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1

Khisina, Natalia R., Dmitry A. Khramov, Anatοly A. Kleschev, and Klaus Langer. "Laihunitization as a mechanism of olivine oxidation." European Journal of Mineralogy 10, no. 2 (1998): 229–38. http://dx.doi.org/10.1127/ejm/10/2/0229.

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2

Starik, A. M., N. S. Titova, A. S. Sharipov, and V. E. Kozlov. "Syngas Oxidation Mechanism." Combustion, Explosion, and Shock Waves 46, no. 5 (2010): 491–506. http://dx.doi.org/10.1007/s10573-010-0065-x.

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3

Goryachev, B. E., and A. A. Nikolaev. "Galena oxidation mechanism." Journal of Mining Science 48, no. 2 (2012): 354–62. http://dx.doi.org/10.1134/s1062739148020177.

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4

Xiao, Ling, Yu Li, Xuan Wang, and Chao Yu. "Study on aging mechanism of special neoprene in hot air." IOP Conference Series: Earth and Environmental Science 1171, no. 1 (2023): 012038. http://dx.doi.org/10.1088/1755-1315/1171/1/012038.

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Abstract The accelerated aging tests of the special neoprene material in hot air were carried in laboratory. The aging mechanism was analyzed by using FTIR, DSC and TG spectra. The results showed that the thermal oxidative aging in air was a self-catalyzed oxidating reaction, the cross-linking reaction firstly in the process of thermo-oxidation, and the degradation reaction occurs at the later stage of aging.
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5

Forlano, Paula, José A. Olabe, Jorge F. Magallanes, and Miguel A. Blesa. "The mechanism of oxidation of 3-mercaptopropionic acid." Canadian Journal of Chemistry 75, no. 1 (1997): 9–13. http://dx.doi.org/10.1139/v97-002.

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The mechanism of the oxidation of 3-mercaptopropionic acid (3-MPA) by hydrogen peroxide was studied in the acidic pH range. The nucleophilic attack by sulphur on the peroxide bond controls the rate. Extrapolation of the pH dependency suggests that the rate of attack by the deprotonated dianion is highest. Traces of Fe(III), at levels below 10−7 mol dm−3, do not catalyze efficiently the process through one-electron mechanisms; at higher concentrations, or on the surface of iron(III) oxides, this type of catalysis becomes important. The electrochemical oxidation of 3-MPA was also studied, using
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6

Wu, Jiang, Bo Shui Chen, Jian Hua Fang, and Jiu Wang. "Anti-Oxidation Stability and its Mechanism of Rapeseed Biodiesel." Advanced Materials Research 772 (September 2013): 287–91. http://dx.doi.org/10.4028/www.scientific.net/amr.772.287.

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The anti-oxidation stability of rapeseed biodiesel (RME) was evaluated on an oxidation simulator set up by the author. The results showed that oxidative stability of RME was worse than that of petrodiesel by exhibiting higher acid values and peroxide values, as well as greater viscosity increases after oxidation. Furthermore, a conjecture was taken about the configurational changes and the oxidation mechanisms of unsaturated fatty acid methyl ester molecules in the oxidation process, according to the principles of free radical reactions and the results of both infrared and ultraviolet spectros
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7

Wu, Jiang, Bo Shui Chen, Jian Hua Fang, and Jiu Wang. "Anti-Oxidation Stability and its Mechanism of Soybean Biodiesel." Applied Mechanics and Materials 339 (July 2013): 695–99. http://dx.doi.org/10.4028/www.scientific.net/amm.339.695.

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The anti-oxidation stability of soybean biodiesel (SME) was evaluated on an oxidation simulator set up by the author. The results showed that oxidative stability of SME was worse than that of petrodiesel by exhibiting higher acid values and peroxide values, as well as greater viscosity increases after oxidation. Furthermore, a conjecture was taken about the configurational changes and the oxidation mechanisms of unsaturated fatty acid methyl ester molecules in the oxidation process, according to the principles of free radical reactions and the results of both infrared and ultraviolet spectrosc
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8

IP, Ivanova. "Mechanism of Hydroquinone Oxidation by Hot Plasma Pulsed Radiation." Physical Science & Biophysics Journal 6, no. 2 (2022): 1–5. http://dx.doi.org/10.23880/psbj-16000226.

