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Journal articles on the topic 'Mesomerism'

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1

Wepster, B. M., and P. E. Verkade. "Steric effects on mesomerism. IV. Steric effects on mesomerism in derivatives of ortho-nitro-acetanilide." Recueil des Travaux Chimiques des Pays-Bas 68, no. 1 (2010): 88–110. http://dx.doi.org/10.1002/recl.19490680110.

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2

Wepster, B. M., and P. E. Verkade. "Steric effects on mesomerism. V.) steric effects on mesomerism in derivatives of para-nitro-acetanilide." Recueil des Travaux Chimiques des Pays-Bas 69, no. 11 (2010): 1393–406. http://dx.doi.org/10.1002/recl.19500691109.

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3

Zotti, Linda A., and Edmund Leary. "Taming quantum interference in single molecule junctions: induction and resonance are key." Physical Chemistry Chemical Physics 22, no. 10 (2020): 5638–46. http://dx.doi.org/10.1039/c9cp06384f.

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4

Ritchie, James P. "A look at mesomerism in nitrobenzene." Tetrahedron 44, no. 24 (1988): 7465–78. http://dx.doi.org/10.1016/s0040-4020(01)86241-4.

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5

Rosenthal, Uwe. "Equilibria and mesomerism/valence tautomerism of group 4 metallocene complexes." Chemical Society Reviews 49, no. 7 (2020): 2119–39. http://dx.doi.org/10.1039/c9cs00637k.

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Priority of equilibrium: reactivity of unusual group 4 metallocene complexes is best explained by the equilibrium and only additionally by the mesomerism/valence tautomerism. The equilibrium predominates the empirically found experimental results.
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6

Carissan, Yannick, Nicolas Goudard, Denis Hagebaum-Reignier, and Stéphane Humbel. "HuLiS, a program to teach mesomerism and more." Journal of Physics: Conference Series 738 (August 2016): 012015. http://dx.doi.org/10.1088/1742-6596/738/1/012015.

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7

Lincke, Gerhard. "On quinacridones and their supramolecular mesomerism within the crystal lattice." Dyes and Pigments 52, no. 3 (2002): 169–81. http://dx.doi.org/10.1016/s0143-7208(01)00085-7.

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8

Wepster, B. M. "Steric effects on mesomerism VIII : Benzoquinuclidine, an aromatic amine without mesomeric interaction between the benzene ring and the amino group." Recueil des Travaux Chimiques des Pays-Bas 71, no. 12 (2010): 1159–70. http://dx.doi.org/10.1002/recl.19520711202.

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9

Kofod, H., L. E. Sutton, W. A. de Jong, P. E. Verkade, and B. M. Wepster. "Steric effects on mesomerism. VI. Preparation and dipole moment of nitrodurene." Recueil des Travaux Chimiques des Pays-Bas 71, no. 5 (2010): 521–24. http://dx.doi.org/10.1002/recl.19520710514.

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10

Wepster, B. M. "Steric effects on mesomerism: XIII. Preparation of 2,6-dimethyl-4-nitroaniline." Recueil des Travaux Chimiques des Pays-Bas 73, no. 10 (2010): 809–18. http://dx.doi.org/10.1002/recl.19540731004.

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11

van Alphen, J. "Some remarks on mesomerism. (The reaction between α-halogenoketones and phenylhydrazine, VI)". Recueil des Travaux Chimiques des Pays-Bas 65, № 2 (2010): 117–20. http://dx.doi.org/10.1002/recl.19460650209.

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12

JURETSCHKE, Hans-Paul, and Aviva LAPIDOT. "Intramolecular interactions, mesomerism and dynamics in actinomycin D studied by 15N NMR spectroscopy." European Journal of Biochemistry 147, no. 2 (1985): 313–24. http://dx.doi.org/10.1111/j.1432-1033.1985.tb08752.x.

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13

Wepster, B. M. "Steric effects on mesomerism IX : The basic strength of benzoquinuclidine and its bearing on the basic strength and the mesomeric energy of aromatic amines." Recueil des Travaux Chimiques des Pays-Bas 71, no. 12 (2010): 1171–78. http://dx.doi.org/10.1002/recl.19520711203.

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14

van der Krogt, S. M. H., and B. M. Wepster. "Steric effects on mesomerism: XIV. The basic strength of dibenzoquinuclidine and its bearing on the basic strength and the mesomeric energy of aromatic amines." Recueil des Travaux Chimiques des Pays-Bas 74, no. 2 (2010): 161–67. http://dx.doi.org/10.1002/recl.19550740205.

