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Relevant bibliographies by topics / Metal atom chemistry

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Academic literature on the topic 'Metal atom chemistry'

Author: Grafiati

Published: 4 June 2021

Last updated: 2 February 2022

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Journal articles on the topic "Metal atom chemistry"

1

Boudalis, Athanassios K., Vassilios Nastopoulos, Aris Terzis, Catherine P. Raptopoulou, and Spyros P. Perlepes. "Reaction between Yttrium Nitrate and 2,2':6',2"-Terpyridine (terpy) in MeCN: Preparation, Crystal Structures and Spectroscopic Characterization of [Y (NO3)3(terpy)(H2O )] and [Y(NO3)3(terpy)(H2O )] · terpy · 3 MeCN." Zeitschrift für Naturforschung B 56, no. 2 (2001): 122–28. http://dx.doi.org/10.1515/znb-2001-0202.

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Abstract The reaction of Y(NO3)3 · 5H2O and 2,2':6',2"-terpyridine (terpy) in MeCN leads to [Y(N03 )3(terpy)(H2O )] (1) and [Y(N03 )3(terpy)(H2O )] terpy-3MeCN (2) in good yields depending on the isolation conditions. The structures of both complexes were determined by single-crystal X-ray crystallography. The YIII atom in 1 is 9-coordinate and ligation is provided by one terdentate terpy molecule, two chelating nitrates, one monodentate nitrate and one terminal H2O molecule; the coordination polyhedron about the metal may be viewed as a tricapped trigonal prism. The YIII atom in 2 is 10-coord

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Melnik, Milan, Markku Rafael Sundberg, and Rolf Uggla. "Analysis of crystallographic and structural data of polymeric iron-alkaline metal complexes." Main Group Metal Chemistry 34, no. 5-6 (2011): 93–126. http://dx.doi.org/10.1515/mgmc-2012-0900.

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Abstract The present review covers almost 100 polymeric MFe (M=Li, Na, K, Rb, and Cs) compounds. The metal atoms of group 1 as partners with iron atom build up complex polymeric chains. The iron atoms are found in the oxidation states 0, +2, and +3, of which the oxidation state +3 prevails. The coordination number of the iron atom ranges from 2 to 10 (sandwiched). The coordination sphere about the main group 1 metals varies, ranging from tetrahedral to mostly trigonal bipyramid. There are also higher coordination numbers involved, namely, from 6 to 10. The most common ligand atoms are oxygen a

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Cabeza, Javier A., Ignacio del Río, Pablo García-Álvarez, and Daniel Miguel. "Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine Novel coordination modes for 2-imidopyridines." Canadian Journal of Chemistry 84, no. 2 (2006): 105–10. http://dx.doi.org/10.1139/v05-228.

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The hexanuclear ruthenium cluster [Ru6(µ3-H)2(µ-H)2(µ4-κ2-ampy)2(CO)14] (1) and the octanuclear one [Ru8(µ-H)(µ4-κ2-ampy)3(µ3-κ2-Hampy)(µ-CO)2(CO)15] (2) have been prepared by treating [Ru6(µ3-H)2(µ5-κ2-ampy)(µ-CO)2(CO)14] with 2-amino-6-methylpyridine (H2ampy) in decane at reflux temperature. Their metal atoms are supported by ligands that derive from the activation of one (complex 2) or both NH bonds (complexes 1 and 2) of the H2ampy amino fragment. Both contain at least one ampy ligand featuring an unprecedented coordination type: the imido N atom caps a triangle of metal atoms while the p

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Zhao, Lili, Chaoqun Chai, Wolfgang Petz, and Gernot Frenking. "Carbones and Carbon Atom as Ligands in Transition Metal Complexes." Molecules 25, no. 21 (2020): 4943. http://dx.doi.org/10.3390/molecules25214943.

