Optoelectronic and Photonics Applications. John Wiley & Sons, Ltd, 2017. http://dx.doi.org/10.1002/9781119007166.ch8.

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Brinkmann, Susanne, Robert H. Morris, Ravindranath Ramachandran, et al. "Pentahydridobis(Tricyclohexylphosphine)-Iridium(V) and Trihydridotris(Triphenylphos-phine)Iridium(III)." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132630.ch49.

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Zhang, Kenneth Yin, Shujuan Liu, Qiang Zhao, Fuyou Li, and Wei Huang. "Phosphorescent Iridium(III) Complexes for Bioimaging." In Luminescent and Photoactive Transition Metal Complexes as Biomolecular Probes and Cellular Reagents. Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/430_2014_166.

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Longhi, Elena, and Luisa De Cola. "Iridium(III) Complexes for OLED Application." In Iridium(III) in Optoelectronic and Photonics Applications. John Wiley & Sons, Ltd, 2017. http://dx.doi.org/10.1002/9781119007166.ch6.

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Corbucci, Ilaria, Alceo Macchioni, and Martin Albrecht. "Iridium Complexes in Water Oxidation Catalysis." In Iridium(III) in Optoelectronic and Photonics Applications. John Wiley & Sons, Ltd, 2017. http://dx.doi.org/10.1002/9781119007166.ch13.

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Crabtree, Robert H., Michelle F. Mellea, Jean M. Mihelcic, Ayusman Sen, and Venkatasuryanaryana Chebolu. "Dihydridobis(Solvent)Bis(Triphenylphosphine)Iridium(III) Tetrafluoroborates." In Inorganic Syntheses. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470132579.ch22.

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Monos, Timothy M., and Corey R. J. Stephenson. "Photoredox Catalysis of Iridium(III)-Based Photosensitizers." In Iridium(III) in Optoelectronic and Photonics Applications. John Wiley & Sons, Ltd, 2017. http://dx.doi.org/10.1002/9781119007166.ch11.

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Winter, Andreas, and Ulrich S. Schubert. "Polymeric Architectures Containing Phosphorescent Iridium(III) Complexes." In Iridium(III) in Optoelectronic and Photonics Applications. John Wiley & Sons, Ltd, 2017. http://dx.doi.org/10.1002/9781119007166.ch5.

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Conference papers on the topic "Mechanism of iridium(III)"

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Chi, Yun, and Jie YAN. "Homoleptic iridium(III) carbene complexes as efficient blue OLED phosphors?" In Organic and Hybrid Light Emitting Materials and Devices XXVIII, edited by Tae-Woo Lee, Franky So, and Ji-Seon Kim. SPIE, 2024. http://dx.doi.org/10.1117/12.3026978.

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Burn, Paul L. "Seeing is believing: experimental 3D mapping of iridium(III) complexes in light-emitting guest:host blends." In Organic and Hybrid Light Emitting Materials and Devices XXVIII, edited by Tae-Woo Lee, Franky So, and Ji-Seon Kim. SPIE, 2024. http://dx.doi.org/10.1117/12.3023720.

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Knorr, Erica S., Jordan C. Kelly, Daniel P. Harrison, and Thomas N. Rohrabaugh. "Effect of electron-donating and -withdrawing groups on the photophysical properties of iridium (iii) diphenyl quinoxaline complexes." In Organic Photonic Materials and Devices XXVII, edited by Ileana Rau, Okihiro Sugihara, and William M. Shensky. SPIE, 2025. https://doi.org/10.1117/12.3047905.

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Liu, Xiao Ying, Gong Yu Fan, and Yan Jun Zhang. "Type III Solar Radio Bursts Recognition Based on Mask R-CNN with Attention Mechanism." In 2024 International Conference on Computer Communication, Networks and Information Science (CCNIS). IEEE, 2024. https://doi.org/10.1109/ccnis64984.2024.00031.

