Dissertations / Theses on the topic 'Mentor Graphics'
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Sari, Mehmet. "Designing fast Golay encoder/decoder in Xilinx XACT with Mentor Graphics CAD interface." Monterey, Calif. : Springfield, Va. : Naval Postgraduate School ; Available from National Technical Information Service, 1997. http://handle.dtic.mil/100.2/ADA331926.
Full textGustafsson, Kristian. "Implementation of a Digital Radio Frequency Memory in a Xilinx Virtex-4 FPGA." Thesis, Linköping University, Department of Electrical Engineering, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-5423.
Full textDigital Radio Frequency Memory (DRFM) is a technique widely used by the defense industry in, for example, electronic countermeasure equipment for generating false radar targets. The purpose of the DRFM technique is to use high-speed sampling to digitally store and recreate radio frequency and microwave signals. At Saab Bofors Dynamics AB the technique is used, among others, in the Electronic Warfare Simulator (ELSI). The DRFM technique is implemented in a full-custom ASIC circuit that has been mounted on circuit boards in ELSI. Today, the progress in the programmable hardware field has made it possible to implement the DRFM design in a Field Programmable Gate Array (FPGA). The FPGA technology has many advantages over a full custom ASIC design.
Hence, the purpose of this master's thesis has been to develop a new DRFM design that can be implemented in an FPGA, using a hardware description language called VHDL. The method for this master's thesis has been to first establish a time plan and a requirement specification. After that, a design specification has been worked out based on the requirement specification. The two specifications have served as a basis for the development of the DRFM circuit. One of the requirements on the design was that the circuit should be able to communicate through an external Ethernet interface. A part of the work has, thus, been to review available external Ethernet modules on the market. The result is a DRFM design that has been tested through simulations. The tests shows that the design works as described in the design specification.
Johansson, Jonas, and Arten Lazarian. "Klass-D Förstärkare." Thesis, Linköping University, Department of Electrical Engineering, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-8737.
Full textSyftet med högskoleavhandlingen var att konstruera en klass-D förstärkare för audio med en DDXi-2161 krets från Apogee. Förstärkaren har en digital stereoingång för I²S-format. Digitalisering av en analog audiosignal sker med codec-kretsen WM8731 från Wolfson. För att möjliggöra implementering av funktioner för digital signalbehandling av audiosignalen ingår en FPGA-krets från Altera i systemet. Gränssnitten mellan codec-kretsen och FPGA:n samt FPGA:n och klass-D förstärkaren är beskrivna med VHDL och implementerade i FPGA:n. Klass-D förstärkaren har byggts upp på ett två-lagers mönsterkort. Ett utvecklingskort från ALTERA (DE2) med codec-krets och FPGA har använts. Resultaten visar goda möjligheter att konstruera en klass-D förstärkare med bra ljud och låg effektförbrukning.
Nilsson, Jesper. "Mixed RTL and gate-level power estimation with low power design iteration." Thesis, Linköping University, Department of Electrical Engineering, 2003. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-1685.
Full textIn the last three decades we have witnessed a remarkable development in the area of integrated circuits. From small logic devices containing some hundred transistors to modern processors containing several tens of million transistors. However, power consumption has become a real problem and may very well be the limiting factor of future development. Designing for low power is therefore increasingly important. To accomplice an efficient low power design, accurate power estimation at early design stage is essential. The aim of this thesis was to set up a power estimation flow to estimate the power consumption at early design stage. The developed flow spans over both RTL- and gate-level incorporating Mentor Graphics Modelsim (RTL-level simulator), Cadence PKS (gate- level synthesizer) and own developed power estimation tools. The power consumption is calculated based on gate-level physical information and RTL- level toggle information. To achieve high estimation accuracy, real node annotations is used together with an own developed on-chip wire model to estimate node voltage swing.
Since the power estimation may be very time consuming, the flow also includes support for low power design iteration. This gives efficient power estimation speedup when concentrating on smaller sub- parts of the design.
