Relevant bibliographies by topics / Metal-Air Batteries

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  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers
  6. Reports

Academic literature on the topic 'Metal-Air Batteries'

Author: Grafiati
Published: 4 June 2021
Last updated: 6 September 2023

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Journal articles on the topic "Metal-Air Batteries"

1

JACOBY, MITCH. "RECHARGEABLE METAL-AIR BATTERIES." Chemical & Engineering News 88, no. 47 (November 22, 2010): 29–31. http://dx.doi.org/10.1021/cen111710100120.

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Milikić, Jadranka, Ana Nastasić, Marta Martins, César A. C. Sequeira, and Biljana Šljukić. "Air Cathodes and Bifunctional Oxygen Electrocatalysts for Aqueous Metal–Air Batteries." Batteries 9, no. 8 (July 28, 2023): 394. http://dx.doi.org/10.3390/batteries9080394.

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One of the most popular solutions for electrochemical energy storage is metal−air batteries, which could be employed in electric vehicles or grid energy storage. Metal–air batteries have a higher theoretical energy density than lithium-ion batteries. The crucial components for the best performance of batteries are the air cathode electrocatalysts and corresponding electrolytes. Herein, we present several of the latest studies on electrocatalysts for air cathodes and bifunctional oxygen electrocatalysts for aqueous zinc–air and aluminium–air batteries.
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Olabi, Abdul Ghani, Enas Taha Sayed, Tabbi Wilberforce, Aisha Jamal, Abdul Hai Alami, Khaled Elsaid, Shek Mohammod Atiqure Rahman, Sheikh Khaleduzzaman Shah, and Mohammad Ali Abdelkareem. "Metal-Air Batteries—A Review." Energies 14, no. 21 (November 5, 2021): 7373. http://dx.doi.org/10.3390/en14217373.

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Metal–air batteries are a promising technology that could be used in several applications, from portable devices to large-scale energy storage applications. This work is a comprehensive review of the recent progress made in metal-air batteries MABs. It covers the theoretical considerations and mechanisms of MABs, electrochemical performance, and the progress made in the development of different structures of MABs. The operational concepts and recent developments in MABs are thoroughly discussed, with a particular focus on innovative materials design and cell structures. The classical research on traditional MABs was chosen and contrasted with metal–air flow systems, demonstrating the merits associated with the latter in terms of achieving higher energy density and efficiency, along with stability. Furthermore, the recent applications of MABs were discussed. Finally, a broad overview of challenges/opportunities and potential directions for commercializing this technology is carefully discussed. The primary focus of this investigation is to present a concise summary and to establish future directions in the development of MABs from traditional static to advanced flow technologies. A systematic analysis of this subject from a material and chemistry standpoint is presented as well.
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Namaeighasemi, Arash, John Staser, and Damilola Daramola. "Materials for Metal-Air Batteries." ECS Meeting Abstracts MA2021-02, no. 1 (October 19, 2021): 83. http://dx.doi.org/10.1149/ma2021-02183mtgabs.

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Staser, John, Omar Movil, Damilola Daramola, and Arash Namaeighasemi. "Materials for Metal-Air Batteries." ECS Meeting Abstracts MA2021-01, no. 26 (May 30, 2021): 940. http://dx.doi.org/10.1149/ma2021-0126940mtgabs.

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Dong, Qi, and Dunwei Wang. "Catalysts in metal–air batteries." MRS Communications 8, no. 02 (April 12, 2018): 372–86. http://dx.doi.org/10.1557/mrc.2018.59.

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Mathialagan, Kowsalya, Saranya T, Ammu Surendran, Ditty Dixon, Nishanthi S.T., and Aiswarya Bhaskar. "(Digital Presentation) Development of Bifunctional Oxygen Electrocatalysts for Electrically Rechargeable Zinc-Air Batteries." ECS Meeting Abstracts MA2022-02, no. 4 (October 9, 2022): 403. http://dx.doi.org/10.1149/ma2022-024403mtgabs.

