Relevant bibliographies by topics / Mechanism of the Hydrolysis

Contents

  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers
  6. Reports

Academic literature on the topic 'Mechanism of the Hydrolysis'

Author: Grafiati
Published: 5 June 2025
Last updated: 1 August 2025

Create a spot-on reference in APA, MLA, Chicago, Harvard, and other styles

Select a source type:

Consult the lists of relevant articles, books, theses, conference reports, and other scholarly sources on the topic 'Mechanism of the Hydrolysis.'

Next to every source in the list of references, there is an 'Add to bibliography' button. Press on it, and we will generate automatically the bibliographic reference to the chosen work in the citation style you need: APA, MLA, Harvard, Chicago, Vancouver, etc.

You can also download the full text of the academic publication as pdf and read online its abstract whenever available in the metadata.

Journal articles on the topic "Mechanism of the Hydrolysis"

1

Zhu, Chao, Zihui Meng, Wenjin Liu, et al. "Investigation on the hydrolytic mechanism of cucurbit[6]uril in alkaline solution." Royal Society Open Science 5, no. 5 (2018): 180038. http://dx.doi.org/10.1098/rsos.180038.

Full text
Abstract:
The structure of cucurbit[6]uril (CB[6]), as a fascinating supramolecular receptor, is regarded as ‘indestructible’. Herein, we investigated the hydrolysis of CB[6] catalysed by alkali. Our results showed that CB[6] was easily hydrolysed in 30% NaOH at 160°C within 3 h. Separation and purification of hydrolytic products demonstrated the presence of NH 3 , CO 2 , HCOONa, glycine and hydantoic acid. Based on the studies of the hydrolysis of substances similar to CB[6] including 4,5-dihydroxyethyleneurea, glycoluril and glycoluril dimer, we proposed that a plausible reaction mechanism involved a
APA, Harvard, Vancouver, ISO, and other styles
2

Paventi, Martino, Francis L. Chubb, and John T. Edward. "Assisted hydrolysis of the nitrile group of 2-aminoadamantane-2-carbonitrile." Canadian Journal of Chemistry 65, no. 9 (1987): 2114–17. http://dx.doi.org/10.1139/v87-351.

Full text
Abstract:
Attempts to hydrolyse the nitrile group of 2-aminoadamantane-2-carbonitrile by mineral acid or alkali have been unsuccessful. However, treatment of the aminonitrile with benzaldehyde in alkaline solution gives the benzal derivative of the α-aminoamide, readily hydrolysed to the α-aminoamide. Alternatively, benzoylation of the amino group followed by acid hydrolysis gives successively the α-benzamido acid and the α-amino acid. Possible mechanisms for these facilitated hydrolyses are advanced.
APA, Harvard, Vancouver, ISO, and other styles
3

Zhou, Rendan, Zemin Dong, Long Wang, et al. "Degradation of a New Herbicide Florpyrauxifen-Benzyl in Water: Kinetics, Various Influencing Factors and Its Reaction Mechanisms." International Journal of Molecular Sciences 24, no. 13 (2023): 10521. http://dx.doi.org/10.3390/ijms241310521.

Full text
Abstract:
Florpyrauxifen-benzyl is a novel herbicide used to control weeds in paddy fields. To clarify and evaluate its hydrolytic behavior and safety in water environments, its hydrolytic characteristics were investigated under varying temperatures, pH values, initial mass concentrations and water types, as well as the effects of 40 environmental factors such as microplastics (MPs) and disposable face masks (DFMs). Meanwhile, hydrolytic products were identified by UPLC-QTOF-MS/MS, and its hydrolytic pathways were proposed. The effects of MPs and DFMs on hydrolytic products and pathways were also invest
APA, Harvard, Vancouver, ISO, and other styles
4

Abbas, Khamis A., Phillip Hurst, and John T. Edward. "Reexamination of the Kirkwood–Westheimer theory of electrostatic effects. V. Effect of charged substituents on the rates of alkaline hydrolysis of substituted strychnines." Canadian Journal of Chemistry 75, no. 4 (1997): 441–48. http://dx.doi.org/10.1139/v97-050.

