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Journal articles on the topic 'Mechanochromism'

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1

Baranyai, Péter, Gábor Marsi, Csaba Jobbágy, Attila Domján, Laura Oláh, and Andrea Deák. "Mechano-induced reversible colour and luminescence switching of a gold(i)–diphosphine complex." Dalton Transactions 44, no. 30 (2015): 13455–59. http://dx.doi.org/10.1039/c5dt01795e.

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2

Yan, Xiaojing, Pengcheng Zhu, Zhiguo Zhou, Hong Yang, Haichuang Lan, and Shuzhang Xiao. "Aggregation-induced emission enhancement (AIEE)-active boron-difluoride dyes with reversible mechanochromic fluorescence." RSC Advances 9, no. 61 (2019): 35872–77. http://dx.doi.org/10.1039/c9ra07437f.

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A class of AIEE-active mechanochromic boron-difluorides were reported, and the mechanochromism was ascribed to the transition between H(J)-aggregation with loose molecular packing and J-aggregation with intense intermolecular interactions.
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3

Barber, Ross W., Molly E. McFadden, Xiaoran Hu, and Maxwell J. Robb. "Mechanochemically Gated Photoswitching: Expanding the Scope of Polymer Mechanochromism." Synlett 30, no. 15 (June 13, 2019): 1725–32. http://dx.doi.org/10.1055/s-0037-1611858.

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Mechanophores are molecules that undergo productive, covalent chemical transformations in response to mechanical force. Over the last decade, a variety of mechanochromic mechanophores have been developed that enable the direct visualization of stress in polymers and polymeric materials through changes in color and chemiluminescence. The recent introduction of mechanochemically gated photoswitching extends the repertoire of polymer mechanochromism by decoupling the mechanical activation from the visible response, enabling the mechanical history of polymers to be recorded and read on-demand using light. Here, we discuss advances in mechanochromic mechanophores and present our design of a cyclopentadiene–maleimide Diels–Alder adduct that undergoes a force-induced retro-[4+2] cycloaddition reaction to reveal a latent diarylethene photoswitch. Following mechanical activation, UV light converts the colorless diarylethene molecule into the colored isomer via a 6π-electrocyclic ring-closing reaction. Mechanically gated photoswitching expands on the fruitful developments in mechanochromic polymers and provides a promising platform for further innovation in materials applications including stress sensing, patterning, and information storage.1 Introduction to Polymer Mechanochemistry2 Mechanochromic Reactions for Stress Sensing3 Regiochemical Effects on Mechanophore Activation4 Mechanochemically Gated Photoswitching5 Conclusions
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4

Jiang, Yejia, Songshan Zeng, Yu Yao, Shiyu Xu, Qiaonan Dong, Pingxu Chen, Zhaofeng Wang, et al. "Dynamic Optics with Transparency and Color Changes under Ambient Conditions." Polymers 11, no. 1 (January 9, 2019): 103. http://dx.doi.org/10.3390/polym11010103.

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Mechanochromic materials have recently received tremendous attention because of their potential applications in humanoid robots, smart windows, strain sensors, anti-counterfeit tags, etc. However, improvements in device design are highly desired for practical implementation in a broader working environment with a high stability. In this article, a novel and robust mechanochromism was designed and fabricated via a facile method. Silica nanoparticles (NPs) that serve as a trigger of color switch were embedded in elastomer to form a bi-layer hybrid film. Upon stretching under ambient conditions, the hybrid film can change color as well as transparency. Furthermore, it demonstrates excellent reversibility and reproducibility and is promising for widespread application.
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5

Chen, Guojian, and Wei Hong. "Mechanochromism of Structural‐Colored Materials." Advanced Optical Materials 8, no. 19 (August 14, 2020): 2000984. http://dx.doi.org/10.1002/adom.202000984.

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6

Xiong, Yi, Jian Huang, Yingjie Liu, Biao Xiao, Bin Xu, Zujin Zhao, and Ben Zhong Tang. "High-contrast luminescence dependent on polymorphism and mechanochromism of AIE-active (4-(phenothiazin-10-yl)phenyl)(pyren-1-yl)methanone." Journal of Materials Chemistry C 8, no. 7 (2020): 2460–66. http://dx.doi.org/10.1039/c9tc05064g.

