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Journal articles on the topic 'Mercure – Solubilité'

Author: Grafiati

Published: 4 June 2021

Last updated: 3 February 2022

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1

Staun, Chris, Neetu Bansal, and James Vaughan. "Electrocrystallization and solubility of mercury in alkaline solution." Canadian Journal of Chemistry 96, no. 4 (2018): 385–93. http://dx.doi.org/10.1139/cjc-2017-0592.

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The chemical thermodynamics of mercury in aqueous sodium hydroxide solution has been investigated through electrochemical polarisation and solubility experiments. A review of thermodynamic data allowed determination of the Hg/HgO electrode potential. Cyclic voltammetry revealed a complex anodic reaction beginning with aqueous dissolution of elemental mercury and subsequent electrocrystallization of mercuric oxide. Cathodic sweeps showed dual reduction reactions, attributed to the presence of aqueous mercury and mercuric oxide. The solubility and hence activity of elemental mercury in sodium hy

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2

Castetbon, A., M. Corralès, M. Potin-Gauthier, and M. Astruc. "Etude cinétique de la complexation du cuivre en milieu hydrogénocarbonate par électrochimie." Revue des sciences de l'eau 4, no. 2 (2005): 239–52. http://dx.doi.org/10.7202/705098ar.

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La détermination de la capacité complexante des eaux naturelles est généralement effectuée par titrage ampérométrique du cuivre à pH fixé. Beaucoup, sinon tous les tampons classiques utilisés perturbent les études de spéciation du cuivre par formation de complexes peu stables. Dans ce travail nous nous sommes intéressés à la complexation du cuivre par les ions carbonates généralement présents dans les eaux naturelles. Afin de mener à bien notre étude, nous avons mesuré, dans un milieu synthétique de force ionique et pH contrôlés (KNO3 0,02 M + NaHCO3 2,38.10-3 M) toutes les constantes des dive

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3

Karup-Møller, Sven, and Emil Makovicky. "Exploratory studies of the solubility of minor elements in tetrahedrite. VI. Zinc and the combined zinc-mercury and iron-mercury substitutions." Neues Jahrbuch für Mineralogie - Monatshefte 2004, no. 11 (2004): 508–24. http://dx.doi.org/10.1127/0028-3649/2004/2004-0508.

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4

Clever, H. Lawrence. "Solubility of mercury." Journal of Chemical Education 62, no. 8 (1985): 720. http://dx.doi.org/10.1021/ed062p720.2.

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5

Naguib, Martha M., Ahmed O. El-Gendy, and Ahmed S. Khairalla. "Microbial Diversity of Mer Operon Genes and Their Potential Rules in Mercury Bioremediation and Resistance." Open Biotechnology Journal 12, no. 1 (2018): 56–77. http://dx.doi.org/10.2174/1874070701812010056.

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Background:Mercury is a toxic metal that is present in small amounts in the environment, but its level is rising steadily, due to different human activities, such as industrialization. It can reach humans through the food chain, amalgam fillings, and other sources, causing different neurological disorders, memory loss, vision impairment, and may even lead to death; making its detoxification an urgent task.Methods:Various physical and chemical mercury remediation techniques are available, which generally aim at: (i) reducing its mobility or solubility; (ii) causing its vaporization or condensat

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6

Осипова, Н., N. Osipova, С. Арбузов, et al. "Eco-Geo-Chemistry of Mercury in Soils and Coals of the South of Kuzbass." Safety in Technosphere 7, no. 1 (2018): 20–26. http://dx.doi.org/10.12737/article_5b5efdbcbdf5b3.43042870.

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Assessment for content of mercury as a toxic component of coal combustion by-product in rocks and deposit environments is aimed at identification of risks caused by impact of hazardous activities on the environment in full concordance with green chemistry concept. In this paper have been presented results of mercury content determination for the South Kuzbass coals and soils of the coal-mining area. The mercury contents in soils (30 samples) and coals (30 samples) were determined by atomic absorption method on the RA‑915+ mercury analyzer with pyrolytic attachment. The mercury content in Mezhd

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7

Ding, Yi Gang, Hai Tao Huang, Yao Ding, Chang Yan Yang, Jun Ji, and Yuan Xin Wu. "Study of Metal Complexes’ Solubility in Supercritical Carbon Dioxide." Advanced Materials Research 236-238 (May 2011): 411–16. http://dx.doi.org/10.4028/www.scientific.net/amr.236-238.411.