Stephenson, J. R., of Western Sydney Nepean University, and Faculty of Education. "Acquisition of graphic symbol use by students with severe intellectual disability." THESIS_FE_XXX_Stephenson_J.xml, 1996. http://handle.uws.edu.au:8081/1959.7/180.
Full textDoctor of Philosophy (PhD)
Pairoj-Boriboon, Tanruk. "Escapism: Indulging in Daydreams." VCU Scholars Compass, 2018. https://scholarscompass.vcu.edu/etd/5463.
Full textFoshay, John D. "Knowledge acquisition from video, video with animated graphics, and laboratory experience predictors for adolescents with mild mental impairments /." Morgantown, W. Va. : [West Virginia University Libraries], 2000. http://etd.wvu.edu/templates/showETD.cfm?recnum=1332.
Full textTitle from document title page. Document formatted into pages; contains vi, 98 p. Includes abstract. Includes bibliographical references (p. 75-82).
Chien, Shu-chen. "The effectiveness of animated and interactive microcomputer graphics on children's development of spatial visualization ability/mental rotation skills /." The Ohio State University, 1986. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487265555441953.
Full textSmith, Alastair David. "Drawing and cognition : on the role of mental imagery and spatial coding in graphic production." Thesis, University of Bristol, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.268787.
Full textObembe, Olufunmilayo. "Development of a probabilistic graphical structure from a model of mental health clinical expertise." Thesis, Aston University, 2013. http://publications.aston.ac.uk/19432/.
Full textAzaiez, Ilhem. "Picturalité et logique numérique : entre mental et matériel." Thesis, Paris 1, 2016. http://www.theses.fr/2016PA01H322.
Full textThe integration of digital technologies within my artistic practice previously included in a pictorial tradition of acrylic painting on canvas aims to expand the scope of this picturial practice by using methods of photography on computer-based image editing. Opting for a pictorial work with digital tools makes progress towards an hybrid image between photo and painting. Such work can then juxtapose genres and identifiable techniques : photography and digital painting. Thus through these fifferent mediums, I am questionning painting between the materiality of the tradition and the art from one hand and the more conceptual aspect of the digital image from the other hand. Painting and photography are now benefiting from new advantages gained from digital technologies. Thse new technologies create new actions as well as new arrangements for the plastic creation. A new image is appearing at the intersection of several orientations : mental and material, visible and invisible. Therefore the choice of computers to renew the pictorial practice and rethink creation has undoubtedly revealed richer opportunities than expected
Karlsson, Linus. "Optimering av sampling quality-parametrar för Mental Ray." Thesis, Högskolan i Gävle, Avdelningen för Industriell utveckling, IT och Samhällsbyggnad, 2011. http://urn.kb.se/resolve?urn=urn:nbn:se:hig:diva-10099.
Full textCullen, Carley Nicole. "Empathy + entropy." Thesis, University of Iowa, 2019. https://ir.uiowa.edu/etd/6721.
Full textRamos, Fernando da Silva. "Geometria e habilidade de rotação mental : uma experiência de ensino com transformações isométricas no design." [s.n.], 2012. http://repositorio.unicamp.br/jspui/handle/REPOSIP/284414.