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7

Qi, Yunpeng, Wenjing Liu, Yongtao Wang, Lei Ma, Yongjiang Yu, Yan Zhang, and Litong Ren. "The inherent mechanism of mechanochromism under different stress: electron cloud density distribution, J-type stacking, pore structure and collapse of J-type stacking." New Journal of Chemistry 42, no. 14 (2018): 11373–80. http://dx.doi.org/10.1039/c7nj04543c.

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8

Naeem, Karattu Chali, Akhila Subhakumari, Sunil Varughese, and Vijayakumar C. Nair. "Heteroatom induced contrasting effects on the stimuli responsive properties of anthracene based donor–π–acceptor fluorophores." Journal of Materials Chemistry C 3, no. 39 (2015): 10225–31. http://dx.doi.org/10.1039/c5tc02062j.

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9

Xu, Bingjia, Yingxiao Mu, Zhu Mao, Zongliang Xie, Haozhong Wu, Yi Zhang, Chongjun Jin, et al. "Achieving remarkable mechanochromism and white-light emission with thermally activated delayed fluorescence through the molecular heredity principle." Chemical Science 7, no. 3 (2016): 2201–6. http://dx.doi.org/10.1039/c5sc04155d.

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10

Wada, Keisuke, Takahiro Kakuta, Tada-aki Yamagishi, and Tomoki Ogoshi. "Obvious vapochromic color changes of a pillar[6]arene containing one benzoquinone unit with a mechanochromic change before vapor exposure." Chemical Communications 56, no. 31 (2020): 4344–47. http://dx.doi.org/10.1039/d0cc01112f.

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11

Seki, Tomohiro, Koh Kobayashi, and Hajime Ito. "Low-temperature-selective luminescent mechanochromism of a thienyl gold isocyanide complex." Chemical Communications 53, no. 50 (2017): 6700–6703. http://dx.doi.org/10.1039/c7cc03190d.

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12

He, Junzhao, Huimin Zhao, Han Wu, Yuhui Yang, Zhaohui Wang, Zhe He, and Guohua Jiang. "Achieving enhanced solid-state photochromism and mechanochromism by introducing a rigid steric hindrance group." Physical Chemistry Chemical Physics 23, no. 33 (2021): 17939–44. http://dx.doi.org/10.1039/d1cp02983e.

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13

Li, Bijin, and Haibo Ge. "Highly selective electrochemical hydrogenation of alkynes: Rapid construction of mechanochromic materials." Science Advances 5, no. 5 (May 2019): eaaw2774. http://dx.doi.org/10.1126/sciadv.aaw2774.

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Electrochemical hydrogenation has emerged as an environmentally benign and operationally simple alternative to traditional catalytic reduction of organic compounds. Here, we have disclosed for the first time the electrochemical hydrogenation of alkynes to a library of synthetically important Z-alkenes under mild conditions with great selectivity and efficiency. The deuterium and control experiments of electrochemical hydrogenation suggest that the hydrogen source comes from the solvent, supporting electrolyte, and base. The scanning electron microscopy and x-ray diffraction experiments demonstrate that palladium nanoparticles generated in the electrochemical reaction act as a chemisorbed hydrogen carrier. Moreover, complete reduction of alkynes to saturated alkanes can be achieved through slightly modified conditions. Furthermore, a series of novel mechanofluorochromic materials have been efficiently constructed with this protocol that showed blue-shifted mechanochromism. This discovery represents the first example of cis-olefins–based organic mechanochromic materials.
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14

Pashazadeh, Ramin, Piotr Pander, Audrius Bucinskas, Peter J. Skabara, Fernando B. Dias, and Juozas V. Grazulevicius. "An iminodibenzyl–quinoxaline–iminodibenzyl scaffold as a mechanochromic and dual emitter: donor and bridge effects on optical properties." Chemical Communications 54, no. 98 (2018): 13857–60. http://dx.doi.org/10.1039/c8cc06981f.