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The solubility of 8-hydroxyquinoline lead, lead diethyldithiocarbamate, 8-hydroxyquinoline mercury and mercury diethyldithiocarbamate in supercritical carbon dioxide under different supercritical conditions was investigated by using supercritical extraction device. It was measured ranged from 308.15K to 328.15K for supercritical temperature, and 10 MPa to 30MPa for pressure. The solubility data of metal complexes were correlated and a mathematical model was put forward from a viewpoint of solvent association theory compared to Chrastil’s model. The results showed that SA model gives fairly goo

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8

Clever, H. Lawrence, and Marian Iwamoto. "Solubility of mercury in normal alkanes." Industrial & Engineering Chemistry Research 26, no. 2 (1987): 336–37. http://dx.doi.org/10.1021/ie00062a026.

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9

Gould, J. P., F. G. Pohland, and W. H. Cross. "Chemical Controls on the Fate of Mercury and Lead Codisposed with Municipal Solid Waste." Water Science and Technology 21, no. 8-9 (1989): 833–43. http://dx.doi.org/10.2166/wst.1989.0286.

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Mercury and lead were among several toxic metals codisposed in test lysimeters with municipal solid waste. Results of analysis of leachates from these landfills during the acid phase of landfill operation have indicated that control of mercury in these systems is a consequence of reduction of divalent mercury to neutral mercury metal. This process was found to occur whether sulfide was present or not. Dissolved mercury in these leachates will exist virtually entirely as chloride complexes. Control of lead solubility was dependent on the presence or absence of sulfide. In the presence of sulfid

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10

Gumiński, Cezary. "Solubility and the periodic table of elements." Pure and Applied Chemistry 87, no. 5 (2015): 477–85. http://dx.doi.org/10.1515/pac-2014-0935.

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AbstractInteresting general tendencies of changes of solubilities of elements and groups of compounds may be observed when the corresponding solubility data are arrayed according to the increasing atomic number of the elements. Such trends are exemplified with the data of various systems (metallic and salt-water type) evaluated in several volumes of the IUPAC-NIST Solubility Data Series. The solubilities of elements in mercury as well as in liquid alkali metals, when ordered according their atomic numbers, change roughly in a corresponding way as the temperatures and energies of melting or boi

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11

Datta, Swapna, Surjyo Jyoti Biswas, and Anisur Rahman Khuda-Bukhsh. "Comparative Efficacy of Pre-feeding, Post-feeding and Combined Pre- and Post-feeding of Two Microdoses of a Potentized Homeopathic Drug, Mercurius Solubilis, in Ameliorating Genotoxic Effects Produced by Mercuric Chloride in Mice." Evidence-Based Complementary and Alternative Medicine 1, no. 3 (2004): 291–300. http://dx.doi.org/10.1093/ecam/neh025.

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Mercury and its derivatives have become an alarming environmental problem, necessitating the search for effective antagonists, including homeopathic drugs, which are generally used in micro doses and are devoid of any palpable side-effects. On the basis of homeopathic similia principle, two potencies ofMercurius solubilis(Merc Sol-30 and Merc Sol-200) were tested by three administrative modes, i.e. pre-feeding, post-feeding and combined pre- and post-feeding, for their possible efficacy in ameliorating mercuric chloride-induced genotoxicity in mice. Healthy mice,Mus musculus, were intraperiton

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12

Alekhin, Y. V., N. R. Zagrtdenov, R. V. Mukhamadiyarova, and A. S. Smirnova. "Experimental study of metallic mercury solubility in water." Vestnik Otdelenia nauk o Zemle RAN 3, Special Issue (2011): 1–7. http://dx.doi.org/10.2205/2011nz000136.

