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Journal articles on the topic 'Mechano-chemistry'

Author: Grafiati

Published: 1 April 2023

Last updated: 31 July 2025

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1

Danielewski, Marek, and Bartłomiej Wierzba. "Mechano-Chemistry; Interdiffusion in Solid Solutions." Defect and Diffusion Forum 277 (April 2008): 61–68. http://dx.doi.org/10.4028/www.scientific.net/ddf.277.61.

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In this work we show that the volume velocity, ρυ , rather than the local centre of mass velocity should be used in continua. We use the volume continuity equation to define the volume frame of reference in the multicomponent, compressible continua. The volume velocity (material velocity) is a unique frame of reference for all internal forces and processes, e.g., the mass diffusion. No basic changes are required in the foundations of linear irreversible thermodynamics except recognizing the need to add volume to the usual list of extensive physical properties undergoing transport in every cont

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2

Preller, Matthias, and Dietmar J. Manstein. "Myosin Structure, Allostery, and Mechano-Chemistry." Structure 21, no. 11 (2013): 1911–22. http://dx.doi.org/10.1016/j.str.2013.09.015.

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3

Li, Jianwei, Shouzhi Ma, Xinjuan Liu, Zhaofeng Zhou, and Chang Q. Sun. "ZnO Meso-Mechano-Thermo Physical Chemistry." Chemical Reviews 112, no. 5 (2012): 2833–52. http://dx.doi.org/10.1021/cr200428m.

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4

Malik, Omri, Hadeel Kahamis, Sergei Rudnizky, and Ariel Kaplan. "The Mechano-Chemistry of Reverse Transcriptase." Biophysical Journal 112, no. 3 (2017): 514a. http://dx.doi.org/10.1016/j.bpj.2016.11.2779.

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5

Popov, Konstantin I., and Garegin A. Papoian. "Capsid Deformations Reveal Complex Mechano-Chemistry." Biophysical Journal 105, no. 10 (2013): 2233–34. http://dx.doi.org/10.1016/j.bpj.2013.09.055.

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6

Tseng, C. Y., A. Wang, and G. Zocchi. "Mechano-chemistry of the enzyme Guanylate Kinase." EPL (Europhysics Letters) 91, no. 1 (2010): 18005. http://dx.doi.org/10.1209/0295-5075/91/18005.

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7

Danielewski, Marek, and Bartłomiej Wierzba. "Mechano-chemistry; diffusion in multicomponent compressible mixtures." Physica A: Statistical Mechanics and its Applications 387, no. 4 (2008): 745–56. http://dx.doi.org/10.1016/j.physa.2007.10.015.

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8

Guo, Ze Cheng, Ming Chen, Dong Bo Zhao, and Fei Meng Zhang. "Tribology and Self-Repairing Nature of RE Nanophase Composite Material." Advanced Materials Research 659 (January 2013): 3–6. http://dx.doi.org/10.4028/www.scientific.net/amr.659.3.

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RE nanophase composite material between the grain size 30nm and 100nm are prepared by the method of mechano-chemistry，in which the material’s adsorptive capacity to metal base is checked，and the nature of anti-friction as well as self-repairing effectiveness to the surface of abrasion is tested by four-ball friction wear testing machine. The results show that RE nanophase composite material prepared by the method of mechano-chemistry has a good adsorptive capacity to metal base，and the wear surface can be covered and repaired under dynamic condition；RE nanophase composite material used as anti

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9

Malik, Omri, Hadeel Khamis, Sergei Rudnizky, and Ariel Kaplan. "The mechano-chemistry of a monomeric reverse transcriptase." Nucleic Acids Research 45, no. 22 (2017): 12954–62. http://dx.doi.org/10.1093/nar/gkx1168.

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10

Shimojo, F., R. K. Kalia, A. Nakano, K. Nomura, and P. Vashishta. "Metascalable molecular dynamics simulation of nano-mechano-chemistry." Journal of Physics: Condensed Matter 20, no. 29 (2008): 294204. http://dx.doi.org/10.1088/0953-8984/20/29/294204.

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11

Lin, Leqi, Vashin Gautham Nanjangud Thyagaraja, Renoy Ranjith, et al. "Degradation of organic molecules by tribovoltaic mechano-chemistry." Nano Energy 107 (March 2023): 108163. http://dx.doi.org/10.1016/j.nanoen.2022.108163.