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The degradation of hydroquinone in interactions with OH• , HO2 • radicals, nitrous and peroxynitrous acids has been studied. Active species were generated using a corona electric discharge and pulsed radiation from hot plasma of a spark electric discharge. When interacting with hydroxyl radicals, hydroquinone breaks down into low molecular weight products. When interacting with species formed under the action of hot plasma radiation, chain oxidation of hydroquinone to benzoquinone occurs. This process is environmentally friendly and does not require the use of additional catalysts. Products fo
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9

Wu, Jiang, Bo Shui Chen, Jian Hua Fang, and Jiu Wang. "Anti-Oxidation Stability and its Mechanism of Waste Oil Biodiesel." Advanced Materials Research 739 (August 2013): 80–84. http://dx.doi.org/10.4028/www.scientific.net/amr.739.80.

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The anti-oxidation stability of waste oil biodiesel (WME) was evaluated on an oxidation simulator set up by the author. The results showed that oxidative stability of WME was worse than that of petrodiesel by exhibiting higher acid values and peroxide values, as well as greater viscosity increases after oxidation. Furthermore, a conjecture was taken about the configurational changes and the oxidation mechanisms of unsaturated fatty acid methyl ester molecules in the oxidation process, according to the principles of free radical reactions and the results of both infrared and ultraviolet spectro
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10

Fan, Jiwen, and Renyi Zhang. "Atmospheric Oxidation Mechanism of Isoprene." Environmental Chemistry 1, no. 3 (2004): 140. http://dx.doi.org/10.1071/en04045.

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Environmental Context. Many plant species biosynthesize and emit the volatile hydrocarbon isoprene. Once in the atmosphere, isoprene is susceptible to a range of reactions involving potentially hundred of products and intermediate compounds. The products of these reactions in turn may pose a risk to human and plant health and impact the climate through the generation of acids, ozone, and atmospheric aerosols. Abstract. The atmospheric oxidation mechanism of isoprene initiated by OH, O3, NO3, and Cl, which incorporates the most recent laboratory and theoretical studies, is described. A box mode
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11

Zhu, Bo, Li-Kai Yan, Yun Geng, Hang Ren, Wei Guan, and Zhong-Min Su. "IrIII/NiII-Metallaphotoredox catalysis: the oxidation state modulation mechanism versus the radical mechanism." Chemical Communications 54, no. 47 (2018): 5968–71. http://dx.doi.org/10.1039/c8cc03550d.

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An oxidation state modulation mechanism, merging oxidative quenching (Ir<sup>III</sup>–*Ir<sup>III</sup>–Ir<sup>IV</sup>–Ir<sup>III</sup>) and nickel catalytic (Ni<sup>II</sup>–Ni<sup>I</sup>–Ni<sup>III</sup>–Ni<sup>I</sup>–Ni<sup>II</sup>) cycles, is disclosed for Ir/Ni-metallaphotoredox catalysis.
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12

Petersen, J. Claine, and P. Michael Harnsberger. "Asphalt Aging: Dual Oxidation Mechanism and Its Interrelationships with Asphalt Composition and Oxidative Age Hardening." Transportation Research Record: Journal of the Transportation Research Board 1638, no. 1 (1998): 47–55. http://dx.doi.org/10.3141/1638-06.

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The kinetic data and chemistry of asphalt oxidative age hardening suggested a sequential, dual mechanism for asphalt oxidation. The dual mechanism rationalizes conflicts between earlier mechanistic investigations and explains the hyperbolic-like, time-versus-property plots characteristic of asphalt oxidative aging. The oxidation kinetics provide further confirmation of the asphalt microstructural model. It is proposed that the rapid initial oxidation rate of asphalt results from reaction of oxygen with limited amounts of highly reactive hydrocarbons. Final oxidation products of this initial re
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13

Jacob, Lorrie Simone Denise, Chiara Giorio, and Alexander Thomas Archibald. "Extension, development, and evaluation of the representation of the OH-initiated dimethyl sulfide (DMS) oxidation mechanism in the Master Chemical Mechanism (MCM) v3.3.1 framework." Atmospheric Chemistry and Physics 24, no. 5 (2024): 3329–47. http://dx.doi.org/10.5194/acp-24-3329-2024.