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Zinc-air battery is a promising battery system as it possesses high theoretical energy density and is cost-effective3. The theoretical energy density of a Zinc-air battery is 1086 Wh kg-1, which is five times greater than that of lithium-ion batteries2. Moreover, zinc metal is one of the most abundant metals in the earth’s crust and is inexpensive. Rechargeable metal-air batteries operate based on two fundamental electrochemical reactions as Oxygen Reduction Reaction (ORR) during discharge and Oxygen Evolution Reaction (OER) during recharge processes, respectively3. Electrocatalytic activity of the bifunctional electrocatalyst towards these two oxygen reactions will decide the performance of the battery1. Recent advancements in catalyst development are the fabrication of rechargeable air electrodes using a single active material that is capable of bifunctionally catalyzing ORR and OER3. The development of bifunctional catalysts with high activity is necessary for rechargeable metal-air batteries, such as zinc-air batteries3. In this work, a perovskite-type LaFeO3 material was synthesized using a citric acid-assisted sol-gel method and is investigated as bifunctional oxygen electrocatalyst for electrically rechargeable zinc-air batteries. Structural studies using X-ray diffraction revealed the formation of phase pure LaFeO3 in space group Pbnm. This catalyst displayed considerable bifunctional catalytic activity for both oxygen reduction (0.74 V vs. RHE) and oxygen evolution reactions (0.40 V vs. RHE at 10 mA cm-2) in 1 M KOH electrolyte. Electrically rechargeable zinc-air batteries assembled using LaFeO3 as the oxygen electrocatalyst deliver a specific capacity of 936.38 mAh g( Zn) -1 after the 1st discharge. Further details will be discussed in the poster. Financial support from Department of Science and Technology, Govt. of India under research grant number DST/TMD/MECSP/2K17/20 is gratefully acknowledged. References: [01] Y. Li, M. Gong, et. al., Nature communications, 4, (2013), 1-7 [02] P. Gu, M. Zheng, et. al., Journal of Material Chemistry, (2017), 1-17 [03] D. U. Lee, P. Xu, et. al., Journal of Material Chemistry, 4, (2016), 7107-7134
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Lee, Jang-Soo, Sun Tai Kim, Ruiguo Cao, Nam-Soon Choi, Meilin Liu, Kyu Tae Lee, and Jaephil Cho. "Metal-Air Batteries: Metal-Air Batteries with High Energy Density: Li-Air versus Zn-Air (Adv. Energy Mater. 1/2011)." Advanced Energy Materials 1, no. 1 (December 30, 2010): 2. http://dx.doi.org/10.1002/aenm.201190001.

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Peng, Xinwen, Tingzhen Li, Linxin Zhong, and Jun Lu. "Flexible metal–air batteries: An overview." SmartMat 2, no. 2 (June 16, 2021): 123–26. http://dx.doi.org/10.1002/smm2.1044.

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Hardwick, Laurence J., and Carlos Ponce de León. "Rechargeable Multi-Valent Metal-Air Batteries." Johnson Matthey Technology Review 62, no. 2 (April 1, 2018): 134–49. http://dx.doi.org/10.1595/205651318x696729.

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Dissertations / Theses on the topic "Metal-Air Batteries"

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Hopkins, Brandon J. (Brandon James). "Stopping self-discharge in metal-air batteries." Thesis, Massachusetts Institute of Technology, 2018. http://hdl.handle.net/1721.1/120466.

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Thesis: Ph. D., Massachusetts Institute of Technology, Department of Mechanical Engineering, 2018.
Cataloged from PDF version of thesis.
Includes bibliographical references (pages 67-78).
Metal-air batteries boast high theoretical energy densities, but negative electrode corrosion can severely reduce their usable capacity and commercial utility. Most methods to mitigate corrosion focus on electrode and electrolyte modification such as electrode alloying, electrolyte additives, and gel and nonaqueous electrolytes. These methods, however, either insufficiently suppress the parasitic reaction or compromise power and energy density. This thesis focuses on a different approach to corrosion mitigation involving electrolyte displacement from the electrode surface. Multiple electrolyte-displacement concepts were generated and investigated. The most promising of the concepts was the reversible displacement of the electrolyte from the electrode surface with an oil. To enable this method, the fundamental physics of underwater oil-fouling resistant surfaces was investigated, tested, and characterized. Design equations that aid in the appropriate selection of electrodes, displacing oils, and separator membranes were also developed. The oil displacement method was demonstrated in a primary (single-use) aluminum-air (Al-air) battery that achieved a 420% increase in useable energy density and was estimated to enable pack-level energy densities as high as 700 Wh 1- and 900 Wh kg-1. This method could, in principle, be used in any of the metal-air batteries, aqueous or nonaqueous, or in other energy storage systems that suffer from corrosion if appropriate displacing oils and separator membranes are found using the discussed design principles. With the oil displacement method, aqueous metal-air batteries that rely on abundant, broadly dispersed materials could provide safe, low-cost, sustainable primary and secondary (rechargeable) batteries for many applications including grid-storage, off-grid storage, robot power, and vehicular propulsion.
by Brandon J. Hopkins.
Ph. D.
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2

Thompson, Stephen. "Bi-functional oxygen catalysts for metal-air flow-batteries." Thesis, University of Southampton, 2016. https://eprints.soton.ac.uk/393071/.