Full textTese (doutorado) - Universidade Estadual de Campinas, Instituto de Artes
Made available in DSpace on 2018-08-20T10:22:35Z (GMT). No. of bitstreams: 1 Ramos_FernandodaSilva_D.pdf: 108739451 bytes, checksum: 0fe74bf691675512a3ed531df19ecf3b (MD5) Previous issue date: 2012
Resumo: A geometria tem sido, ao longo da história, disciplina prescritiva de uma extensa série de atividades cientificas e artísticas, e modernamente, sabe se que é fundamento para diversas profissões como arquitetura, design, engenharias, química, física, geologia, astronomia, etc. Apesar da importância reconhecida, seu ensino regular ao longo da vida acadêmica do indivíduo tem passado por muitas transformações (nem sempre para melhor) desde a segunda metade do século XX, e é hoje, assunto complexo e controverso no Brasil e no mundo. Entretanto, parece consensual entre os pesquisadores que a capacidade de visualização - que para a Psicologia Cognitiva, está categorizada entre as habilidades espaciais do indivíduo - pode ser positivamente afetada através do treinamento adequado em geometria. Tal vocação é muitas vezes descrita como seu maior potencial e principal justificativa para seu ensino sistemático. Esta pesquisa descreve um experimento que envolveu um grupo de sessenta alunos de um curso de bacharelado em design, onde procurou se compreender o impacto causado sobre sua capacidade cognitiva de rotação mental, a partir da administração de uma série de conceitos e exercícios relacionados ao tópico das Transformações Isométricas. Os estudantes foram divididos em duas turmas, e receberam instruções distintas em relação ao uso dos meios expressivos. A primeira turma exercitou se utilizando exclusivamente recursos bidimensionais, enquanto a segunda o fez incluindo exercícios com manipulativos físicos tridimensionais. Os desempenhos cognitivo e conceitual foram avaliados através de dois testes respectivamente: O MRT (mental rotation test) e TS (teste de simetria), e os dados analisados estatisticamente. A pesquisa procura assim, evidências que contribuam no sentido de esclarecer algumas das relações possíveis entre tópicos em geometria, cognição e método pedagógico
Abstract: Along history, geometry has been the prescriptive discipline of a large range of scientific and artistic activities. It is known to be the base of several professions such as architecture, design, engineering, chemicals, physics, geology, astronomy, etc. In spite of its acknowledged importance, its regular teaching throughout an individual's academic life has gone through many changes (not always for better) since the second half of the 20th century and it is nowadays a complex and controvert subject in Brazil and worldwide. Nevertheless, researchers seem to agree that the ability of visualizing - which is classified among the individual's spatial skills from the Cognitive Psychology standpoint - might be positively affected by means of appropriate training in geometry. Many times such vocation is described as a major potential and main justification for its systematic teaching. This research outlines an experiment which involved a group of sixty pupils of a design bachelor's program and aims at trying to understand the impact caused on their mental rotation cognitive ability as from the administration of a range of concepts and exercises related to Isometric Transformations. The students were set out into two groups and received different instructions regarding the use of means of expression. The first group performed exercises using uniquely bidimensional resources, while the second group's exercises included as well activities containing 3D physical manipulatives. The cognitive and conceptual performances were evaluated by two tests, respectively, MRT (mental rotation test) and TS (Symmetry Test), and all data were statistically analyzed. This study, thus, seeks for evidences that may contribute to clarify some of the possible relationships between topics in geometry, cognition, and the pedagogical method
Doutorado
Artes Visuais
Doutor em Artes
Morris, Timothy Jewlon. "The Effect of Verbal and Graphic Feedback on Direct Care Trainers' Data-Tecording Behavior." Thesis, University of North Texas, 1994. https://digital.library.unt.edu/ark:/67531/metadc500981/.
Full textValle, Raoni Bernardo Maranhão. "Mentes graníticas e mentes areníticas: fronteira geo-cognitiva nas gravuras rupestres do baixo Rio Negro, Amazônia Setentrional." Universidade de São Paulo, 2012. http://www.teses.usp.br/teses/disponiveis/71/71131/tde-12042013-163726/.