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Abstract. Understanding dimethyl sulfide (DMS) oxidation can help us constrain its contribution to Earth's radiative balance. Following the discovery of hydroperoxymethyl thioformate (HPMTF) as a DMS oxidation product, a range of new experimental chamber studies have since improved our knowledge of the oxidation mechanism of DMS and delivered detailed chemical mechanisms. However, these mechanisms have not undergone formal intercomparisons to evaluate their performance. This study aimed to synthesise the recent experimental studies and develop a new, near-explicit, DMS mechanism, through a tho
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14

Yang, Lingwei, Xueren Xiao, Liping Liu, et al. "Dynamic oxidation mechanism of carbon fiber reinforced SiC matrix composite in high-enthalpy and high-speed plasmas." Journal of Advanced Ceramics 11, no. 2 (2022): 365–77. http://dx.doi.org/10.1007/s40145-021-0540-8.

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AbstractThis work employed an inductively coupled plasma wind tunnel to study the dynamic oxidation mechanisms of carbon fiber reinforced SiC matrix composite (Cf/SiC) in high-enthalpy and high-speed plasmas. The results highlighted a transition of passive/active oxidations of SiC at 800–1600 °C and 1–5 kPa. Specially, the active oxidation led to the corrosion of the SiC coating and interruption of the SiO2 growth. The transition borders of active/passive oxidations were thus defined with respect to oxidation temperature and partial pressure of atomic O in the high-enthalpy and high-speed plas
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15

Yan, Liang-Jun. "Protein Redox Modification as a Cellular Defense Mechanism against Tissue Ischemic Injury." Oxidative Medicine and Cellular Longevity 2014 (2014): 1–12. http://dx.doi.org/10.1155/2014/343154.

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Protein oxidative or redox modifications induced by reactive oxygen species (ROS) or reactive nitrogen species (RNS) not only can impair protein function, but also can regulate and expand protein function under a variety of stressful conditions. Protein oxidative modifications can generally be classified into two categories: irreversible oxidation and reversible oxidation. While irreversible oxidation usually leads to protein aggregation and degradation, reversible oxidation that usually occurs on protein cysteine residues can often serve as an “on and off” switch that regulates protein functi
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16

Nicol, D. G., P. C. Malte, A. J. Hamer, R. J. Roby, and R. C. Steele. "Development of a Five-Step Global Methane Oxidation-NO Formation Mechanism for Lean-Premixed Gas Turbine Combustion." Journal of Engineering for Gas Turbines and Power 121, no. 2 (1999): 272–80. http://dx.doi.org/10.1115/1.2817117.

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It is known that many of the previously published global methane oxidation mechanisms used in conjunction with computational fluid dynamics (CFD) codes do not accurately predict CH4 and CO concentrations under typical lean-premixed combustion turbine operating conditions. In an effort to improve the accuracy of the global oxidation mechanism under these conditions, an optimization method for selectively adjusting the reaction rate parameters of the global mechanisms (e.g., pre-exponential factor, activation temperature, and species concentration exponents) using chemical reactor modeling is de
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17

Aghamammadova, S. A. "MECHANISM OF BIOMIMETIC OXIDATION OF CYCLOHEXANE TO CYCLOHEXANONE BY HYDROGEN PEROXIDE." Azerbaijan Chemical Journal, no. 1 (April 9, 2021): 61–66. http://dx.doi.org/10.32737/0005-2531-2021-1-61-66.

