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Journal articles on the topic 'Metal Ammine Complexes'

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Published: 5 June 2025

Last updated: 1 August 2025

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1

Christensen, Claus Hviid, Rasmus Zink Sørensen, Tue Johannessen, et al. "Metal ammine complexes for hydrogen storage." Journal of Materials Chemistry 15, no. 38 (2005): 4106. http://dx.doi.org/10.1039/b511589b.

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2

Pozas-Tormo, Rafaela, Sebastián Bruque Gamez, María Martinez-Lara, and Laureano Moreno-Real. "Interlayer ammine complexes of metal uranyl phosphates." Canadian Journal of Chemistry 66, no. 11 (1988): 2849–54. http://dx.doi.org/10.1139/v88-441.

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The solids derived from HUP by substituting metallic ions for protons, take up Lewis base molecules (like NH3 and C4H9NH2) in the interlamellar space. The diffractograms of these inclusion compounds indicate that the host crystallinity was preserved.The infrared spectroscopy of the Ni, Co, Cu, Zn, and Cd intercalates revealed that part of the sorbate was protonated in the interlaminar space while the other part displaced the water in their coordination spheres. However, in the Mn derivative, no coordinated or free Lewis base could be detected: it was all in the protonated form.

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3

Baer, Sebastian A., and Florian Kraus. "mer-Triammine Trifluorido Iron(III), mer-[FeF3(NH3)3]." Zeitschrift für Naturforschung B 66, no. 8 (2011): 865–67. http://dx.doi.org/10.1515/znb-2011-0814.

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Metal fluorides are scarcely soluble in liquid ammonia, and their ammine complexes are rare. The synthesis and crystal structure of the first ammine complex of an iron fluoride, the mer-triammine trifluorido iron(III), mer-[FeF3(NH3)3], is presented. The compound crystallizes in the form of colorless, needle-shaped single crystals in the monoclinic space group P21/n with Z = 4. The molecules are interconnected by strong N-H· · ·F hydrogen bonds.

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4

Nakashima, Yoshiaki, Masayuki Muto, Keiichi Kawano, Yoshimasa Kyogoku, and Yuzo Yoshikawa. "Nitrogen-15 NMR Chemical Shifts in Metal–Ammine Complexes. II. Cobalt(III) Ammine and Amine Complexes." Bulletin of the Chemical Society of Japan 62, no. 8 (1989): 2455–60. http://dx.doi.org/10.1246/bcsj.62.2455.

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5

Nilsson, Kersti B., Mikhail Maliarik, and Ingmar Persson. "Coordination Chemistry of Solvated Metal Ions in Soft Donor Solvents." Molecules 30, no. 15 (2025): 3063. https://doi.org/10.3390/molecules30153063.

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The structures of hexaammine solvated indium(III) and thallium(III) ions in liquid ammonia solution are determined by EXAFS. Both complexes have regular octahedral coordination geometry with mean In-N and Tl-N bond distances of 2.23(1) and 2.29(2) Å, respectively. Ammine solvated thallium(III) in liquid ammonia is characterized with 205Tl NMR measurements. Solvents such as liquid ammonia, N,N-dimethylthioformamide (DMTF), trialkyl and triphenyl phosphite and phosphine are strong electron pair donors and thereby able to form bonds with a large covalent contribution with strong electron pair acc

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6

Grinderslev, Jakob B., Mads B. Amdisen, and Torben R. Jensen. "Synthesis, Crystal Structures and Thermal Properties of Ammine Barium Borohydrides." Inorganics 8, no. 10 (2020): 57. http://dx.doi.org/10.3390/inorganics8100057.