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15

van Hoek, T. C., P. E. Verkade, and B. M. Wepster. "Steric effects on mesomerism: XVIII). Steric inhibition of the mesomerism in aromatic amines with bulky N-alkyl groups of compact structure: Nitrosation and coupling of the four N-methyl-N-butylanilines." Recueil des Travaux Chimiques des Pays-Bas 77, no. 6 (2010): 559–68. http://dx.doi.org/10.1002/recl.19580770606.

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16

Lee, Kyu Cheol, Gi-Seong Ryu, Shanshan Chen, Gyoungsik Kim, Yong-Young Noh, and Changduk Yang. "Dicyanomethylene-quinoid vs. dicyanovinyl-benzenoid organic semiconductors: Understanding structure-property correlations in mesomerism-like forms." Organic Electronics 37 (October 2016): 402–10. http://dx.doi.org/10.1016/j.orgel.2016.07.017.

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17

Biekart, H. J. B., H. B. Dessens, P. E. Verkade, and B. M. Wepster. "Steric effects on mesomerism. X . Deacylation of some tert.butyl-acetylamino-nitrobenzenes in an alkaline medium." Recueil des Travaux Chimiques des Pays-Bas 71, no. 12 (2010): 1245–52. http://dx.doi.org/10.1002/recl.19520711213.

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18

Wang, Wen-Feng, Man Nien Schuchmann, Heinz-Peter Schuchmann та Clemens von Sonntag. "The Importance of Mesomerism in the Termination ofα-Carboxymethyl Radicals from Aqueous Malonic and Acetic Acids". Chemistry 7, № 4 (2001): 791–95. http://dx.doi.org/10.1002/1521-3765(20010216)7:4<791::aid-chem791>3.0.co;2-2.

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19

Koudelka, Juraj, David Šaman, and Otto Exner. "Secondary steric effects in 2,4,6-trialkylated acetophenones and nitrobenzenes: Dipole moments and 13C NMR spectra." Collection of Czechoslovak Chemical Communications 50, no. 1 (1985): 208–14. http://dx.doi.org/10.1135/cccc19850208.

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Dipole moments of 2,4,6-trialkylated acetophenones (II) and bromobenzenes (III) with variable size of the alkyl groups were measured in two solvents. The main intention was to shed more light on the previous results with similarly substituted nitrobenzenes (I). The comparison reveals a steady decrease of the dipole moment with the increasing size of the alkyl group in all three series. In addition, there is a stronger effect of steric inhibition of mesomerism in the series II and a comparably strong effect of the anisotropic polarizability in I; the two cannot be distinguished on the basis of
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20

Krol, L. H., P. E. Verkade, and B. M. Wepster. "Steric effects on mesomerism: VII. Deacylation of a number of acetylamino-nitronaphthalenes and some of their derivatives." Recueil des Travaux Chimiques des Pays-Bas 71, no. 6 (2010): 545–64. http://dx.doi.org/10.1002/recl.19520710603.

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21

van Helden, R., P. E. Verkade, and B. M. Wepster. "Steric effects on mesomerism: XII). On the effective size of methyl(ene) groups, especially in ortho-xylene derivatives." Recueil des Travaux Chimiques des Pays-Bas 73, no. 1 (2010): 39–59. http://dx.doi.org/10.1002/recl.19540730108.

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22

Burgers, J., M. A. Hoefnagel, P. E. Verkade, H. Visser, and B. M. Wepster. "Steric effects on mesomerism. XVII. Some properties of aromatic nitro-, amino-, and acylamino compounds with bulky ortho-substituents." Recueil des Travaux Chimiques des Pays-Bas 77, no. 6 (2010): 491–530. http://dx.doi.org/10.1002/recl.19580770602.

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23

Wepster, B. M. "Steric effects on mesomerism: XI, The ultra-violet absorption spectrum of Tröger's base and the stereochemistry of aromatic amines." Recueil des Travaux Chimiques des Pays-Bas 72, no. 8 (2010): 661–72. http://dx.doi.org/10.1002/recl.19530720806.

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24

Klages, Gerhard. "Molekülinterne Dipolorientierung und dielektrische Absorption in verdünnter Lösung bei Mikro- und Submillimeterwellen. III. Methyläther." Zeitschrift für Naturforschung A 40, no. 12 (1985): 1206–19. http://dx.doi.org/10.1515/zna-1985-1205.

