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Dissertations / Theses on the topic 'Metal Catalysed Coupling'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Adams, Kirsty. "Metal catalysed cross-coupling reactions of heterocycles." Thesis, University of Huddersfield, 2013. http://eprints.hud.ac.uk/id/eprint/20889/.

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This report describes two methodology studies dedicated towards development of metal catalysed crosscoupling reactions in the synthesis of novel heterocyclic compounds. Firstly, a Heck-Mizoroki arylation reaction is reported for the direct functionalisation of tetrahydropyridines, towards the synthesis of kainoid analogues. Kainoids are a group of non-proteinogenic pyrrolidine dicarboxylic acids, which have attracted considerable interest because of their potent biological activity, including insecticidal, anthelmintic and neuroexcitatory properties. The ideal synthesis of kainoids would allow

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2

Siddle, James Spencer. "Metal-catalysed cross-coupling reactions of nitrogen heterocycles." Thesis, Durham University, 2010. http://etheses.dur.ac.uk/617/.

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Described herein are copper-catalysed N-C heteroarylations of benzimidazole, 1-methylbenzimidazolone, imidazole and pyrrole. The products of these reactions then undergo palladium-catalysed C-C cross-couplings with aryl or heteroarylboronic acids under Suzuki-Miyaura conditions to provide a rapid entry to tris(hetero)aryl scaffolds comprising two or three N-heterocyclic rings. The sequential N-C and C-C couplings can be performed in a one-pot process. 1,5-Di(hetero)arylated-pyridin-2(1H)-one derivatives have been synthesised in good yields starting from (2-fluoro-5-pyridyl)boronic acid. The se

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3

Fodor, Anna. "Heterogeneous metal-catalysed C-C coupling reactions : research and development." Thesis, Poitiers, 2016. http://www.theses.fr/2016POIT2256/document.

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Des nouveaux catalyseurs bimétalliques à base de palladium et de cuivre ont été développés. Deux voies de préparation ont été testées : l'imprégnation successive (TSI) et la co-imprégnation (CI) en utilisant la zéolithe 4Å (4A) et l'oxyde mixte MgAlxOy comme support. Les catalyseurs ont été caractérisés à l'état frais et testés dans la réaction de couplage Suzuki–Miyaura afin de comparer leurs activités, sélectivités et stabilités. L'étude de stabilité nous a montré que le catalyseur Cu-Pd-4A-TSI restait actif pendant six cycles alors que l'activité du catalyseur Cu-Pd-4A-CI diminuait. Sur le

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4

Chapman, Christopher J. "Applications of transition metal-catalysed coupling reactions in organic synthesis." Thesis, University of Bath, 2003. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.425885.

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5

Dwivedi, Seema. "Green approaches towards transition-metal catalyzed and metal-free c - c and c - heteroatom coupling reactions." Thesis, University of North Bengal, 2019. http://ir.nbu.ac.in/handle/123456789/3646.

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6

Robinson, Matthew Peter. "Ortho-substituted arylsilanes in oxidative gold catalysis." Thesis, University of Edinburgh, 2018. http://hdl.handle.net/1842/31394.

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Organometallic compounds derived from tin, boron, and zinc, have been used extensively in transition metal-catalysed cross-coupling, and continue to hold status as the go-to reagents to form new carbon-carbon bonds. Recently, organosilicon compounds have emerged as an attractive alternative to these established reagents, benefitting from low toxicity, low cost, and general ease of handling. While the fundamental reactivity of arylsilane reagents (Ar-SiR3) is well known, their role in transition metal-catalysed reactions is generally less well studied. This thesis comprises an investigation int

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7

Font, Molins Marc. "Model aryl halide macrocyclic substrates for the elucidation of coinage metal catalysed cross-coupling reaction mechanism." Doctoral thesis, Universitat de Girona, 2015. http://hdl.handle.net/10803/285975.

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Aryl-Cu(III) species have been often implicated as the intermediate species that operate Ullmann-type couplings. However, such species have long remained elusive and the fundamental pathways that govern Ullmann-type couplings, first discovered in the beginning of the last century, are still under debate. The first part of this thesis deals with the reactivity of a well-defined aryl-Cu(III) complex in the presence of sulphur, selenium and phosphorus-based nucleophiles. The results obtained demonstrate the plausibility of Cu(I)/Cu(III) redox cycles in copper-catalysed C-S, C-Se and C-P cross-cou

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8

Lillo, García Vanesa. "Transition metal catalysed functionalisation of c=c through boron chemistry: a tandem approach." Doctoral thesis, Universitat Rovira i Virgili, 2009. http://hdl.handle.net/10803/9101.