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Ammine metal borohydrides show large compositional and structural diversity, and have been proposed as candidates for solid-state ammonia and hydrogen storage as well as fast cationic conductors. Here, we report the synthesis method of ammine barium borohydrides, Ba(BH4)2·xNH3 (x = 1, 2). The two new compounds were investigated with time-resolved temperature-varied in situ synchrotron radiation powder X-ray diffraction, thermal analysis, infrared spectroscopy and photographic analysis. The compound Ba(BH4)2·2NH3 crystallizes in an orthorhombic unit cell with space group symmetry Pnc2, and is i

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7

Lauerer, Brigitte, A. Pusch, K. H. Stadler, and H. P. Boehm. "Adsorption of Tetrammine-carbonato and -cis-diaqua and Triethylenetetramine-carbonato and -cis-diaqua Complexes of Cobalt(III) on Titanium Dioxide as Models for the Binding of Uranyl Ions from the Tricarbonatouranyl Complex Ion." Zeitschrift für Naturforschung B 47, no. 5 (1992): 625–34. http://dx.doi.org/10.1515/znb-1992-0504.

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The adsorption of several cobalt(III) complex ions with carbonato or two aqua ligands in cis-position (and related complexes) was studied with the objective of a comparison with the adsorption of UO22+ ions from [UO2(CO3)3]4- solutions. One CO32- group per adsorbed UO22+ ion was found on the TiO2 surface after vacuum-drying at room temperature. Pre-adsorption of HPO42- ions resulted in an increased UO22+ uptake, whilst coverage of the TiO2 surface with adsorbed Al hydroxo complexes resulted in the opposite effect. The adsorption rate as well as the saturation uptake were higher for the cis-[Co

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8

Mehrotra, Raj Narain. "Review on the Chemistry of [M(NH3)n](XO4)m (M = Transition Metal, X = Mn, Tc or Re, n = 1–6, m = 1–3) Ammine Complexes." Inorganics 11, no. 7 (2023): 308. http://dx.doi.org/10.3390/inorganics11070308.

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The preparation of ammine complexes of transition metals having oxidizing anions such as permanganate and perrhenate ions is a great challenge due to possible reactions between ammonia and oxidizing anions during the synthesis of these materials. However, it has an important role in both the development of new oxidants in organic chemistry and especially in the preparation of mixed-metal oxide catalyst precursors and metal alloys for their controlled temperature decomposition reactions. Therefore, in this paper, synthetic procedures to prepare ammonia complexes of transition metal permanganate

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9

Nazmutdinov, Renat R., Maria Yu Rusanova, David VanderPorten, Galina A. Tsirlina, and W. Ronald Fawcett. "Toward the Reactivity Prediction: Outersphere Electroreduction of Transition-Metal Ammine Complexes." Journal of Physical Chemistry C 113, no. 7 (2009): 2881–90. http://dx.doi.org/10.1021/jp807926t.

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10

Mashaly, M. M. "A study of the effect of ammonia gas on the solid mono- and dinuclear oxorhenium(V) complexes." Journal of the Serbian Chemical Society 64, no. 9 (1999): 519–31. http://dx.doi.org/10.2298/jsc9909519m.

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The reaction of ammonia gas with the solid oxorhenium(V) complexes [Re2 O3L2Cl4].2H2O, [Re2O2L3Cl6].2H2O, [ReOLCl(OH2)3]Cl2, [ReOL2(OH2)3]Cl3, [ReOLCl3(OH2)], [ReOL(SCN)2Cl(OH2)].H2O and [ReOL(SCN)Cl2(OH2)] (where L = 2-benzimadazolethione), yielded the corresponding ammine and/or amine complexes, [Re2O3L2(NH3)2(NH2)2]Cl2 (I), [Re2O2L3(NH3)2(NH2)4]Cl2(II), [Re2O3L2(NH3)2 (NH2)4].H2O (III), [Re2O3L4(NH2)4] (IV), [Re2O3L2(NH3)2(NH2)4] (V), [Re2O3L2 (SCN)4(NH3)2] (VI) and [Re2O3L2(Thio)2(NH2)4] (VII), respectively, (Thio = thiourea) where ammonia gas has replaced other ligands such as chlorine an

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11

Mersel, Maali-Amel, Lajos Fodor, Péter Pekker, Miklós Jakab, Éva Makó, and Ottó Horváth. "Effects of Preparation Conditions on the Efficiency of Visible-Light-Driven Hydrogen Generation Based on Cd0.25Zn0.75S Photocatalysts." Catalysts 11, no. 12 (2021): 1534. http://dx.doi.org/10.3390/catal11121534.