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The rise in wind, solar and tidal renewable power generation presents a new challenge for the future stability of electrical networks on the national and international scale. The modal nature of renewable power and its incompatibility with consumer demand necessitates a means for largescale energy storage with high efficiency and relatively low cost. Zinc-air flow batteries represent one possible solution to this problem. The energy is stored in the metallic zinc, and reversed with the oxidation to form zincate releasing the energy on demand. The majority of energy losses in the zinc-air battery are for the O2 evolution and reduction reactions on the air electrode. A stable, durable and low-cost bi-functional air electrode would allow the introduction of zinc-air flow batteries to support the power grids of the future. The work in this thesis will investigate the activity of NiCo2O4 electrocatalysts prepared by various methods, for their use as bi-functional electrocatalysts in the air-electrode. The electrocatalyst prepared on to a gas diffusion electrode, to determine activity in lab-scale half-cells. Improvements to catalyst activity are then considered through the addition of metal nanoparticles to the surface of NiCo2O4, with in-situ X-ray absorbance measurements to determine the oxidation states of ruthenium during the O2 evolution reaction. The activity of NiCo2O4 was compared to alternative perovskite mixed metal oxide electrocatalysts.
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Kang, ShinYoung. "Ab initio prediction of thermodynamics in alkali metal-air batteries." Thesis, Massachusetts Institute of Technology, 2014. http://hdl.handle.net/1721.1/89952.

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Thesis: Ph. D., Massachusetts Institute of Technology, Department of Materials Science and Engineering, 2014.
Cataloged from PDF version of thesis.
Includes bibliographical references (pages 93-100).
Electric vehicles ("EVs") require high-energy-density batteries with reliable cyclability and rate capability. However, the current state-of-the-art Li-ion batteries only exhibit energy densities near ~150 Wh/kg, limiting the long-range driving of EVs with one charge and hindering their wide-scale commercial adoption.1-3 Recently, non-aqueous metal-O₂ batteries have drawn attention due to their high theoretical specific energy.2, 4-6 Specifically, the issues surrounding battery studies involve Li-O₂ and Na-O₂ batteries due to their high theoretical specific energies of 3.5 kWh/kg (assuming Li 20 2 as a discharge product in Li-O₂ batteries) and 1.6 and 1.1 kWh/kg (assuming Na₂O₂ and NaO₂ as discharge products, respectively, in Na-O₂ batteries). Since the potential of Li-O₂ batteries as an energy storage system was first proposed in 1996,1 various studies have criticized and verified their shortcomings, such as their low power density, poor cyclability, and poor rate capability. ₇, ₈ Substantial research attempts have been made to identify the cause of the high overpotentials and electrolyte decomposition and to search for better cathode/electrolyte/anode and/or catalyst material combinations. However, Li-O₂ battery technology remains in its infancy primarily due to the lack of understanding of the underlying mechanisms. Therefore, we investigate the charging mechanism, which contributes to the considerable energy loss using first-principles calculations and propose a new charging mechanism based on experimental observations and knowledge concerning Li-ion and Na-ion batteries. Most studies on metal-O₂ batteries have mainly focused on Li-O₂ batteries. However, recently, the promising performance of Na-O₂ systems has been reported.₉, ₁₀ Although Na-O₂ batteries exhibit slightly lower theoretical specific energies than those of the Li-O₂ batteries as specified above, the chemical difference between the two alkali metals substantially distinguishes the electrochemistry properties of Na-O₂ and Li-O₂. In the Na-O₂ system, both NaO₂ and Na₂O₂ are stable compounds, while in the Li-O system, LiO₂ is not a stable compound under standard state conditions (300 K and 1 atm).₁₁, ₁₂ Presumably, due to this chemical difference, the Na-O₂ system has exhibited a much smaller charging overpotential, as low as 0.2 V, when NaO₂ is formed as a discharge product, compared with that in Li-O₂ system, >1 V. Such a low charging overpotential in Na-O₂ batteries demonstrates their potential as a next generation electrochemical system for commercially viable EVs .₉,₁₀ In this thesis, we study the thermodynamic stability of Na-O compounds to identify the phase selection conditions that affect the performance of Na-O₂ batteries.
by ShinYoung Kang.
Ph. D.
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Alwast, Dorothea [Verfasser]. "Electrochemical Model Studies on Metal-air and Lithium-ion Batteries / Dorothea Alwast." Ulm : Universität Ulm, 2021. http://d-nb.info/1237750822/34.

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Hosseini-Benhangi, Pooya. "Bifunctional oxygen reduction/evolution catalysts for rechargeable metal-air batteries and regenerative alkaline fuel cells." Thesis, University of British Columbia, 2016. http://hdl.handle.net/2429/60227.

