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Journal articles on the topic 'Menshutkin reaction'

Author: Grafiati

Published: 11 December 2022

Last updated: 31 July 2025

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1

Alkorta, Ibon, and José Elguero. "The SN2 reaction and its relationship with the Walden inversion, the Finkelstein and Menshutkin reactions together with theoretical calculations for the Finkelstein reaction." Structural Chemistry 32, no. 5 (2021): 1755–61. http://dx.doi.org/10.1007/s11224-021-01805-y.

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AbstractThis communication gives an overview of the relationships between four reactions that although related were not always perceived as such: SN2, Walden, Finkelstein, and Menshutkin. Binary interactions (SN2 & Walden, SN2 & Menshutkin, SN2 & Finkelstein, Walden & Menshutkin, Walden & Finkelstein, Menshutkin & Finkelstein) were reported. Carbon, silicon, nitrogen, and phosphorus as central atoms and fluorides, chlorides, bromides, and iodides as lateral atoms were considered. Theoretical calculations provide Gibbs free energies that were analyzed with linear models

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2

Turan, Haydar Taylan, Sebastian Brickel, and Markus Meuwly. "Solvent Effects on the Menshutkin Reaction." Journal of Physical Chemistry B 126, no. 9 (2022): 1951–61. http://dx.doi.org/10.1021/acs.jpcb.1c09710.

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3

Castejon, Henry, and Kenneth B. Wiberg. "Solvent Effects on Methyl Transfer Reactions. 1. The Menshutkin Reaction." Journal of the American Chemical Society 121, no. 10 (1999): 2139–46. http://dx.doi.org/10.1021/ja983736t.

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4

Das, Gobinda, Tina Skorjanc, Thirumurugan Prakasam, Selbi Nuryyeva, John-Carl Olsen, and Ali Trabolsi. "Microwave-assisted synthesis of a viologen-based covalent organic polymer with redox-tunable polarity for dye adsorption." RSC Advances 7, no. 6 (2017): 3594–98. http://dx.doi.org/10.1039/c6ra26332a.

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5

Ohligschläger, A., and M. A. Liauw. "Intricate kinetics: in situ FTIR-spectroscopy discloses a phase change during ionic liquid synthesis." Physical Chemistry Chemical Physics 19, no. 27 (2017): 18018–22. http://dx.doi.org/10.1039/c7cp03257a.

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6

Sola, Miquel, Agusti Lledos, Miquel Duran, Juan Bertran, and Jose Luis M. Abboud. "Analysis of solvent effects on the Menshutkin reaction." Journal of the American Chemical Society 113, no. 8 (1991): 2873–79. http://dx.doi.org/10.1021/ja00008a013.

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7

Halls, Mathew D., and H. Bernhard Schlegel. "Chemistry Inside Carbon Nanotubes: the Menshutkin SN2 Reaction." Journal of Physical Chemistry B 106, no. 8 (2002): 1921–25. http://dx.doi.org/10.1021/jp0137165.

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8

Kanemaru, K., Y. Watanabe, N. Yoshida, and H. Nakano. "Application of the reference interaction site model self-consistent field method based on the Dirac-Hartree–Fock wave function to a chemical reaction." IOP Conference Series: Materials Science and Engineering 1280, no. 1 (2023): 012002. http://dx.doi.org/10.1088/1757-899x/1280/1/012002.

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Abstract The reference interaction site model self-consistent field (RISM-SCF) method is a combined method of the electronic structure theory of molecules and the integral equation theory of molecular liquids. The RISM-SCF method based on the Dirac-Hartree-Fock wave function, recently proposed, is applied to a chemical reaction, specifically, a Menshutkin reaction in aqueous solution. The Helmholtz energy profile along the reaction coordinate is calculated and the characteristics of the reaction are discussed based on energy component analysis.

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9

Jung, Jiyoon, Young Sang Park, Gwan Hyun Choi, et al. "Alkaline-Stable, In Situ Menshutkin Coat and Curable Ammonium Network: Ion-Solvating Membranes for Anion Exchange Membrane Water Electrolyzers." International Journal of Energy Research 2023 (September 30, 2023): 1–12. http://dx.doi.org/10.1155/2023/7416537.