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Photocatalytic H2 production utilizing H2S, an industrial side-product, is regarded as an environmentally friendly process to produce clean energy through direct solar energy conversion. For this purpose, sulfide-based materials, such as photocatalysts, have been widely used due to their good solar response and high photocatalytic activity. In this work, a ZnS–CdS composite was studied, and special attention was dedicated to the influence of the preparation parameters on its H2 production activity. The ZnS–CdS composite, with an enhanced photoactivity for H2 production, was synthesized both fr

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12

Weil, K. S. "The synthesis of transition metal nitrides via thermolysis of metal–ammine complexes, Part I: Chromium nitride." Journal of Solid State Chemistry 181, no. 1 (2008): 199–210. http://dx.doi.org/10.1016/j.jssc.2007.11.008.

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13

Jacobs, Herbert, Rainer Niewa, Thomas Sichla, Andreas Tenten, and Uwe Zachwieja. "Metal nitrogen compounds with unusual chemical bonding: nitrides, imides, amides and ammine complexes." Journal of Alloys and Compounds 246, no. 1-2 (1997): 91–100. http://dx.doi.org/10.1016/s0925-8388(96)02458-9.

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14

Shaw, Jiajiu, and Grover W. Everett. "Second-sphere coordination of transition-metal ammine complexes by lasalocid A, a natural ionophore." Inorganic Chemistry 24, no. 12 (1985): 1917–20. http://dx.doi.org/10.1021/ic00206a044.

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15

Chen, Yuying, D. H. Christensen, G. O. Sørensen, O. Faurskov Nielsen, and E. Pedersen. "The skeletal vibrational spectra and metal—ligand force constants of cobalt(III) ammine complexes." Journal of Molecular Structure 299 (October 1993): 61–72. http://dx.doi.org/10.1016/0022-2860(93)80283-2.

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16

Abubakar, Oluwafemi David, and Thomas Hamann. "Ligand Design for Enhanced Ruthenium-Based Electrocatalytic Ammonia Oxidation." ECS Meeting Abstracts MA2025-01, no. 52 (2025): 2589. https://doi.org/10.1149/ma2025-01522589mtgabs.

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The electrocatalytic oxidation of ammonia remains a critical challenge in energy and environmental technologies, with current molecular catalysts struggling with high overpotentials, limited stability, and low turnover frequencies. Since the first molecular catalyst, [Ru(tpy)(dmabpy)NH3)]2+, was reported in 2019, there has been progress in investigating alternative ligand frameworks and transition metal centers to better understand and control the reaction. This presentation will highlight a novel strategy for improving the electrocatalytic performance by systematically optimizing ligand bite

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17

Reynolds, PA, and BN Figgis. "On the Charge Density Distribution in Cobalt(III) Ammine Hexacyanochromate(III) Complexes." Australian Journal of Chemistry 43, no. 11 (1990): 1929. http://dx.doi.org/10.1071/ch9901929.

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A charge density refinement using effective anharmonic isotropic thermal parameters was performed on the X-ray diffraction data for pentaammineaquacobalt(III) hexacyanochromate(III) and for hexaamminecobalt(III) hexacyanochromate(III), constraining the unit cells of the crystals to be electically neutral. Our previous refinements, which did not admit of anharmonicity, could not simultaneously give a good fit and provide electroneutrality of the unit cell. The effective anharmonic parameters correct a systematic error observed in these, and, less extremely, in other transition-metal complex cry

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18

JACOBS, H., R. NIEWA, T. SICHLA, A. TENTEN, and U. ZACHWIEJA. "ChemInform Abstract: Metal Nitrogen Compounds with Unusual Chemical Bonding: Nitrides, Imides, Amides, and Ammine Complexes." ChemInform 28, no. 24 (2010): no. http://dx.doi.org/10.1002/chin.199724284.