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This review summarizes experimental and theoretical studies of transition metal complexes with two types of novel metal-carbon bonds. One type features complexes with carbones CL2 as ligands, where the carbon(0) atom has two electron lone pairs which engage in double (σ and π) donation to the metal atom [M]⇇CL2. The second part of this review reports complexes which have a neutral carbon atom C as ligand. Carbido complexes with naked carbon atoms may be considered as endpoint of the series [M]-CR3 → [M]-CR2 → [M]-CR → [M]-C. This review includes some work on uranium and cerium complexes, but i

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Severin, Kay. "Synthetic chemistry with nitrous oxide." Chemical Society Reviews 44, no. 17 (2015): 6375–86. http://dx.doi.org/10.1039/c5cs00339c.

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Nitrous oxide (N<sub>2</sub>O, ‘laughing gas’) is a very inert molecule. Still, it can be used as a reagent in synthetic organic and inorganic chemistry, serving as O-atom donor, as N-atom donor, or as a oxidant in metal-catalyzed reactions.

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Joly, Helen A., Maria Kepes, Natalie Roy, and Jason Prpic. "The reactivity of the high-energy intermediates formed in the reactions of Group 13 metal atoms and aromatic alkenes." Canadian Journal of Chemistry 76, no. 4 (1998): 400–406. http://dx.doi.org/10.1139/v98-033.

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Group 13 metal atoms were reacted with aromatic alkenes in a specialized metal atom reactor known as a "rotating cryostat." The nature of the intermediates formed was deduced from a GC-MS study of their hydrolysis and deuterolysis products. The product studies suggest that 2-phenylaluminacyclopropane, cis- and trans-3,4-diphenylaluminacyclopentane, and cis- and trans- 2,4-diphenylaluminacyclopentane are formed when Al atoms react with styrene, and 2-methyl-2-phenylaluminacyclopropane and 3,4-dimethyl- 3,4-diphenylaluminacyclopentane are formed when Al atoms react with α -methylstyrene. These f

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Scharfe, Sandra, and Thomas F. Fässler. "Polyhedral nine-atom clusters of tetrel elements and intermetalloid derivatives." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 368, no. 1915 (2010): 1265–84. http://dx.doi.org/10.1098/rsta.2009.0270.

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Homoatomic polyanions have the basic capability for a bottom-up synthesis of nanostructured materials. Therefore, the chemistry and the structures of polyhedral nine-atom clusters of tetrel elements [E 9 ] 4− is highlighted. The nine-atom Zintl ions are available in good quantities for E = Si–Pb as binary alkali metal (A) phases of the composition A 4 E 9 or A 12 E 17 . Dissolution or extraction of the neat solids with aprotic solvents and crystallization with alkali metal-sequestering molecules or crown ethers leads to a large variety of structures containing homoatomic clusters with up to 45

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Hulva, Jan, Matthias Meier, Roland Bliem, et al. "Unraveling CO adsorption on model single-atom catalysts." Science 371, no. 6527 (2021): 375–79. http://dx.doi.org/10.1126/science.abe5757.

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Understanding how the local environment of a “single-atom” catalyst affects stability and reactivity remains a challenge. We present an in-depth study of copper1, silver1, gold1, nickel1, palladium1, platinum1, rhodium1, and iridium1 species on Fe3O4(001), a model support in which all metals occupy the same twofold-coordinated adsorption site upon deposition at room temperature. Surface science techniques revealed that CO adsorption strength at single metal sites differs from the respective metal surfaces and supported clusters. Charge transfer into the support modifies the d-states of the met

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Chen, Taoyi, and Thomas A. Manz. "A collection of forcefield precursors for metal–organic frameworks." RSC Advances 9, no. 63 (2019): 36492–507. http://dx.doi.org/10.1039/c9ra07327b.

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Atom-in-material (AIM) partial charges, dipoles and quadrupoles, dispersion coefficients (C<sub>6</sub>, C<sub>8</sub>, C<sub>10</sub>), polarizabilities, electron cloud parameters, radial moments, and atom types were extracted from quantum chemistry calculations for >3000 MOFs.

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Klabunde, Kenneth J., Yong Xi Li, and Beng Jit Tan. "Solvated metal atom dispersed catalysts." Chemistry of Materials 3, no. 1 (1991): 30–39. http://dx.doi.org/10.1021/cm00013a013.