Full text
Abstract:
The rates of hydrolysis in aqueous sodium hydroxide of the alkaloid strychnine and seven of its derivatives have been determined at 50 and 75 °C. The kinetic data indicate that all the compounds, except strychninesulfoni acid-I, hydrolyze by competing second- and third-order mechanisms, involving one and two hydroxide ions, respectively; strychninesulfonic acid-I hydrolyzes by the second-order mechanism only. The quantitative effect of positively charged groups in enhancing, and negatively charged groups in depressing, the rates of hydrolysis is in rough agreement with calculations using Kirkw
APA, Harvard, Vancouver, ISO, and other styles
5

BECKER, Dieter, Karin S. H. JOHNSON, Anu KOIVULA, Martin SCHÜLEIN та Michael L. SINNOTT. "Hydrolyses of α- and β-cellobiosyl fluorides by Cel6A (cellobiohydrolase II) of Trichoderma reesei and Humicola insolens". Biochemical Journal 345, № 2 (2000): 315–19. http://dx.doi.org/10.1042/bj3450315.

Full text
Abstract:
We have measured the hydrolyses of α- and β-cellobiosyl fluorides by the Cel6A [cellobiohydrolase II (CBHII)] enzymes of Humicola insolens and Trichoderma reesei, which have essentially identical crystal structures [Varrot, Hastrup, Schülein and Davies (1999) Biochem. J. 337, 297-304]. The β-fluoride is hydrolysed according to Michaelis-Menten kinetics by both enzymes. When the ~ 2.0% of β-fluoride which is an inevitable contaminant in all preparations of the α-fluoride is hydrolysed by Cel7A (CBHI) of T. reesei before initial-rate measurements are made, both Cel6A enzymes show a sigmoidal dep
APA, Harvard, Vancouver, ISO, and other styles
6

Cox, Robin A. "A comparison of the mechanisms of hydrolysis of benzimidates, esters, and amides in sulfuric acid media." Canadian Journal of Chemistry 83, no. 9 (2005): 1391–99. http://dx.doi.org/10.1139/v05-142.

Full text
Abstract:
The mechanisms given in textbooks for both ester and amide hydrolysis in acid media are in need of revision. To illustrate this, benzimidates were chosen as model compounds for oxygen protonated benzamides. In aqueous sulfuric acid media they hydrolyze either by a mechanism involving attack of two water molecules at the carbonyl carbon to give a neutral tetrahedral intermediate directly, as in ester hydrolysis, or by an SN2 attack of two water molecules at the alkyl group of the alkoxy oxygen to form the corresponding amide, or by both mechanisms, depending on the structure of the benzimidate.
APA, Harvard, Vancouver, ISO, and other styles
7

Di Bisceglie, Federico, Felice Quartinello, Robert Vielnascher, Georg M. Guebitz, and Alessandro Pellis. "Cutinase-Catalyzed Polyester-Polyurethane Degradation: Elucidation of the Hydrolysis Mechanism." Polymers 14, no. 3 (2022): 411. http://dx.doi.org/10.3390/polym14030411.

Full text
Abstract:
Polyurethanes (PU) are one of the most-used classes of synthetic polymers in Europe, having a considerable impact on the plastic waste management in the European Union. Therefore, they represent a major challenge for the recycling industry, which requires environmentally friendly strategies to be able to re-utilize their monomers without applying hazardous and polluting substances in the process. In this work, enzymatic hydrolysis of a polyurethane-polyester (PU-PE) copolymer using Humicola insolens cutinase (HiC) has been investigated in order to achieve decomposition at milder conditions and
APA, Harvard, Vancouver, ISO, and other styles
8

KEROVUO, Janne, Juha ROUVINEN, and Frank HATZACK. "Analysis of myo-inositol hexakisphosphate hydrolysis by Bacillus phytase: indication of a novel reaction mechanism." Biochemical Journal 352, no. 3 (2000): 623–28. http://dx.doi.org/10.1042/bj3520623.

Full text
Abstract:
Phytic acid (myo-inositol hexakisphosphate, InsP6) hydrolysis by Bacillus phytase (PhyC) was studied. The enzyme hydrolyses only three phosphates from phytic acid. Moreover, the enzyme seems to prefer the hydrolysis of every second phosphate over that of adjacent ones. Furthermore, it is very likely that the enzyme has two alternative pathways for the hydrolysis of phytic acid, resulting in two different myo-inositol trisphosphate end products: Ins(2,4,6)P3 and Ins(1,3,5)P3. These results, together with inhibition studies with fluoride, vanadate, substrate and a substrate analogue, indicate a
APA, Harvard, Vancouver, ISO, and other styles
9

YU, LINGJUAN, DACHENG FENG, MAOXIA HE, RUI LI та ZHENGTING CAI. "THEORETICAL STUDY ON HYDROLYSIS MECHANISM OF β-PHOSPHOLACTAMS". Journal of Theoretical and Computational Chemistry 05, spec01 (2006): 421–31. http://dx.doi.org/10.1142/s0219633606002362.