Full textThis research presents a preliminary study about the petroglyphs from a sample area between Old Ayrão village and Branco river\'s mouth, at the lower Negro river basin, Western Brazilian Amazon. They comprise a corpus of open air and underwater Rock Art sites, fifteen (15) up until now, located on sandstone and granite riverine boulders and outcrops. Given the absence of archaeological stratified deposits, these sites can neither be excavated nor unequivocally related to adjacent ceramic sites in the survey area (which remains a possibility to be tested). Thus, they are bound in contextual isolation, lacking spatial as well as chronological control, remaining as outsiders of the archaeological record. The area presents geological variability (contact between crystalline Guiana shield and Amazon sedimentary basin) as well as hydrographical variability (confluence among Negro, Branco, Jauaperi, Unini and Jaú rivers). We propose that this environmental set contributes to the graphical variability we are detecting inside the rock art corpus (suggesting discrete corpora), which indicates possible chronological and cultural distinctions in the prehistoric authorship of these petroglyphs. Indeed, the preliminary knowledge of the actual geological context of the survey area, as well as its major fluvial confluence, has led us to first postulate the hypothesis of stylistic variability which was confirmed in the first contact with these petroglyphs. This, in fact, constitutes the first concrete result of our research, the identification of a multi-stylistic rock art zone in the Negro\'s basin, which we think is deeply related to the environmental set of the survey area, which in its turn was partially responsible for the establishment of different cultural groups, and the development of different cultural ways of representing the cognizable world (visible and invisible) into discrete strategies of visual thinking on the basin along the Holocene. Among the current approaches to rock art study we have chosen to apply two different but complementary general methods, Formal and Informed, as a dialectical reflexive conjunct. The first part of the text is committed to the formal method. Under this token, we are considering the petroglyphs (and pictographs) like prehistoric systems of visual thinking and communication, quasi-linguistically organized graphic-symbolic codes, of the authors\' communities. Focus on rock art under this scope (as a variable, or resultant, of human past behavior, culturally organized, inserted in the environment - archaeological record) is a profitable strategy in order to identify and measure formal material characteristics of rock art assemblages, which, we believe, can lead to the identification of discrete sets of structured graphical patterns that, hypothetically and simplistically, could be related to the socialcognitive profiles of those communities. So, we are applying a set of theoretical constructs, basically derived from semiotics, visual anthropology and cognitive archaeology, to the analysis of visual symbolic codes, holding our attention on the graphic signifier (the material object) and avoiding the interpretation of specific meanings over the form (guessing signified concepts deriving from iconic resemblances between forms and \"real things\" in the non- Indian archaeologist\'s cosmology). By material signifier in rock art we comprehend those material aspects such like technique, morphology, thematic, syntactical combinations and compositions, taphonomy and other geo-environmental variables. The second approach, informed method, is devoted here to a tentative interpretation of one of the stylistic profiles identified; comparing some of its distinctive iconic patterns to the Upper Negro River Myth- Ritual Complex of Jurupari, devised as a multi-ethnic religious complex that hypothetically pervaded the entire basin during pre-colonial times. We are suggesting by the present evidence that these cultural manifestations (Jurupari and this specific rock art corpus), separated in time-space, could be related to a same system of expressive, ideological and cognitive phenomena in the past, with a specific locational insertion in the surveyed area. So, if identifying forms (formal disambiguation), and classification (ordering of graphic-spatial patterns) of observed differences among forms are converted into the spinal cord of this research, the second part is, nevertheless, equally important in the way it provides a rudimentary tentative of looking to rock art through Amerindian eyes and test the potential of ethnographic meta-representations to illuminate archaeological reasoning about rock art phenomena in the Negro\'s basin. That is, an interpretive approach targeting some sort of explanation beyond the non-indigenous formal stylistic constructs (but, what remains to be tested in the area is the rock art analysis directly through Amerindian prefrontal cortex, a kind of neural-cognitive otherness experiential approach, which would imply, for future experiments, in direct participative observations, possibly involving an Indian specialist and archaeologist\'s Caapi - B. caapi - consumption for perceptual and ontological purification and subsequent observation of petroglyphs and dialogue among them and the rocks).
Key, Matthew. "EnVRMent: Investigating Experience in a Virtual User-Composed Environment." DigitalCommons@CalPoly, 2020. https://digitalcommons.calpoly.edu/theses/2235.
Full textVorster, Lize. "Shared mental models as a cultural phenomenon : fact or fiction? Using the card-sorting method to investigate the shared mental models of web users." Thesis, Stellenbosch : University of Stellenbosch, 2006. http://hdl.handle.net/10019.1/1049.