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12

Shi, Wu Chao, Cheng Chen, Hao Wu, Dan Yu Jiang, and Qiang Li. "The Mechano-Chemical Synthesis and Characteristics of PMN and PZT." Key Engineering Materials 544 (March 2013): 92–95. http://dx.doi.org/10.4028/www.scientific.net/kem.544.92.

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Both PMN and PZT are perovskite oxides and typical functional materials applicable to various devices for its chemistry and physics properties. The conventional method solid-state reaction method has some drawbacks of high reaction temperature, large particle size and limited degree of chemical homogeneity. So, an easy, low cost and environmental method of synthesizing fine and homogenous powders is required. This paper discusses the synthesis of PMN and PZT by the new mechano-chemical method, the screw grinding method. Through experiments, it was found that the mechanism of mechano-chemical m

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13

Lin, Fengcai, Zi Wang, Yanping Shen, et al. "Natural skin-inspired versatile cellulose biomimetic hydrogels." Journal of Materials Chemistry A 7, no. 46 (2019): 26442–55. http://dx.doi.org/10.1039/c9ta10502f.

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A skin-like cellulose biomimetic hydrogel was prepared based on dynamic covalent chemistry, which realized the combination of ultra-stretchability, self-healing, adhesiveness, antibacterial and mechano-stimuli sensitivity within a single structure.

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14

Danielewski, Marek, Maciej Pietrzyk, and Bartłomiej Wierzba. "Electro-Mechano-Chemistry; Transport Problem in Four Time Scales." Solid State Phenomena 129 (November 2007): 11–18. http://dx.doi.org/10.4028/www.scientific.net/ssp.129.11.

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The mass transport in the presence of stress, electrical, mechanical and chemical potential gradients in multicomponent solid solution is analyzed. The method bases on the Darken concept and the calorimetric equation of state. We effectively coupled the conservation of the mass (continuity equations), energy, momentum and Gauss equations. The diffusion fluxes of the components are given by the Nernst-Planck formulae and take into account the electro-chemical and mechanical potentials. We simulate the deformation field during the diffusion caused by the gradients of the chemical potential of al

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15

Pajak, Joshua, Nikolai S. Prokhorov, Paul J. Jardine, and Marc C. Morais. "The mechano-chemistry of a viral genome packaging motor." Current Opinion in Structural Biology 89 (December 2024): 102945. http://dx.doi.org/10.1016/j.sbi.2024.102945.

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16

Claramunt, Rosa M., Concepcion Lopez, Dionisia Sanz, and Jose Elguero. "ChemInform Abstract: Mechano Heterocyclic Chemistry: Grinding and Ball Mills." ChemInform 46, no. 24 (2015): no. http://dx.doi.org/10.1002/chin.201524263.

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17

Tan, L. S., A. J. McHugh, M. A. Gülgün, and W. M. Kriven. "Evolution of mechano-chemistry and microstructure of a calcium aluminate-polymer composite: Part II. Mixing rate effects." Journal of Materials Research 11, no. 7 (1996): 1739–47. http://dx.doi.org/10.1557/jmr.1996.0218.

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Microstructure, microchemistry and mechanical properties of hardened macro-defect-free (MDF) composites processed at various rotor rates in a Banbury mixer were investigated. A quiescently formed calcium aluminate-polyvinyl alcohol composite served as a substitute for an unmixed system. Results from the Banbury studies in conjunction with microchemical analysis of the unmixed composite showed evidence that the polymer-particle interaction is a mechanically induced crosslinking reaction. The rate of the mechano-chemistry increases with mixing speeds. Scanning electron micrographs (SEM) and tran

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18

Wang, Zixing, Xiang Zhang, Jordan A. Hachtel, et al. "Etching of transition metal dichalcogenide monolayers into nanoribbon arrays." Nanoscale Horizons 4, no. 3 (2019): 689–96. http://dx.doi.org/10.1039/c8nh00364e.

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A facile mechano-chemical method was developed to etch TMDC monolayers into anisotropic nanoribbon arrays through wet chemistry. The etching is done under both the effect of chemical reaction with ascorbic acid, and mechanical detachment from the substrate using water's dipole moment.

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19

Asamoah, Richmond K. "Specific Refractory Gold Flotation and Bio-Oxidation Products: Research Overview." Minerals 11, no. 1 (2021): 93. http://dx.doi.org/10.3390/min11010093.

