Academic literature on the topic 'Metal Catalysed Coupling'

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Journal articles on the topic "Metal Catalysed Coupling"

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Steven, Alan. "Micelle-Mediated Chemistry in Water for the Synthesis of Drug Candidates." Synthesis 51, no. 13 (2019): 2632–47. http://dx.doi.org/10.1055/s-0037-1610714.

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Micellar reaction conditions, in a predominantly aqueous medium, have been developed for transformations commonly used by synthetic chemists working in the pharmaceutical industry to discover and develop drug candidates. The reactions covered in this review are the Suzuki–Miyaura, Miyaura borylation, Sonogashira coupling, transition-metal-catalysed CAr–N coupling, SNAr, amidation, and nitro reduction. Pharmaceutically relevant examples of these applications will be used to show how micellar conditions can offer advantages in yield, operational ease, amount of waste generated, transition-metal
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Guangqing, Zhang, Shenjun Qin, Li Zhen, Han Haiyan, Li Hui, and Tao Chang. "Coupling reaction of epoxide and carbon dioxide catalysed by alkali metal salts in the presence of ß-cyclodextrin derivatives." World Journal of Engineering 14, no. 2 (2017): 159–64. http://dx.doi.org/10.1108/wje-12-2016-0172.

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Purpose This study aims to investigate the coupling reaction of epoxide and CO2 catalysed by alkali metal salts in the presence of ß-cyclodextrin (ß-CD) derivatives to generate cyclic carbonates at various conditions. Design/methodology/approach The coupling reaction was catalysed by alkali metal salts. The effects of the co-catalysts were investigated by using the conversion rate of raw materials. The affecting factors, such as reaction temperature, amount of the co-catalyst and reaction time, were explored. The possible mechanism of the coupling reaction was discussed. Findings Results showe
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Yuan, Jia, Ying Zhang, Hong Yu, et al. "Transition metal complexes with functionalized indenyl phosphine ligands: structures and catalytic properties." Organic & Biomolecular Chemistry 20, no. 3 (2022): 485–97. http://dx.doi.org/10.1039/d1ob01884a.

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This review summarizes the recent development of the use and impact of indenyl phosphines in the coordination chemistry and transition-metal-catalysed transformations, especially in E–H (E = H, C, Si and B) bonds activation, and palladium-catalyzed cross-coupling reactions.
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Thapa, Surendra, Bijay Shrestha, Santosh K. Gurung, and Ramesh Giri. "Copper-catalysed cross-coupling: an untapped potential." Organic & Biomolecular Chemistry 13, no. 17 (2015): 4816–27. http://dx.doi.org/10.1039/c5ob00200a.

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Camp, Jason, Thomas Bousfield, Jay Dunsford, et al. "Dehydrative Cross-Coupling of 1-Phenylethanol Catalysed by Palladium Nanoparticles Formed in situ Under Acidic Conditions." Synthesis 50, no. 19 (2018): 3862–74. http://dx.doi.org/10.1055/s-0037-1610246.

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A dehydrative cross-coupling of 1-phenylethanol catalysed by sugar derived, in situ formed palladium(0) nanoparticles under acidic conditions is realised. The acidic conditions allow for use of alcohols as a feedstock in metal-mediated coupling reactions via their in situ dehydration and subsequent cross-coupling. Extensive analysis of the size and morphology of the palladium nanoparticles formed in situ showed that the zero-valent metal was surrounded by hydrophilic hydroxyl groups. EDX-TEM imaging studies using a prototype silicon drift detector provided insight into the problematic role of
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Farhi, Jonathan, Ioannis N. Lykakis, and George E. Kostakis. "Metal-Catalysed A3 Coupling Methodologies: Classification and Visualisation." Catalysts 12, no. 6 (2022): 660. http://dx.doi.org/10.3390/catal12060660.

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The multicomponent reaction of aldehydes, amines, and alkynes, known as A3 coupling, yields propargylamines, a valuable organic scaffold, and has received significant interest and attention in the last years. In order to fully realise the potential of the metal-based catalytic protocols that facilitate this transformation, we summarise substrates, in situ and well-characterised synthetic methods that provide this scaffold and attempt a monumental classification considering several variables (Metal, Coordinating atom(s), Ligand type and name, in-situ or well-characterised, co-catalyst, catalyst
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Vendeville, Jean-Baptiste, Rebecca F. Matters, Anqi Chen, et al. "A synthetic approach to chrysophaentin F." Chemical Communications 55, no. 33 (2019): 4837–40. http://dx.doi.org/10.1039/c9cc01666j.