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15

Wang, Yongtao, Wenjing Liu, Litong Ren, and Guixian Ge. "Deep insights into polymorphism initiated by exploring multicolor conversion materials." Materials Chemistry Frontiers 3, no. 8 (2019): 1661–70. http://dx.doi.org/10.1039/c9qm00293f.

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16

Seki, Tomohiro, Kentaro Kashiyama, and Hajime Ito. "Luminescent mechanochromism of gold N-heterocyclic carbene complexes with hypso- and bathochromic spectral shifts." Dalton Transactions 48, no. 21 (2019): 7105–9. http://dx.doi.org/10.1039/c9dt00566h.

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17

Zhu, Yuan-yuan, Hong-ying Xia, Li-feng Yao, Dan-ping Huang, Jun-yan Song, Hai-feng He, Liang Shen, and Feng Zhao. "High-contrast mechanochromic benzothiadiazole derivatives based on a triphenylamine or a carbazole unit." RSC Advances 9, no. 13 (2019): 7176–80. http://dx.doi.org/10.1039/c9ra00141g.

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18

Yu, Chin-Yang, Chia-Chieh Hsu, and Hsi-Chen Weng. "Synthesis, characterization, aggregation-induced emission, solvatochromism and mechanochromism of fluorinated benzothiadiazole bonded to tetraphenylethenes." RSC Advances 8, no. 23 (2018): 12619–27. http://dx.doi.org/10.1039/c8ra01448e.

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19

Bao, Suping, Jianhua Li, Ka I. Lee, Sijie Shao, Jianhua Hao, Bin Fei, and John H. Xin. "Reversible Mechanochromism of a Luminescent Elastomer." ACS Applied Materials & Interfaces 5, no. 11 (May 16, 2013): 4625–31. http://dx.doi.org/10.1021/am4013648.

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20

Huitorel, Brendan, Hani El Moll, Marie Cordier, Alexandre Fargues, Alain Garcia, Florian Massuyeau, Charlotte Martineau-Corcos, Thierry Gacoin, and Sandrine Perruchas. "Luminescence Mechanochromism Induced by Cluster Isomerization." Inorganic Chemistry 56, no. 20 (September 26, 2017): 12379–88. http://dx.doi.org/10.1021/acs.inorgchem.7b01870.

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21

Yang, Wei, Yiyu Yang, Yuntao Qiu, Xiaosong Cao, Zhongyan Huang, Shaolong Gong, and Chuluo Yang. "AIE-active multicolor tunable luminogens: simultaneous mechanochromism and acidochromism with high contrast beyond 100 nm." Materials Chemistry Frontiers 4, no. 7 (2020): 2047–53. http://dx.doi.org/10.1039/d0qm00247j.

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22

Chen, Zhao, Lan Yang, Yuxuan Hu, Di Wu, Jun Yin, Guang-Ao Yu, and Sheng Hua Liu. "Carbazole-based gold(i) complexes with alkyl chains of different lengths: tunable solid-state fluorescence, aggregation-induced emission (AIE), and reversible mechanochromism characteristics." RSC Advances 5, no. 114 (2015): 93757–64. http://dx.doi.org/10.1039/c5ra19378h.

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23

Chen, Zhao, Yuting Nie, and Sheng Hua Liu. "Fluorene-based mononuclear gold(i) complexes: the effect of alkyl chain, aggregation-induced emission (AIE) and mechanochromism characteristics." RSC Advances 6, no. 77 (2016): 73933–38. http://dx.doi.org/10.1039/c6ra17806e.

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24

Seki, Tomohiro, Kentaro Ida, and Hajime Ito. "A meta-diisocyanide benzene-based aryl gold isocyanide complex exhibiting multiple solid-state molecular arrangements and luminescent mechanochromism." Materials Chemistry Frontiers 2, no. 6 (2018): 1195–200. http://dx.doi.org/10.1039/c8qm00074c.

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25

Ruiz de Luzuriaga, Alaitz, Jon M. Matxain, Fernando Ruipérez, Roberto Martin, José M. Asua, Germán Cabañero, and Ibon Odriozola. "Transient mechanochromism in epoxy vitrimer composites containing aromatic disulfide crosslinks." Journal of Materials Chemistry C 4, no. 26 (2016): 6220–23. http://dx.doi.org/10.1039/c6tc02383e.