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This paper presents a research overview, reconciling key and useful case study findings, towards uncovering major causes of gold refractoriness and maximising extraction performance of specific gold flotation and bio-oxidation products. Through systematic investigation of the ore mineralogical and gold deportment properties, leaching mechanisms, and kinetic behaviour and pulp rheology, it was observed that the predominant cause of the poor extraction efficacy of one bio-oxidised product is the presence of recalcitrant sulphate minerals (e.g., jarosite and gypsum) produced during the oxidation

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20

Kabbani, Mohamad A., Vidya Kochat, Sanjit Bhowmick, et al. "Consolidation of functionalized graphene at ambient temperature via mechano-chemistry." Carbon 134 (August 2018): 491–99. http://dx.doi.org/10.1016/j.carbon.2018.03.049.

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21

Kharmyssov, Chingis, Kairolla Sekerbayev, Zhangatay Nurekeyev, Abduzhappar Gaipov, and Zhandos N. Utegulov. "Mechano-Chemistry across Phase Transitions in Heated Albumin Protein Solutions." Polymers 15, no. 9 (2023): 2039. http://dx.doi.org/10.3390/polym15092039.

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The presence of certain proteins in biofluids such as synovial fluid, blood plasma, and saliva gives these fluids non-Newtonian viscoelastic properties. The amount of these protein macromolecules in biofluids is an important biomarker for the diagnosis of various health conditions, including Alzheimer’s disease, cardiovascular disorders, and joint quality. However, existing technologies for measuring the behavior of macromolecules in biofluids have limitations, such as long turnaround times, complex protocols, and insufficient sensitivity. To address these issues, we propose non-contact, optic

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22

Vejjasilpa, Ketpat, Iram Maqsood, Michaela Schulz-Siegmund, and Michael C. Hacker. "Adjustable Thermo-Responsive, Cell-Adhesive Tissue Engineering Scaffolds for Cell Stimulation through Periodic Changes in Culture Temperature." International Journal of Molecular Sciences 24, no. 1 (2022): 572. http://dx.doi.org/10.3390/ijms24010572.

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A three-dimensional (3D) scaffold ideally provides hierarchical complexity and imitates the chemistry and mechanical properties of the natural cell environment. Here, we report on a stimuli-responsive photo-cross-linkable resin formulation for the fabrication of scaffolds by continuous digital light processing (cDLP), which allows for the mechano-stimulation of adherent cells. The resin comprises a network-forming trifunctional acrylate ester monomer (trimethylolpropane triacrylate, or TMPTA), N-isopropyl acrylamide (NiPAAm), cationic dimethylaminoethyl acrylate (DMAEA) for enhanced cell inter

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23

Cichosz, Stefan, and Anna Masek. "Superiority of Cellulose Non-Solvent Chemical Modification over Solvent-Involving Treatment: Solution for Green Chemistry (Part I)." Materials 13, no. 11 (2020): 2552. http://dx.doi.org/10.3390/ma13112552.

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In the following article, a new approach of cellulose modification, which does not incorporate any solvents (NS), is introduced. It is compared for the first time with the traditional solvent-involving (S) treatment. The analysed non-solvent modification process is carried out in a planetary mill. This provides the opportunity for cellulose mechanical degradation, decreasing its size, simultaneously with ongoing silane coupling agent grafting. Fourier-transform infrared spectroscopy (FT-IR) indicated the possibility of intense cleavage of the glucose rings in the cellulose chains during the me

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24

Elfakhri, Rehab, and Jonathan C. Burley. "Investigation of Potential Amorphisation and Co-Amorphisation Behaviour of the Benzene Di-Carboxylic Acids upon Cryo-Milling." Molecules 24, no. 21 (2019): 3990. http://dx.doi.org/10.3390/molecules24213990.

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Multi-component formulations offer a way to modulate the physico-chemical properties of drug molecules and thereby enhance their efficacy as medicines compared to using only the raw drug, with mechano-chemical synthesis being an increasingly popular way to create these novel materials in a research setting. However, to date studies have focussed on employing pharmaceutically acceptable components, which has led to the literature featuring chemically diverse pairings of drug and excipient. Here we investigate the outcome of cryo-milling and co-cryo-milling of a series of three simple geometrica

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25

Mateti, Srikanth, Alexey M. Glushenkov, Lu Hua Li, Qian Ma, Chunyi Zhi, and Ying Chen. "In situ doping and synthesis of two-dimensional nanomaterials using mechano-chemistry." Nanoscale Horizons 4, no. 3 (2019): 642–46. http://dx.doi.org/10.1039/c8nh00369f.