Full textENGLISH ABSTRACT: In this study, the mental models of the target audience of the FACT web site (official Stellenbosch University HIV/Aids web site) were investigated and compared with the structure of the web site (representing the mental model of the expert). The target audience were divided into six groups representing three different race groups (white, coloured and black) and the two sexes (male and female).
Trethewey, Sally Olin. "Effects of computer based two and three dimensional visualization training for male and female engineering graphics students with low, middle, and high levels of visualization skill as measured by mental rotation and hidden figures tasks." Connect to resource, 1990. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1228748592.
Full textMelin, Matilda. "Hur visuellt material används för att påverka känslor och upplevelser i stunden : En analys av nio Instagraminlägg på temat välmående." Thesis, Malmö universitet, Institutionen för konst, kultur och kommunikation (K3), 2021. http://urn.kb.se/resolve?urn=urn:nbn:se:mau:diva-43958.
Full textBétrancourt, Mireille. "Facteurs spaciaux et temporels dans le traitement cognitif des complexes texte-figure." Grenoble INPG, 1996. http://www.theses.fr/1996INPG0132.
Full textKoehler, Karen E. "Examining the Conceptual Understandings of Geoscience Concepts of Students with Visual Impairments: Implications of 3-D Printing." The Ohio State University, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=osu1494273823844707.
Full textEllison, Cassandra J. "Recovery From Design." VCU Scholars Compass, 2017. http://scholarscompass.vcu.edu/etd/4884.
Full textSalas, Leslie. "Mirrors and Vanities." Master's thesis, University of Central Florida, 2013. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/5697.
Full textM.F.A.
Masters
English
Arts and Humanities
Creative Writing
Chao, Shih-Fann, and 趙世範. "The Empirical Study Based on Graphic Fundamentals for Mental Rotation of Spatial Dimensions." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/31558948989742032767.
Full text高雄師範大學
工業科技教育學系
100
This study adopts graphics fundamentals to extend the application of the original mental rotation theories in plane and depth axis. Mental rotation is an important instrument to measure human subjects portraying real objects rotating to different orientations, the linear relations between all variables can be found from behavior data. However, current mental rotation appears to have some problems. For example, it has to consider diverse forms of pictures, including unidentifiable perspective, unidentifiable projection way, unidentifiable axis, gray level, shadow implication, etc. There is no standardized coordinates system that is able to quantize and portray spatial orientations of graphs. Instruments of measuring human subjects’ spatial capability are made, but their spatial orientations of graphic appearances contain some unclear disputes. This study aims at combining graphic fundamentals to solve the problems addressed above. The graphic appearance of mental rotation is redrawn by graphic projection, and its rotation direction follows the spatial dimension of the coordinates system. Experiments are employed to examine the process. Data collected from each experimental are analyzed with statistic approaches. The results are presented as the following: 1. In this study, through literatures collection and analysis that based on the fundamentals of graphics, summarized eight rules, by solve problem for the image of the graphics representation of the mental rotation. 2. Combination the rules and application of computer-aided drawing of CAD tools, according to developing the mental rotation library of different spatial dimensions. 