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P., G. MORE, J. DESAI B., and S. Y. MULLA (MISS). "Transition Metal Catalysed Coupling Reactions of Aryl Halides with Acrylic Acid." Journal of Indian Chemical Society Vol. 74, Jul 1997 (1997): 571–72. https://doi.org/10.5281/zenodo.5908783.

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Department of Chemistry, Shivaji University, P. G. Centre, Solapur-413 003 Shtvraj College, Gadhinglaj (Kolhapur)-416 502 <em>Manuscript received 6 April 1994, revised 2 April 1996, accepted 25 June 1996</em> Transition Metal Catalysed Coupling Reactions of Aryl Halides with Acrylic Acid.
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Cooper, Alasdair K., Paul M. Burton, and David J. Nelson. "Nickel versus Palladium in Cross-Coupling Catalysis: On the Role of Substrate Coordination to Zerovalent Metal Complexes." Synthesis 52, no. 04 (2019): 565–73. http://dx.doi.org/10.1055/s-0039-1690045.

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A detailed comparison of the effect of coordinating functional groups on the performance of Suzuki–Miyaura reactions catalysed by nickel and palladium is reported, using competition experiments, robustness screening, and density functional theory calculations. Nickel can interact with a variety of functional groups, which manifests as selectivity in competitive cross-coupling reactions. The presence of these functional groups on exogenous additives has effects on cross-coupling reactions that range from a slight improvement in yield to the complete cessation of the reaction. In contrast, palla
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Bassoli, Angela, Giuseppina Di Gregorio, Bruno Rindone, Stefano Tollari, and Francesco Chioccara. "Metal complex-catalysed phenol coupling of phenolic benzylisoquinoline alkaloids." Journal of Molecular Catalysis 53, no. 2 (1989): 173–78. http://dx.doi.org/10.1016/0304-5102(89)85002-3.

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Dissertations / Theses on the topic "Metal Catalysed Coupling"

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Adams, Kirsty. "Metal catalysed cross-coupling reactions of heterocycles." Thesis, University of Huddersfield, 2013. http://eprints.hud.ac.uk/id/eprint/20889/.

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This report describes two methodology studies dedicated towards development of metal catalysed crosscoupling reactions in the synthesis of novel heterocyclic compounds. Firstly, a Heck-Mizoroki arylation reaction is reported for the direct functionalisation of tetrahydropyridines, towards the synthesis of kainoid analogues. Kainoids are a group of non-proteinogenic pyrrolidine dicarboxylic acids, which have attracted considerable interest because of their potent biological activity, including insecticidal, anthelmintic and neuroexcitatory properties. The ideal synthesis of kainoids would allow
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Siddle, James Spencer. "Metal-catalysed cross-coupling reactions of nitrogen heterocycles." Thesis, Durham University, 2010. http://etheses.dur.ac.uk/617/.

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Described herein are copper-catalysed N-C heteroarylations of benzimidazole, 1-methylbenzimidazolone, imidazole and pyrrole. The products of these reactions then undergo palladium-catalysed C-C cross-couplings with aryl or heteroarylboronic acids under Suzuki-Miyaura conditions to provide a rapid entry to tris(hetero)aryl scaffolds comprising two or three N-heterocyclic rings. The sequential N-C and C-C couplings can be performed in a one-pot process. 1,5-Di(hetero)arylated-pyridin-2(1H)-one derivatives have been synthesised in good yields starting from (2-fluoro-5-pyridyl)boronic acid. The se
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Fodor, Anna. "Heterogeneous metal-catalysed C-C coupling reactions : research and development." Thesis, Poitiers, 2016. http://www.theses.fr/2016POIT2256/document.

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Des nouveaux catalyseurs bimétalliques à base de palladium et de cuivre ont été développés. Deux voies de préparation ont été testées : l'imprégnation successive (TSI) et la co-imprégnation (CI) en utilisant la zéolithe 4Å (4A) et l'oxyde mixte MgAlxOy comme support. Les catalyseurs ont été caractérisés à l'état frais et testés dans la réaction de couplage Suzuki–Miyaura afin de comparer leurs activités, sélectivités et stabilités. L'étude de stabilité nous a montré que le catalyseur Cu-Pd-4A-TSI restait actif pendant six cycles alors que l'activité du catalyseur Cu-Pd-4A-CI diminuait. Sur le
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Chapman, Christopher J. "Applications of transition metal-catalysed coupling reactions in organic synthesis." Thesis, University of Bath, 2003. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.425885.