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13

Eysseltová, Jitka. "Ionic Processes in Saturated Solutions of MgCl2·6H2O in Solutions of Other Divalent Metals." Collection of Czechoslovak Chemical Communications 66, no. 1 (2001): 89–98. http://dx.doi.org/10.1135/cccc20010089.

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Solubility isotherms of MgCl2·6H2O at 25 °C in solutions of chlorides of bivalent beryllium, calcium, manganese, iron, cobalt, zinc and mercury were treated by the hydration analysis. In addition to the usual procedure, the recently developed modified transfer energy Ξ was used to characterize the situation in saturated solutions. As a result, the following ionic processes were established in the saturated solutions under consideration: competition for water in solutions of MgCl2·6H2O containing beryllium and calcium chloride, complex formation in solutions of MgCl2·6H2O containing manganese,

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14

Marsh, Kenneth N., John W. Bevan, James C. Holste, David L. McFarlane, Michael Eliades, and William J. Rogers. "Solubility of Mercury in Liquid Hydrocarbons and Hydrocarbon Mixtures." Journal of Chemical & Engineering Data 61, no. 8 (2016): 2805–17. http://dx.doi.org/10.1021/acs.jced.6b00173.

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15

Koulocheris, Vassilis, Vasiliki Louli, Eleni Panteli, Stathis Skouras, and Epaminondas Voutsas. "Modelling of elemental mercury solubility in natural gas components." Fuel 233 (December 2018): 558–64. http://dx.doi.org/10.1016/j.fuel.2018.06.077.

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16

Liu, Lu, Cheng Hang Zheng, and Xiang Gao. "Treatment of V₂O₅/TiO₂ by Non-Thermal Plasma: Changes in Surface Characters and Mercury Oxidation Activity." Key Engineering Materials 744 (July 2017): 519–24. http://dx.doi.org/10.4028/www.scientific.net/kem.744.519.

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The technology for mercury removal in coal-fired power plant is still under development. In the flue gas, elemental mercury is the main component of mercury, and is hard to be removed due to its high volatility and low solubility. So converting Hg0 to Hg2+ in or ahead of the FGD is significant to enhance mercury removal. In this work, plasma treatment method was used to prepare V2O5/TiO2 catalysts for effectively oxidation of Hg0. Plasma treatment of V2O5/TiO2 resulted in the improvement of mercury oxidation activity. The Hg0 oxidation efficiency of the catalysts treated by plasma is over 82%

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17

Hasegawa, S., T. Naoe, and M. Futakawa. "Solubility of helium in mercury for bubbling technology of the spallation neutron mercury target." Journal of Nuclear Materials 398, no. 1-3 (2010): 189–92. http://dx.doi.org/10.1016/j.jnucmat.2009.10.031.

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18

Clarkson, Thomes W. "Mercury." Journal of the American College of Toxicology 8, no. 7 (1989): 1291–95. http://dx.doi.org/10.3109/10915818909009120.

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New findings on the environmental fate of Hg indicate that lakes can be contaminated by long distance transport on mercury vapor in the atmosphere and that higher levels of Me Hg in fish are associated with acidification of lakes and with the creation of hydroelectric reservoirs. Considerable progress has been made in the understanding of the disposition and metabolism of mercury in the body. Inhaled mercury vapor rapidly enters cells in view of its lipid solubility. Inside the cell, it is oxidized by the enzyme, catalase, to inorganic divalent mercury. The latter may be the proximate toxic sp

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19

Melamed, R., F. E. Trigueiro, and R. C. Villas B�as. "The effect of humic acid on mercury solubility and complexation." Applied Organometallic Chemistry 14, no. 9 (2000): 473–76. http://dx.doi.org/10.1002/1099-0739(200009)14:9<473::aid-aoc25>3.0.co;2-w.

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20

Li, Jian, Yunlong Zhao, Qituan Yan, et al. "Measurement of Elemental Mercury Solubility in Natural Gas Dehydrating Solvents." IOP Conference Series: Materials Science and Engineering 394 (August 7, 2018): 022060. http://dx.doi.org/10.1088/1757-899x/394/2/022060.