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26

Han, Ting, Xinggui Gu, Jacky W. Y. Lam, Anakin C. S. Leung, Ryan T. K. Kwok, Tianyu Han, Bin Tong, Jianbing Shi, Yuping Dong, and Ben Zhong Tang. "Diaminomaleonitrile-based Schiff bases: aggregation-enhanced emission, red fluorescence, mechanochromism and bioimaging applications." Journal of Materials Chemistry C 4, no. 44 (2016): 10430–34. http://dx.doi.org/10.1039/c6tc03883b.

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27

Zhang, Huan, Dezhi Zeng, Yifei Pan, Yinjun Chen, Yonghong Ruan, Yuanze Xu, Roman Boulatov, Costantino Creton, and Wengui Weng. "Mechanochromism and optical remodeling of multi-network elastomers containing anthracene dimers." Chemical Science 10, no. 36 (2019): 8367–73. http://dx.doi.org/10.1039/c9sc02580d.

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28

Chen, Xing-Wei, Li-Hua He, Peng Ju, Jing-Lin Chen, Sui-Jun Liu, and He-Rui Wen. "Mechanochromic luminescent materials of bimetallic Cu(i) complexes showing thermally activated delayed fluorescence." Journal of Materials Chemistry C 8, no. 45 (2020): 16160–67. http://dx.doi.org/10.1039/d0tc04607h.

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29

Sudhakar, Pagidi, Kalluvettukuzhy K. Neena, and Pakkirisamy Thilagar. "H-Bond assisted mechanoluminescence of borylated aryl amines: tunable emission and polymorphism." Journal of Materials Chemistry C 5, no. 26 (2017): 6537–46. http://dx.doi.org/10.1039/c7tc01676j.

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30

Chen, Zhao, Jing Zhang, Min Song, Jun Yin, Guang-Ao Yu, and Sheng Hua Liu. "A novel fluorene-based aggregation-induced emission (AIE)-active gold(i) complex with crystallization-induced emission enhancement (CIEE) and reversible mechanochromism characteristics." Chemical Communications 51, no. 2 (2015): 326–29. http://dx.doi.org/10.1039/c4cc08087d.

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31

Divya, Thekke Thattariyil, Kalluruttimmal Ramshad, Velluvakandi Chaluvalappil Saheer, and Lakshmi Chakkumkumarath. "Self-reversible mechanochromism and aggregation induced emission in neutral triarylmethanes and their application in water sensing." New Journal of Chemistry 42, no. 24 (2018): 20227–38. http://dx.doi.org/10.1039/c8nj04479a.

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32

Jiang, Yuqing, Jiaqiang Wang, Guangxi Huang, Zhen Li, Bing Shi Li, and Ben Zhong Tang. "Insight from the old: mechanochromism and mechanoluminescence of two amine-containing tetraphenylethylene isomers." Journal of Materials Chemistry C 7, no. 38 (2019): 11790–96. http://dx.doi.org/10.1039/c9tc04140k.

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33

Feng, Xin, Yating Chen, Yunxiang Lei, Yunbing Zhou, Wenxia Gao, Miaochang Liu, Xiaobo Huang, and Huayue Wu. "Multifunctional properties of a star-shaped triphenylamine-benzene-1,3,5-tricarbohydrazide fluorescent molecule containing multiple flexible chains." Chemical Communications 56, no. 88 (2020): 13638–41. http://dx.doi.org/10.1039/d0cc05538g.

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A star-shaped triphenylamine-benzene-1,3,5-tricarbohydrazide molecule containing multiple flexible hydrazide chains displays solvatochromism, gelation, aggregation-induced emission, polymorphism, and mechanochromism.
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34

Zhao, Kai-Yue, Hui-Ting Mao, Li-Li Wen, Guo-Gang Shan, Qiang Fu, Hai-Zhu Sun, and Zhong-Min Su. "A simple strategy to achieve remarkable mechanochromism of cationic Ir(iii) phosphors through subtle ligand modification." Journal of Materials Chemistry C 6, no. 43 (2018): 11686–93. http://dx.doi.org/10.1039/c8tc03696a.