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Los compuestos organoborados son considerados de gran interés en síntesis orgánica debido a que el enlace C-B puede ser transformado en una amplia variedad de grupos funcionales. La adicción catalítica de H-B o B-B a enlaces C-C insaturados se considera uno de los procesos catalíticos con mayor control selectivo en la formación de dichos intermedios organoborados. <br/>En el capítulo primero de la presente tesis se muestra la evolución a través de la bibliografía de las tres principales reacciones de adición catalítica de boro a alquenos, como son hidroboración, diboración y -boración.

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9

Truscott, Fiona Rosemary. "Transition metal catalysed C-C bond formation via C-H functionalisation." Thesis, University of Oxford, 2012. http://ora.ox.ac.uk/objects/uuid:6a1ef296-8d63-470d-96bd-3e01a887c81f.

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The functionalisation of C-H bonds has been widely studied in organic synthesis. This work presents the results of investigation into two areas of current research, copper-catalysed aromatic C-H functionalisation and rhodium-catalysed hydroacylation. Chapter 1 presents the development of palladium- and copper-catalysed aromatic C-H functionalisation with particular attention paid to regiocontrol. Chapter 2 describes the development of copper-catalysed cross-coupling of perfluorinated arenes and alkenyl halides along with efforts to expand this methodology to a more general reaction. In Chapter

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10

Marelli, Enrico. "Nickel- and palladium-catalysed deprotonative cross-couplings." Thesis, University of St Andrews, 2017. http://hdl.handle.net/10023/15603.

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Transition metal-catalysed cross coupling chemistry is a valuable tool for synthetic organic chemistry, enabling the preparation of compounds of great interest. The catalytic metal of choice is usually palladium, which generally offer better performances in term of catalytic activity and easy handling. On the other hand, the use of nickel in this class of reactions is gaining attention, as it would provide more economically and environmentally sustainable processes. Deprotonative cross couplings are a subgroup of these reactions, in which the nucleophile is generated in situ by direct deproton

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11

Kienle, Marcel. "Oxidative and Transition-Metal Catalyzed Cross-Coupling Reactions, Preparation and Coupling of S-Heterocycles." Diss., lmu, 2010. http://nbn-resolving.de/urn:nbn:de:bvb:19-113699.

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12

Jensen, Anne Eeg. "Transition metal-catalyzed cross-coupling reactions of functionalized organometallic reagents." Diss., lmu, 2001. http://nbn-resolving.de/urn:nbn:de:bvb:19-2331.

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13

Chae, Junghyun 1973. "Development and application of transition metal-catalyzed cross-coupling reactions." Thesis, Massachusetts Institute of Technology, 2004. http://hdl.handle.net/1721.1/17735.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2004.<br>Includes bibliographical references.<br>Chapter 1. PALLADIUM-CATALYZED REGIOSELECTIVE HYDRODEBROMINATION OF DIBROMOINDOLES A novel approach to the selective preparation of 4-bromoindoles has been developed via a Pd-catalyzed reaction. A variety of 4,6-dibromoindoles, which are prepared via Cu-catalyzed chemoselective C-N bond-forming reaction and subsequent Fischer indole cyclization, are transformed to 4-bromoindoles with high regioselectivity using a catalytic Pd(OAc)2/rac-BINAP system. This new method allow

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14

Nunn, Joshua. "Insights into cross-coupling reactions using cheaper metal catalysts." Thesis, University of Bristol, 2014. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.687059.

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The mechanisms of a range of cross-coupling reactions catalysed by cheaper metal catalysts have been investigated in detail using a combination of spectroscopic techniques and computational modelling. For iron-catalysed Negishi cross-coupling reactions supported by phosphine ligands, it is shown that the iron(II) pre-catalysts are reduced in situ to iron(I), which is found to be the only kinetically relevant oxidation state. The characterisation of a range of relevant low-spin iron(l) phosphine complexes has allowed the study of the mechanism in significantly greater detail than before via dir

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15

Manan, Rajith Singh. "Late Transition Metal-Catalyst Development for Alkyne Coupling Reactions." Diss., North Dakota State University, 2016. https://hdl.handle.net/10365/28024.

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Alkynes are versatile and valuable synthetic precursors in a variety of organic transformations and have found tremendous applications in materials science and pharmaceutical chemistry. In recent years, there has been a tremendous growth in the development of transitionmetal catalyzed organic transformations by alkynes coupling reactions such as ring constructions (carbocycles and heterocycles), hydroarylation and hydroamination. This thesis describes the development of new transition metal catalyst for alkyne coupling reactions. The results are highlighted by chemoselective coupling bet

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16

Nelson, Amanda Kay. "Metal-Catalyzed Formation and Transformations of Carbon-Boron Bonds." Diss., Virginia Tech, 2016. http://hdl.handle.net/10919/83400.