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The electrocatalysis of oxygen reduction and evolution reactions (ORR and OER, respectively) on the same catalyst surface is among the long-standing challenges in electrochemistry with paramount significance for a variety of electrochemical systems including regenerative fuel cells and rechargeable metal-air batteries. Non-precious group metals (non-PGMs) and their oxides, such as manganese oxides, are the alternative cost-effective solutions for the next generation of high-performance bifunctional oxygen catalyst materials. Here, initial stage electrocatalytic activity and long-term durability of four non-PGM oxides and their combinations, i.e. MnO₂, perovskites (LaCoO₃ and LaNiO₃) and fluorite-type oxide (Nd₃IrO₇), were investigated for ORR and OER in alkaline media. The combination of structurally diverse oxides revealed synergistic catalytic effect by improved bifunctional activity compared to the individual oxide components. Next, the novel role of alkali-metal ion insertion and the mechanism involved for performance promotion of oxide catalysts were investigated. Potassium insertion in the oxide structures enhanced both ORR and OER performances, e.g. 110 and 75 mV decrease in the OER (5 mAcm-²) and ORR (-2 mAcm-²) overpotentials (in absolute values) of MnO₂-LaCoO₃, respectively, during galvanostatic polarization tests. In addition, the stability of K⁺ activated catalysts was improved compared to unactivated samples. Further, a factorial design study has been performed to find an active nanostructured manganese oxide for both ORR and OER, synthesized via a surfactant-assisted anodic electrodeposition method. Two-hour-long galvanostatic polarization at 5 mAcm-² showed the lowest OER degradation rate of 5 mVh-¹ for the electrodeposited MnOx with 270 mV lower OER overpotential compared to the commercial γ-MnO₂ electrode. Lastly, the effect of carbon addition to the catalyst layer, e.g. Vulcan XC-72, carbon nanotubes and graphene-based materials, was examined on the ORR/OER bifunctional activity and durability of MnO₂ LaCoO₃. The highest ORR and OER mass activities of -6.7 and 15.5 Ag-¹ at 850 and 1650 mVRHE, respectively, were achieved for MnO₂-LaCoO₃-multi_walled_carbon_nanotube-graphene, outperforming a commercial Pt electrode. The factors affecting the durability of mixed-oxide catalysts were discussed, mainly attributing the performance degradation to Mn valence changes during ORR/OER. A wide range of surface analyses were employed to support the presented electrochemical results as well as the proposed mechanisms.
Applied Science, Faculty of
Chemical and Biological Engineering, Department of
Graduate
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PEZZOLATO, LORENZO. "Fe-N-C non-noble catalysts for applications in Fuel Cells and Metal Air Batteries." Doctoral thesis, Politecnico di Torino, 2020. http://hdl.handle.net/11583/2809320.

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Zan, Lingxing [Verfasser]. "Metal-air Batteries: RRDE and EC-SPM Studies of Electrode Kinetics and Electrode Structure / Lingxing Zan." Bonn : Universitäts- und Landesbibliothek Bonn, 2017. http://d-nb.info/1149154039/34.

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Liu, Chenjuan. "Exploration of Non-Aqueous Metal-O2 Batteries via In Operando X-ray Diffraction." Doctoral thesis, Uppsala universitet, Strukturkemi, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-330889.

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Non-aqueous metal-air (Li-O2 and Na-O2) batteries have been emerging as one of the most promising high-energy storage systems to meet the requirements for demanding applications due to their high theoretical specific energy. In the present thesis work, advanced characterization techniques are demonstrated for the exploration of metal-O2 batteries. Prominently, the electrochemical reactions occurring within the Li-O2 and Na-O2 batteries upon cycling are studied by in operando powder X-ray diffraction (XRD). In the first part, a new in operando cell with a combined form of coin cell and pouch cell is designed. In operando synchrotron radiation powder X-ray diffraction (SR-PXD) is applied to investigate the evolution of Li2O2 inside the Li-O2 cells with carbon and Ru-TiC cathodes. By quantitatively tracking the Li2O2 evolution, a two-step process during growth and oxidation is observed. This newly developed analysis technique is further applied to the Na-O2 battery system. The formation of NaO2 and the influence of the electrolyte salt are followed quantitatively by in operando SR-PXD. The results indicate that the discharge capacity of Na-O2 cells containing a weak solvating ether solvent depends heavily on the choice of the conducting salt anion, which also has impact on the growth of NaO2 particles. In addition, the stability of the discharge product in Na-O2 cells is studied. Using both ex situ and in operando XRD, the influence of sodium anode, solvent, salt and oxygen on the stability of NaO2 are quantitatively identified. These findings bring new insights into the understanding of conflicting observations of different discharge products in previous studies. In the last part, a binder-free graphene based cathode concept is developed for Li-O2 cells. The formation of discharge products and their decomposition upon charge, as well as different morphologies of the discharge products on the electrode, are demonstrated. Moreover, considering the instability of carbon based cathode materials, a new type of titanium carbide on carbon cloth cathode is designed and fabricated. With a surface modification by loading Ru nanoparticles, the titanium carbide shows enhanced oxygen reduction/evolution activity and stability. Compared with the carbon based cathode materials, titanium carbide demonstrated a higher discharge and charge efficiency.
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Gehring, Markus Verfasser], Rüdiger-A. [Akademischer Betreuer] [Eichel, Dirk Uwe [Akademischer Betreuer] Sauer, and Joachim [Akademischer Betreuer] Mayer. "Electrospun fibres as efficient cathodes for metal-air batteries / Markus Gehring ; Rüdiger-A. Eichel, Dirk Uwe Sauer, Joachim Mayer." Aachen : Universitätsbibliothek der RWTH Aachen, 2020. http://d-nb.info/122621858X/34.