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Anion exchange membranes fabricated through a one-step Menshutkin reaction with down-selected multifunctional alkyl halides and multifunctional tertiary amines within an ion-solvating matrix, poly(ethylene-co-vinyl alcohol), yielded alkaline-stable ammonium network polymers. Due to the vast simplicity in fabrication due to the quaternization/Menshutkin reaction between tertiary amine and alkyl bromides, which does not evolve any by-products that require purification, alkaline-stable membranes were fabricated in one step through facile mixing and curing of alkaline-stable ammonium network formi

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10

Hou, Shengtai, Minshan Meng, Dandan Liu, and Pengfei Zhang. "Mechanochemical Process to Construct Porous Ionic Polymers by Menshutkin Reaction." ChemSusChem 14, no. 15 (2021): 3059–63. http://dx.doi.org/10.1002/cssc.202101093.

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11

Maran, Uko, Tapani A. Pakkanen, and Mati Karelson. "Semiempirical study of the solvent effect on the Menshutkin reaction." Journal of the Chemical Society, Perkin Transactions 2, no. 12 (1994): 2445. http://dx.doi.org/10.1039/p29940002445.

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12

Maran, Uko, Mati Karelson, and Tapani A. Pakkanen. "A gas phase ab initio study of the Menshutkin reaction." Journal of Molecular Structure: THEOCHEM 397, no. 1-3 (1997): 263–72. http://dx.doi.org/10.1016/s0166-1280(96)05029-4.

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13

Szylhabel-Godala, A., S. Madhavan, J. Rudzi?ski, M. H. O'Leary, and P. Paneth. "Nitrogen and deuterium kinetic isotope effects on the Menshutkin reaction." Journal of Physical Organic Chemistry 9, no. 1 (1996): 35–40. http://dx.doi.org/10.1002/(sici)1099-1395(199601)9:1<35::aid-poc753>3.0.co;2-y.

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14

Gawlita, E., A. Szylhabel-Godala, and P. Paneth. "Kinetic isotope effects on the Menshutkin reaction: Theory versus experiment." Journal of Physical Organic Chemistry 9, no. 1 (1996): 41–49. http://dx.doi.org/10.1002/(sici)1099-1395(199601)9:1<41::aid-poc754>3.0.co;2-5.

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15

Malkanduev, Yusuf A., Madina B. Begieva, Aneta A. Kokoeva, and Аblulakhat T. Dzhalilov. "Self-Voluntary Polymerization with Formation of Quaternary Ammonium Groups." Key Engineering Materials 899 (September 8, 2021): 253–61. http://dx.doi.org/10.4028/www.scientific.net/kem.899.253.

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The reaction of spontaneous polymerization in the N, N-dialkylaminoethyl methacrylate - alkyl halide system in organic solvent solutions is considered. It is shown that polymerization in the system under study begins only after the formation of quaternary ammonium salt in the reaction medium (at a concentration of about 0.2 mol/L) by the Menshutkin reaction, as a result of quaternization of the unsaturated amine with an alkyl halide. For the explanation of the aggregate of the obtained experimental data, fundamental considerations were formulated, kinetic schemes were developed, and the corres

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16

Spooner, Jacob, and Noham Weinberg. "A comparative analysis of empirical equations describing pressure dependence of equilibrium and reaction rate constants." Canadian Journal of Chemistry 95, no. 2 (2017): 149–61. http://dx.doi.org/10.1139/cjc-2016-0454.

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General properties of the empirical analytical functions used to describe the effect of pressure on rate and equilibrium constants in solution are reviewed, and the effects of experimental errors on the accuracy of activation and reaction volumes predicted by these equations are compared. When the error levels are low (1%–2%) and pressure ranges are small (0–1 kbar), all functions perform well, but when fitting data with high error or extending to higher pressures, special care must be taken to obtain reliable results. Analysis of the results from fitting the equations to simulated data, as we

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17

ABBOUD, J. L. M., R. NOTARIO, J. BERTRAN, and M. SOLA. "ChemInform Abstract: One Century of Physical Organic Chemistry: The Menshutkin Reaction." ChemInform 25, no. 50 (2010): no. http://dx.doi.org/10.1002/chin.199450300.

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18

Gao, Jiali. "A priori computation of a solvent-enhanced SN2 reaction profile in water: the Menshutkin reaction." Journal of the American Chemical Society 113, no. 20 (1991): 7796–97. http://dx.doi.org/10.1021/ja00020a070.

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19

Lewis, David E. "Early Physical Organic Chemistry: Nikolai Aleksandrovich Menshutkin (1842–1907) and Reaction Velocities." Chemistry – A European Journal 27, no. 64 (2021): 15829–41. http://dx.doi.org/10.1002/chem.202101823.