Full text
Abstract:
The neutral hydrolysis mechanisms of a simple β-phospholactam with and without water-assisted reaction have been studied by using quantum chemical method at HF/6-31G**, MP2/6-31G** and B3LYP/6-31G** levels, respectively. The reaction can proceed by two different mechanisms: concerted and stepwise. There are two pathways in stepwise, i.e. pathway a and b, and the energy barriers of them are close. The energy barriers of water-assisted hydrolysis of β-phospholactam are obviously lower than those of no-water-assisted hydrolysis system. The energy barriers of stepwise mechanism are much lower than
APA, Harvard, Vancouver, ISO, and other styles
10

Kulakova, A. M., M. G. Khrenova, and A. V. Nemukhin. "Molecular mechanism of chromogenic substrate hydrolysis in the active site of human carboxylesterase-1." Biomeditsinskaya Khimiya 67, no. 3 (2021): 300–305. http://dx.doi.org/10.18097/pbmc20216703300.

Full text
Abstract:
Human carboxylesterases are involved in the protective processes of detoxification during the hydrolytic metabolism of xenobiotics. Knowledge of the molecular mechanisms of substrates hydrolysis in the enzymes active site is necessary for the rational drug design. In this work, the molecular mechanism of the hydrolysis reaction of para-nitrophenyl acetate in the active site of human carboxylesterase was determined using modern methods of molecular modeling. According to the combined method of quantum mechanics/molecular mechanics calculations, the chemical reaction occurs within four elementar
APA, Harvard, Vancouver, ISO, and other styles
More sources

Dissertations / Theses on the topic "Mechanism of the Hydrolysis"

1

González, González Jorge Augusto. "MIDA boronate hydrolysis." Thesis, University of Edinburgh, 2017. http://hdl.handle.net/1842/23461.

Full text
Abstract:
The application of MIDA boronates (MIDA = N-methyliminodiacetic acid) in Suzuki- Miyaura reactions has increased over the last years. This is mainly because in many cases, the replacement of the boronic acid for the respective MIDA boronate has a positive result in the reaction yield. The key feature that makes MIDA boronates efficient coupling partners is that they can undergo a slow hydrolysis reaction under Suzuki-Miyaura conditions, which generates the boronic acid in situ. The control of the hydrolysis rate is crucial to keep a low concentration of the boronic acid to avoid some of the si
APA, Harvard, Vancouver, ISO, and other styles
2

Hall, Darren James. "Simple mechanism-based inhibitors of glycoside hydrolysis." Thesis, University of East Anglia, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.390654.

Full text
APA, Harvard, Vancouver, ISO, and other styles
3

Aubert, Sarah Dwyer. "Mechanism for the hydrolysis of organophosphates and investigations into the stereoselective hydrolysis of organophosphorus Esters by Phosphotriesterase." Texas A&M University, 2004. http://hdl.handle.net/1969.1/3308.

Full text
Abstract:
Phosphotriesterase (PTE) is a zinc metalloenzyme that catalyzes the hydrolysis of organophosphorus compounds. Metal ion roles during binding and catalysis are probed by comparing the kinetic properties of Zn/Zn, Cd/Cd, and Zn/Cd PTE with a variety of phosphate trisesters. The metal in the α-site of the binuclear metal center modulates the pKa values determined from pH-rate profiles. These results suggest that the α-metal is responsible for activating the nucleophilic hydroxide. In an effort to determine the function of the β-metal, the kinetic parameters for diethyl p-chloro
APA, Harvard, Vancouver, ISO, and other styles
4

Patel, Jagvi Ramesh. "Kinetics and mechanism of hydrolysis and proton transfer reactions in solution." Thesis, King's College London (University of London), 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.271412.