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21

Khalifa, Mansour, and Leo Lue. "A group contribution method for predicting the solubility of mercury." Fluid Phase Equilibria 432 (January 2017): 76–84. http://dx.doi.org/10.1016/j.fluid.2016.10.025.

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22

Yamada, Junya, Takehiro Shibuya, Atsushi Kobayashi, and Tomoya Tsuji. "Mercury solubility measurements in natural gas components at high pressure." Fluid Phase Equilibria 506 (February 2020): 112342. http://dx.doi.org/10.1016/j.fluid.2019.112342.

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23

Gumiński, Cezary. "Electroanalytical determination of the solubility of noble metals in mercury." Journal of the Less Common Metals 168, no. 2 (1991): 329–34. http://dx.doi.org/10.1016/0022-5088(91)90315-u.

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24

Clever, H. Lawrence, Susan A. Johnson, and M. Elizabeth Derrick. "The Solubility of Mercury and Some Sparingly Soluble Mercury Salts in Water and Aqueous Electrolyte Solutions." Journal of Physical and Chemical Reference Data 14, no. 3 (1985): 631–80. http://dx.doi.org/10.1063/1.555732.

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25

Barek, Jiří, and Roman Hrnčíř. "Polarographic determination of azobenzene." Collection of Czechoslovak Chemical Communications 51, no. 1 (1986): 25–33. http://dx.doi.org/10.1135/cccc19860025.

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Conditions were found for the determination of azobenzene by means of DC, AC, TAST, DP, and FSDP polarography and linear sweep voltammetry on a hanging mercury drop electrode in the medium of aqueous methanol, which ensures a sufficient solubility of azobenzene. In the latter two methods, the detection limit was around 10-8 mol/l; a still lower value could be attained by preliminary accumulation of azobenzene, i.e. adsorption on the electrode surface.

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26

Larrauri, A., P. López, M. J. Gómez-Lechón, and J. V. Castell. "A cytochemical stain for glutathione in rat hepatocytes cultured on plastic." Journal of Histochemistry & Cytochemistry 35, no. 2 (1987): 271–74. http://dx.doi.org/10.1177/35.2.2432118.

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Thiol groups of glutathione react with the organomercurial azo dye mercury orange at a faster rate than with -SH groups of proteins. This property makes possible visualization of glutathione in cells without appreciable interference from other -SH groups. To render this method useful for cytochemical localization of glutathione in plastic cultured cells, it was necessary to adapt this reaction to the specific characteristics of the biological samples to be assayed. First, the choice of a solvent that would allow a convenient solubility of the dye and at the same time be compatible with the pla

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27

Lu, Bo, Arthur E. Ruggles, and Matthew W. Francis. "Numerical study of helium solubility and helium bubble stability in mercury." Annals of Nuclear Energy 59 (September 2013): 75–79. http://dx.doi.org/10.1016/j.anucene.2013.04.001.

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28

Belzile, Nelson, Yu-Wei Chen, John M. Gunn, et al. "The effect of selenium on mercury assimilation by freshwater organisms." Canadian Journal of Fisheries and Aquatic Sciences 63, no. 1 (2006): 1–10. http://dx.doi.org/10.1139/f05-202.

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In this study, we showed that selenium (Se) deposition from metal smelters in Sudbury, Ontario, greatly re duces the bioassimilation of mercury (Hg) by aquatic biota throughout the food web. Concentrations of total and methyl mercury in tissues of zooplankton, mayflies (Stenonema femoratum), amphipods (Hyalella azteca), and young-of-the-year perch (Perca flavescens) were positively correlated with increasing distance from Sudbury smelters and inversely correlated with Se concentrations in lake water. Although concentrations of total Hg and total Se in tissues showed weak or no correlation in m

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29

Skovorod’ko, S. N., A. G. Mozgovoi, and E. V. Rezenova. "Solubility of gaseous helium in liquid mercury at temperatures 600–1500 K." High Temperature 49, no. 1 (2011): 141–42. http://dx.doi.org/10.1134/s0018151x11010202.

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30

Greene, G. A., and C. C. Finfrock. "Short-term solubility of eight alloys circulating in mercury at room temperature." AIChE Journal 49, no. 4 (2003): 1066–69. http://dx.doi.org/10.1002/aic.690490424.