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Abdelghani-Idrissi, Soufiane. "La charge rapide d'une batterie métal-air par la maîtrise de la fluidique diphasique." Electronic Thesis or Diss., Université Paris sciences et lettres, 2020. http://www.theses.fr/2020UPSLS013.

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La charge rapide des batteries métal-air représente un des verrous technologiques auquel cette technologie est confrontée. Pour répondre à cette problématique, l'électrolyte est soumis à un écoulement pour évacuer les bulles d’oxygène sources d'affaiblissement de l'efficacité de ces batteries. L’écoulement de l'électrolyte permet une réduction du potentiel des électrodes à dégagement de gaz. L’électrode présente une surface active plus élevée, réduisant son potentiel électrique pour un courant donné. La microscopie optique met en évidence le caractère bimodal de la répartition de la taille de bulles qui tend vers une répartition monomodal lorsque le débit augmente. Ces caractérisations électrochimiques et optiques apportent les informations pour développer un modèle analytique pour la prédiction du comportement dynamique de ces systèmes. Ce modèle est complété par une simulation numérique qui met en évidence les phénomènes oscillatoires mesurés à forts courants. L’optimisation énergétique du procédé est réalisée par le choix d’un débit optimal qui concilie le gain en puissance électrique et les pertes de charges hydrauliques. La diminution des pertes par l'adaptation de la géométrie de la cellule d’écoulement a été abordée. La cellule à configuration triangulaire permet une double optimisation énergétique. Ces cellules ont été testées expérimentalement et présentent de meilleures caractéristiques en termes d’évacuation naturelle et forcée des bulles. Une étude préliminaire et les perspectives de l’effet de l’écoulement sur les dendrites de zinc sont présentées. L'écoulement de l'électrolyte dans la cellule augmente le temps de court-circuit
The fast charge of metal-air batteries represent one of the main scientific and technical challenges facing this technology. Oxygen bubbles formed during the charge process has a negative impact on the performances of the cells. Using flowing electrolyte for the evacuation of oxygen bubbles leads to a decrease of the electric potential of the gas evolving electrodes. For a given current, the electrode has more active surface, decreasing its potential. Optical measurement under microscope shows the bimodal distribution of the bubbles sizes. This repartition trends to a uni-modal distribution when the flow rate of the electrolyte increases. Those electrochemical and optical characterizations bring information to develop an analytical modelling for the predictions of the dynamic behavior of these systems. A numerical simulation is also proposed to complete the analytical model. This simulation is able to reproduce the oscillatory behavior at high currents. The optimization of the energy efficiency of the process is done by calculating and choosing an optimal flow rate, corresponding to the best balance between the power gained and the hydraulic power consumed by the flow. The decrease of the hydraulic power needed is done by the adaptation of the geometry of the flow cells. Triangular configuration for the inlet and outlet zones of the flow are tested and shows better characteristics for natural and forced evacuation of the bubbles. A preliminary study and outlooks of the effect of flowing electrolyte on zinc dendrites are presented. Flowing electrolyte increase the time before a short-circuit occurs
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Books on the topic "Metal-Air Batteries"

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Zhang, Xin-bo, ed. Metal-Air Batteries. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2018. http://dx.doi.org/10.1002/9783527807666.

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Gupta, Ram K. Metal-Air Batteries. Boca Raton: CRC Press, 2023. http://dx.doi.org/10.1201/9781003295761.

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Neburchilov, Vladimir, and Jiujun Zhang, eds. Metal-Air and Metal-Sulfur Batteries. Boca Raton : Taylor & Francis, CRC Press, 2016. | Series:: CRC Press, 2016. http://dx.doi.org/10.1201/9781315372280.

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Wang, Yan-Jie, Rusheng Yuan, Anna Ignaszak, David P. Wilkinson, and Jiujun Zhang. Advanced Bifunctional Electrochemical Catalysts for Metal-Air Batteries. Boca Raton : Taylor & Francis, a CRC title, part of the Taylor & Francis imprint, a member of the Taylor & Francis Group, the academic division of T&F Informa, plc, 2018.: CRC Press, 2018. http://dx.doi.org/10.1201/9781351170727.