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The process of gas-phase oxidation of cyclohexane was studied in the presence of a heterogeneous biomimetic catalyst (per-FTPhPFe(III)OH/Al2O3), at 130–2500C, in which high yields of cyclohexanone and cyclohexanol were obtained up to 25.2% with a selectivity of ~80% at a cyclohexane conversion of 34%. The mechanism of the conversion of cyclohexane to cyclohexanone has been studied in detail, and the coherently synchronized character of the reaction proceeding is shown
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18

Emerenciano, Vicente P., D. Cabrol-Bass, Marcelo J. P. Ferreira, et al. "Chemical Evolution in the Asteraceae. The Oxidation– Reduction Mechanism and Production of Secondary Metabolites." Natural Product Communications 1, no. 6 (2006): 1934578X0600100. http://dx.doi.org/10.1177/1934578x0600100612.

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This work describes the application of partial least squares (PLS) regression to variables that represent the oxidation data of several types of secondary metabolite isolated from the family Asteraceae. The oxidation states were calculated for each carbon atom of the involved compounds after these had been matched with their biogenetic precursor. The states of oxidation variations were named oxidation steps. This methodology represents a new approach to inspect the oxidative changes in taxa. Partial least square (PLS) regression was used to inspect the relationships among terpenoids, coumarins
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19

Liu, Yang. "Thermal enhancement of the oxidation layer of micron-sized aluminum powder and its anti-oxidation performance." Cambridge Science Advance 2024, no. 1 (2024): 43–54. http://dx.doi.org/10.62852/csa/2024/5.

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Micron-sized aluminum powder, with its typical core-shell structure, exhibits oxidation behavior upon slow heating in an oxidative atmosphere that is related to the particle size of the aluminum powder. A particle size-dependent thermal response mechanism for micron-sized aluminum powder is established: a "shell-breaking eruption" thermal response mechanism. The oxide layer is thermally enhanced, and the anti-oxidation reaction behavior mechanism of the enhanced samples is studied. Aluminum powder samples, heated slowly to specific temperatures to obtain changes in the oxide layer structure, a
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20

Wu, Runrun, Shanshan Pan, Yun Li, and Liming Wang. "Atmospheric Oxidation Mechanism of Toluene." Journal of Physical Chemistry A 118, no. 25 (2014): 4533–47. http://dx.doi.org/10.1021/jp500077f.

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21

Taskinen, Pekka, Sonja Patana, Petri Kobylin, and Petri Latostenmaa. "Oxidation Mechanism of Copper Selenide." High Temperature Materials and Processes 33, no. 5 (2014): 469–76. http://dx.doi.org/10.1515/htmp-2013-0097.

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AbstractThe oxidation mechanism of copper selenide was investigated at deselenization temperatures of copper refining anode slimes. The isothermal roasting of synthetic, massive copper selenide in flowing oxygen and oxygen – 20% sulfur dioxide mixtures at 450–550 °C indicate that in both atmospheres the mass of Cu2Se increases as a function of time, due to formation of copper selenite as an intermediate product. Copper selenide oxidises to copper oxides without formation of thick copper selenite scales, and a significant fraction of selenium is vaporized as SeO2(g). The oxidation product scale
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22

Brudvig, G. W., W. F. Beck, and J. C. Paula. "Mechanism of Photosynthetic Water Oxidation." Annual Review of Biophysics and Biophysical Chemistry 18, no. 1 (1989): 25–46. http://dx.doi.org/10.1146/annurev.bb.18.060189.000325.

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23

Baumstark, A. L., M. Beeson, and P. C. Vasquez. "Dimethyldioxirane: Mechanism of benzaldehyde oxidation." Tetrahedron Letters 30, no. 41 (1989): 5567–70. http://dx.doi.org/10.1016/s0040-4039(01)93801-8.

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24

Guo, Ling, Xiaoyu An, Shuying Li, and Aixia Li. "CO oxidation mechanism on AlAun." Journal of Molecular Structure 1085 (April 2015): 1–12. http://dx.doi.org/10.1016/j.molstruc.2014.11.075.

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25

Martínez-Avilés, Mónica, Claudette M. Rosado-Reyes, and Joseph S. Francisco. "Atmospheric Oxidation Mechanism of Bromoethane." Journal of Physical Chemistry A 111, no. 45 (2007): 11652–60. http://dx.doi.org/10.1021/jp073862w.