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26

Vera Lillo, Javier, Anna V. Shnyrova, and Vadim A. Frolov. "Highly Charged Membrane Templates for Studying the Mechano-Chemistry of Dynamin 1." Biophysical Journal 114, no. 3 (2018): 281a. http://dx.doi.org/10.1016/j.bpj.2017.11.1616.

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27

Stilinović, Vladimir, Dominik Cinčić, Marija Zbačnik, and Branko Kaitner. "Controlling Solvate Formation of a Schiff Base by Combining Mechano-chemistry with Solution Synthesis." Croatica Chemica Acta 85, no. 4 (2012): 485–93. http://dx.doi.org/10.5562/cca2111.

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28

Feng, Lajun, Wenning Shen, Hui Feng, Ali Lei, and Zheng Liu. "Magnetic and sterilizing properties of Ag(II)O–Fe3O4 hybrids synthesized via mechano-chemistry." Ceramics International 40, no. 5 (2014): 6963–72. http://dx.doi.org/10.1016/j.ceramint.2013.12.021.

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29

Ienco, Andrea, Giulia Tuci, Annalisa Guerri, and Ferdinando Costantino. "Mechanochemical Access to Elusive Metal Diphosphinate Coordination Polymer." Crystals 9, no. 6 (2019): 283. http://dx.doi.org/10.3390/cryst9060283.

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Several binary metal diphosphinate compounds (ML) have been reported for diphosphinate bonded by a single methylene fragment. In case of longer bridges, binary products are difficult to isolate in crystalline form. Here, using a solvent assisted mechano-chemistry synthesis, we report two new ML crystalline phases, one hydrated and one anhydrous. The hydrated phase is a 2D coordination polymer with an open framework structure. Its network displays a new topology for coordination polymers and metal organic frameworks. The thermal behavior of the two phases has been studied. Finally, the importan

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30

Chu, Liangyong, Alexander V. Korobko, Marcel Bus, Bart Boshuizen, Ernst J. R. Sudhölter, and Nicolaas A. M. Besseling. "Fast and controlled fabrication of porous graphene oxide: application of AFM tapping for mechano-chemistry." Nanotechnology 29, no. 18 (2018): 185301. http://dx.doi.org/10.1088/1361-6528/aaafc5.

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31

Jones, Ivy Krystal, Uwe Hommerich, Kesete Ghebreyessus, et al. "Mechano-Chemical Synthesis and Characterization of Undoped and Mn²⁺ Doped Cspb(Br_1-xCl_x)₃ Halide Perovskite for Light Source Application." ECS Meeting Abstracts MA2023-01, no. 32 (2023): 1827. http://dx.doi.org/10.1149/ma2023-01321827mtgabs.

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All-inorganic halide perovskites (HPs) continue to be of current interest for light source applications (e.g. lasers, LED’s) because of their high emission quantum yields and wide wavelength tunability due to compositional engineering [1]. The development of red and near-IR emitting lead halide perovskites, however, has been hampered by low emission efficiency and instability of iodine based compositions at room temperature. Recent studies employing transition metal or lanthanide doping have demonstrated an alternative approach to achieve red and near-IR emitting HPs structures [2-4]. In this

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32

Garrick, Taylor R., Yong Miao, Srikanth Arisetty, et al. "(Invited) Modeling Aging Induced Volume Change of Porous Electrodes." ECS Meeting Abstracts MA2023-01, no. 25 (2023): 1624. http://dx.doi.org/10.1149/ma2023-01251624mtgabs.

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Automotive battery manufacturers are improving individual cell and overall battery pack design by focusing on increasing performance, durability, and range while reducing cost. However, the coupled mechano-electrochemical phenomena caused by lithiation-based active material volume change significantly complicates the adoption and design of advanced battery systems, especially those with a high degree of volume change. Battery pack engineers mitigate the effects of volume change using a variety of methods, though, these mitigation strategies rely on extensive testing with anytime a change in ch

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33

Chowdhury, Debashish, and Dipanwita Ghanti. "Soft mechano-chemistry of molecular hubs in mitotic spindle: biomechanics and mechanical proofreading at microtubule ends." Journal of Physics: Condensed Matter 32, no. 28 (2020): 284001. http://dx.doi.org/10.1088/1361-648x/ab7cc5.