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19

Galešić, N., and V. M. Leovac. "Transition-metal complexes with thiosemicarbazide-based ligands. VIII. Structure of ammine(benzoylacetoneS-methylisothiosemicarbazonato)nickel(II) iodide." Acta Crystallographica Section C Crystal Structure Communications 45, no. 5 (1989): 745–47. http://dx.doi.org/10.1107/s0108270188013897.

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20

Möller, Angela, and Gerd Meyer. "The ammonium ion and the ammine ligand as internal reducing agents for platinum-group-metal complexes." Thermochimica Acta 210 (November 1992): 147–50. http://dx.doi.org/10.1016/0040-6031(92)80284-4.

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21

Chia, Peter S. K., Leonard F. Lindoy, Glen W. Walker, and Grover W. Everett. "Supramolecular transport of metal ammine and amine complexes through chloroform membranes by the natural ionophore lasalocid A. The selective enantiomeric transport of chiral metal complexes." Journal of the American Chemical Society 113, no. 7 (1991): 2533–37. http://dx.doi.org/10.1021/ja00007a030.

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22

Kahani, S. A., and H. Molaei. "Synthesis of nickel metal nanoparticles via a chemical reduction of nickel ammine and alkylamine complexes by hydrazine." Journal of the Iranian Chemical Society 10, no. 6 (2013): 1263–70. http://dx.doi.org/10.1007/s13738-013-0267-8.

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23

CHIA, P. S. K., L. F. LINDOY, G. W. WALKER, and G. W. EVERETT. "ChemInform Abstract: Supramolecular Transport of Metal Ammine and Amine Complexes Through Chloroform Membranes by the Natural Ionophore Lasalocid A. The Selective Enantiomeric Transport of Chiral Metal Complexes." ChemInform 22, no. 28 (2010): no. http://dx.doi.org/10.1002/chin.199128045.

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24

Li, Long, Yuyang He, Zhe Zhang, and Yun Liu. "Nitrogen isotope fractionations among gaseous and aqueous NH4+, NH3, N2, and metal-ammine complexes: Theoretical calculations and applications." Geochimica et Cosmochimica Acta 295 (February 2021): 80–97. http://dx.doi.org/10.1016/j.gca.2020.12.010.

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25

Weit, Scott K., and Charles Kutal. "Contrasting reactivities of ligand-to-metal charge transfer excited states in ammine and methylamine complexes of cobalt(III)." Inorganic Chemistry 29, no. 8 (1990): 1455–56. http://dx.doi.org/10.1021/ic00333a001.

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26

Sakane, Hideto, Takafumi Miyanaga, Iwao Watanabe, and Yu Yokoyama. "EXAFS Amplitudes of Six-Coordinate Aqua and Ammine 3d Transition Metal Complexes in Solids and in Aqueous Solutions." Chemistry Letters 19, no. 9 (1990): 1623–26. http://dx.doi.org/10.1246/cl.1990.1623.

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27

Yaskelchyk, V. V., I. M. Zharsky, and A. A. Chernik. "Kinetic specifics of electrochemical deposition of copper on in citrate-ammonia copper plating electrolyte." Proceedings of the National Academy of Sciences of Belarus, Chemical Series 60, no. 4 (2024): 290–99. https://doi.org/10.29235/1561-8331-2024-60-4-290-299.