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26

Taskinen, Pekka, Sonja Patana, Petri Kobylin, and Petri Latostenmaa. "Oxidation Mechanism of Silver Selenide." Oxidation of Metals 81, no. 5-6 (2013): 503–13. http://dx.doi.org/10.1007/s11085-013-9461-4.

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27

Dimitrov, R., and I. Bonev. "Mechanism of zinc sulphide oxidation." Thermochimica Acta 106 (September 1986): 9–25. http://dx.doi.org/10.1016/0040-6031(86)85111-5.

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28

Coulet, Marie-Vanessa, Benoit Rufino, Pierre-Henry Esposito, Thomas Neisius, Olivier Isnard, and Renaud Denoyel. "Oxidation Mechanism of Aluminum Nanopowders." Journal of Physical Chemistry C 119, no. 44 (2015): 25063–70. http://dx.doi.org/10.1021/acs.jpcc.5b07321.

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29

van Manen, P. A., G. W. R. Leibbrandt, R. Klumpes, and J. H. W. de Wit. "The oxidation mechanism of Pt20Ni30Al50." Le Journal de Physique IV 03, no. C9 (1993): C9–123—C9–131. http://dx.doi.org/10.1051/jp4:1993910.

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30

Liao, K., Y. Cong, L. Kang, and X. Q. Deng. "The Mechanism of Paraffin Oxidation." Petroleum Science and Technology 26, no. 15 (2008): 1852–58. http://dx.doi.org/10.1080/10916460701426056.

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31

Wu, Runrun, Sainan Wang, and Liming Wang. "Atmospheric oxidation mechanism of chlorobenzene." Chemosphere 111 (September 2014): 537–44. http://dx.doi.org/10.1016/j.chemosphere.2014.04.067.

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32

Utigard, T. "Oxidation Mechanism of Molybdenite Concentrate." Metallurgical and Materials Transactions B 40, no. 4 (2009): 490–96. http://dx.doi.org/10.1007/s11663-009-9245-z.

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33

Luanpitpong, Sudjit, Pithi Chanvorachote, Christian Stehlik, et al. "Regulation of apoptosis by Bcl-2 cysteine oxidation in human lung epithelial cells." Molecular Biology of the Cell 24, no. 6 (2013): 858–69. http://dx.doi.org/10.1091/mbc.e12-10-0747.

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Hydrogen peroxide is a key mediator of oxidative stress known to be important in various cellular processes, including apoptosis. B-cell lymphoma-2 (Bcl-2) is an oxidative stress–responsive protein and a key regulator of apoptosis; however, the underlying mechanisms of oxidative regulation of Bcl-2 are not well understood. The present study investigates the direct effect of H2O2on Bcl-2 cysteine oxidation as a potential mechanism of apoptosis regulation. Exposure of human lung epithelial cells to H2O2induces apoptosis concomitant with cysteine oxidation and down-regulation of Bcl-2. Inhibition
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34

Ganster, Patrick, Bagas Pujilaksono, and Krzysztof Wolski. "Kinetics and Mechanism of High Temperature Internal Oxidation of Ni-14wt%W Alloy at 1000°C." Defect and Diffusion Forum 323-325 (April 2012): 321–26. http://dx.doi.org/10.4028/www.scientific.net/ddf.323-325.321.

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Ni-14wt%W model-alloy has been used to study the kinetics and the mechanism of high temperature internal oxidation in presence of an external oxide scale. Oxidations have been done in air at 1000°C for different oxidation times and have allowed the evaluation of the oxidation kinetic from mass gain and from oxide thickness measurements. The oxidation kinetic which follows a parabolic oxidation rate indicates a diffusive behaviour of species during the oxide formation. Cross-section observations by Scanning Electron Microscopy (SEM) and analysis by Grazing Incidence X-Rays Diffraction (GIXRD) s
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35

Mujawar, S. I., R. S. Yalgudre, D. J. Sutar, and G. S. Gokavi. "Waugh Type Polyoxometalate Enneamolybdomangate(IV) as an Acid Catalyst for Hydrolysis and as an Oxidant for Aspirin: A Kinetic Study." Asian Journal of Chemistry 36, no. 1 (2023): 97–103. http://dx.doi.org/10.14233/ajchem.2024.30296.