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34

Gülgün, M. A., W. M. Kriven, L. S. Tan, and A. J. McHugh. "Evolution of mechano-chemistry and microstructure of a calcium aluminate-polymer composite: Part I. Mixing time effects." Journal of Materials Research 10, no. 7 (1995): 1746–55. http://dx.doi.org/10.1557/jmr.1995.1746.

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Paste development and evolution of microstructure, microchemistry, and mechanical properties of macro-defect-free composites were investigated. Mixing torque plots from a Banbury mixer showed a “window of processibility” within which an optimum polymer-particle network structure formed. This processing window can be controlled by mixing rate and temperature. Network development during paste formation governed the flexural strength and microstructure of the cured material. Electron microscopy studies of the composites corresponding to various points along the mixing torque curve revealed a matr

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35

Cui, Chenglin, Hao Ding, Li Cao, and Daimei Chen. "Preparation of CaCO3-SiO2 composite with core-shell structure and its application in silicone rubber." Polish Journal of Chemical Technology 17, no. 4 (2015): 128–33. http://dx.doi.org/10.1515/pjct-2015-0079.

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Abstract A new CaCO3-SiO2 composite with core-shell structure was successfully prepared by mechano-chemistry method (MCM). SEM and FTIR indicated that SiO2 particles were homogeneously immobilized on the surface of CaCO3. The well dispersion of this CaCO3-SiO2 composite into silicone rubber can not only reduce the usage amount of SiO2, but also improve the mechanical properties of silicone rubber. By the calculation, the theoretical numbers of the SiO2 particles is about 10 times as large as that of CaCO3 particles in the CaCO3-SiO2 composite. Mixing CaCO3-SiO2 composite in silicone rubber can

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36

Kadhim, Mohammed Abed, Amin Farouk Mohamed Fahmy, Emad Khelil Mohammed Zangana, Aya Ibrahim Hassaballah, and Sameh Ahmed Rizk. "A Sustainable synthesis, eco-safe approach efficiency and DFT study of novel 5,6,7,8-Tetrahyroquinazolin-2(1H)-one derivatives as antioxidant reagents." Indonesian Journal of Chemistry 23, no. 4 (2023): 1138. http://dx.doi.org/10.22146/ijc.83583.

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5,6,7,8-Tetrahydroquinazolin-2-(thio)-ones (THQ) fits the class of N-heterocycles as a structural core in numerous bioactive compounds. They promptly extended previous decades. They were significantly recognized in combinatorial chemistry and materials science to determine the drug discovery, antioxidants, and pharmaceuticals fields. In the present work, one-pot multicomponent sustainable synthesis of THQ with easily accessible starting materials, i.e., cyclohexanone, different aromatic aldehydes and (thio)urea, has been performed to determine the proposed Biginelli mechanism that is supported

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37

Danielewski, Marek, and Bartek Wierzba. "Bi-Velocity Method and Linear Nonreversible Thermodynamics, Interdiffusion in R2." Defect and Diffusion Forum 297-301 (April 2010): 1461–68. http://dx.doi.org/10.4028/www.scientific.net/ddf.297-301.1461.

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Kirkendall and Darken findings of the drift velocity since 1948 have stimulated progress in transport phenomenological models. The convection velocity (the Darken drift in solids), , and velocity of diffusion, , require definition and the method how the diffusion displacement is defined, computed and measured. The equation of volume continuity allowed the extension of the Darken method and avoids the rigid assumption of the constant molar concentration. In this work, we use the bi-velocity approach, i.e., the generalized Darken method, to model interdiffusion in two-dimensional diffusion multi

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38

Pagnanelli, Francesca, Pier Giorgio Schiavi, Pietro Altimari, et al. "Economic and Environmental Sustainability of an Innovative Cryo-Mechano-Hydrometallurgical Process Validated at Pilot Scale for the Recycling of Li Batteries." Metals 13, no. 3 (2023): 497. http://dx.doi.org/10.3390/met13030497.