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Dwivedi, Seema. "Green approaches towards transition-metal catalyzed and metal-free c - c and c - heteroatom coupling reactions." Thesis, University of North Bengal, 2019. http://ir.nbu.ac.in/handle/123456789/3646.

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Robinson, Matthew Peter. "Ortho-substituted arylsilanes in oxidative gold catalysis." Thesis, University of Edinburgh, 2018. http://hdl.handle.net/1842/31394.

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Organometallic compounds derived from tin, boron, and zinc, have been used extensively in transition metal-catalysed cross-coupling, and continue to hold status as the go-to reagents to form new carbon-carbon bonds. Recently, organosilicon compounds have emerged as an attractive alternative to these established reagents, benefitting from low toxicity, low cost, and general ease of handling. While the fundamental reactivity of arylsilane reagents (Ar-SiR3) is well known, their role in transition metal-catalysed reactions is generally less well studied. This thesis comprises an investigation int
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Font, Molins Marc. "Model aryl halide macrocyclic substrates for the elucidation of coinage metal catalysed cross-coupling reaction mechanism." Doctoral thesis, Universitat de Girona, 2015. http://hdl.handle.net/10803/285975.

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Aryl-Cu(III) species have been often implicated as the intermediate species that operate Ullmann-type couplings. However, such species have long remained elusive and the fundamental pathways that govern Ullmann-type couplings, first discovered in the beginning of the last century, are still under debate. The first part of this thesis deals with the reactivity of a well-defined aryl-Cu(III) complex in the presence of sulphur, selenium and phosphorus-based nucleophiles. The results obtained demonstrate the plausibility of Cu(I)/Cu(III) redox cycles in copper-catalysed C-S, C-Se and C-P cross-cou
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Lillo, García Vanesa. "Transition metal catalysed functionalisation of c=c through boron chemistry: a tandem approach." Doctoral thesis, Universitat Rovira i Virgili, 2009. http://hdl.handle.net/10803/9101.

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Los compuestos organoborados son considerados de gran interés en síntesis orgánica debido a que el enlace C-B puede ser transformado en una amplia variedad de grupos funcionales. La adicción catalítica de H-B o B-B a enlaces C-C insaturados se considera uno de los procesos catalíticos con mayor control selectivo en la formación de dichos intermedios organoborados. <br/>En el capítulo primero de la presente tesis se muestra la evolución a través de la bibliografía de las tres principales reacciones de adición catalítica de boro a alquenos, como son hidroboración, diboración y &#61538;-boración.
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Truscott, Fiona Rosemary. "Transition metal catalysed C-C bond formation via C-H functionalisation." Thesis, University of Oxford, 2012. http://ora.ox.ac.uk/objects/uuid:6a1ef296-8d63-470d-96bd-3e01a887c81f.

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The functionalisation of C-H bonds has been widely studied in organic synthesis. This work presents the results of investigation into two areas of current research, copper-catalysed aromatic C-H functionalisation and rhodium-catalysed hydroacylation. Chapter 1 presents the development of palladium- and copper-catalysed aromatic C-H functionalisation with particular attention paid to regiocontrol. Chapter 2 describes the development of copper-catalysed cross-coupling of perfluorinated arenes and alkenyl halides along with efforts to expand this methodology to a more general reaction. In Chapter
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Marelli, Enrico. "Nickel- and palladium-catalysed deprotonative cross-couplings." Thesis, University of St Andrews, 2017. http://hdl.handle.net/10023/15603.

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Transition metal-catalysed cross coupling chemistry is a valuable tool for synthetic organic chemistry, enabling the preparation of compounds of great interest. The catalytic metal of choice is usually palladium, which generally offer better performances in term of catalytic activity and easy handling. On the other hand, the use of nickel in this class of reactions is gaining attention, as it would provide more economically and environmentally sustainable processes. Deprotonative cross couplings are a subgroup of these reactions, in which the nucleophile is generated in situ by direct deproton
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Books on the topic "Metal Catalysed Coupling"

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Diederich, François, and Peter J. Stang, eds. Metal-Catalyzed Cross-Coupling Reactions. Wiley-VCH Verlag GmbH, 1998. http://dx.doi.org/10.1002/9783527612222.

