Academic literature on the topic 'Mechanism photodegradation'

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Journal articles on the topic "Mechanism photodegradation"

1

Trefonas, Peter, Robert West, and Robert D. Miller. "Polysilane high polymers: mechanism of photodegradation." Journal of the American Chemical Society 107, no. 9 (1985): 2737–42. http://dx.doi.org/10.1021/ja00295a028.

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2

Liu, Pengyan, Yujie Liu, Qingxue Liu, and Jinwei Liu. "Photodegradation mechanism of deltamethrin and fenvalerate." Journal of Environmental Sciences 22, no. 7 (2010): 1123–28. http://dx.doi.org/10.1016/s1001-0742(09)60227-8.

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3

Xu, Jian-hui, Bin-bin Ding, Xiao-mei Lv, Shan-hong Lan, Chao-lin Li, and Liu Peng. "Mathematical Modeling and Mechanism of VUV Photodegradation of H2S in the Absence of O2." International Journal of Photoenergy 2018 (June 27, 2018): 1–8. http://dx.doi.org/10.1155/2018/2769213.

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The existence of H2S has limited the biogas energy promotion. The traditional photodegradation of H2S is usually conducted in the presence of O2, yet this is unsuitable for biogas desulfurization which should be avoided. Therefore, the ultraviolet degradation of H2S in the absence of O2 was investigated for the first time in the present study from a mathematical point of view. Light wavelength and intensity applied were 185 nm and 2.16 × 10−12 Einstein/cm2·s, respectively. Firstly, the mathematical model of H2S photodegradation was established with MATLAB software, including the gas flow distr
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4

ION, Chim Rodica-Mariana, and Cristina MANDRAVEL. "THE PHOTODEGRADATION REACTION OF SOME PORPHYRINS." SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 5, no. 5 (1997): 111–29. http://dx.doi.org/10.48141/sbjchem.v5.n5.1997.109_1997.pdf.

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One of the most important but undesirable properties of the porphyrins is their oxidative photodegradation which can occur in non-polar solvents, under irradiation, and in the presence of molecular oxygen. The mechanism of this oxidative photodegradation implies singlet oxygen and different radical species. This paper is concerned with the mechanism of the photodegradation of some meso-tetra(4-X-phenyl)porphyrins(TXPP) and meso-tetra(4-X-1-naphtyl)porphyrins(TXNP), where X could have different organic structures (-NH2,-N02,-S03H,-OH,-OCH3,-CH3). Based on different spectral methods (UV-Vis and
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Kanehiro, Haruyuki, and John E. Kasu. "Mechanism of photodegradation of nylon netting twine." NIPPON SUISAN GAKKAISHI 54, no. 10 (1988): 1777–82. http://dx.doi.org/10.2331/suisan.54.1777.

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6

Burrows, Hugh D., Ludmila S. Ernestova, Terence J. Kemp, Yuri I. Skurlatov, Anatol P. Purmal, and Alexander N. Yermakov. "KINETICS AND MECHANISM OF PHOTODEGRADATION OF CHLOROPHENOLS." Progress in Reaction Kinetics and Mechanism 23, no. 1 (1998): 145–207. http://dx.doi.org/10.3184/007967498103165022.

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7

Li, Xu Chun, Jun Ma, and Si Yang Yue. "Total and Efficient Removal of Tribromoacetic Acid by Ultraviolet Irradiation." Advanced Materials Research 518-523 (May 2012): 2939–43. http://dx.doi.org/10.4028/www.scientific.net/amr.518-523.2939.

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Tribromoacetic acid (TBAA), one of the typically recalcitrant and toxic chlorine disinfection byproducts (DBPs), is widespread in the drinking water and threating human health. The environment-friendly technology, UV irradiation, could efficiently destruct TBAA. The present study investigated the removal efficiency, photodegradation kinetics, and photodegradation mechanism of TBAA under UV irradiation. It revealed that the photodegradaton process of TBAA agreed well with the pseudo-first order kinetics, with the rate constant of 1.084 min-1and half-time of 0.64 minutes. Further study on interm
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8

Serdechnova, Maria, Vladimir L. Ivanov, M. Rosario M. Domingues, Dmitry V. Evtuguin, Mario G. S. Ferreira, and Mikhail L. Zheludkevich. "Photodegradation of 2-mercaptobenzothiazole and 1,2,3-benzotriazole corrosion inhibitors in aqueous solutions and organic solvents." Phys. Chem. Chem. Phys. 16, no. 45 (2014): 25152–60. http://dx.doi.org/10.1039/c4cp03867c.

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9

Wang, Lei, Hongwen Sun, Yinghong Wu, Guolan Huang, and Shugui Dai. "Photodegradation of nonylphenol polyethoxylates in aqueous solution." Environmental Chemistry 6, no. 2 (2009): 185. http://dx.doi.org/10.1071/en08101.

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Environmental context. Nonylphenol polyethoxylates (NPEOs) are widely used non-ionic surfactants, and they cause environmental concern because some metabolites of NPEOs possess endocrine-disrupting activities. Photodegradation is an important pathway for NPEOs degradation, and different degradation products may lead to different environmental risks. The present paper looks at the kinetics and pathways of NPEO photodegradation in aqueous solutions, focussing on the effects of humic acid, H2O2, and FeIII. We found that the presence of different chemicals led to different degradation pathways, an
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10

Li, Xiao Jing, Guan Jun Qiao, and Jie Rong Chen. "Mechanism of PVC’s Solid-Phase Photocatalytic Degradation Enhanced by Plasma." Materials Science Forum 544-545 (May 2007): 155–58. http://dx.doi.org/10.4028/www.scientific.net/msf.544-545.155.

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The solid-phase photocatalytic degradation of poly (vinyl chloride) (PVC) films was investigated in ambient air. The photodegradation of the PVC and PVC-TiO2 was compared with that of plasma-treated PVC and plasma-treated PVC-TiO2 performing a weight loss monitoring and scanning electron microscopic (SEM) analysis. The SEM of the PVC-TiO2 film treated by plasma showed many cracks on the surface after photodegradation. Furthermore, the surface wettability and surface structure of PVC after nitrogen plasma treatment was characterized by contact angle, surface tension, and electron spin resonance
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