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31

Alekhin, Yu V., N. R. Zagrtdenov, and R. V. Mukhamadiyarova. "Hg0(liq)-Hg0(solution) equilibrium and solubility of elementary mercury in water." Moscow University Geology Bulletin 66, no. 6 (2011): 439–41. http://dx.doi.org/10.3103/s0145875211060020.

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32

Yamada, Junya, Midori Kawasaki, Machie Otsuka, Atsushi Kobayashi, and Tomoya Tsuji. "Measurement and Modeling of Mercury Solubility in Methanol, Glycols, and N-methyldiethanolamine." Journal of Solution Chemistry 50, no. 7 (2021): 968–82. http://dx.doi.org/10.1007/s10953-021-01095-2.

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33

Al-Nuaim, Maan, H. N. K. AL-Salman, and Hussein H. Hussein. "Super Extended Calix[4]Pyrroles as Candidate for Binding Mercury." Oriental Journal of Chemistry 34, no. 6 (2018): 2789–95. http://dx.doi.org/10.13005/ojc/340615.

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The binding of mercury Hg (II) by calix[4]pyrrole derivative; 2 has been much less discovered than anion complexation. The presence of hydroxyl group in the structure of meso-tetramethyl-tetrakis-[2(4-hydroxyphenyl)ethylcalix[4]pyrrole is important for further modifications in the next steps. The modification of the hydroxyl group by the substitution of ester group was carried out to produce the ester derivative for the modified calix[4]pyrrole 2. The ester group would be expected to deliver high electronic contributions in the complexation processes with the guests as well as to increase the

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34

Garrard, WNC, and FG Thomas. "On the Electrochemical Behavior of Pyrylium Ions at the Mercury-Electrode. III. Adsorption Behavior at the Aqueous-Mercury Interface." Australian Journal of Chemistry 40, no. 3 (1987): 579. http://dx.doi.org/10.1071/ch9870579.

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The adsorption behaviour of four pyrylium ions-2,4,6-trimethylpyrylium, 2,4,6-tri-t- butylpyrylium , 2,4,6-triphenylpyrylium and 7-phenyl-5,6,8,9-tetrahydrodibenzo[ c,h ] xanthylium -at the mercury-aqueous 0.5 M sulfuric acid interface is reported. The 2,4,6-trimethylpyrylium ion shows little tendency to adsorb at the mercury interface even at concentrations approaching saturated solution. The tri-t- butylpyrylium ion is adsorbed in a vertical orientation on a positively charged electrode, while on a negatively charged electrode it exhibits two position adsorption- initially flat then reorient

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35

Costa, G. A., M. M. Carnasciali, and E. Kaiser. "Evidence for Oxygen and Mercury Non-Stoichiometry in Hg-1201 HTC Superconductor." International Journal of Modern Physics B 13, no. 09n10 (1999): 1023–28. http://dx.doi.org/10.1142/s0217979299000898.

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A review of the structural existing data on Hg-1201 shows evidence of non stoichiometry of the sample. In this compound not only oxygen but also Hg seems to be released or, perhaps, substituted. So, the production of bulk samples with optimal oxygen doping and homogeneus Hg content could be profitable for the study of the effect of the Hg solubility, allowing to confirm its existence till to room temperatures, and to test the effect of Hg impoverishment on other critical superconducting parameter different from Tc.

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36

Biester, Harald, and Holger Zimmer. "Solubility and Changes of Mercury Binding Forms in Contaminated Soils after Immobilization Treatment." Environmental Science & Technology 32, no. 18 (1998): 2755–62. http://dx.doi.org/10.1021/es9709379.

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37

Marceca, Ernesto, Friedrich Hensel, and Herman Uchtmann. "Spectroscopic Determination of the Solubility of Mercury in Rare Gases to High Pressures." Zeitschrift für Physikalische Chemie 193, Part_1_2 (1996): 95–107. http://dx.doi.org/10.1524/zpch.1996.193.part_1_2.095.