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Lo, Shih-Chun. "Phosphorescent Iridium (III) Complexes for Organic Light Emitting Diodes." In Solid-State and Organic Lighting. OSA, 2014. http://dx.doi.org/10.1364/soled.2014.dth4c.3.

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Ribierre, J. C., S. V. Staton, P. L. Burn, and I. D. W. Samuel. "Phosphorescent iridium(III) cored dendrimers for light-emitting displays." In SPIE Optics + Photonics, edited by Zakya H. Kafafi and Franky So. SPIE, 2006. http://dx.doi.org/10.1117/12.683380.

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Tong, Bihai, and Zhao Han. "Electrophosphorescence of a Thiocyanate-Bridging Dimeric Cyclometalated Iridium(III) Complex." In 2012 Symposium on Photonics and Optoelectronics (SOPO 2012). IEEE, 2012. http://dx.doi.org/10.1109/sopo.2012.6270556.

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Wong, Wai-Yeung. "New Color-Tunable Metallophosphors of Iridium(III) and Platinum(II)." In Photonics for Energy. OSA, 2019. http://dx.doi.org/10.1364/pfe.2019.ptu2e.1.

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Huang, J., Y. D. Jiang, X. Z. Tang, and J. Bi. "Synthesis and characterization of a novel organic phosphorescent Iridium(III) complex." In 2009 16th IEEE International Symposium on the Physical and Failure Analysis of Integrated Circuits (IPFA). IEEE, 2009. http://dx.doi.org/10.1109/ipfa.2009.5232572.

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Li, Steve Po-Yam, Johnson Lui-Lui Tsai, and Kenneth Kam-Wing Lo. "Luminescent iridium(III) polypyridine PEG complexes: Synthesis, photophysical, and biological properties." In 2010 IEEE 4th International Conference on Nano/Molecular Medicine and Engineering (NANOMED). IEEE, 2010. http://dx.doi.org/10.1109/nanomed.2010.5749807.

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Reports on the topic "Mechanism of iridium(III)"

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Neal, Andrew. Molecular Mechanism of Bacterial Attachment to Fe(III)-Oxide Surfaces. Office of Scientific and Technical Information (OSTI), 2006. http://dx.doi.org/10.2172/896798.

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Fugate, G., J. F. Feil-Jenkins, J. C. Sullivan, and K. L. Nash. Actinide complexation kinetics: rate and mechanism of dioxoneptunium (V) reaction with chlorophosphonazo III. Office of Scientific and Technical Information (OSTI), 1996. http://dx.doi.org/10.2172/436450.

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Wilmsen, C. W. Growth Mechanism and Properties of the Thermal and Anodic Oxides of the III-V Compound Semiconductors. Defense Technical Information Center, 1985. http://dx.doi.org/10.21236/ada153406.

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Wagner, Rodrigo. Mechanism for Market Valuation of State-Owned Enterprises without Privatization. Inter-American Development Bank, 2017. http://dx.doi.org/10.18235/0007032.

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State-owned enterprises (SOEs), including state-owned banks, can be both systemically and politically important for many economies. While many of these firms have been privatized in recent decades, for various political or practical reasons many are likely to remain 100 percent state-owned, which prevents them from obtaining a market-based valuation. Having a market signal for the value of SOEs could be desirable because it could help: (i) inform the treasury of the net present value (NPV) of expected cash flows; (ii) impose some discipline on management; (iii) signal changes in capture by ent
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Banin, Amos, Joseph Stucki, and Joel Kostka. Redox Processes in Soils Irrigated with Reclaimed Sewage Effluents: Field Cycles and Basic Mechanism. United States Department of Agriculture, 2004. http://dx.doi.org/10.32747/2004.7695870.bard.