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The practice of electrochemical research is inevitably associated with the need to study the kinetic features of the metal electrocrystallization process on a foreign or its own surface. The process of copper electrolytic deposition on a steel substrate (steel 3) from a citrate-ammonia copper plating electrolyte was studied, which includes (g / l): CuSOO – 100; (NH4)2SO4 – 120; citric acid (C6H8O7) – 53, NaOH – up to pH = 8.0. The uniqueness of the above electrolyte is that electrolytic copper plating of steel can be carried out without applying a preliminary sublayer (for example, nickel, 3 μ

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28

Newton, Marshall D. "Comparison of electron-transfer matrix elements for transition-metal complexes: t2g vs. eg transfer and ammine vs. aqua ligands." Journal of Physical Chemistry 90, no. 16 (1986): 3734–39. http://dx.doi.org/10.1021/j100407a047.

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29

Johannessen, Tue, Henning Schmidt, Anne Mette Frey, and Claus Hviid Christensen. "Improved Automotive NO x Aftertreatment System: Metal Ammine Complexes as NH3 Source for SCR Using Fe-Containing Zeolite Catalysts." Catalysis Letters 128, no. 1-2 (2009): 94–100. http://dx.doi.org/10.1007/s10562-008-9809-6.

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30

Castillo, Ezer, and Nikolay Dimitrov. "Electrodeposition of Cu-Mn Films as Precursor Alloys for the Synthesis of Nanoporous Cu." Electrochem 2, no. 3 (2021): 520–33. http://dx.doi.org/10.3390/electrochem2030033.

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Cu-Mn alloy films are electrodeposited on Au substrates as precursor alloys for the synthesis of fine-structured nanoporous Cu structures. The alloys are deposited galvanostatically in a solution containing ammonium sulfate, (NH4)2SO4, which serves as a source of the ammine ligand that complexes with Cu, thereby decreasing the inherent standard reduction potential difference between Cu and Mn. The formation of the [Cu(NH3)n]2+ complex was confirmed by UV-Vis spectroscopic and voltammetric studies. Galvanostatic deposition at current densities ranging from 100 to 200 mA⋅cm−2 generally resulted

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31

Roy, Sudipta, and Christine Tambe. "Electrodeposition of Copper from a Cu(I) Electrolyte in an Bespoke Reactor." ECS Meeting Abstracts MA2025-01, no. 24 (2025): 1446. https://doi.org/10.1149/ma2025-01241446mtgabs.

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Electronic waste is considered one of the fastest growing solid wastes due to the shortening service lifespan of electronic products and their increased consumption [1]. Currently, there are major gaps in volume of copper produced and recovered in numerous countries worldwide. With copper being a critical material for electrical and electronic components, governments are trying to develop a circular economy for copper, based on the exploitation of resources recovered from wastes, such as printed circuit boards (PCBs) as they contain a significant portion of the value embedded into e-wastes [2]

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32

Roy, Sudipta, Bailie Morrison, and Todd Green. "Copper Electrodeposition from Ammoniacal Electrolytes." ECS Meeting Abstracts MA2025-01, no. 23 (2025): 1408. https://doi.org/10.1149/ma2025-01231408mtgabs.

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Abstract Electronic waste is considered one of the fastest growing solid wastes due to shortening service lifespan of electronic products and their increased consumption [1]. Currently, there are major gaps in volume of copper produced and recovered in numerous countries worldwide (Wang et al., 2021). Copper being a critical material for electrical and electronic components, governments are trying to develop a circular economy for copper, based on the exploitation of resources recovered from wastes, such as printed circuit boards (WPCBs) as they contain a significant portion of the value embed

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33

Meske, Wilmar, and Dietrich Babel. "Kristallstrukturen von Octacyanomolybdaten(IV). V. Quadratisch-antiprismatische [Mo(CN)8]-Koordination in den cyanoverbrückten Kupfer- und Cadmium-Amminkomplexen Cu2(NH3)8[Mo(CN)8] und Cd2(NH3)6[Mo(CN)8]·H2O/Crystal Structures of Octacyanomolybdates(IV). V. Square Antiprismatic [Mo(CN)8]-Coordination of the Cyano-Bridged Copper and Cadmium Ammine Complexes Cu2(NH3)8[Mo(CN)8] and Cd2(NH3)6[Mo(CN)8]·H2O." Zeitschrift für Naturforschung B 54, no. 1 (1999): 117–22. http://dx.doi.org/10.1515/znb-1999-0122.