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The dielectric loss of seven aromatic ethers (anisole, 1,2- and 1.4-dimethoxybenzene, 4-methylanisole, 4-chloranisole, 1- and 2-naphtholmethylether) and of three aliphatic ethers has been measured at 20 °C in very dilute solutions of aliphatic solvents (n-heptene, cyclohexene and decalin). The microwave frequencies used cover 2 to 70 GHz, in the far infrared region (FIR), wave numbers 40 to 300 cm-1 have been available. All microwave spectra of loss factor ε´´ are analysed in terms of two or three absorption areas by fitting dispersion steps and Debye relaxation times and employing non-zero co
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25

Brouwers, J. A. C. Th, S. C. Bijlsma, P. E. Verkade, and B. M. Wepster. "Steric effects on mesomerism: XIX . A Comparison of some properties of a number of N-mono-n.alkyl- and N,N-di-n.alkylanilines." Recueil des Travaux Chimiques des Pays-Bas 77, no. 11 (2010): 1080–88. http://dx.doi.org/10.1002/recl.19580771112.

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26

Canty, Allan J., Alireza Ariafard та Gerard Koten. "Computational Analysis of Mesomerism in para ‐Substituted mer ‐NCN Pincer Platinum(II) Complexes, Including its Relationships with Hammett σ p Substituent Parameters". Chemistry – A European Journal 26, № 67 (2020): 15629–35. http://dx.doi.org/10.1002/chem.202003023.

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27

Wepster, B. M. "Steric effects on mesomerism. XVI). Comparative investigations involving ultra-violet absorption spectra, molecular refractions, rates of reaction, and basic strengths of aromatic amines." Recueil des Travaux Chimiques des Pays-Bas 76, no. 5 (2010): 357–89. http://dx.doi.org/10.1002/recl.19570760503.

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28

Wepster, B. M., and P. E. Verkade. "Steric effects on mesomerism. III). Estimation of the direct influence of substituents on the rate of deacylation of ortho- and para-nitro-acetanilide." Recueil des Travaux Chimiques des Pays-Bas 68, no. 1 (2010): 77–87. http://dx.doi.org/10.1002/recl.19490680109.

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29

Wepster, B. M. "Steric effects on mesomerism. XV. Comparative investigations involving ultra-violet absorption spectra, molecular refractions, basic strengths, and rates of reaction of derivatives of nitrobenzene." Recueil des Travaux Chimiques des Pays-Bas 76, no. 5 (2010): 335–56. http://dx.doi.org/10.1002/recl.19570760502.

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30

Wepster, B. M., and P. E. Verkade. "Steric effects on mesomerism: II. The experimental procedures for following the deacylation of aromatic acylamino-nitro compounds. The deacylation of ortho-, meta- and para-nitro-acetanilide." Recueil des Travaux Chimiques des Pays-Bas 67, no. 6 (2010): 425–37. http://dx.doi.org/10.1002/recl.19480670602.

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31

Khaner, O., and F. Wilt. "Interactions of different vegetal cells with mesomeres during early stages of sea urchin development." Development 112, no. 3 (1991): 881–90. http://dx.doi.org/10.1242/dev.112.3.881.

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It has been known from results obtained in the classical experiments on sea urchin embryos that cell isolation and transplantation showed extensive interactions between the early blastomeres and/or their descendants. In the experiments reported here a systematic reexamination of recombination of mesomeres and their progeny (which come from the animal hemisphere) with various vegetal cells derived from blastomeres of the 32- and 64-cell stage was carried out. Cells were marked with lineage tracers to follow which cell gave rise to what structures, and newly available molecular markers have been
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32

Ollis, W. David, Stepher P. Stanforth, and Christopher A. Ramsden. "Heterocyclic mesomeric betaines." Tetrahedron 41, no. 12 (1985): 2239–329. http://dx.doi.org/10.1016/s0040-4020(01)96625-6.

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33

Gründler, Wolfgang. "Mesomerie und Quantenmechanik." Zeitschrift für Chemie 23, no. 5 (2010): 157–67. http://dx.doi.org/10.1002/zfch.19830230502.

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34

Livingston, B. T., and F. H. Wilt. "Range and stability of cell fate determination in isolated sea urchin blastomeres." Development 108, no. 3 (1990): 403–10. http://dx.doi.org/10.1242/dev.108.3.403.