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20

Acevedo, Orlando, and William L. Jorgensen. "Exploring Solvent Effects upon the Menshutkin Reaction Using a Polarizable Force Field." Journal of Physical Chemistry B 114, no. 25 (2010): 8425–30. http://dx.doi.org/10.1021/jp100765v.

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21

Gerber, Hazel, and Paul Kohl. "Advances in Anion Exchange Membrane Fabrication through Improvements in Quaternization of the Prepolymer." ECS Meeting Abstracts MA2025-01, no. 40 (2025): 2137. https://doi.org/10.1149/ma2025-01402137mtgabs.

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Hydrogen is a promising large-scale, long-term energy storage material which can be used as an alternative fuel to oil, gas, and coal. Water electrolysis can produce hydrogen with minimal or no CO2 emissions when coupled to renewable energy sources. Water electrolysis with anion conducting polymer electrolytes has several advantages over that with conventional proton exchange membranes in terms of its materials and scalability. The development of scalable and efficient water electrolyzers is limited by the poor processability of anion exchange membranes. A post polymerization modification step

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22

Bekárek, Vojtěch, та Vojtěch Bekárek. "Effect of medium on electronic spectra of 4-dimethylamino-ω-nitrostyrenes. Effective Kirkwood-Onsager functions of medium". Collection of Czechoslovak Chemical Communications 52, № 2 (1987): 287–98. http://dx.doi.org/10.1135/cccc19870287.

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Wavenumbers of the longest-wave maxima of 1-nitro-2-(4'-dimethylaminophenyl)ethene and 2-nitro-1-(4'-dimethylaminophenyl)propene have been measured in 60 aprotic solvents. The values obtained along with the published data on the effect of medium on electronic spectra of eight other indicators (also measured in gas phase) have been used to suggest effective Kirkwood-Onsager functions for characterization of the overall polarizability of medium, inclusive of the gas phase, in the sense of the method of the product term. Applicability of these functions has been tested for evaluation of the effec

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23

Webb, Simon P., and Mark S. Gordon. "Solvation of the Menshutkin Reaction: A Rigorous Test of the Effective Fragment Method." Journal of Physical Chemistry A 103, no. 9 (1999): 1265–73. http://dx.doi.org/10.1021/jp983781n.

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24

Giacinto, Pietro, Francesco Zerbetto, Andrea Bottoni, and Matteo Calvaresi. "CNT-Confinement Effects on the Menshutkin SN2 Reaction: The Role of Nonbonded Interactions." Journal of Chemical Theory and Computation 12, no. 8 (2016): 4082–92. http://dx.doi.org/10.1021/acs.jctc.6b00260.

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25

Zheng, Weizhong, Shuangfu Wang, Fan Zhang, et al. "Understanding into interfacial properties and reactivity of COFs toward accelerating Menshutkin SN2 reaction." Chemical Engineering Science 294 (July 2024): 120106. http://dx.doi.org/10.1016/j.ces.2024.120106.

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26

Viana, C�sar A. N., Ant�nio R. T. Calado, and L�dia M. V. Pinheiro. "Pressure and solvent effects on the kinetics of a Menshutkin reaction in aliphatic alcohols." Journal of Physical Organic Chemistry 8, no. 2 (1995): 63–70. http://dx.doi.org/10.1002/poc.610080202.

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27

Cravotto, Giancarlo, Luisa Boffa, Jean-Marc Lévêque, Julien Estager, Micheline Draye, and Werner Bonrath. "A Speedy One-Pot Synthesis of Second-Generation Ionic Liquids Under Ultrasound and/or Microwave Irradiation." Australian Journal of Chemistry 60, no. 12 (2007): 946. http://dx.doi.org/10.1071/ch07309.

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The present work describes an efficient one-pot synthesis of second-generation ionic liquids (ILs), combining in one step the Menshutkin reaction and anion metathesis. Working in a closed vessel under microwaves, or better still under simultaneous ultrasound and/or microwave irradiation, in a few minutes a series of ILs with 1-methylimidazole or pyridine cores were obtained in high yields (80–97% isolated). Under conventional heating, ILs could not be prepared in one pot in acceptable times and yields, whereas our protocol, carried out with commercially available equipment, was highly effectiv

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28

Bashpa, P., P. Rajendran, and K. Bijudas. "KINETICS OF QUATERNIZATION BETWEEN N, N-DIMETHYLANILINE AND BENZYL CHLORIDE IN POLAR SOLVENTS-A REVISIT TO MENSHUTKIN REACTION." Journal of Advanced Scientific Research 12, no. 03 (2021): 89–94. http://dx.doi.org/10.55218/jasr.202112311.