3. The experiment confirmed in a two-dimensional plane, the degree variable of mental rotation has a positive association with the reaction time, in which a linear function is significant. In a two-dimensional plane, the degree variable of mental rotation has a negative association with the accuracy rate. When rotation degrees are higher, accuracy rates are lower. This could be a crucial factor for gauging the subjects’ mental rotation ability about a plane axis. 4. The experiment confirmed in a three-dimensional plane, the degree variable of all-axis of mental rotation has a positive association with the reaction time, in which a linear function is significant. In a three-dimensional plane, the degree variable of all-axis of mental rotation has a negative association with the accuracy rates. When rotation degrees are higher, the accuracy rates are lower. This could be a crucial factor for gauging the subjects’ mental rotation ability about a depth axis. 5. In a two-dimensional plane, the dependent variables of mental rotation, including the test of gender differences in reaction time and accuracy rate, do not have significant outcomes. In a three-dimensional plane, the dependent variables of all-axis of mental rotation, including the test of gender differences in reaction time, do not have significant outcomes. 6. In a two-dimensional plane, the degree variable of all-axis of mental rotation has a positive association with the reaction time, in which a linear function is significant. 7. In all three-dimensional plane, the degree variable of all-axis of mental rotation has a positive association with the reaction time, in which a linear function is significant. Like two-dimensional plane this is consistent with the study of Shepard et al. 8. In a three-dimensional plane, the dependent variables of Y-axis of mental rotation, the test of gender differences in accuracy rates is significant: that of the boys’ is higher than that of the girls. This is different from the outcomes of other experimental steps. 9. The EEG data of event-related potentials that by analysis and comparison of quantitative, this study found that different gender during the three-dimensional plane, the degree variable of Y-axis of mental rotation operation process, the brain activation regions have lateralization of gender. Girls during the three-dimensional plane, the degree variable of Y-axis of mental rotation operation process, its main focus on the regional activation of left frontal lobe of the brain. Boys during mental rotation operation process of Y-axis, the main active region was at the brain's left parietal lobe.
Stephenson, J. R., University of Western Sydney, and Faculty of Education. "Acquisition of graphic symbol use by students with severe intellectual disability." 1996. http://handle.uws.edu.au:8081/1959.7/41689.
Full textDoctor of Philosophy (PhD)
Pleet, Lawrence Joseph. "The effects of computer graphics and mira on acquisition of transformation geometry concepts and development of mental rotation skills in grade eight /." 1990. http://hdl.handle.net/1957/9682.
Full text(6420809), Jon-Marc G. Rodriguez. "STUDENTS’ UNDERSTANDING OF MICHAELIS-MENTEN KINETICS AND ENZYME INHIBITION." Thesis, 2019.
Find full textCurrently there is a need for research that explores students’ understanding of advanced topics in order to improve teaching and learning beyond the context of introductory-level courses. This work investigates students’ reasoning about graphs used in enzyme kinetics. Using semi-structured interviews and a think aloud-protocol, 14 second-year students enrolled in a biochemistry course were provided two graphs to prompt their reasoning, a typical Michaelis-Menten graph and a Michaelis-Menten graph involving enzyme inhibition. Student responses were coded using a combination of inductive and deductive analysis, influenced by the resource-based model of cognition. Results involve a discussion regarding how students utilized mathematical resources to reason about chemical kinetics and enzyme kinetics, such as engaging in the use of symbolic/graphical forms and focusing on surface-level features of the equations/graphs. This work also addresses student conceptions of the particulate-level mechanism associated with competitive, noncompetitive, and uncompetitive enzyme inhibition. Based on the findings of this study, suggestions are made regarding the teaching and learning of enzyme kinetics.
Oosthuizen–Van, Tonder Mariska Elizabeth. "Unit managers' role in improving nursing teamwork in a mental health care facility / Mariska Elizabeth Oosthuizen–Van Tonder." Thesis, 2014. http://hdl.handle.net/10394/13404.
Full textMCur, North-West University, Potchefstroom Campus, 2014
Huang, Chiung-Yi, and 黃瓊誼. "The effects of “3D Graphic-based Virtual Reality” on the improvement of walking skills to school for elementary school students with moderate and severe mental retardation." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/94511132897312335970.