Full text
APA, Harvard, Vancouver, ISO, and other styles
5

Schwarzl, Sonja M. "Understanding the ATP hydrolysis mechanism in myosin using computer simulation techniques." [S.l. : s.n.], 2005. http://nbn-resolving.de/urn:nbn:de:bsz:16-opus-63890.

Full text
Abstract:
Heidelberg, Univ., Diss., 2005.<br>Aus: S.M. Schwarzl, Understanding the ATP hydrolysis mechanism in myosin using computer simulation techniques, Mensch und Buch Verlag Berlin 2006, ISBN 3-86664-044-7.
APA, Harvard, Vancouver, ISO, and other styles
6

Jones, Christopher Buchan. "The hydrolysis of cirazoline and the mechanism of stabilization by SDDS." Thesis, University of Bath, 1988. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.380945.

Full text
APA, Harvard, Vancouver, ISO, and other styles
7

Shaw, Sudipta. "Role of ATP Hydrolysis and Mechanism of Substrate Reduction in Nitrogenase." DigitalCommons@USU, 2017. https://digitalcommons.usu.edu/etd/5729.

Full text
Abstract:
Nitrogenase consists of two metalloproteins, the MoFe protein and the Fe protein. The MoFe protein is an α2β2 heterotetramer and the Fe protein is an α2 homodimer. The catalytic cycle of nitrogenase involves binding of the Fe protein to each αβ catalytic half of the MoFe protein, electron transfer followed by ATP hydrolysis, Pi release and eventually dissociation of the two proteins. This cycle has to be repeated eight consecutive times to reduce one molecule of N2. The two catalytic halves of the MoFe protein had been considered to be independent of each other. The research presented here sho
APA, Harvard, Vancouver, ISO, and other styles
8

Mills, Judith Frances. "Kinetics and mechanism of the hydrolysis of benzoxazines and their ring opened derivatives." Thesis, King's College London (University of London), 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.267701.

Full text
APA, Harvard, Vancouver, ISO, and other styles
9

Hui, Ka-long Aaron, and 許家朗. "Structural analysis of Zn-Zn distance in NDM-1's beta-lactam hydrolysis mechanism." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/206564.

Full text
Abstract:
Introduction: The New Delhi metallo-β-lactamase (NDM-1) is an enzyme synthesized by bacterium which hydrolyses β-lactam antibiotics and inhibits their antibiotic effects. Its active site is highly diverse and the hydrolysis mechanism is not yet fully understood. So, there is currently no clinically useful inhibitor for this enzyme. Due to this β-lactam resistant characteristics and the ease of horizontal gene transfer between bacteria, NDM-1 producing bacteria poses a great threat to public health. Objective: Structural analysis on Zn-Zn distance in the active site of NDM-1 was carried out
APA, Harvard, Vancouver, ISO, and other styles
10

Balasubramanian, Krithika. "ATP hydrolysis in Rho: Identifying active site residues and their roles." Diss., Temple University Libraries, 2010. http://cdm16002.contentdm.oclc.org/cdm/ref/collection/p245801coll10/id/80319.

Full text
Abstract:
Biochemistry<br>Ph.D.<br>Escherichia coli transcription termination factor Rho is a hexameric RNA/DNA helicase that terminates transcription using energy derived from the hydrolysis of ATP. The ATP binding sites of Rho are located at the interfaces of adjoining subunit Cterminal domains and have the Walker A and B motifs, characteristic of many ATPases (Skordalakes & Berger, 2003; Richardson 2002). Available Rho crystal structures capture the protein with its active site in an open configuration that must close to permit ATP hydrolysis. Because of this, the identities of active site residues p
APA, Harvard, Vancouver, ISO, and other styles
More sources

Books on the topic "Mechanism of the Hydrolysis"

1

Lehikoinen, Pertti. Hydrolytic decomposition of purine nucleosides in aqueous acid and alkali: Kinetics and mechanisms. Dept. of Chemistry and Biochemistry, University of Turku, 1986.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
2

Myers, George E. Resin hydrolysis and mechanisms of formaldehyde release from bonded wood products. [Forest Products Laboratory, 1987.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
3

Fan, Liang-tseng, Mahendra Moreshwar Gharpuray, and Yong-Hyun Lee. Cellulose Hydrolysis. Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-72575-3.