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This work reports an extension of Menshutkin reaction and involves the studies on kinetics of quaternization reaction between N,N-Dimethylaniline and benzyl chloride in acetone and in other various solvents at 300 K. The progress of the reaction was followed by measuring the conductance of the product formed at regular intervals of time. The effect of [benzyl chloride] and [N,N-Dimethylaniline] on reaction rate was studied under pseudo-first order condition and the rate showed first order dependence on both [benzyl chloride] and [N,N-Dimethylaniline]. The effect of dielectric constant of the m

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29

Bušić, Valentina, Maja Molnar, Vice Tomičić, Dalia Božanović, Igor Jerković, and Dajana Gašo-Sokač. "Choline Chloride-Based Deep Eutectic Solvents as Green Effective Medium for Quaternization Reactions." Molecules 27, no. 21 (2022): 7429. http://dx.doi.org/10.3390/molecules27217429.

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The Menshutkin reaction represents the alkylation of tertiary amines by alkyl halide where the reactants are neutral and the products, quaternary ammonium salts, are two ions with opposite signs. The most commonly used organic solvents in quaternization reactions are volatile organic solvents (VOSs), namely acetone, anhydrous benzene, dry dichloromethane (DCM), dimethylformamide (DMF) and acetonitrile (ACN). The purpose of this work was to examine eutectic solvents as a “greener” alternative to conventional solvents so that quaternization reactions take place in accordance with the principles

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30

Amovilli, Claudio, Benedetta Mennucci, and Franca Maria Floris. "MCSCF Study of the SN2 Menshutkin Reaction in Aqueous Solution within the Polarizable Continuum Model." Journal of Physical Chemistry B 102, no. 16 (1998): 3023–28. http://dx.doi.org/10.1021/jp9803945.

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31

Su, Peifeng, Fuming Ying, Wei Wu, Philippe C. Hiberty, and Sason Shaik. "The Menshutkin Reaction in the Gas Phase and in Aqueous Solution: A Valence Bond Study." ChemPhysChem 8, no. 18 (2007): 2603–14. http://dx.doi.org/10.1002/cphc.200700626.

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32

Ohmiya, Kazuhiro, and Shigeki Kato. "Solution reaction path Hamiltonian based on reference interaction site model self-consistent field method: Application to Menshutkin-type reactions." Journal of Chemical Physics 119, no. 3 (2003): 1601–10. http://dx.doi.org/10.1063/1.1580803.

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33

Atlaskin, A. A., A. A. Andronova, and O. V. Kazarina. "Thermal Decomposition Characteristics of Poly((4-Vinylbenzyl) Trimethylammonium Bis (Trifluoromethanesulfonimide)) Studied by Pyrolysis-GS / MS." Key Engineering Materials 887 (May 2021): 91–97. http://dx.doi.org/10.4028/www.scientific.net/kem.887.91.

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Over the past decades, significant advances have been made in the development and research of gas separation membranes based on ionic liquids (IL) and their polymer analogs (PIL) for membrane separation of "acid gases" such as CO2 and H2S from gas mixtures. Polymers containing various amino groups are of great interest for the selective separation of acid gases from gas mixtures, since ammonia and its derivatives are used in conventional purification. In this work, we have synthesized a monomeric ionic liquid based on 4 vinylbenzyl chloride with included triethylamine by the Menshutkin reactio

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34

Lee, Seunghyun, Hyejin Lee, Tae-Hyun Yang, et al. "Quaternary Ammonium-Bearing Perfluorinated Polymers for Anion Exchange Membrane Applications." Membranes 10, no. 11 (2020): 306. http://dx.doi.org/10.3390/membranes10110306.

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Perfluorinated polymers are widely used in polymer electrolyte membranes because of their excellent ion conductivity, which are attributed to the well-defined morphologies resulting from their extremely hydrophobic main-chains and flexible hydrophilic side-chains. Perfluorinated polymers containing quaternary ammonium groups were prepared from Nafion- and Aquivion-based sulfonyl fluoride precursors by the Menshutkin reaction to give anion exchange membranes. Perfluorinated polymers tend to exhibit poor solubility in organic solvents; however, clear polymer dispersions and transparent membranes

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35

Salajkova, Sarka, Marketa Benkova, Jan Marek, et al. "Wide-Antimicrobial Spectrum of Picolinium Salts." Molecules 25, no. 9 (2020): 2254. http://dx.doi.org/10.3390/molecules25092254.