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Metal-Air Batteries: Fundamentals and Applications. Wiley-VCH, 2019.

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Zhang, Xin-bo. High Energy Density Metal-Air Batteries. Wiley & Sons, Incorporated, John, 2018.

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Zhang, Xin-bo. Metal-Air Batteries: Fundamentals and Applications. Wiley & Sons, Incorporated, John, 2018.

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Zhang, Xin-bo. Metal-Air Batteries: Fundamentals and Applications. Wiley & Sons, Incorporated, John, 2018.

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Zhang, Xin-bo. Metal-Air Batteries: Fundamentals and Applications. Wiley & Sons, Limited, John, 2018.

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Metal-Air and Metal-Sulfur Batteries: Fundamentals and Applications. Taylor & Francis Group, 2016.

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Book chapters on the topic "Metal-Air Batteries"

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de Souza, Felipe M., Anuj Kumar, and Ram K. Gupta. "Metal-Air Batteries." In Metal-Air Batteries, 1–13. Boca Raton: CRC Press, 2023. http://dx.doi.org/10.1201/9781003295761-1.

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Yu, Tongwen, Rui Cai, and Zhongwei Chen. "Zn-Air Batteries." In Metal-Air Batteries, 265–91. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2018. http://dx.doi.org/10.1002/9783527807666.ch10.

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Zhang, Ji-Guang, Peter G. Bruce, and X. Gregory Zhang. "Metal-Air Batteries." In Handbook of Battery Materials, 757–95. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2011. http://dx.doi.org/10.1002/9783527637188.ch22.

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Middaugh, Richard L. "Metal-Air Batteries." In Encyclopedia of Applied Electrochemistry, 1245–48. New York, NY: Springer New York, 2014. http://dx.doi.org/10.1007/978-1-4419-6996-5_416.

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Chutia, Bhugendra, Chiranjita Goswami, and Pankaj Bharali. "Metal Oxide-Based Electrocatalysts for Metal-Air Batteries." In Metal-Air Batteries, 209–25. Boca Raton: CRC Press, 2023. http://dx.doi.org/10.1201/9781003295761-15.

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Mei, Jun. "Noble Metal-Based Electrocatalysts for Metal-Air Batteries." In Metal-Air Batteries, 135–50. Boca Raton: CRC Press, 2023. http://dx.doi.org/10.1201/9781003295761-10.

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Fu, Jing, and Zhongwei Chen. "Zinc–Air Batteries." In Metal–Air and Metal–Sulfur Batteries, 1–20. Taylor & Francis Group, 6000 Broken Sound Parkway NW, Suite 300, Boca Raton, FL 33487-2742: CRC Press, 2016. http://dx.doi.org/10.1201/9781315372280-2.

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Imanishi, Nobuyuki, and Osamu Yamamoto. "Lithium–Air Batteries." In Metal–Air and Metal–Sulfur Batteries, 21–64. Taylor & Francis Group, 6000 Broken Sound Parkway NW, Suite 300, Boca Raton, FL 33487-2742: CRC Press, 2016. http://dx.doi.org/10.1201/9781315372280-3.

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Ding, Fei, Jun Zong, Sihui Wang, Hai Zhong, Qingqing Zhang, and Qing Zhao. "Aluminum–Air Batteries." In Metal–Air and Metal–Sulfur Batteries, 65–109. Taylor & Francis Group, 6000 Broken Sound Parkway NW, Suite 300, Boca Raton, FL 33487-2742: CRC Press, 2016. http://dx.doi.org/10.1201/9781315372280-4.

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Chang, Zhiwen, and Xin-bo Zhang. "Introduction to Metal-Air Batteries: Theory and Basic Principles." In Metal-Air Batteries, 1–9. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2018. http://dx.doi.org/10.1002/9783527807666.ch1.

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Conference papers on the topic "Metal-Air Batteries"

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Martin, J. J., V. Neburchilov, H. Wang, and W. Qu. "Air cathodes for metal-air batteries and fuel cells." In Energy Conference (EPEC). IEEE, 2009. http://dx.doi.org/10.1109/epec.2009.5420955.

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Lochte, Andre, Jan-Ole Thranow, Felix Winters, and Peter Glosekotter. "Analysis of switching electronics for metal-air batteries." In 2022 International Conference on Electrical, Computer and Energy Technologies (ICECET). IEEE, 2022. http://dx.doi.org/10.1109/icecet55527.2022.9872910.