Full text
APA, Harvard, Vancouver, ISO, and other styles
4

1958-, Gharpuray M. M., and Lee Y. H. 1943-, eds. Cellulose hydrolysis. Springer-Verlag, 1987.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
5

Brown, Paul L., and Christian Ekberg, eds. Hydrolysis of Metal Ions. Wiley-VCH Verlag GmbH & Co. KGaA, 2016. http://dx.doi.org/10.1002/9783527656189.

Full text
APA, Harvard, Vancouver, ISO, and other styles
6

name, No. Hydrolysis, oxidation and reduction. Wiley, 2003.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
7

Baes, Charles F. The hydrolysis of cations. R.E. Krieger, 1986.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
8

M, Roberts Stanley, and Poignant Geraldine, eds. Hydrolysis, oxidation and reduction. Wiley, 2002.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
9

1945-, Young Raymond Allen, and Rowell Roger M, eds. Cellulose: Structure, modification, and hydrolysis. Wiley, 1986.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
10

Lennox, Alastair J. J. Organotrifluoroborate Preparation, Coupling and Hydrolysis. Springer International Publishing, 2013. http://dx.doi.org/10.1007/978-3-319-01134-9.

Full text
APA, Harvard, Vancouver, ISO, and other styles
More sources

Book chapters on the topic "Mechanism of the Hydrolysis"

1

Bagshaw, Clive R. "Mechanism of ATP hydrolysis." In Muscle Contraction. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-015-6839-5_5.

Full text
APA, Harvard, Vancouver, ISO, and other styles
2

Williams, N. H. "DNA Hydrolysis: Mechanism and Reactivity." In Artificial Nucleases. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-642-18510-6_2.

Full text
APA, Harvard, Vancouver, ISO, and other styles
3

Caldwell, Steven R., and Frank M. Raushel. "Mechanism of Enyzmatic Phosphotriester Hydrolysis." In Chemical Aspects of Enzyme Biotechnology. Springer US, 1990. http://dx.doi.org/10.1007/978-1-4757-9637-7_4.

Full text
APA, Harvard, Vancouver, ISO, and other styles
4

Varfolomeev, Sergey, Bella Grigorenko, Sofya Lushchekina, Patrick Masson, Galina Mahaeva, and Alexander Nemuchin. "Human cholinesterases." In ORGANOPHOSPHORUS NEUROTOXINS. Publishing Center RIOR, 2020. http://dx.doi.org/10.29039/21_069-126.

Full text
Abstract:
The work is devoted to modeling the elementary stages of the hydrolysis reaction in the active site of enzymes belonging to the class of cholinesterases — acetylcholinesterase (AChE) and butyrylcholinesterase (BChE). The study allowed to describe at the molecular level the effect of the polymorphic modification of BChE, causing serious physiolog ical consequences. Cholinesterase plays a crucial role in the human body. AChE is one of the key enzymes of the central nervous system, and BChE performs protective functions in the body. According to the results of calculations using the combined meth
APA, Harvard, Vancouver, ISO, and other styles
5

Varfolomeev, Sergey, Bella Grigorenko, Sofya Lushchekina, and Alexander Nemuchin. "Human cholinesterases." In Organophosphorous Neurotoxins. Publishing Center RIOR, 2020. http://dx.doi.org/10.29039/chapter_5e4132b5f22366.15634219.

Full text
Abstract:
The work is devoted to modeling the elementary stages of the hydrolysis reaction in the active site of enzymes belonging to the class of cholinesterases — acetylcholinesterase (AChE) and butyrylcholinesterase (BChE). The study allowed to describe at the molecular level the effect of the polymorphic modification of BChE, causing serious physiolog ical consequences. Cholinesterase plays a crucial role in the human body. AChE is one of the key enzymes of the central nervous system, and BChE performs protective functions in the body. According to the results of calculations using the combined meth
APA, Harvard, Vancouver, ISO, and other styles
6

Dupont, C., D. Kluepfel, and R. Morosoli. "Evidence for lysozyme-type mechanism of hydrolysis in xylanases." In Experientia Supplementum. Birkhäuser Basel, 1996. http://dx.doi.org/10.1007/978-3-0348-9225-4_20.

Full text
APA, Harvard, Vancouver, ISO, and other styles
7

Davies, D. R., and A. L. Green. "The Mechanism of Hydrolysis by Cholinesterase and Related Enzymes." In Advances in Enzymology - and Related Areas of Molecular Biology. John Wiley & Sons, Inc., 2006. http://dx.doi.org/10.1002/9780470122655.ch9.