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Nosocomial infections, which greatly increase morbidity among hospitalized patients, together with growing antibiotic resistance still encourage many researchers to search for novel antimicrobial compounds. Picolinium salts with different lengths of alkyl chains (C12, C14, C16) were prepared by Menshutkin-like reaction and evaluated with respect to their biological activity, i.e., lipophilicity and critical micellar concentration. Picolinium salts with C14 and C16 side chains achieved similar or even better results when in terms of antimicrobial efficacy than benzalkoniums; notably, their fung

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36

Berg, Ulf, Michel Chanon, Roger Gallo, and Michel Rajzmann. "Transition State Structural Variations in the Menshutkin Reaction. A Computational Study of Steric and Electronic Substituent Effects." Journal of Organic Chemistry 60, no. 7 (1995): 1975–80. http://dx.doi.org/10.1021/jo00112a017.

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37

Xie, Xuqiu, Wenjing Jia, Changyuan Liu, Yongzhe Li, Anhou Xu, and Xundao Liu. "Ion-Exchange Strategy Enabling Direct Reformation of Unreliable Perfluorinated Cationic Polymer for Robust Proton Exchange Membrane towards Hydrogen Fuel Cells." Energies 17, no. 12 (2024): 2954. http://dx.doi.org/10.3390/en17122954.

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Perfluorosulfonated anionic ionomers are known for their robust ion conductivity and chemical and mechanical stability. However, the structure and transport property degradation of perfluorinated cationic polymers (PfCPs) are not well understood. Herein, we propose an ion-exchange strategy to identify the structural degradation, ion transport mechanisms, and architectural reformation of PfCPs. Particularly, we demonstrate that the utility of a –SO2–N+ strategy employing the Menshutkin reaction cannot yield reliable PfCPs and anion-exchange membranes, but can yield an unreliable zwitterionic in

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38

Pfrunder, Michael C., Aaron S. Micallef, Llewellyn Rintoul, Dennis P. Arnold, Karl J. P. Davy, and John McMurtrie. "Exploitation of the Menshutkin Reaction for the Controlled Assembly of Halogen Bonded Architectures Incorporating 1,2-Diiodotetrafluorobenzene and 1,3,5-Triiodotrifluorobenzene." Crystal Growth & Design 12, no. 2 (2012): 714–24. http://dx.doi.org/10.1021/cg201017r.

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39

Poater, Jordi, Miquel Solà, Miquel Duran, and Xavier Fradera. "Effects of Solvation on the Pairing of Electrons in a Series of Simple Molecules and in the Menshutkin Reaction." Journal of Physical Chemistry A 105, no. 25 (2001): 6249–57. http://dx.doi.org/10.1021/jp0108364.

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40

Truong, Thanh N., Thanh-Thai T. Truong, and Eugene V. Stefanovich. "A general methodology for quantum modeling of free-energy profile of reactions in solution: An application to the Menshutkin NH3+CH3Cl reaction in water." Journal of Chemical Physics 107, no. 6 (1997): 1881–89. http://dx.doi.org/10.1063/1.474538.

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41

Hirao, Hajime, Yukihiko Nagae, and Masataka Nagaoka. "Transition-state optimization by the free energy gradient method: Application to aqueous-phase Menshutkin reaction between ammonia and methyl chloride." Chemical Physics Letters 348, no. 3-4 (2001): 350–56. http://dx.doi.org/10.1016/s0009-2614(01)01131-9.

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42

Tavares, I. S., C. F. B. R. Figueiredo, and A. L. Magalhães. "The Inner Cavity of a Carbon Nanotube as a Chemical Reactor: Effect of Geometry on the Catalysis of a Menshutkin SN2 Reaction." Journal of Physical Chemistry C 121, no. 4 (2017): 2165–72. http://dx.doi.org/10.1021/acs.jpcc.6b08466.

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43

Nowacki, Andrzej, Justyna Wielińska, Dominik Walczak, Karol Sikora, Barbara Dmochowska, and Beata Liberek. "The conformational behavior, geometry and energy parameters of Menshutkin-like reaction of O-isopropylidene-protected glycofuranoid mesylates in view of DFT calculations." Journal of Molecular Graphics and Modelling 52 (July 2014): 91–102. http://dx.doi.org/10.1016/j.jmgm.2014.06.009.

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44

Saitow, Masaaki, Kazuma Uemura, and Takeshi Yanai. "A local pair-natural orbital-based complete-active space perturbation theory using orthogonal localized virtual molecular orbitals." Journal of Chemical Physics 157, no. 8 (2022): 084101. http://dx.doi.org/10.1063/5.0094777.