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At single crystals of the cyano complexes Cu2(NH3)8[Mo(CN)8] (a = 934.1(4), b = 1595.9(3), c = 1391.9(4) pm, β = 90.57(2)°, monoclinic space group Cc, Z = 4) and Cd2(NH3)6[Mo(CN)8]·H2O (a = 1708.7(12), b = 1307.8(4), c = 942.9(3) pm, orthorhombic space group Pna21, Z = 4) X-ray structure determinations were performed at temperatures of about 175 K. Both compounds, prepared at about 275 K in aqueous ammonia solutions and easily decomposing, exhibit distorted square antiprismatic [Mo(CN)8]4- coordination of closely resembling dimensions (mean distances Mo-C: 215.7 and 215.3 pm, resp.). The anion

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34

Bakalova, Adriana G., Rossen T. Buyukliev, Rositsa P. Nikolova, Boris L. Shivachev, Rositsa A. Mihaylova, and Spiro M. Konstantinov. "Synthesis, Spectroscopic Properties, Crystal Structure And Biological Evaluation of New Platinum Complexes with 5-methyl-5-(2-thiomethyl)ethyl Hydantoin." Anti-Cancer Agents in Medicinal Chemistry 19, no. 10 (2019): 1243–52. http://dx.doi.org/10.2174/1871520619666190214103345.

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Background: The accidental discovery of Cisplatin’s growth-inhibiting properties a few decades ago led to the resurgence of interest in metal-based chemotherapeutics. A number of well-discussed factors such as severe systemic toxicity and unfavourable physicochemical properties further limit the clinical application of the platinating agents. Great efforts have been undertaken in the development of alternative platinum derivatives with an extended antitumor spectrum and amended toxicity profile as compared to the reference drug cisplatin. The rational design of conventional platinum analogues

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35

Sellmann, Dieter, Joachim Kaeppler, Matthias Moll, and Falk Knoch. "Transition metal complexes with sulfur ligands. 95. Diazene, hydrazine, ammine and azido complexes with sulfur dominated [Ru(PPh3)('buS4')] fragments ('buS4'2- = 1,2-bis(2-mercapto-3,5-di-tert-butylphenylthio)ethanato(2-))." Inorganic Chemistry 32, no. 6 (1993): 960–64. http://dx.doi.org/10.1021/ic00058a035.

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36

Ashmawy, Fathy M., Mohamed Y. El-Sheikh, Ibrahim A. Salem, and Ahmed B. Zaki. "The catalytic effect of transition metal-ion ammine complexes on the decomposition of hydrogen peroxide in the presence of Dower-50W resin in aqueous medium." Transition Metal Chemistry 12, no. 1 (1987): 51–55. http://dx.doi.org/10.1007/bf01023132.

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37

Leovac, Vukadin M., Valerija I. Češljević, Nikolai V. Gerbeleu, Yuri A. Simonov, Aleksandar A. Dvorkin, and Vladimir B. Arion. "Transition metal complexes with the thiosemicarbazide-based ligands. Part 12. Synthesis, structure and template reaction of ammine [2,4-pentane-dione S-methylisothiosemicarbazonato(2-)] nickel(II) dihydrate." Transition Metal Chemistry 18, no. 3 (1993): 309–11. http://dx.doi.org/10.1007/bf00207953.

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38

TAGASHIRA, Shoji, Tatsuya ICHIMARU, Kouji NOZAKI, and Yoshiko MURAKAMI. "Surfactant Gel Extraction of Metal Ammine Complexes using SDS and KCl at Room Temperature, and a Small-angle X-ray Diffraction Study of the Surfactant Phase." Solvent Extraction Research and Development, Japan 20 (2013): 39–52. http://dx.doi.org/10.15261/serdj.20.39.