Full text
APA, Harvard, Vancouver, ISO, and other styles
8

Nederkoorn, Paul H. J., Henk Timmerman, and Gabriëlle M. Donné-Op den Kelder. "ATP Hydrolysis and Synthesis Mechanisms." In Signal Transduction by G Protein-Coupled Receptors. Springer US, 1997. http://dx.doi.org/10.1007/978-1-4684-1407-3_3.

Full text
APA, Harvard, Vancouver, ISO, and other styles
9

Pohl, E. R., and F. D. Osterholtz. "Kinetics and Mechanism of Aqueous Hydrolysis and Condensation of Alkyltrialkoxysilanes." In Molecular Characterization of Composite Interfaces. Springer US, 1985. http://dx.doi.org/10.1007/978-1-4899-2251-9_10.

Full text
APA, Harvard, Vancouver, ISO, and other styles
10

Pohl, E. R., and F. D. Osterholtz. "Kinetics and Mechanism of Aqueous Hydrolysis and Condensation of Alkyltrialkoxysilanes." In Molecular Characterization of Composite Interfaces. Springer Berlin Heidelberg, 1985. http://dx.doi.org/10.1007/978-3-662-29084-2_10.

Full text
APA, Harvard, Vancouver, ISO, and other styles

Conference papers on the topic "Mechanism of the Hydrolysis"

1

Fang, Haitao, Bruce Brown, David Young, and Srdjan Nešić. "Investigation of Elemental Sulfur Corrosion Mechanisms." In CORROSION 2011. NACE International, 2011. https://doi.org/10.5006/c2011-11398.

Full text
Abstract:
Abstract Sour gas wells frequently co-produce elemental sulfur which can cause catastrophic corrosion of mild steel. As producing wells become increasingly sour, the incidence of sulfur corrosion will likely increase. Despite the severity of this problem, limited mechanistic information about this process exists in the literature. The objective of this study is investigation of the corrosion mechanism involving elemental sulfur. Building on the knowledge found in open literature, sulfur hydrolysis and the sulfur/iron reaction mechanisms were both studied in this work. It was found that a sulfu
APA, Harvard, Vancouver, ISO, and other styles
2

Prian, L., and A. Barkatt. "Chemical, Thermochemical, and Mechanical Studies of FRP Degradation in Corrosive Environments." In CORROSION 1998. NACE International, 1998. https://doi.org/10.5006/c1998-98455.

Full text
Abstract:
Abstract Extensive measurements on E-glass/vinylester rods exposed to air, water, and ammonia solutions at temperatures between 23°C and 80°C for 7 to 224 days showed that integration of the chemical, thermochemical, and mechanical data is necessary for developing useful models of FRP degradation. For instance, fiber dissolution is a major mechanism in basic environments while resin hydrolysis is most pronounced in acidic environments1,2. Dramatic increases in degradation rates may be observed in some cases of environmental exposure after a certain induction period, even at relatively low temp
APA, Harvard, Vancouver, ISO, and other styles
3

Chandrasekaran, P., and S. C. Dexter. "Bacterial Metabolism in Biofilm Consortia: Consequences for Potential Ennoblement." In CORROSION 1994. NACE International, 1994. https://doi.org/10.5006/c1994-94276.

Full text
Abstract:
Abstract Platinum metal coupons were used in studying the mechanism of ennoblement in the presence of mature seawater biofilms. Presence of a bacterial consortia, rather than any single organism is determined to be necessary for ennoblement. Millimolar concentrations of iron and manganese were measured in biofilms formed over platinum. EDAX and ICP techniques were used for measuring the chemistry of particles in a biofilm. Utilization of various electron acceptors like oxygen, iron, manganese etc are thought to be important for ennoblement to take place over platinum. Heavy metal accumulation
APA, Harvard, Vancouver, ISO, and other styles
4

Sugama, T. "Sol-Gel Derived Polytitanosiloxane Coatings." In CORROSION 1990. NACE International, 1990. https://doi.org/10.5006/c1990-90454.