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An innovative cryo-mechano-hydrometallurgical process (named LIBAT) was demonstrated at pilot scale for the treatment of EOL lithium primary batteries with chemistry Li(0)-MnO2. The process allowed the recycling of steel scraps from external cases after cryomechanical dismantling, and the recovery of Mn and Li products after hydrometallurgical processing. During demonstration activities, about nine tons of batteries were treated in the cryomechanical section, and one ton of black mass was treated in the hydrometallurgical section for the recovery of Mn hydroxides and Li2CO3. The environmental

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39

Quattrocchi, F., R. Favara, G. Capasso, et al. "Thermal anomalies and fluid geochemistry framework in occurrence of the 2000-2001 Nizza Monferrate seismic sequence (northern Italy): Episodic changes in the fault zone heat flow or chemical mixing phenomena?" Natural Hazards and Earth System Sciences 3, no. 3/4 (2003): 269–77. http://dx.doi.org/10.5194/nhess-3-269-2003.

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Abstract. The paper discusses the correlation between the heating of shallow groundwater over a 10 × 20 km wide area close to the town of Nizza Monferrato (Piemonte Region, Northern Italy) and the concomitant local seismic sequences during the period August 2000 – July 2001. The first seismic sequence started on 21 August 2000 with a Ml = 5.2 earthquake. Within few hours, the local authorities received calls alerting that the groundwater temperature rose from 10 to 30°C in many shallow wells. Our geochemical experimental data and the geological-seismotectonic framework do not allow the hypothe

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40

Tang, Huidong, Qing Hu, Feng Jiang, et al. "Size control of C@ZrSiO4 pigments via soft mechano-chemistry assisted non-aqueous sol-gel method and their application in ceramic glaze." Ceramics International 45, no. 8 (2019): 10756–64. http://dx.doi.org/10.1016/j.ceramint.2019.02.149.

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41

Umar, Sheriff, and Alexander Samokhvalov. "Encapsulation of Gemcitabine on Porphyrin Aluminum Metal-Organic Framework by Mechano-Chemistry, Delayed Drug Release and Cytotoxicity to Pancreatic Cancer PANC-1 Cells." Molecules 29, no. 13 (2024): 3189. http://dx.doi.org/10.3390/molecules29133189.

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Gemcitabine is a widely used antimetabolite drug of pyrimidine structure, which can exist as a free-base molecular form (Gem). The encapsulated forms of medicinal drugs are of interest for delayed and local drug release. We utilized, for the first time, a novel approach of mechano-chemistry by liquid-assisted grinding (LAG) to encapsulate Gem on a “matrix” of porphyrin aluminum metal-organic framework Al-MOF-TCPPH2 (compound 2). The chemical bonding of Gem to compound 2 was studied by ATR-FTIR spectroscopy and powder XRD. The interaction involves the C=O group of Gem molecules, which indicates

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42

Aghayar, Zahra, Massoud Malaki, and Yizhou Zhang. "MXene-Based Ink Design for Printed Applications." Nanomaterials 12, no. 23 (2022): 4346. http://dx.doi.org/10.3390/nano12234346.

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MXenes are a class of two-dimensional nanomaterials with a rich chemistry, hydrophilic surface and mechano-ceramic nature, and have been employed in a wide variety of applications ranging from medical and sensing devises to electronics, supercapacitors, electromagnetic shielding, and environmental applications, to name a few. To date, the main focus has mostly been paid to studying the chemical and physical properties of MXenes and MXene-based hybrids, while relatively less attention has been paid to the optimal application forms of these materials. It has been frequently observed that MXenes

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43

Umar, Sheriff, Xavier Welch, Chihurumanya Obichere, Brandon Carter-Cooper, and Alexander Samokhvalov. "Interaction of 6-Thioguanine with Aluminum Metal–Organic Framework Assisted by Mechano-Chemistry, In Vitro Delayed Drug Release, and Time-Dependent Toxicity to Leukemia Cells." Nanomaterials 14, no. 19 (2024): 1571. http://dx.doi.org/10.3390/nano14191571.

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6-thioguanine (6-TG) is an antimetabolite drug of purine structure, approved by the FDA for the treatment of acute myeloid lesukemia, and it is of interest in treating other diseases. The interaction of drugs with matrices is of interest to achieving a delayed, sustained, and local release. The interaction of 6-TG with an aluminum metal–organic framework (Al-MOF) DUT-4 is studied using a novel experimental approach, namely, mechano-chemistry by liquid-assisted grinding (LAG). The bonding of 6-TG to the DUT-4 matrix in the composite (6-TG)(DUT-4) was studied using ATR-FTIR spectroscopy and XRD.