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The oxidations of aspirin and salicylic acid by enneamolybdomanganate(IV) were studied in perchloric acid medium. The aspirin undergo hydrolysis prior to the oxidation to generate salicylic acid, which was found to be catalyzed by both HClO4 as well as the oxidant. The rate of hydrolysis of aspirin catalyzed by the oxidant was found to be lesser than that of HClO4. A mechanism based on the kinetic results is proposed for oxidation of both aspirin and salicylic acid. Initially, aspirin undergo hydrolysis to give salicylic acid, which is catalyzed by both the oxidant, which also acts as an acid
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36

Faraci, G., S. La Rosa, A. R. Pennisi, and G. Margaritondo. "Na-promoted oxidation of Si: The specific oxidation mechanism." Physical Review B 49, no. 4 (1994): 2943–46. http://dx.doi.org/10.1103/physrevb.49.2943.

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37

Chuprina, V. G. "Oxidation of porous nanocrystalline titanium nitride. III. Oxidation mechanism." Powder Metallurgy and Metal Ceramics 46, no. 3-4 (2007): 182–88. http://dx.doi.org/10.1007/s11106-007-0029-1.

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38

Chuprina, V. G. "Oxidation of Ni — Ta alloys. III. Mechanism of oxidation." Powder Metallurgy and Metal Ceramics 39, no. 5-6 (2000): 275–82. http://dx.doi.org/10.1007/bf02684679.

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39

Mitovski, Aleksandra, Nada Štrbac, Miroslav Sokić, Milan Kragović, and Vesna Grekulović. "Reaction mechanism and kinetics of sulfide copper concentrate oxidation at elevated temperatures." Metallurgical and Materials Engineering 23, no. 3 (2017): 267–80. http://dx.doi.org/10.30544/320.

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Sulfide copper concentrate from domestic ore deposit (Bor, Serbia) was subjected to oxidation in the air atmosphere due to a better understanding of reaction mechanism and oxidation of various sulfides present in the copper concentrate at elevated temperatures. Results of the initial sample characterization showed that concentrate is chalcopyrite–enargite-tennantite type, with an increased arsenic content. Characterization of the oxidation products showed the presence of sulfates, oxysulfates, and oxides. Based on predominance area diagrams for Me-S-O systems (Me = Cu, Fe, As) combined with th
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40

Lu, Qinyue, Weicheng Zong, Mingyixing Zhang, Zhi Chen та Zhangping Yang. "The Overlooked Transformation Mechanisms of VLCFAs: Peroxisomal β-Oxidation". Agriculture 12, № 7 (2022): 947. http://dx.doi.org/10.3390/agriculture12070947.

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Beta-oxidation(β-oxidation) is an important metabolic process involving multiple steps by which fatty acid molecules are broken down to produce energy. The very long-chain fatty acids (VLCFAs), a type of fatty acid (FA), are usually highly toxic when free in vivo, and their oxidative metabolism depends on the peroxisomal β-oxidation. For a long time, although β-oxidation takes place in both mitochondria and peroxisomes, most studies have been keen to explore the mechanism of β-oxidation in mitochondria while ignoring the importance of peroxisomal β-oxidation. However, current studies indicate
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41

A., ABDUL JAMEEL. "Kinetics and Mechanism of Oxidation of Benzaldehydes by Quinolinium Chlorochromate." Journal of Indian Chemical Society Vol. 75, Aug 1998 (1998): 439–42. https://doi.org/10.5281/zenodo.5926691.