Full text
Abstract:
Abstract Amorphous polytitanosiloxane (PTS) was formed by hydrolysis-polycondensation and hydrolysis-polycondensation-pyrolysis reaction mechanisms of precursor sol solutions consisting of monomeric organosilanes, Ti(OC2H5)4, methanol, water and hydrochloric acid, over the temperature range 100° to 500°C. These reaction processes which are responsible for the assemblage of PTS networks were found to depend mainly on the species of organosilane used. The PTS was applied as a coating on aluminum substrates, and the factors which play an important role in providing corrosion protection were inves
APA, Harvard, Vancouver, ISO, and other styles
5

Keitelman, A. D., and M. G. Alvarez. "40 Years of J.R. Galvele′S Localized Acidification Pitting Model: Past, Present, and Future." In CORROSION 2016. NACE International, 2016. https://doi.org/10.5006/c2016-07214.

Full text
Abstract:
Abstract The localized acidification mechanism for stable pitting growth was the result of the pitting research performed by many investigators, led by Dr. J.R. Galvele. The key point of the mechanism is that there is a pH drop on the anode surface, and that this pH drop is a necessary condition to sustain pitting.The analysis of the transport processes taking place inside a pit, taking into account the hydrolysis of the metal ions, allowed to explain the pitting potential significance and give a quantitative explanation of the influence of solution pH, reducible ions, inhibitors and aggressiv
APA, Harvard, Vancouver, ISO, and other styles
6

Sprague, Paul A., and Hira S. Ahluwalia. "Corrosion Barrier Deterioration and Detection in FRP Structures." In CORROSION 2000. NACE International, 2000. https://doi.org/10.5006/c2000-00551.

Full text
Abstract:
Abstract Exposing vinyl ester FRP corrosion barriers to five chemical environments illustrated distinctly different degradation mechanisms. Electrical resistance measurements were successful in detecting the extent of damage in each of the environments. The degradation mechanisms included solvent swelling, acid permeation, nitric acid cracking, bleach attack, and caustic hydrolysis attack.
APA, Harvard, Vancouver, ISO, and other styles
7

Rahman, Mohammad Mizanur. "Biodegradable SPC Polyurethane Coating." In CORROSION 2020. NACE International, 2020. https://doi.org/10.5006/c2020-14721.

Full text
Abstract:
Abstract Self-polishing coatings (SPC) are widely being used in marine structures to protect metals from fouling. After restrictions on using toxic metals, coating industry are seeking environmentally-friendly SPC coatings that maintain their performance over extended periods. Unfortunately, most of the commercial SPC coatings contain different toxic materials, besides their performance is inadequate to prevent fouling under adverse conditions. The main mechanism of SPC coating is to facilitate the continuous renewal of the surface and the release of active compound via a hydrolysis reaction o
APA, Harvard, Vancouver, ISO, and other styles
8

Alink, B., B. Outlaw, V. Jovancicevic, S. Ramachandran, and S. Campbell. "Mechanism of CO2 Corrosion Inhibition by Phosphate Esters." In CORROSION 1999. NACE International, 1999. https://doi.org/10.5006/c1999-99037.

Full text
Abstract:
Abstract The mechanisms of corrosion inhibition of mild steel by phosphate esters in a CO2 containing environment is studied by using various inhibitor solution characterization techniques (residual analysis, dynamic surface tension, emulsion tendency). Corrosion inhibition and inhibitor film persistancy is monitored over time by using a rotating cylinder electrode (RCE) system and linear polarization resistance (LPR) technique. Corrosion rate-time/concentration profiles are obtained for all phosphate esters studied. Optical profilometry is used to assess surface microstructure as related to i
APA, Harvard, Vancouver, ISO, and other styles
9

Lucan, D., M. Fulger, Al Woinaroschy, and Ghe Jinescu. "Experimental Research and Mathematical Modelling of the Impurities Concentration Processes into Candu Steam Generator Crevices." In CORROSION 2002. NACE International, 2002. https://doi.org/10.5006/c2002-02520.

Full text
Abstract:
Abstract Crevice corrosion involves a number of simultaneous and interacting operations, including mass transfer processes, production of metal ions within the crevice and hydrolysis reactions, resulting in a very aggressive solution from the point of view of corrosion. These intermediary corrosion processes are in a complex interdependence and they imply a number of important parameters, including both the crevice gap and depth. The major goal of this paper was development of a mathematical model for the calculation of the impurities concentrations (Na+, Cl-, Fe2+) into crevices and experimen
APA, Harvard, Vancouver, ISO, and other styles
10

Watson, M. K., and J. Postlethwaite. "Numerical Simulation of Crevice Corrosion." In CORROSION 1990. NACE International, 1990. https://doi.org/10.5006/c1990-90156.