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de, Meijere A., and Diederich François, eds. Metal-catalyzed cross-coupling reactions. 2nd ed. Wiley-VCH, 2004.

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Diederich, François. Metal-catalyzed cross-coupling reactions. Wiley-VCH, 1998.

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N, Diederich François, and Stang P. J, eds. Metal-catalyzed cross-coupling reactions. 2nd ed. Wiley-VCH, 2004.

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de Meijere, Armin, Stefan Bräse, and Martin Oestreich, eds. Metal-Catalyzed Cross-Coupling Reactions and More. Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527655588.

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Lei, Aiwen, ed. Transition Metal Catalyzed Oxidative Cross-Coupling Reactions. Springer Berlin Heidelberg, 2019. http://dx.doi.org/10.1007/978-3-662-58104-9.

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Magano, Javier, and Joshua R. Dunetz, eds. Transition Metal-Catalyzed Couplings in Process Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA, 2003. http://dx.doi.org/10.1002/9783527658909.

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Patonay, Tamás, and Krisztina Kónya, eds. Synthesis and Modification of Heterocycles by Metal-Catalyzed Cross-coupling Reactions. Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-32610-8.

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Wu, Xiao-Feng, ed. C-C Cross Couplings with 3d Base Metal Catalysts. Springer International Publishing, 2023. http://dx.doi.org/10.1007/978-3-031-32867-1.

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Wolfe, J. P. (James Philip), 1943- and Larhed Mats, eds. Science of synthesis: Cross coupling and Heck-type reactions. Georg Thieme Verlag KG, 2013.

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Book chapters on the topic "Metal Catalysed Coupling"

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Abreu, Ana S., Paula M. T. Ferreira, Maria-João R. P. Queiroz, et al. "Suzuki Coupling Reactions." In Catalysts for Fine Chemical Synthesis, Volume 3, Metal Catalysed Carbon-Carbon Bond-Forming Reactions. John Wiley & Sons, Ltd, 2005. http://dx.doi.org/10.1002/0470862017.ch4.

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Nilsson, Peter, Mats Larhed, Lijin Xu, et al. "Heck Coupling Reactions." In Catalysts for Fine Chemical Synthesis, Volume 3, Metal Catalysed Carbon-Carbon Bond-Forming Reactions. John Wiley & Sons, Ltd, 2005. http://dx.doi.org/10.1002/0470862017.ch5.

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Datta, Anupama, Herbert Plenio, Chih-An Lin, and Fen-Tair Luo. "Sonogashira Coupling Reactions." In Catalysts for Fine Chemical Synthesis, Volume 3, Metal Catalysed Carbon-Carbon Bond-Forming Reactions. John Wiley & Sons, Ltd, 2005. http://dx.doi.org/10.1002/0470862017.ch6.

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Terao, Jun, Nobuaki Kambe, Luis A. Sarandeses, et al. "Cross-Coupling Reactions." In Catalysts for Fine Chemical Synthesis, Volume 3, Metal Catalysed Carbon-Carbon Bond-Forming Reactions. John Wiley & Sons, Ltd, 2005. http://dx.doi.org/10.1002/0470862017.ch7.

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Seixas, Raquel S. G. R., Vera L. M. Silva, and Artur M. S. Silva. "Metal-Catalysed Cross-Coupling Reactions in the Synthesis and Transformations of Quinolones and Acridones." In Topics in Heterocyclic Chemistry. Springer International Publishing, 2015. http://dx.doi.org/10.1007/7081_2015_140.

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Mitchell, Terence N. "Organotin Reagents in Cross-Coupling." In Metal-Catalyzed Cross-Coupling Reactions. Wiley-VCH Verlag GmbH, 2007. http://dx.doi.org/10.1002/9783527612222.ch4.

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Schafer, Laurel L., Jacky C. H. Yim, and Neal Yonson. "Transition-Metal-Catalyzed Hydroamination Reactions." In Metal-Catalyzed Cross-Coupling Reactions and More. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527655588.ch15.