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Post-Graduate Department of Chemistry, Jamal Mohamed College, Tiruchirappalli-620 020 <em>Manuscript received 28 November 1997, accepted 23 March 1998</em> The kinetics of oxidation of benzaldehyde (BA) and several para- and meta-substituted benzaldehydes to the corresponding benzoic acids by quinolinium chlorochromate (QCC) have been studied. The reaction is first order each in (QCC), (substrate) and (H+). The reaction rates have been determined at different temperatures and the activation parameters calculated. The rate decreases with an increase in the amount of acetic acid in its aqueous m
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42

CH., SANJEEVA REDDY, and V. SUNDARAM E. "Kinetics and Mechanism of Acid Bromate Oxidation of Tartaric Acid." Journal of Indian Chemical Society Vol. 62, Mar 1985 (1985): 209–12. https://doi.org/10.5281/zenodo.6321954.

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Department of Chemistry, University College, Kakatiya University, Warangal-506 009 <em>Manuscript received&nbsp;21 February 1982, revised 22 July 1983, accepted 19 January 1985</em> The bromate oxidation of dextro-and meso-tartaric acids has been carried out in aqueous acetic acid medium containing mercuric acetate and sulphuric or percbloric acid in the temperature range 30-60&deg;. The reaction exhibits first order dependance each in [bromate] and [substrate], and shows no stable complex formation between the oxidant and the substrate. The reactions are acid catalysed and the absence of wate
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43

Wiser, Forwood, Bryan K. Place, Siddhartha Sen, et al. "AMORE-Isoprene v1.0: a new reduced mechanism for gas-phase isoprene oxidation." Geoscientific Model Development 16, no. 6 (2023): 1801–21. http://dx.doi.org/10.5194/gmd-16-1801-2023.

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Abstract. Gas-phase oxidation of isoprene by ozone (O3) and the hydroxyl (OH) and nitrate (NO3) radicals significantly impacts tropospheric oxidant levels and secondary organic aerosol formation. The most comprehensive and up-to-date chemical mechanism for isoprene oxidation consists of several hundred species and over 800 reactions. Therefore, the computational expense of including the entire mechanism in large-scale atmospheric chemical transport models is usually prohibitive, and most models employ reduced isoprene mechanisms ranging in size from ∼ 10 to ∼ 200 species. We have developed a n
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44

Ni, Hong Jun, Lei Chen, De Qin She, and Yin Nan Yuan. "Current Situation of the Study on Oxidative Stability of Biodiesel." Advanced Materials Research 887-888 (February 2014): 484–87. http://dx.doi.org/10.4028/www.scientific.net/amr.887-888.484.

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As a high quality alternative of fossil diesel, biodiesel is widely concerned at domestic and abroad for its environmentally friendly and renewable. Oxidation stability is one of the important properties of biodiesel, which is also one of the quality criteria in storing and using. The oxidative mechanism and the influencing factors of Oxidation stability, oxidation stabilitys evaluation methods and the application of biodiesel antioxidants were reviewed. Then the direction of oxidation stability is put forward.
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45

Yang, Liqiu, Subodh C. Tiwari, Seong Soon Jo, et al. "Unveiling oxidation mechanism of bulk ZrS2." MRS Advances 6, no. 11 (2021): 303–6. http://dx.doi.org/10.1557/s43580-021-00007-2.

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Abstract Transition metal dichalcogenides have shown great potential for next-generation electronic and optoelectronic devices. However, native oxidation remains a major issue in achieving their long-term stability, especially for Zr-containing materials such as ZrS2. Here, we develop a first principles-informed reactive forcefield for Zr/O/S to study oxidation dynamics of ZrS2. Simulation results reveal anisotropic oxidation rates between (210) and (001) surfaces. The oxidation rate is highly dependent on the initial adsorption of oxygen molecules on the surface. Simulation results also provi
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46

Yan, Ge, Pu Wang, Yuqian Li та ін. "Adsorption-Oxidation Mechanism of δ-MnO2 to Remove Methylene Blue". Adsorption Science & Technology 2021 (26 жовтня 2021): 1–12. http://dx.doi.org/10.1155/2021/3069392.