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Dissertations / Theses on the topic "Metal atom chemistry"

1

Tovey, R. C. "Studies in metal vapour synthesis." Thesis, University of Oxford, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.375325.

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Ren, Wendong. "Photoinduced Atom Transfer Radical Polymerization." University of Akron / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=akron1619122320374689.

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Harris, Neil. "A matrix isolation study of main group and transition metal atom cryochemistry." Thesis, University of Hull, 2001. http://hydra.hull.ac.uk/resources/hull:12359.

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The majority of the work described in this thesis is concerned with the isolation of transition metal and main group atoms in dilute reactive ligand matrices. The previously uncharacterised matrix isolated species were characterised using IR, UV-Vis-NIR and XAFS spectroscopic techniques. Various metal atom sources were investigated for the production and subsequent isolation of atomic species in both inert and reactive ligand matrices. Some 4d and 5d transition metals atoms were produced from a hollow cathode sputtering source (laser ablation was also employed as an atom source in some of the

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Yassine, T. "The hot atom chemistry of some metal complexes and its application to radio isotope production." Thesis, University of Salford, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.381739.

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King, Evan. "Metal-Ligand Multiple Bonds in High-Spin Complexes." Thesis, Harvard University, 2012. http://dissertations.umi.com/gsas.harvard:10356.

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The chemistry of late first row transition metals supported by dipyrromethane and dipyrromethene ligands bearing sterically bulky substituents was explored. Transition metal complexes (Mn, Fe, Co, Ni, Zn) of the dipyrromethane ligand 1,9-dimesityl-5,5-dimethyldipyrromethane (dpma) were prepared. Structural and magnetic characterization (SQUID, EPR) of the bis-pyridine adducts \((dpma)Mn(py)_2\), \((dpma)Fe(py)_2\), and \((dpma)Co(py)_2\) showed each tetrahedral divalent ion to be high-spin, while square planar \((dpma)Ni^{II}(py)_2\) and tetrahedral \((dpma)Zn(py)_2\) were shown to be diamagne

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Dioses, Castro Silvio, and Richard Korswagen. "Over the possible role of metal atom clusters in cosmochemistry and in the origin of life." Revista de Química, 2013. http://repositorio.pucp.edu.pe/index/handle/123456789/100714.

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We present here the hypothesis of a possible relationship between metal atom clusters and the formation of organic molecules in the interstellar medium and on small bodies as a possible pathway to the origin of such molecules. Two distinct stages are díscussed: a) the possible formation and presence of atom clusters in space and on the primitive Earth, and b) the synthesis of interstellar and terrestrial prebiotic organic molecules, a process in which metalclusters could be the active catalysts. The confirmatíon of these suggestions might be very important in arder to explain the presence of e

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Ozcan, Gurbetoglu Pelin Gulistan. "Determination Of Cadmium Using Slotted Quartz Tube Atom Trap Atomic Absorption Spectrometry And Metal Coatings." Master's thesis, METU, 2010. http://etd.lib.metu.edu.tr/upload/12612212/index.pdf.

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ABSTRACT DETERMINATION OF CADMIUM USING SLOTTED QUARTZ TUBE ATOM TRAP ATOMIC ABSORPTION SPECTROMETRY AND METAL COATINGS &Ouml<br>zcan Gurbetoglu, G. Pelin M.S., Department of Chemistry Supervisor: Prof. Dr. O. Yavuz Ataman July 2010, 76 pages Flame atomic absorption spectroscopy (FAAS) is a common technique for detecting metals and metalloids in environmental, biological and metallurgical samples. Although it is a rather old technique, it is still very reliable, simple to use and inexpensive. The technique can be used to determine the concentration of over 70 different metals in a soluti

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Demirtas, Ilknur. "Lead Determination By Flame Atomic Absorption Spectrometry Using A Slotted Quartz Tube Atom Trap And Metal Coatings." Master's thesis, METU, 2009. http://etd.lib.metu.edu.tr/upload/3/12610794/index.pdf.