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Hiyama, Tamejiro. "Organosilicon Compounds in Cross-Coupling Reactions." In Metal-Catalyzed Cross-Coupling Reactions. Wiley-VCH Verlag GmbH, 2007. http://dx.doi.org/10.1002/9783527612222.ch10.

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Beller, Matthias, and Xiao-Feng Wu. "Carbonylative Coupling Reactions with Organometallic Reagents." In Transition Metal Catalyzed Carbonylation Reactions. Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-39016-6_4.

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Tsuji, Jiro, and Tadakatsu Mandai. "Palladium-Catalyzed Coupling Reactions of Propargylic Compounds." In Metal-Catalyzed Cross-Coupling Reactions. Wiley-VCH Verlag GmbH, 2007. http://dx.doi.org/10.1002/9783527612222.ch11.

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Conference papers on the topic "Metal Catalysed Coupling"

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Huszár, Bianka, Zoltán Mucsi, and György Keglevich. "Transition Metal-Catalyzed, “Ligand Free” P–C Coupling Reactions under MW Conditions." In International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2022. http://dx.doi.org/10.3390/ecsoc-26-13647.

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An, Zhong W., and Xin B. Chen. "New cross-coupling reaction of arylbromide with arylboric acid catalyzed by nano metals." In XIV Conference on Liquid Crystals, Chemistry, Physics, and Applications, edited by Jolanta Rutkowska, Stanislaw J. Klosowicz, and Jerzy Zielinski. SPIE, 2002. http://dx.doi.org/10.1117/12.472133.

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Perić, Marko, Magdalena Radović, Marija Mirković, et al. "DFT STUDY OF HYPERFINE COUPLINGS IN D METAL COMPLEXES WITH TETRAHYDRO BORATE LIGANDS." In 17th International Conference on Fundamental and Applied Aspects of Physical Chemistry. Society of Physical Chemists of Serbia, 2024. https://doi.org/10.46793/phys.chem24ii.573p.

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Metal complexes with BH4- ligands show peculiar structural and dynamic properties, and possess many important and applicable qualities (potent reducing agents and catalysts, materials for hydrogen storage). Electron paramagnetic resonance (EPR) is very important for the characterization of complex compounds, determination of their electronic configuration and geometry. Also, Density Functional Theory (DFT) can predict EPR parameters and explain them more profoundly. Hence, in this paper hyperfine coupling constants of d metal complexes with BH4- ligands have been determined by DFT calculations
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Zuben, Theodora Von, Airton Salles Junior, and Gabriela de Souza. "A metal-catalyst-free oxidative coupling of anilines to aromatic azo compounds in water using bleach." In Congresso de Iniciação Científica UNICAMP. Universidade Estadual de Campinas, 2019. http://dx.doi.org/10.20396/revpibic2720192327.

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Haaland, Peter, and James Targove. "Flowing Afterglow Synthesis of Polythiophene Films." In Nonlinear Guided-Wave Phenomena. Optica Publishing Group, 1991. http://dx.doi.org/10.1364/nlgwp.1991.tue4.

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Polymers of aromatic heterocycles such as thiophene and pyrrole have been actively investigated for their promising electrical and optical characteristics. However the use of these materials in waveguide structures has been constrained by morphological and synthetic barriers. Specifically, larger oligomers are less soluble causing multiphase chemical kinetics and irregular morphology in the metal-catalyzed coupling syntheses.fi] Electrochemical preparation methods also produce grainy or fibrillar material, most probably because the heterogeneous boundary conditions on film growth change as ins
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Beckerle, J. D., M. P. Casassa, R. R. Cavanagh, E. J. Heilweil, and J. C. Stephenson. "Ultrafast laser studies of vibrational relaxation on surfaces: CO (v = 1)/Pt(111)." In OSA Annual Meeting. Optica Publishing Group, 1990. http://dx.doi.org/10.1364/oam.1990.fa2.

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Energy transfer at surfaces is important in physical processes such as sticking, desorption, diffusion, and the chemistry of oxidation, catalysis, and electronic materials processing. Early information on rates and mechanisms of vibrational energy dissipation came from theory or were inferred from linewidths of optical spectra. We have used tunable subpicosecond IR laser pulses in pump-probe experiments to obtain time-resolved information about the vibrational energy relaxation time (T1) and homogeneous dephasing time (T2) for the high-frequency CO (v = 1) stretch mode of an ordered monolayer
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