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We have examined the developmental potential of blastomeres isolated from either the animal (mesomeres) or vegetal (macromeres-micromeres) half of 16-cell embryos of the sea urchin Lytechinus pictus. We have also examined the effects of two known vegetalizing agents on the development of isolated mesomeres; LiCl treatment and combination with micromeres, the small blastomeres found at the vegetal pole of the 16-cell embryo. The markers for differentiation used were both morphological (invaginations, spicules and pigment cells) and molecular (gut-specific alkaline phosphatase activity, and mono
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35

Dreger, Andrij, Martin Nieger, Martin Drafz, and Andreas Schmidt. "Synthesis of a Pyrazol-3-ylidene Palladium Complex, Pyrazolium Salts and Mesomeric Betaines of Pyrazole as N-Heterocyclic Carbene Precursors." Zeitschrift für Naturforschung B 67, no. 4 (2012): 359–66. http://dx.doi.org/10.1515/znb-2012-0410.

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The synthesis of a pyrazol-3-ylidene palladium complex is described, and results of a single-crystal X-ray diffraction study are presented. The properties of pyrazolium salts as well as of two types of heterocyclic mesomeric betaines, the pseudo-cross-conjugated mesomeric betaine pyrazolium-3- carboxylate and its cross-conjugated analog pyrazolium-4-carboxylate, are compared.
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36

Barboiu, M., F. Dumitru, E. Petit, Y. M. Legrand, and A. V. D. Lee. "Mesomeric metallosupramolecular grid architectures." Supramolecular Chemistry 27, no. 5-6 (2014): 393–400. http://dx.doi.org/10.1080/10610278.2014.965708.

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37

Maier, Günther, Hans-Otto Kalinowski, and Klaus Euler. "Cyclobutadien: Mesomerie oder Valenzisomerie?" Angewandte Chemie 94, no. 9 (2006): 706–7. http://dx.doi.org/10.1002/ange.19820940909.

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38

CHEN, YOU-SHENG. "Youngia baoxingensis, a new species of Asteraceae (tribe Cichorieae) from Sichuan, China." Phytotaxa 382, no. 2 (2018): 239. http://dx.doi.org/10.11646/phytotaxa.382.2.10.

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Youngia baoxingensis (Asteraceae, Cichorieae), a new species from Baoxing in Sichuan, China, is described and illustrated. This species belongs to Youngia sect. Mesomeris and is similar to Y. yilingii, but is distinct by its oblong and subentire leaf blade, brown pappus, and 6–7 florets.
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39

Gonsior, Nina, Fabian Mohr, and Helmut Ritter. "Synthesis of mesomeric betaine compounds with imidazolium-enolate structure." Beilstein Journal of Organic Chemistry 8 (March 13, 2012): 390–97. http://dx.doi.org/10.3762/bjoc.8.42.

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The synthesis of a heterocyclic mesomeric betaine by quaternization reaction of 1-butylimidazole and tetrabromo-1,4-benzoquinone is presented. The structure was verified by means of X-ray single-crystal analysis, NMR and IR spectroscopy. Inclusion complexes of the heterocyclic mesomeric betaine with randomly methylated (1.8) β-cyclodextrin were investigated by UV–vis spectroscopy. Furthermore, the reaction conditions were applied to poly(vinylimidazole) and 1,4-bis(1H-imidazol-1-yl)butane to obtain functionalized polymer networks and condensate polymers, respectively.
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40

Exner, Otto, Roberta Fruttero, and Alberto Gasco. "Mesomeric dipole moments. Part 12." Structural Chemistry 1, no. 5 (1990): 417–21. http://dx.doi.org/10.1007/bf00671227.

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41

He, Taoyuan, Di Li, Yanan Yang, et al. "Mesomeric configuration makes polyleucine micelle an optimal nanocarrier." Biomaterials Science 4, no. 5 (2016): 814–18. http://dx.doi.org/10.1039/c6bm00022c.

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42

Batsyts, Sviatoslav, Francisco J. Ramírez, Juan Casado, Jan C. Namyslo, and Andreas Schmidt. "Chemistry and spectroscopy of cross-conjugated and pseudo-cross-conjugated quinolinium-ethynyl-benzoate mesomeric betaines." Zeitschrift für Naturforschung B 73, no. 7 (2018): 481–91. http://dx.doi.org/10.1515/znb-2018-0020.

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AbstractThe three isomers 1-methylquinolinium-2-, 3-, and 4-ethynyl(phenyl-4-carboxylates) belong to two distinct types of heterocyclic mesomeric betaines. The quinolinium substituted in position 3 is a cross-conjugated mesomeric betaine (CCMB), whereas the quinolinium derivatives substituted in positions 2 and 4 are members of the class of pseudo-cross-conjugated mesomeric betaines (PCCMBs). While the charges are strictly separated within the common π-electron system of the CCMB according to the canonical formulae, the charges are effectively but not exclusively delocalized in the PCCMBs beca
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43

Raczyńska, Ewa Daniela. "Substituent Effects on the Basicity of ortho-, meta- and para-substituted N1,N1-Dimethyl-N2-phenylformamidines in Ethanol and in Water." Collection of Czechoslovak Chemical Communications 57, no. 1 (1992): 113–18. http://dx.doi.org/10.1135/cccc19920113.