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Flame Atomic Absorption Spectrometry (FAAS) still keeps its importance despite the relatively low sensitivity<br>because it is a simple and economical technique for determination of metals. In recent years atom traps have been developed to increase the sensitivity of FAAS. Although the detection limit of FAAS is only at the level of mg/L, with the use of atom traps it can reach to ng/mL. Slotted quartz tube (SQT) is one of these atom traps, it is applied for determination of volatile elements<br>it is economical, commercially available and easy to use. In this study, a sensitive analytical met

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Osmanbasoglu, Mahmut. "Tellurium Determination By Flame Atomic Absorption Spectrometry Using A Slotted Quartz Tube Atom Trap And Metal Coatings." Master's thesis, METU, 2011. http://etd.lib.metu.edu.tr/upload/12613029/index.pdf.

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Flame Atomic Absorption Spectroscopy (FAAS) has lover sensitivity than similar analytical methods, however it has an important place for analysis due to its easy application and economic practicability especially in metal determinations. In order to increase the sensitivity of FAAS from mg/L level to ng/L level, various atom trap systems have been used. One of these atom traps, Slotted Quartz Tube (SQT), which is easy, economical and useful for volatile element determination, is used in this study as a sensitive analytical method for determination of tellurium. In the study, determination of T

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O'Hare, D. M. "Activation of carbon hydrogen bonds by metal atoms." Thesis, University of Oxford, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.355789.

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Books on the topic "Metal atom chemistry"

1

Yassine, Taufik. The hot atom chemistry of some metal complexes and its application to radio isotope production. University of Salford, 1987.

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2

Martin, T. P. Large Clusters of Atoms and Molecules. Springer Netherlands, 1996.

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3

Sugano, Satoru. Microcluster physics. 2nd ed. Springer, 1998.

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Sugano, Satoru. Microcluster physics. Springer-Verlag, 1991.

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5

Coskuner, Orkid, Thomas Clayton Allison, and Carlos A. González. Metallic systems: A quantum chemist's perspective. Taylor & Francis, 2011.

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6

Clusters of Atoms and Molecules: Theory, Experiment, and Clusters of Atoms. Brand: Springer, 2011.

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7

1939-, Haberland Hellmut, ed. Clusters of atoms and molecules: Theory, experiment, and clusters of atoms. Springer-Verlag, 1994.

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8

Li, Wai-Kee, Hung Kay Lee, Dennis Kee Pui Ng, Yu-San Cheung, Kendrew Kin Wah Mak, and Thomas Chung Wai Mak. Problems in Structural Inorganic Chemistry. Oxford University Press, 2018. http://dx.doi.org/10.1093/oso/9780198823902.001.0001.

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The First Edition of this book, which appeared in 2013, serves as a problem text for Part I (Fundamentals of Chemical Bonding) and Part II (Symmetry in Chemistry) of the book Advanced Structural Inorganic Chemistry published by Oxford University Press in 2008. A Chinese edition was published by Peking University Press in August in the same year. Since then the authors have received much feedback from users and reviewers, which prompted them to prepare a Second Edition for students ranging from freshmen to senior undergraduates who aspire to attend graduate school after finishing their first de

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1939-, Haberland Hellmut, ed. Clusters of atoms and molecules II: Solvation and chemistry of free clusters, and embedded, supported, and compressed clusters. Springer-Verlag, 1994.

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10

Yuryea, Elmira I. Quantum Chemistry and Nuclear Resonance Spectroscopy Data of Natural and Synthetic Nanotechnological Materials With Nd-metal Atoms Participations. Nova Science Pub Inc, 2007.

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Book chapters on the topic "Metal atom chemistry"

1

Creutz, Carol. "Intrinsic Barriers to Atom Transfer Between Transition-Metal Centers." In Advances in Chemistry. American Chemical Society, 1997. http://dx.doi.org/10.1021/ba-1997-0253.ch009.

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2

Osakada, Kohtaro. "Chapter 11. Chemistry of Transition Metal Complexes with Group 16 Elements: Transition Metal Complexes with Two Lone Pairs of Electrons on the Coordinating Atom." In Organometallic Chemistry. Royal Society of Chemistry, 2021. http://dx.doi.org/10.1039/9781839164200-00203.