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The material, δ-MnO2, has exhibited superior performance on the removal of methylene blue (MB), but the process is significantly impacted by pH, and the impacting mechanism is still unclear. In this study, the effects of pH on the removal mechanism of MB using synthesized δ-MnO2 were investigated by distinguishing the adsorption and oxidation of MB by δ-MnO2 during the removal process in the dark. The results show that the total removal efficiency of MB by δ-MnO2 decreased significantly with an increase in the pH. MB could be removed by δ-MnO2 via an adsorption mechanism and oxidation mechanis
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47

Li, Zongdong, Michael A. Nardi, Steven J. Feinmark, and Simon Karpatkin. "A New Mechanism of Platelet Activation, Oxidation and Death Induced by ADAMTS-18." Blood 106, no. 11 (2005): 652. http://dx.doi.org/10.1182/blood.v106.11.652.652.

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Abstract Anti-platelet GPIII49–66 Ab obtained from HIV-1-ITP patients (or raised in rabbits) induces platelet oxidation, fragmentation and death by activating platelet 12-lipoxygenase (generating 12(S)-HETE) and NADPH-oxidase with exposure of membrane fragment phosphatidyl serine and thrombin-generating capacity (Cell106:551, 2001; JCI113: 973, 2004). Our recent studies reveal that activation of oxidative platelet death requires classic Ca++ flux (fura-2, AM) (completely inhibited by 100uM EGTA or 10uM BAPTA), and is associated with mild GPIIIa activation (PAC Ab binding) and prominent P-selec
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48

Azarapin, Nikita O., Nikolay A. Khritokhin, Victor V. Atuchin, et al. "Kinetics and Mechanism of BaLaCuS3 Oxidation." Crystals 13, no. 6 (2023): 903. http://dx.doi.org/10.3390/cryst13060903.

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The oxidation reactions of BaLaCuS3 in the artificial air atmosphere were studied at different heating rates in the temperature range of 50–1200 °C. The oxidation stages were determined by DSC-TG, XRD and IR–vis methods. The kinetic characteristics of the proceeding reactions were obtained with the use of the Kissinger model in a linearized form. Compound BaLaCuS3 was stable in the air up to 280 °C. Upon further heating up to 1200 °C, this complex sulfide underwent three main oxidation stages. The first stage is the formation of BaSO4 and CuLaS2. The second stage is the oxidation of CuLaS2 to
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49

Wu, Zhi, Shui Ping Zhong, Zhong Sheng Huang, Ren Man Ruan, Zeng Ling Wu, and Gang Zou. "Dissolution of Pyrite Particles by Chemical Oxidation and Bioleaching." Advanced Materials Research 634-638 (January 2013): 3059–64. http://dx.doi.org/10.4028/www.scientific.net/amr.634-638.3059.

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Dissolution of pyrite by chemical oxidation and bioleaching were studied with using short-term batch experiments. The results show that the rate of oxidative dissolution of pyrite increases with the increasing concentration of ferric in ferric sulfate solutions. With the corresponding in the bioleaching, the leaching rate of pyrite is markedly affected by the Eh of the solution. The ferric/ferrous ratio controls the relative rate of the oxidation reactions involved in the process. Additionally, the leaching rate of pyrite is controlled by the pH. The phase analysis of products indicated that S
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50

Davidson, V. L., M. E. Graichen, and L. H. Jones. "Mechanism of reaction of allylamine with the quinoprotein methylamine dehydrogenase." Biochemical Journal 308, no. 2 (1995): 487–92. http://dx.doi.org/10.1042/bj3080487.

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Allylamine did not serve as an efficient substrate for methylamine dehydrogenase (EC 1.4.99.3) in a steady-state assay of activity and appeared to act as a competitive inhibitor of methylamine oxidation by methylamine dehydrogenase. Transient kinetic studies, however, revealed that allylamine rapidly reduced the tryptophan tryptophylquinone (TTQ) cofactor of methylamine dehydrogenase. The rate of TTQ reduction by allylamine was 322 s-1, slightly faster than the rate of reduction by methylamine. These data were explained by a kinetic mechanism in which allylamine and methylamine are alternative
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