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35

Miyagi, K., and Y. Teramoto. "Exploration of immobilization conditions of cellulosic lyotropic liquid crystals in monomeric solvents by in situ polymerization and achievement of dual mechanochromism at room temperature." RSC Advances 8, no. 44 (2018): 24724–30. http://dx.doi.org/10.1039/c8ra04878a.

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36

Ishizuki, Kuniaki, Hironori Oka, Daisuke Aoki, Raita Goseki, and Hideyuki Otsuka. "Mechanochromic Polymers That Turn Green Upon the Dissociation of Diarylbibenzothiophenonyl: The Missing Piece toward Rainbow Mechanochromism." Chemistry - A European Journal 24, no. 13 (February 5, 2018): 3170–73. http://dx.doi.org/10.1002/chem.201800194.

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37

De, Joydip, Abdul Haseeb M. M., Rohit Ashok Kumar Yadav, Santosh Prasad Gupta, Indu Bala, Prateek Chawla, Kiran Kishore Kesavan, Jwo-Huei Jou, and Santanu Kumar Pal. "AIE-active mechanoluminescent discotic liquid crystals for applications in OLEDs and bio-imaging." Chemical Communications 56, no. 91 (2020): 14279–82. http://dx.doi.org/10.1039/d0cc05813k.

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38

Sinha, Sanghamitra, Bijit Chowdhury, Uttam Kumar Ghorai, and Pradyut Ghosh. "Multitasking behaviour of a small organic compound: solid state bright white-light emission, mechanochromism and ratiometric sensing of Al(iii) and pyrophosphate." Chemical Communications 55, no. 35 (2019): 5127–30. http://dx.doi.org/10.1039/c8cc10258a.

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39

Hsu, Ying-Feng, Ssu-Ying Chen, Subhendu Maity, Yi-Hung Liu, Shie-Ming Peng, and Jye-Shane Yang. "A polymorphic pentiptycene-containing gold(i) isocyanide complex: solvent- and conformation-dependent supramolecular luminescence." Dalton Transactions 49, no. 44 (2020): 15602–6. http://dx.doi.org/10.1039/d0dt03105d.

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A pentiptycene-containing Au(i) complex reveals the supramolecular factors behind the luminescence and displays solvent-dependent aggregation-induced emission and luminescence vapochromism and mechanochromism.
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40

Hogan, David T., Benjamin S. Gelfand, Denis M. Spasyuk, and Todd C. Sutherland. "Subtle substitution controls the rainbow chromatic behaviour of multi-stimuli responsive core-expanded pyrenes." Materials Chemistry Frontiers 4, no. 1 (2020): 268–76. http://dx.doi.org/10.1039/c9qm00710e.

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Core-expanded pyrenes exhibit rainbow solvatochromism, reversible acidochromism in both solution and solid-state, and reversible crystal-to-crystal mechanochromism all governed by substitution pattern.
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41

Zhang, De-Xiang, Hai-Xia Zhang, Tian Wen, Dong-Sheng Li, and Jian Zhang. "Mechanochromic Cu(i) boron imidazolate frameworks with low-dimensional structures and reducing function." Inorganic Chemistry Frontiers 3, no. 2 (2016): 263–67. http://dx.doi.org/10.1039/c5qi00155b.

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42

Yu, Hai-Xia, Junge Zhi, Tianjiao Shen, Weilu Ding, Xiaoling Zhang, and Jin-Liang Wang. "Donor–acceptor type aggregation-induced emission luminophores based on the 1,1-dicyanomethylene-3-indanone unit for bridge-dependent reversible mechanochromism and light-up biosensing of hypochlorites." Journal of Materials Chemistry C 7, no. 29 (2019): 8888–97. http://dx.doi.org/10.1039/c9tc01772k.

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43

Jiang, Meijuan, Xinggui Gu, Ryan T. K. Kwok, Ying Li, Herman H. Y. Sung, Xiaoyan Zheng, Yilin Zhang, et al. "Mechanochromism: Multifunctional AIEgens: Ready Synthesis, Tunable Emission, Mechanochromism, Mitochondrial, and Bacterial Imaging (Adv. Funct. Mater. 1/2018)." Advanced Functional Materials 28, no. 1 (January 2018): 1870006. http://dx.doi.org/10.1002/adfm.201870006.