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Matsuzaka, Hiroyuki, and Tsutomu Mizuta. "Chapter 10. Chemistry of Transition Metal Complexes with Group 15 Elements: Transition Metal Complexes with One Lone Pair of Electrons on the Coordinating Atom." In Organometallic Chemistry. Royal Society of Chemistry, 2021. http://dx.doi.org/10.1039/9781839164200-00176.

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Strich, Alain. "A Miscellany of AB Initio Quantum Chemistry the Helium Atom Studied by Various Methods." In Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules. Experiment and Theory. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2698-4_17.

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Riley, S. J. "The Chemistry of Transition Metal Clusters." In Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2822-3_2.

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Jeung, G. H. "Scandium Atom Interacting with Diatomic Groups." In Quantum Chemistry: The Challenge of Transition Metals and Coordination Chemistry. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4656-9_8.

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Dedieu, A., C. Bo, and F. Ingold. "Carbon Dioxide Organometallic Chemistry: Theoretical Developments." In Metal-Ligand Interactions: From Atoms, to Clusters, to Surfaces. Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2822-3_9.

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Gingerich, K. A. "The Maximum Strength of the Chemical Bond between Two Metal Atoms." In Metal-Metal Bonds and Clusters in Chemistry and Catalysis. Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-2492-6_28.

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Li, Jin‑Cheng, Zidong Wei, Dong Liu, Dan Du, Yuehe Lin, and Minhua Shao. "Dispersive Single‑Atom Metals Anchored on Functionalized Nanocarbons for Electrochemical Reactions." In Topics in Current Chemistry Collections. Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-030-43294-2_5.

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Sachtler, W. M. H. "Transition Metal Clusters and Isolated Atoms in Zeolite Cages." In Chemistry and Physics of Solid Surfaces VIII. Springer Berlin Heidelberg, 1990. http://dx.doi.org/10.1007/978-3-642-75762-4_5.

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Conference papers on the topic "Metal atom chemistry"

1

Lu, Junqing. "Numerical estimates of metal atom energy in reactive sputter deposition of TiN and TaN thin films." In THE 6TH INTERNATIONAL CONFERENCE ON SCIENCE & ENGINEERING IN MATHEMATICS, CHEMISTRY AND PHYSICS: ScieTech18: The Nature Math - The Science. Author(s), 2018. http://dx.doi.org/10.1063/1.5080020.

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Watson, Isaac, Angelika Sebald, and Susan Stepney. "A Meta-Atom Based Sub-Symbolic Artificial Chemistry." In The 2019 Conference on Artificial Life. MIT Press, 2019. http://dx.doi.org/10.1162/isal_a_00151.

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Watson, Isaac, Angelika Sebald, and Susan Stepney. "A Meta-Atom Based Sub-Symbolic Artificial Chemistry." In The 2019 Conference on Artificial Life. MIT Press, 2019. http://dx.doi.org/10.1162/isal_a_00151.xml.

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Majid, Abdul, and Suyono Suyono. "Misconception Analysis Based On Students Mental Model In Atom Structure Materials." In Seminar Nasional Kimia - National Seminar on Chemistry (SNK 2018). Atlantis Press, 2018. http://dx.doi.org/10.2991/snk-18.2018.53.

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Sitorus, Berlian, Charlotte Pughe, Arin Mizouri, Andrew M. Ellis, and Shengfu Yang. "Ion-molecule reactions of organic molecules with noble metal atoms in superfluid helium droplets." In THE 3RD INTERNATIONAL SEMINAR ON CHEMISTRY: Green Chemistry and its Role for Sustainability. Author(s), 2018. http://dx.doi.org/10.1063/1.5082471.

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Gildenast, Hans, Franziska Busse, and Ulli Englert. "Competition of the Donor Atoms - Coordination Chemistry of a O,P,N tritopic Ligand - Complexes, Supramolecules and Metal-Organic Frameworks." In The 2nd International Online Conference on Crystals. MDPI, 2020. http://dx.doi.org/10.3390/iocc_2020-07321.

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