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38

Paquette, K., and G. Helz. "Solubility of cinnabar (red HgS) and implications for mercury speciation in sulfidic waters." Water, Air, & Soil Pollution 80, no. 1-4 (1995): 1053–56. http://dx.doi.org/10.1007/bf01189765.

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39

Zhang, Shuo, Yao Hu, and Qun Hao. "Advances of Sensitive Infrared Detectors with HgTe Colloidal Quantum Dots." Coatings 10, no. 8 (2020): 760. http://dx.doi.org/10.3390/coatings10080760.

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The application of infrared detectors based on epitaxially grown semiconductors such as HgCdTe, InSb and InGaAs is limited by their high cost and difficulty in raising operating temperature. The development of infrared detectors depends on cheaper materials with high carrier mobility, tunable spectral response and compatibility with large-scale semiconductor processes. In recent years, the appearance of mercury telluride colloidal quantum dots (HgTe CQDs) provided a new choice for infrared detection and had attracted wide attention due to their excellent optical properties, solubility processa

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40

Wu, Yin, Wen Jie Si, and He Zhuo Miao. "Kinetics for Supercritical CO₂ Debinding of Injection Molded ZrO₂." Key Engineering Materials 368-372 (February 2008): 736–39. http://dx.doi.org/10.4028/www.scientific.net/kem.368-372.736.

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Mercury porosimeter and scanning electron microscope (SEM) were used to analyze the pore structures evolution and distributions for supercritical CO2 debinding of injection molding ceramics. Classical diffusion equation was used to describe the mass transfer of supercritical CO2 debinding of the injection molded ZrO2 ceramics. The behavior and kinetics of the debinding were studied and analyzed. Results show that the solubility and diffusivity of soluble binder are the key factors in supercritical CO2 debinding, while the diffusivity is a dominant factor. The calculation data from the theoreti

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41

Ayub, Nur Farizah, Shahrir Hashim, and Nadia Adrus. "Development of UV LED Hydrogel Formulation Based on Polyacrylamide Hydrogel." Applied Mechanics and Materials 695 (November 2014): 102–5. http://dx.doi.org/10.4028/www.scientific.net/amm.695.102.

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Recent trends show that the UV LED light source can greatly reduce environmental effect without compromising performance as compared to conventional UV mercury-based lamp (UV Hg) system. In this study, the possibility of using UV LED technology for photopolymerization of polyacrylamide (PAAm) hydrogels is presented. This has strongly drives the needs for suitable water-soluble photoinitiator formulation. Specifically, the photoinitiator must possess characteristic wavelength within UV LED range as UV LED emits monochromatic light sources only (365 nm or 385 nm). Here, the commercially availabl

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42

JIAO Yang, 焦. 扬., 郑舒丹 ZHENG Shu-dan, and 周. 硼. ZHOU Peng. "Synthesis and Immobilization of Water-solubility Fluorescent Probe and Recognition of Mercury(Ⅱ) Ions in Water." Chinese Journal of Luminescence 37, no. 3 (2016): 379–85. http://dx.doi.org/10.3788/fgxb20163703.0379.

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43

Sarkar, Dibyendu. "Preliminary studies on mercury solubility in the presence of iron oxide phases using static headspace analysis." Environmental Geosciences 10, no. 4 (2003): 151–55. http://dx.doi.org/10.1306/eg100403015.

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44

Gallup, Darrell L. "The behavior of mercury in water, alcohols, monoethylene glycol and triethylene glycol II. Elemental mercury solubility in alcohols, ethers and acetone; gas plant mercury distribution; and speciation in monoethylene glycol solution." Fluid Phase Equilibria 477 (December 2018): 58–61. http://dx.doi.org/10.1016/j.fluid.2018.08.014.

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45

Pokharel, A. K., and D. Obrist. "Fate of mercury in tree litter during decomposition." Biogeosciences Discussions 8, no. 2 (2011): 2593–627. http://dx.doi.org/10.5194/bgd-8-2593-2011.