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Ortiz-Vitoriano, Nagore, Marina Enterría, Domenico Frattini, Estíbaliz García-Gaitán, Arantzazu Letona, and Lidia Medinilla. "Unlocking the Potential of Aqueous and Aprotic Metal-Air Batteries." In MATSUS23 & Sustainable Technology Forum València (STECH23). València: FUNDACIO DE LA COMUNITAT VALENCIANA SCITO, 2022. http://dx.doi.org/10.29363/nanoge.matsus.2023.296.

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Prabu, M., and S. Shanmugam. "NiCo2O4 - Graphene oxide hybrid as a bifunctional electrocatalyst for air breathing cathode material in metal air batteries." In International Conference on Advanced Nanomaterials & Emerging Engineering Technologies (ICANMEET-2013). IEEE, 2013. http://dx.doi.org/10.1109/icanmeet.2013.6609319.

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Padmaraj, O., and C. Venkateswaran. "A study of hybrid bifunctional CuCo2O4/rGO electrocatalytic oxygen reduction and evolution reactions for rechargeable metal-air batteries." In DAE SOLID STATE PHYSICS SYMPOSIUM 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0017380.

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Carter, Rachel, Landon Oakes, and Cary L. Pint. "Three Dimensional Single-Walled Carbon Nanotube Foams for Ultrahigh Energy Density Lithium Air Battery Cathodes." In ASME 2015 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2015. http://dx.doi.org/10.1115/imece2015-52333.

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This paper highlights our progress in developing pristine single-walled carbon nanotubes (SWCNTs) into functional materials for lightweight, conductive cathodes in lithium air (Li-air) batteries. We outline a process to produce foams of single-walled carbon nanotubes using liquid processing routes that are free of additives or surfactants, using polar solvents and electrophoretic deposition. To accomplish this, SWCNTs are deposited onto sacrificial metal foam templates, and the metal foam is removed to yield a freestanding, all-SWCNT foam material. We couple this material into a cathode for a Li-air battery and demonstrate excellent performance that includes first discharge capacity over 8200 mAh/g, and specific energy density of ∼ 21.2 kWh/kg (carbon) and ∼ 3.3 kWh/kg (full cell). We further compare this to the performance of foams prepared with SWCNTs that are dispersed with surfactant, and our results indicate that surfactant residues completely inhibit the nucleation of stable lithium peroxide materials — a result measured across multiple devices. Comparing to multi-walled carbon nanotubes produced using the same technique indicates a discharge capacity of only ∼ 1500 mAh/g, which is over 5X lower than SWCNTs in the same processing technique and material architecture. Overall, this work highlights SWCNT materials in the absence of impurities introduced during experimental processing as a lightweight and high performance electrode material for lithium-air batteries.
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Kazemiabnavi, Saeed, Prashanta Dutta, and Soumik Banerjee. "Ab Initio Modeling of the Electron Transfer Reaction Rate at the Electrode-Electrolyte Interface in Lithium-Air Batteries." In ASME 2014 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2014. http://dx.doi.org/10.1115/imece2014-40239.

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Lithium-air batteries are very promising energy storage systems for meeting current demands in electric vehicles. However, the performance of these batteries is highly dependent on the electrochemical stability and physicochemical properties of the electrolyte such as ionic conductivity, vapor pressure, static and optical dielectric constant, and ability to dissolve oxygen and lithium peroxide. Room temperature ionic liquids, which have high electrical conductivity, wide electrochemical stability window and also low vapor pressure, are considered potential electrolytes for these batteries. Moreover, since the physicochemical and electrochemical properties of ionic liquids are dependent on the structure of their constitutive cations and anions, it is possible to tune these properties by choosing from various combinations of cations and anions. One of the important factors on the performance of lithium-air batteries is the local current density. The current density on each electrode can be obtained by calculating the rate constant of the electron transfer reactions at the surface of the electrode. In lithium-air batteries, the oxidation of pure lithium metal into lithium ions happens at the anode. In this study, Marcus theory formulation was used to calculate the rate constant of the electron transfer reaction in the anode side using the respective thermodynamics data. The Nelsen’s four-point method of separating oxidants and reductants was used to evaluate the inner-sphere reorganization energy. In addition, the Conductor-like Screening Model (COSMO) which is an approach to dielectric screening in solvents has been implemented to investigate the effect of solvent on these reaction rates. All calculations were done using Density Functional Theory (DFT) at B3LYP level of theory with a high level 6-311++G** basis set which is a Valence Triple Zeta basis set with polarization and diffuse on all atoms (VTZPD) that gives excellent reproducibility of energies. Using this methodology, the electron transfer rate constant for the oxidation of lithium in the anode side was calculated in an ionic liquids electrolyte. Our results present a novel approach for choosing the most appropriate electrolyte(s) that results in enhanced current densities in these batteries.
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Yoo, Kisoo, Prashanta Dutta, and Soumik Banerjee. "A Mathematical Model for Li-Air Battery Considering Volume Change Phenomena." In ASME 2014 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2014. http://dx.doi.org/10.1115/imece2014-37627.