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44

Chen, Zhao, Jinhua Liang, Yuting Nie, Xuqingfeng Xu, Guang-Ao Yu, Jun Yin, and Sheng Hua Liu. "A novel carbazole-based gold(i) complex with interesting solid-state, multistimuli-responsive characteristics." Dalton Transactions 44, no. 40 (2015): 17473–77. http://dx.doi.org/10.1039/c5dt02035b.

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A novel carbazole-based gold(ι) complex is reported. The luminogen exhibits significative solid-state reversible mechanochromism, dual-responsive thermochromism and sensitive thin-film vapochromism properties.
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45

Hu, Huan, Zhiyong Ma, and Xinru Jia. "Reaction Cascades in Polymer Mechanochemistry." Materials Chemistry Frontiers 4, no. 11 (2020): 3115–29. http://dx.doi.org/10.1039/d0qm00435a.

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This review categorizes the reported reaction cascades in polymer mechanochemistry into five parts, including mechanocatalysis, cargo-releasing, self-strengthening, gating, and mechanochromism. Some outlook is also provided.
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46

Yang, Xinzhe, Qian Wang, Peiyu Hu, Chao Xu, Wenjing Guo, Zhi Wang, Zhu Mao, et al. "Achieving remarkable and reversible mechanochromism from a bright ionic AIEgen with high specificity for mitochondrial imaging and secondary aggregation emission enhancement for long-term tracking of tumors." Materials Chemistry Frontiers 4, no. 3 (2020): 941–49. http://dx.doi.org/10.1039/c9qm00744j.

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47

Yang, Jie, Qingxun Guo, Xiaodong Wen, Xuming Gao, Qian Peng, Qianqian Li, Dongge Ma, and Zhen Li. "Pyrene-based blue AIEgens: tunable intramolecular conjugation, good hole mobility and reversible mechanochromism." Journal of Materials Chemistry C 4, no. 36 (2016): 8506–13. http://dx.doi.org/10.1039/c6tc02533a.

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Six blue AIEgens were designed by combining the TPE core and pyrene side groups, which exhibited multifunctional properties of good blue emitters, high hole mobility and reversible mechanochromism property.
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48

Seki, Tomohiro, Koh Kobayashi, Takaki Mashimo, and Hajime Ito. "Correction: A gold isocyanide complex with a pendant carboxy group: orthogonal molecular arrangements and hypsochromically shifted luminescent mechanochromism." Chemical Communications 54, no. 93 (2018): 13160. http://dx.doi.org/10.1039/c8cc90488j.

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Correction for ‘A gold isocyanide complex with a pendant carboxy group: orthogonal molecular arrangements and hypsochromically shifted luminescent mechanochromism’ by Tomohiro Seki et al., Chem. Commun., 2018, 54, 11136–11139.
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49

Xue, Pengchong, Boqi Yao, Panpan Wang, Jiabao Sun, Zhenqi Zhang, and Ran Lu. "Response of strongly fluorescent carbazole-based benzoxazole derivatives to external force and acidic vapors." RSC Adv. 4, no. 102 (2014): 58732–39. http://dx.doi.org/10.1039/c4ra10330k.

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The nanofibers have enhanced emission and exhibited an isothermal reversible mechanochromism. Furthermore, acetic acid vapor may selectively act as stabilizer and developer to retain the information imparted by mechanical force.
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50

Jadhav, Thaksen, Bhausaheb Dhokale, Shaikh M. Mobin, and Rajneesh Misra. "Aggregation induced emission and mechanochromism in pyrenoimidazoles." Journal of Materials Chemistry C 3, no. 38 (2015): 9981–88. http://dx.doi.org/10.1039/c5tc02181b.

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Pyrene-based solid state emitters 3a and 3b were designed and synthesized by the Pd-catalyzed Suzuki cross-coupling reaction. Pyrenoimidazoles 3a and 3b exhibit strong AIE and reversible mechanochromic behavior with color contrast between blue and green.
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