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39

Gröning, Östen, Alan M. Sargeson, Robert J. Deeth, and Lars I. Elding. "Kinetics and Mechanism for Reversible Chloride Transfer between Mercury(II) and Square-Planar Platinum(II) Chloro Ammine, Aqua, and Sulfoxide Complexes. Stabilities, Spectra, and Reactivities of Transient Metal−Metal Bonded Platinum−Mercury Adducts." Inorganic Chemistry 39, no. 19 (2000): 4286–94. http://dx.doi.org/10.1021/ic000320j.

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40

Castillo, Ezer, and Nikolay Dimitrov. "Electrodeposition of Cu-Zn and Cu-Mn Films As Precursors for Nanoporous Copper Synthesis." ECS Meeting Abstracts MA2022-01, no. 22 (2022): 1118. http://dx.doi.org/10.1149/ma2022-01221118mtgabs.

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An all-electrochemical approach for the synthesis of fine-structured nanoporous copper (np-Cu) films has been developed which involves the initial electrodeposition of Cu-containing alloys followed by a selective dissolution or dealloying of the less noble metal via anodization. This process leaves a nanoporous, three-dimensional spongy structure. Among these alloys are Cu-Zn and Cu-Mn that are commonly used as protective and decorative coatings. These types of coatings are typically rich in Cu; however, precursor alloys for dealloying purposes must contain high atomic percentages (at%) of the

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41

Kujirai, O., and Kei Yamada. "Application of cobalt ammine complexes for the simultaneous determination of traces of As, Fe, Ti, V and Zr in high-purity cobalt metal by lanthanum hydroxide coprecipitation and inductively coupled plasma-atomic emission spectrometry." Analytical and Bioanalytical Chemistry 354, no. 4 (1996): 428–31. http://dx.doi.org/10.1007/s0021663540428.

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42

Müller, Matthias, and Magnus R. Buchner. "Preparation and crystal structures of the beryllium ammines [Be(NH3)4]X2 (X = Br, I, CN, SCN, N3) and Be(NH3)2X'2 (X' = Cl, Br, I)." Chemical Communications 55, no. 91 (2019): 13649–52. http://dx.doi.org/10.1039/c9cc07712j.

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43

Young, Dianna M., George L. Schimek, and Joseph W. Kolis. "Synthesis and Characterization of [Yb(NH3)8][Cu(S4)2]·NH3, [Yb(NH3)8][Ag(S4)2]·2NH3, and [La(NH3)9][Cu(S4)2] in Supercritical Ammonia: Metal Sulfide Salts of the First Homoleptic Lanthanide Ammine Complexes." Inorganic Chemistry 35, no. 26 (1996): 7620–25. http://dx.doi.org/10.1021/ic9601403.

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44

TEBBE, K. F., та T. GILLES. "ChemInform Abstract: Studies of Polyhalides. Part 37. Heptaiodides(3-) of Ammine Complexes of Chromium and Cobalt: Hexamminechromium(III) Heptaiodide [Cr(NH3)6](I3)(I4) and the Tri-μ-hydroxo-bis[metal(III)-triammine] Heptaiodides [(NH3)3M(OH)3M(NH3)3] (I3". ChemInform 30, № 3 (2010): no. http://dx.doi.org/10.1002/chin.199903019.

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YOUNG, D. M., G. L. SCHIMEK, and J. W. KOLIS. "ChemInform Abstract: Synthesis and Characterization of (Yb(NH3)8)(Cu(S4)2)×NH3 (I), ( Yb(NH3)8)(Ag(S4)2)×2 NH3 (II), and (La(NH3)9)(Cu(S4)2) (III) in Supercritical Ammonia: Metal Sulfide Salts of the First Homoleptic Lanthanide Ammine Complexes." ChemInform 28, no. 12 (2010): no. http://dx.doi.org/10.1002/chin.199712002.