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Li-air battery has the potential to be the next generation energy storage device because of its much higher energy density and power density. However, the development of Li-air battery has been hindered by a number of technical challenges such as passivation of cathode, change in effective reaction area, volume change during charge and discharge, etc. In a lithium-air cell, the volume change can take place due to Li metal oxidation in anode during charge as well as due to the solubility of reaction product (lithium peroxide) in the electrolyte at cathode. In this study, a mathematical model is developed to study the performance of lithium-air batteries considering the significant volume changes at the anode and cathode sides using moving boundary technique. A numerical method was introduced to solve moving boundary problem using finite volume method. Using this model, the electric performance of lithium-air battery is obtained for various load conditions. Numerical results indicate that cell voltage drops faster with increase in load which is consistent with experimental observations. Also, the volume changes significantly affect the electric performance of lithium-air cell.
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Aliahmad, Nojan, Mangilal Agarwal, Sudhir Shrestha, and Kody Varahramyan. "Paper-Based Lithium Magnesium Oxide Battery." In ASME 2013 International Manufacturing Science and Engineering Conference collocated with the 41st North American Manufacturing Research Conference. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/msec2013-1243.

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Replacing of metal current collectors with flexible materials has great potentials of improving flexibility, weight, and applications of Li-ion batteries. This paper presents fabrication and experimental results of lithium magnesium oxide (LiMn2O4) battery using conductive paper current collectors. A thin layer of LiMn2O4 was coated on paper current collectors using air-spray method, and half-cell devices were fabricated. Experimental capacity of 130 mAh/g is reported. The porous structure of cellulous fibers in the current collector improves the adhesion of electrode materials on the substrate, which provides higher flexibility and lighter weight.
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Azam, Reem, Tasneem ElMakki, Sifani Zavahir, Zubair Ahmad, Gago Guillermo Hijós, and Dong Suk Han. "Lithium capture in Seawater Reverse Osmosis (SWRO) Brine using membrane-based Capacitive Deionization (MCDI) System." In Qatar University Annual Research Forum & Exhibition. Qatar University Press, 2021. http://dx.doi.org/10.29117/quarfe.2021.0013.

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Lithium-battery based industries including vehicles, electronics, fusion and thermonuclear, consume lithium rapidly, which raises the need for developing a lithium recovery system. Lithium global market consumption in 2016 was reported to be 35% in batteries manufacturing. The total content of lithium in seawater and oceans is estimated at 2.5 × 1014 kg, with an average concentration of 0.17 mg/L. Salt lakes contain 1,000–3,000 mg/L of lithium, while geothermal water up to 15 mg/L. In 2020, the US Geological Survey (USGS) reported that the total Li resource is about 80 million ton. In nature, lithium does not exist as pure metal owing to its high reactivity with water, air, and nitrogen. Commonly lithium is mined from metallic minerals from earth or brine salt marsh and used in various fields in the form of lithium carbonate (60%), lithium hydroxide (23%), lithium metal (5%), lithium chloride (3%), and butyl lithium (4%). The extraction of 1 kg of lithium needs around 5.3 kg of lithium carbonate. The amount required to produce lithium-ion batteries (LIB) for cell phones or electric cars is estimated to be 0.8 kg/s of lithium metal, which is equivalent to 25,000 tons per year. As we use this much of LIB, this will end up having significant amounts of lithium battery waste, thus recovering LIBS and using it as cathode electrode in MCDI is an excellent way with benefit. This work proposes to efficiently utilize seawater reverse osmosis (SWRO) brine as a medium to recover lithium from seawater followed by its selective capture of lithium element using SLIB as MCDI cathode electrode material. Thus, these attempts could be closer to an improved and more effective loop of lithium targeted capture-reuse system.
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Reports on the topic "Metal-Air Batteries"

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Zhu, C., and W. Chen. 3D printed Ni-Mn-Fe Bi-Functional Catalyst for Metal Air Batteries. Office of Scientific and Technical Information (OSTI), September 2021. http://dx.doi.org/10.2172/1860934.

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Swette, L. L., M. Manoukian, and A. B. LaConti. Bi-functional air electrodes for metal-air batteries. Final report, September 15, 1993--December 14, 1994. Office of Scientific and Technical Information (OSTI), December 1995. http://dx.doi.org/10.2172/188906.

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Marschilok, Amy C. Porous Ag/P/C Composite Electrodes: A New Approach for Metal Air Batteries. Fort Belvoir, VA: Defense Technical Information Center, February 2012. http://dx.doi.org/10.21236/ada565200.

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