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The overall objectives of the project were: (a) To measure and study in situ the effect of irrigation with reclaimed sewage effluents on redox processes and related chemical dynamics in soil profiles of agricultural fields. (b) To study under controlled conditions the kinetics and equilibrium states of selected processes that affect redox conditions in field soils or that are effected by them. Specifically, these include the effects on heavy metals sorption and desorption, and the effect on pesticide degradation. On the basis of the initial results from the field study, increased effort was de
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Cárdenas, Juan Camilo, Alberto E. Chong, and Hugo R. Ñopo. To What Extent do Latin Americans Trust and Cooperate?: Field Experiments on Social Exclusion In Six Latin American Countries. Inter-American Development Bank, 2008. http://dx.doi.org/10.18235/0010887.

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This paper explores the extent to which individuals trust, reciprocate, cooperate and pool risk by using a battery of field experiments containing the trust game, the voluntary contributions mechanism and the risk pooling game; applied in six capital cities in Latin America. The results suggest that: (i) on average, the propensity to trust and cooperate among Latin Americans is remarkably similar to that found in other regions of the world; (ii) expectations about the behavior of other players are the main driver of trust, reciprocity and cooperation; and (iii) behaviors involving socializatio
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Linker, Taylor, and Timothy Jacobs. PR-457-18204-R01 Variable Fuel Effects on Legacy Compressor Engines Phase IV - Predictive NOx Modeling. Pipeline Research Council International, Inc. (PRCI), 2019. http://dx.doi.org/10.55274/r0011584.

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The ultimate goal of this work is to improve the current control methods for large bore, lean burn natural gas engines in order to combat performance and emissions issues during variable fuel composition events. This will be achieved in the long term by simulating the effects of variable fuel composition on a large bore, natural gas engine and developing engine control strategies which work to mitigate adverse effects. The work of Phase IV adds onto previous work by enabling the prediction of NOxemissions in the validated, full-scale engine simulation of a Cooper-Bessemer GMWH-10C developed in
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Székely, Miguel. Policy Options for Poverty Alleviation. Inter-American Development Bank, 1997. http://dx.doi.org/10.18235/0010754.

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This work builds on previous research to develop a methodology that simplifies the identification of the best policy options for poverty alleviation in a given country. When a population can be divided into subgroups according to an easily identifiable characteristic, the problem of alleviating poverty through a targeted mechanism can be viewed as one of choosing of three options: (i) provoking a marginal change in the average income of certain subgroups; (ii) changing the resource distribution within marginal subgroups; and (iii) generating a marginal change in the differences between the sub
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Pinzón-Puerto, Freddy, and Mauricio Villamizar-Villegas. Do Actions Speak Louder than Words? A Foreign Exchange Intervention Analysis. Banco de la República Colombia, 2023. http://dx.doi.org/10.32468/be.1223.

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We revisit an old question but with a new identification strategy, namely the difference in exchange rate effects between announced (“vocal”) and secret (“dirty”) foreign exchange intervention. Using a Regression Discontinuity Design, we exploit a rule-based intervention mechanism enacted by the Central Bank of Colombia that, under observable and deterministic conditions, triggered either the issuance of FX options or the ability to exercise them. We take the former (issuance) as central bank announcements under a sharp setting, since the rule and information that triggered the issuance of opt
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Juco, Marianne, Ricxie Maddawin, Robert Hector Palomar, Mark Gerald Ruiz, and Charlotte Justine Diokno-Sicat. Baseline Study on the State of Devolution in the (Pre-Mandanas) Philippines. Philippine Institute for Development Studies, 2023. http://dx.doi.org/10.62986/dp2023.09.

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Two key recent events pushed forward the country’s decentralization agenda. In 2019, the Mandanas-Garcia Supreme Court (“Mandanas”) ruling increased the tax base for intergovernmental fiscal transfers in support of local governments’ autonomy and revenue-raising capacity. In 2021, Executive Order No. 138 (EO 138) laid the guidelines for effectively transitioning functions and responsibilities from the national to the local governments. Part of the directives in EO 138 is the design and review of devolution transition plans (DTPs). Given the country’s current state of devolution, uncertainty ar
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