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Upadhyay, Raj Kumar, Arun K. Bajpai, and Kamlesh Rathore. "Chemistry of the phenylglyoxal-p-diethylaminoanil and/or thiourea substituted ammine complexes." Transition Metal Chemistry 10, no. 1 (1985): 24–27. http://dx.doi.org/10.1007/bf00620627.

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dos Santos Silva, Hildo Antonio, Bruce R. McGarvey, Regina Helena de Almeida Santos, Mauro Bertotti, Vânia Mori, and Douglas Wagner Franco. "Sulfate as a ligand in ruthenium(II) and (III) ammines." Canadian Journal of Chemistry 79, no. 5-6 (2001): 679–87. http://dx.doi.org/10.1139/v01-036.

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The trans-[RuSO4(NH3)4(L)]Cl complexes, (L = nicotinamide (nia), L-histidine (L-hist), 4-picoline (4-pic), 4-chloropyridine (4-Clpy), isonicotinamide (isn), pyrazine (pyz), 4-aminopyridine (4-NH2py), 4-cyanopyridine (4-CNpy), pyridine (py), imidazole (Him), and water (H2O)), were characterized by elemental analysis cyclic voltammetry, UV-vis, IR, and electron paramagnetic resonance spectroscopies. From the four ν (SO42) observed only ν3 and ν4 split in two bands each for the sulfate unidentate coordination. The values of Δ/ξ parameters, extracted from g values, allow us to write the following

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Reithofer, Michael R., Markus Galanski, Vladimir B. Arion, and Bernhard K. Keppler. "Unprecedented twofold intramolecular hydroamination in diam(m)ine-dicarboxylatodichloridoplatinum(iv) complexes – ethane-1,2-diamine vs. ammine ligands." Chemical Communications, no. 9 (2008): 1091. http://dx.doi.org/10.1039/b715680d.

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Harman, W. Dean, and Henry Taube. ".pi.-Localization in aromatic ligands: formation of mixed-metal .eta.2:.eta.2-.mu.-arene complexes of ruthenium(II) and osmium(II) ammines." Journal of the American Chemical Society 110, no. 22 (1988): 7555–57. http://dx.doi.org/10.1021/ja00230a056.

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Tebbe, Karl-Friedrich, та Theo Gilles. "Untersuchungen an Polyhalogeniden, XXXVII [1]. Heptaiodide(3-) von Amminkomplexen des Chroms und Cobalts: Hexamminchrom(III)heptaiodid [Cr(NH3)6](I3)(I4) und die Tri-μ-hydroxo-bis[metall(III)-triammin]heptaiodide [(NH3)3 M(OH)3M(NH3)3](I3)2I mit M = Co, Cr / Studies o f Polyhalides, XXXVII [1]. Heptaiodides(3-) of Ammine Complexes of Chromium and Cobalt: Hexamminechromium(III) heptaiodide [Cr(NH3)6](I3)(I4) and the Tri-μ-hydroxo-bis[metal(III)-triammine] heptaiodides [(NH3)3M(OH)3M(NH3)3](I3)2I with M = Co, Cr". Zeitschrift für Naturforschung B 53, № 10 (1998): 1127–34. http://dx.doi.org/10.1515/znb-1998-1008.

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AbstractThe new compounds [Cr(NH3)6](I3)(I4) and [(NH3)3M(OH)3M(NH3)3](I3)2I with M = Cr, Co have been prepared by the reaction of [M(NH3)6]X3 (M = Cr, Co; X = Cl, I, NO3), KI, and I2 in water under controlled stoichiometric and pH conditions. The first compound is isotypic with the cobalt compound of the same composition. It crystallizes in the monoclinic space group I2/m with a = 984.7(3), b = 786.6(1), c = 1330.1(3) pm, β = 95.34(2)° and Z = 2 and contains nearly octahedral cations [Cr(NH3)6]3+, a linear triiodide ion I3- and a tetraiodide ion I42-. The two other compounds are isotypic. The

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