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The relative δpKa values of ortho-, meta-, and para-substituted N1,N1-dimethyl-N2-phenylformamidines obtained in 95.6% aqueous ethanol have been compared with those in water. The comparison shows only some differences in the ortho substituent effects. The meta and para substituent effects in ethanol are not very different from those in water. Quantitative analysis of the experimental δpKa values based on the Taft equation has led to separation of the total electromeric effects into the inductive and mesomeric effects. As compared to the amino group in anilines, the formamidine group is more se
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44

Sharma, Nivedita, Manjinder Kour, Raakhi Gupta, and Raj K. Bansal. "A new cross-conjugated mesomeric betaine." RSC Advances 11, no. 41 (2021): 25296–304. http://dx.doi.org/10.1039/d1ra03981d.

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Cross-conjugated mesomeric betaine (CCMB) has been defined as the dipolar species in which positive and negative charges are exclusively restricted to different parts of the molecule. A new CCMB isoconjugate with odd non-alternant hydrocarbon anion is reported.
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45

Litvinenko, S. V., Yu M. Volovenko, and F. S. Babichev. "Pseudo-cross-conjugated mesomeric betaines. 1. Synthesis of pseudo-cross-conjugated mesomeric betaines from quinoxaline derivatives." Chemistry of Heterocyclic Compounds 28, no. 11 (1992): 1307–11. http://dx.doi.org/10.1007/bf00532084.

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46

Fekete, Csaba, Ilona Kovács, László Nyulászi, and Tamás Holczbauer. "Planar lithium silolide: aromaticity, with significant contribution of non-classical resonance structures." Chem. Commun. 53, no. 80 (2017): 11064–67. http://dx.doi.org/10.1039/c7cc07004g.

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47

Konishi, Hayato, Tsukasa Hirokane, Hajime Hashimoto, et al. "Synthesis of diaryl ether components of ellagitannins using ortho-quinone with consonant mesomeric effects." Chemical Communications 56, no. 28 (2020): 3991–94. http://dx.doi.org/10.1039/d0cc00889c.

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Methods for synthesizing C–O digallate structures, the basic unit of diaryl ether components of natural ellagitannins, are described. In the designed building block, consonantly overlapped mesomeric effects enhanced its electrophilicity.
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48

Dale, B., I. Yazaki, and E. Tosti. "Polarized distribution of L-type calcium channels in early sea urchin embryos." American Journal of Physiology-Cell Physiology 273, no. 3 (1997): C822—C825. http://dx.doi.org/10.1152/ajpcell.1997.273.3.c822.

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Using the whole cell clamp technique, we have measured calcium-dependent currents and steady-state conductance in early sea urchin blastomeres. The calcium currents in M phase decreased from 8.5 microA/cm2 at the four-cell stage to 5.4 microA/cm2 at the eight-cell stage. In 16-cell stage embryos, calcium currents were 7.4 microA/cm2 in the mesomeres, 2.3 microA/cm2 in the macromeres, and were not detected in the micromeres. In contrast, the micromeres had a two- to threefold higher steady-state conductance than the mesomeres or macromeres, which may be due to potassium ion conductivity. Nifedi
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49

Ledwon, Przemyslaw, Neil Thomson, Enrico Angioni, Neil J. Findlay, Peter J. Skabara, and Wojciech Domagala. "The role of structural and electronic factors in shaping the ambipolar properties of donor–acceptor polymers of thiophene and benzothiadiazole." RSC Advances 5, no. 94 (2015): 77303–15. http://dx.doi.org/10.1039/c5ra06993a.

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p- and n-doped states of thiophene-benzothiadiazole based donor–acceptor π-conjugated polymer materials are studied. Results reveal that mesomeric factors mainly influence p-doping, while steric factors account for n-doping peculiarities.
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50

Musicki, Branislav. "Synthesis and 1,3-dipolar cycloaddition reactions of novel heteropentalene mesomeric betaines, pyrrolo[1,2-c]imidazole mesomeric betaines." Journal of Organic Chemistry 55, no. 3 (1990): 910–18. http://dx.doi.org/10.1021/jo00290a022.

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