Full text國立臺北教育大學
特殊教育學系碩士班
94
The purpose of this study was to investigate the effectiveness of the “3D Graphic-based Virtual Reality” on the improvement of walking skill to school for elementary school students with moderate and severe mental retardation. Single-subject experimental design with changing criterion design was used to evaluate the effectiveness.”3D Graphic-based Virtual Reality” is an independent variable and the “walking skills to school” are dependent variables. Two students with moderate and severe mental retardation were monitored, which their grade were ranged from four to six. During this experiment, each student received individual teaching. Every teaching class consisted of an indoor desktop learning and an outdoor practice at their commute routes. The teaching continued until students became skilled, which took about four to five weeks. The students received additional three other learning reservation tests after the experiment. These were to assure their learning reservation outcome. All data were videotaped, and were analyzed by using visual inspection techniques. The effects of other observation data as well as the social validity of the interview data were also analyzed. The results of this study included: 1. After teaching, two students did improve their walking skills to school. This implied that virtual experience could be successfully transferred, and applied to real environment, and the effectiveness of “3D Graphic-based Virtual Reality〞learning was positve. 2. The commute time to school of monitored students was gradually reduced even after this experiment. This confirms the walking skill has been improved. 3. The feedback from teachers and parents of monitored students on the “3D Graphic-based Virtual Reality〞learning were positive. Instead of outdoor learning, “3D Graphic-based Virtual Reality〞learning brought students more safety, and indoor learning made them more focused. As a result, monitored students improved their walking skills. In addition to the discussions of above-mentioned results, suggestions on the teaching contents and directions of future studies of students with mental retardation were proposed in this study.
Duong, Adam. "Contrôle de l'organisation moléculaire en 2D et 3D par l’utilisation de liaisons hydrogène, de coordination métallique et d'autres interactions." Thèse, 2011. http://hdl.handle.net/1866/5324.
Full textIn recent years, molecular tectonics has been a useful strategy in the construction of new materials. It relies on the spontaneous self-assembly of molecules called tectons. These molecules have the ability to recognize themselves using various intermolecular interactions. The resulting assembly can produce molecular materials with predictable organization. This strategy requires the creation of new tectons, which are sometimes difficult to synthesize and require in most cases many synthetic steps, which prevents or limits their practical application. Moreover, once formed, the bonds joining the central core of the tecton with the groups used for molecular recognition cannot be broken, which means that it is not possible to recycle or reform the tecton by simple synthetic procedures. To avoid these obstacles, we propose to use a hybrid strategy that uses metal coordination to build the central core of the tecton, combined with the use of weaker interactions to control the association. We call such entities metallotectons due to the presence of metal. To explore this strategy, we constructed a series of ditopic ligands containing either pyridine, bipyridine or phenanthroline to promote metal coordination, substituted with diaminotriazinyl groups (DAT) to allow inter-complex association by the formation of hydrogen bonds. In addition to the possibility of creating metallotectons by coordination, these ditopic ligands have an intrinsic interest in supramolecular chemistry as entities that can associate in 3D and 2D. In parallel to our study of coordination chemistry, we examined the association of ligands by X-ray diffraction (XRD) and scanning tunneling microscopy (STM). The adsorption of these molecules on the graphite surface at the liquid-solid interface results in the formation of different networks through a process of 2D nanopatterning. To understand the details of iv molecular adsorption, we systematically compared the 2D organization observed STM with the 3D structures determined by XRD. We also simulated the adsorption by theoretical calculations. This integrated approach is essential to characterize the molecular organization in 2D and to understand the origin of the observed preferences. These studies of the ligands themselves may therefore serve as a reference when we study the association of metallotectons derived by ligands coordination. Our work demonstrates that the strategy combining coordination chemistry and molecular recognition is a rapid and an efficient method to create supramolecular networks. We verified that the strategy of molecular tectonics is also effective in leading the organization in 3D and 2D, which often shows a significant homology. We found that our heterocyclic ligands have unexpected ability to adsorb strongly on the graphite surface, creating networks organize in nanoscale. Together, these results provide promising applications in several fields, including heterogeneous catalysis and nanotechnology. Keywords : molecular tectonics, intermolecular interactions, hybrid strategy, metal coordination, X-ray diffraction, scanning tunneling microscopy, graphite, nanopatterning phenomenon, theoretical calculations, hydrogen bonds, supramolecular chemistry, ligands, DAT groups, heterogeneous catalysis, nanotechnology.