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The multireference second-order perturbation theory (CASPT2) is known to deliver a quantitative description of various complex electronic states. Despite its near-size-consistent nature, the applicability of the CASPT2 method to large, real-life systems is mostly hindered by large computational and storage costs for the two-external tensors, such as two-electron integrals, amplitudes, and residuum. To this end, Menezes and co-workers developed a reduced-scaling CASPT2 scheme by incorporating the local pair-natural orbital (PNO) representation of the many-body wave functions using non-orthonorm

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45

Yang, DaEun, and Hyo Kang. "Thermoresponsive Ionic Liquid with Different Cation–Anion Pairs as Draw Solutes in Forward Osmosis." Molecules 27, no. 24 (2022): 8869. http://dx.doi.org/10.3390/molecules27248869.

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We synthesized various phosphonium- and ammonium-based ionic liquids (ILs), using benzenesulfonate (BS) and 4-methylbenzenesulfonate (MBS) to establish the criteria for designing an ideal draw solute in a forward osmosis (FO) system. Additionally, the effects of monocationic, dicationic, and anionic species on FO performance were studied. Monocationic compounds ([P4444][BS], [P4444][MBS], [N4444][BS], and [N4444][MBS]) were obtained in one step via anion exchange. Dicationic compounds ([(P4444)2][BS], [(P4444)2][MBS], [(N4444)2][BS], and [(N4444)2][MBS]) were prepared in two steps via a Menshu

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46

Skorjanc, Mavrič, Sorensen, Mali, Wu, and Valant. "Cationic Covalent Organic Polymer Thin Film for Label-free Electrochemical Bacterial Cell Detection." ACS Sensors 7, no. 9 (2022): 2743–49. https://doi.org/10.1021/acssensors.2c01292.

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  Numerous species of bacteria pose a serious threat to human health and cause several million deaths annually. It is therefore essential to have quick, efficient, and easily operable methods of bacterial cell detection. Herein, we synthesize a novel cationic covalent organic polymer (COP) named <strong>CATN</strong> through the Menshutkin reaction and evaluate its potential as an impedance sensor for <em>Escherichia coli</em> cells. On account of its positive surface charge (ζ-potential = +21.0 mV) and pyridinium moieties, <strong>CATN</strong> is expected to interact favorably with

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47

Aissou, Karim, Maximilien Coronas, Jason Richard, et al. "Ion and Water Transports in Double Gyroid Nanochannels Formed by Block Copolymer Anion Exchange Membranes." Batteries 11, no. 4 (2025): 126. https://doi.org/10.3390/batteries11040126.

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Mechanically improved polymeric membranes with high ionic conductivity (IC) and good permeability are highly desired for next-generation anion exchange membranes (AEMs) in order to reduce Ohmic losses and enhance water management in alkaline membrane fuel cells. To move towards the fabrication of such high-performance membranes, the creation of hydrophilic ion-conducting double gyroid (DG) nanochannels within block copolymer (BCP) AEMs is a promising approach. However, this attractive solution remains difficult to implement due to the complexity of constructing a well-developed ion-conducting

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48

Dutta Dubey, Kshatresh, Thijs Stuyver, Surajit Kalita, and Sason Shaik. "Solvent Organization and Rate Regulation of a Menshutkin Reaction by Oriented External Electric Fields are Revealed by Combined MD and QM/MM Calculations." Journal of the American Chemical Society 142, no. 22 (2020): 9955–65. http://dx.doi.org/10.1021/jacs.9b13029.

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49

Narita, Kunihiro, Yohei Ishida, Shuichi Nukui, Zhong Huang, and Tetsu Yonezawa. "Surface Menshutkin S_N2 Reaction on Basic Gold Clusters Provides Novel Opportunities for the Cationization and Functionalization of Molecular Metal Clusters." Journal of Physical Chemistry Letters 12, no. 49 (2021): 11761–65. http://dx.doi.org/10.1021/acs.jpclett.1c03498.

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Melo, André, António J. I. Alfaia, João Carlos R. Reis, and António R. T. Calado. "Unusual Solvent Effect on a SN2 Reaction. A Quantum-Mechanical and Kinetic Study of the Menshutkin Reaction between 2-Amino-1-methylbenzimidazole and Iodomethane in the Gas Phase and in Acetonitrile." Journal of Physical Chemistry B 110, no. 4 (2006): 1877–88. http://dx.doi.org/10.1021/jp055660a.

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