Full text
Abstract:
Abstract The process of crevice corrosion consists of anodic metal dissolution from the alloy to the crevice solution, cathodic reduction of oxygen on the bold surface of the metal outside the crevice, metal ion hydrolysis reactions, and mass transfer between the crevice solution and the bulk solution. The mass transfer process mechanisms are ionic migration and diffusion. An improved mathematical model has been developed for the numerical simulation of the incubation period of crevice corrosion. The model utilizes a new equation for the transport processes, which includes both ionic migration
APA, Harvard, Vancouver, ISO, and other styles

Reports on the topic "Mechanism of the Hydrolysis"

1

Moore, R. M. Jr. Preparations and mechanism of hydrolysis of ((8)annulene)actinide compounds. [Uranocene]. Office of Scientific and Technical Information (OSTI), 1985. http://dx.doi.org/10.2172/5319654.

Full text
APA, Harvard, Vancouver, ISO, and other styles
2

Burgeson, I. Mechanism and applicability of hydrolysis of peptides and proteins utilizing Pt(II) complexes. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/6812379.

Full text
APA, Harvard, Vancouver, ISO, and other styles
3

Hoffsommer, J. C. Kinetics and Mechanism for the Basic Hydrolysis of BIS (2,2- Dinitropropyl) Acetal (BDNPA) and BIS (2,2-Dinitropropyl) Formal (BDNPF). Defense Technical Information Center, 1985. http://dx.doi.org/10.21236/ada153201.

Full text
APA, Harvard, Vancouver, ISO, and other styles
4

Tan, Haisong. Kinetics and mechanism of the oxidation of alkenes and silanes by hydrogen peroxide catalyzed by methylrhenium trioxide (MTO) and a novel application of electrospray mass spectrometry to study the hydrolysis of MTO. Office of Scientific and Technical Information (OSTI), 1999. http://dx.doi.org/10.2172/754781.

Full text
APA, Harvard, Vancouver, ISO, and other styles
5

Pavlov, Julius, Muhammad Sidhoum, Chris Christodoulatos, Wendy Balas, and Steven Nicolich. Hydrolysis of CL-20. Defense Technical Information Center, 2005. http://dx.doi.org/10.21236/ada437522.

Full text
APA, Harvard, Vancouver, ISO, and other styles
6

Marek, J. C. Hydrolysis of late-washed, irradiated tetraphenylborate slurry simulants I: Phenylboric acid hydrolysis kinetics. Office of Scientific and Technical Information (OSTI), 2000. http://dx.doi.org/10.2172/751282.

Full text
APA, Harvard, Vancouver, ISO, and other styles
7

Karakaya, P., M. Sidhourn, C. Christodoulatos, Wendy Balas, and Steven Nicolich. Alkaline Hydrolysis of CL-20. Defense Technical Information Center, 2005. http://dx.doi.org/10.21236/ada436623.

Full text
APA, Harvard, Vancouver, ISO, and other styles
8

Rohrbaugh, Dennis K., George W. Wagner, Kenneth B. Sumpter, and Steven P. Harvey. Hydrolysis of Levinstein Mustard (H). Defense Technical Information Center, 2003. http://dx.doi.org/10.21236/ada418867.

Full text
APA, Harvard, Vancouver, ISO, and other styles
9

Quiroga, Ariel D., and Richard Lehner. Acylglycerol Lipases (Neutral Lipid Hydrolysis). AOCS, 2011. http://dx.doi.org/10.21748/lipidlibrary.39188.

Full text
APA, Harvard, Vancouver, ISO, and other styles
10

Mihailovic, E. M. Controlling Hydrolysis to Treat Lithium Wastes. Office of Scientific and Technical Information (OSTI), 2020. http://dx.doi.org/10.2172/1615578.

Full text
APA, Harvard, Vancouver, ISO, and other styles
You might also be interested in the extended bibliographies on the topic 'Mechanism of the Hydrolysis' for particular source types:
Journal articles Dissertations / Theses Books
We offer discounts on all premium plans for authors whose works are included in thematic literature selections. Contact us to get a unique promo code!

To the bibliography