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44

Kim, Lidia, Gheorghe Dobra, Raluca Isopescu, et al. "Short review on mechanical activation in non-metallurgical alumina production." Romanian Journal of Ecology & Environmental Chemistry 4, no. 2 (2022): 62–79. http://dx.doi.org/10.21698/rjeec.2022.206.

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The terms mechano-chemistry and mechanical activation of solid materials were introduced in chemical literature by Ostwald at the beginning of the XX century. Both terms cover a whole range of interconnected phenomena taking place during the mechanical action on solids or their separate parts participating in chemical reactions, phase transitions, mixing and creating composite materials, alloying and crystal growth in the solid state, deformation and changing physical and thermal properties, all of them at low temperature. The common effects of the mechanical activation on solid material are f

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45

Hamed, Gary R. "Molecular Aspects of the Fatigue and Fracture of Rubber." Rubber Chemistry and Technology 67, no. 3 (1994): 529–36. http://dx.doi.org/10.5254/1.3538689.

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Abstract This short review highlights molecular mechanisms controlling the fracture of rubber and rubber reinforcement, with emphasis on the importance of mechano-chemistry. The manuscript is an extension and update of a previous short review published in Rubber Chemistry and Technology in 1991. All solids, including vulcanizates, contain inevitable ubiquitous flaws of various shapes and sizes. When a solid is subjected to a global stress, the local stresses at the tips of these flaws are magnified and can be many times larger than the average applied stress. Generally, there will be a single

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Dintheer, A. M., P. K. Jaeger, A. A. Hussien, and J. G. Snedeker. "MECHANICAL REGULATION OF MATRIX REMODELLING IN TENDON WOUND HEALING." Orthopaedic Proceedings 106-B, SUPP_1 (2024): 69. http://dx.doi.org/10.1302/1358-992x.2024.1.069.

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Extracellular matrix (ECM) mechanical cues guide healing in tendons. Yet, the molecular mechanisms orchestrating the healing processes remain elusive. Appropriate tissue tension is essential for tendon homeostasis and tissue health. By mapping the attainment of tensional homeostasis, we aim to understand how ECM tension regulates healing. We hypothesize that diseased tendon returns to homeostasis only after the cells reach a mechanically gated exit from wound healing.We engineered a 3D mechano-culture system to create tendon-like constructs by embedding patient-derived tendon cells into a coll

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Linert, W., V. Woronow, and V. Gutmann. "Mechano-elektrochemische Effekte, II." Monatshefte f�r Chemie Chemical Monthly 116, no. 11 (1985): 1263–74. http://dx.doi.org/10.1007/bf00811098.

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Dinarelli, Simone, Giovanni Longo, Antonio Francioso, Luciana Mosca, and Marco Girasole. "Mechano-Transduction Boosts the Aging Effects in Human Erythrocytes Submitted to Mechanical Stimulation." International Journal of Molecular Sciences 23, no. 17 (2022): 10180. http://dx.doi.org/10.3390/ijms231710180.

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Erythrocytes’ aging and mechano-transduction are fundamental cellular pathways that determine the red blood cells’ (RBCs) behavior and function. The aging pattern can be influenced, in morphological, biochemical, and metabolic terms by the environmental conditions. In this paper, we studied the effect of a moderate mechanical stimulation applied through external shaking during the RBCs aging and revealed a strong acceleration of the aging pattern induced by such stimulation. Moreover, we evaluated the behavior of the main cellular effectors and resources in the presence of drugs (diamide) or o

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Muraoka, Takahiro, Kaori Umetsu, Kazuhito V. Tabata, et al. "Mechano-Sensitive Synthetic Ion Channels." Journal of the American Chemical Society 139, no. 49 (2017): 18016–23. http://dx.doi.org/10.1021/jacs.7b09515.

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Surampudi, Sravan K., Harik R. Patel, G. Nagarjuna, and D. Venkataraman. "Mechano-isomerization of azobenzene." Chemical Communications 49, no. 68 (2013): 7519. http://dx.doi.org/10.1039/c3cc43797c.

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