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Abstract. We performed a controlled laboratory litter incubation study to assess changes in dry mass, carbon (C) mass and concentration, mercury (Hg) mass and concentration, and stoichiometric relations between elements during decomposition. Twenty-five surface litter samples each, collected from four forest stands, were placed in incubation jars open to the atmosphere, and were harvested sequentially at 0, 3, 6, 12, and 18 months. Using a mass balance approach, we observed significant mass losses of Hg during decomposition (5 to 23% of initial mass after 18 months), which we attribute to gase

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46

Pokharel, A. K., and D. Obrist. "Fate of mercury in tree litter during decomposition." Biogeosciences 8, no. 9 (2011): 2507–21. http://dx.doi.org/10.5194/bg-8-2507-2011.

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Abstract. We performed a controlled laboratory litter incubation study to assess changes in dry mass, carbon (C) mass and concentration, mercury (Hg) mass and concentration, and stoichiometric relations between elements during decomposition. Twenty-five surface litter samples each, collected from four forest stands, were placed in incubation jars open to the atmosphere, and were harvested sequentially at 0, 3, 6, 12, and 18 months. Using a mass balance approach, we observed significant mass losses of Hg during decomposition (5 to 23 % of initial mass after 18 months), which we attribute to gas

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47

Qi, Lin, Chen-Yu Guo, Meng-Ge Huang Fu, et al. "Enhancement of Solvent Resistance of Polyimide Electrospun Mat via the UV-Assisted Electrospinning and Photosensitive Varnish." Polymers 11, no. 12 (2019): 2055. http://dx.doi.org/10.3390/polym11122055.

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A new methodology for enhancing the solvent resistance of electrospun polyimide (PI) ultrafine fibrous mat (UFM) was investigated in the current work. For this purpose, a negative intrinsically photosensitive polyimide (PSPI) resin was prepared by the one-step high- temperature polycondensation procedure from 3,3’,4,4’-benzophenonetetracarboxylic dianhydride (BTDA) and α,α-bis(4-amino-3,5-dimethylphenyl)phenylmethane (PTMDA). The PI varnish, by dissolving the derived PI (BTDA-PTMDA) resin in N,N-dimethylacetamide (DMAc) at a solid of 20 wt %, was used as the starting material for the standard

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48

Huang, Chibao, Daohai Zhang, Junle Qu, et al. "Open-Chain Crown-Ether-Derived Two-Photon Fluorescence Probe for Real-Time Dynamic Biopsy of Mercury Ions." Australian Journal of Chemistry 70, no. 6 (2017): 705. http://dx.doi.org/10.1071/ch16224.

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A novel two-photon fluorescence probe for Hg2+ derived from bis(styryl)terephthalonitrile, as a two-photon fluorophore, and bis[2-(2-hydroxyethyl sulfanyl) ethyl]amino group (ionophore), as a novel Hg2+ ligand, was developed. The probe possesses small molecule size, large two-photon absorption cross-section (1067 GM) in H2O, non-cytotoxic effect, long wavelength emission at 588 nm, large Stokes shift (121 nm), excellent photostability, high water solubility, good cell permeability, and pH insensitivity in the biologically relevant range. The probe can selectively detect Hg2+ ions in live cells

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Reeves, Matthew G., Peter A. Wood, and Simon Parsons. "MrPIXEL: automated execution of Pixel calculations via the Mercury interface." Journal of Applied Crystallography 53, no. 4 (2020): 1154–62. http://dx.doi.org/10.1107/s1600576720008444.

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The interpretation of crystal structures in terms of intermolecular interaction energies enables phase stability and polymorphism to be rationalized in terms of quantitative thermodynamic models, while also providing insight into the origin of physical and chemical properties including solubility, compressibility and host–guest formation. The Pixel method is a semi-empirical procedure for the calculation of intermolecular interactions and lattice energies based only on crystal structure information. Molecules are represented as blocks of undistorted ab initio molecular electron and nuclear den

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50

Namur, Olivier, Bernard Charlier, Francois Holtz, Camille Cartier, and Catherine McCammon. "Sulfur solubility in reduced mafic silicate melts: Implications for the speciation and distribution of sulfur on Mercury." Earth and Planetary Science Letters 448 (August 2016): 102–14. http://dx.doi.org/10.1016/j.epsl.2016.05.024.

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