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Our research seeks new methods for functionalizing organic small molecules using organoboronic derivatives as a versatile handle for late-stage manipulations. Metal-catalyzed formation of new carbon-boron bonds and their subsequent transformations are highlighted. Among the myriad of unsaturated substrates for conducting borylation reactions, allenes have received minimal attention. These substrates are uniquely advantageous given that diboration results in the formation of both allylic and vinylic boronates. Orthogonal reactivity of the sp2 and the sp3 C-B bonds can allow for chemoselective

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17

ELAZAB, HANY. "Graphene-Supported Metal Nanoparticles For Applications in Heterogeneous Catalysis." VCU Scholars Compass, 2013. http://scholarscompass.vcu.edu/etd/560.

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Due to its unique properties and high surface area, Graphene has become a good candidate as an effective solid support for metal catalysts. The Nobel Prize in Physics for 2010 was awarded to Andre Geim and Konstantin Novoselov "for groundbreaking experiments regarding the two-dimensional material graphene". Microwave-assisted synthesis of various metallic nanostructured materials was investigated for CO oxidation applications. These metallic nanostructured materials were used to convert CO to CO2 as an effective approach for carbon monoxide elimination due to its harmful effect on health and e

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18

Teverovskiy, Georgiy. "Development of novel transition metal-catalyzed cross-coupling reactions and applications thereof." Thesis, Massachusetts Institute of Technology, 2013. http://hdl.handle.net/1721.1/82322.

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Thesis (Ph. D. in Organic Chemistry)--Massachusetts Institute of Technology, Dept. of Chemistry, 2013.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references.<br>Chapter 1 The first example of Pd(0)/(II) catalyzed fluorination of aryl bromides is reported herein. Based on these data, an analogous method was developed for the fluorination of aryl triflates. The reaction proceeds under mild conditions and represents the first report of reductive elimination from a Pd(II) center of a C-F bond. Chapter 2 Herein we report the first example of a Pd-catalyzed synthesis of ary

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19

Shirakawa, Eiji. "Studies on Novel Aspects of the Transition Metal-Catalyzed Coupling Reactions of Organostannanes." Kyoto University, 1997. http://hdl.handle.net/2433/157021.

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本文データは平成22年度国立国会図書館の学位論文(博士)のデジタル化実施により作成された画像ファイルを基にpdf変換したものである<br>Kyoto University (京都大学)<br>0048<br>新制・論文博士<br>博士(工学)<br>乙第9725号<br>論工博第3285号<br>新制||工||1096(附属図書館)<br>UT51-97-Y53<br>(主査)教授檜山爲次郎, 教授内本喜一朗, 教授伊藤嘉彦<br>学位規則第4条第2項該当

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20

Heusser, Carolyn Andrea. "Efforts Towards the Cross Coupling of Acylsilanes and Electrophiles via a Metal-Catalyzed Brook Rearrangement." Thesis, Boston College, 2013. http://hdl.handle.net/2345/3402.

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Thesis advisor: Jeffrey A. Byers<br>Chapter 1: There are a limited number of examples of metal-catalyzed Brook rearrangements in the literature, none of which involve ruthenium, rhodium, or iridium which are common ketone hydrogenation catalysts. The content of this chapter introduces the traditional Brook rearrangement and its advantages and disadvantages in chemical synthesis. Furthermore, the few examples of metal-catalyzed Brook rearrangements of acylsilanes and structurally similar moieties are discussed. Chapter 2: Utilizing a Brook rearrangement under hydrogenation or transfer hydrogena

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21

Muscroft-Taylor, Andrew Clive. "Investigations of the type ii intramolecular Diels-Alder reaction directed toward natural product synthesis." Thesis, University of Canterbury. Chemistry, 2006. http://hdl.handle.net/10092/1290.

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This thesis describes synthetic studies directed towards the total synthesis of the nakafuran and florlide marine natural products. Chapter One provides an overview of the importance of natural products to current medicinal chemistry and describes how the "supply issue" associated with these biologically derived compounds can be resolved through the process of total synthesis. Two families of marine natural products, the nakafurans and the florlides, are introduced as synthetic targets and strategies utilising a type II intramolecular Diels-Alder (IMDA) reaction to achieve their total synthesi

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22

Dunet, Guillaume. "Preparation and Reactions of Allylic Zinc Reagents and Transition Metal-Catalyzed Cross-Coupling Reactions." Diss., lmu, 2007. http://nbn-resolving.de/urn:nbn:de:bvb:19-78249.

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23

Correia, Camille. "Oxidative C-C bond formation via metal-catalyzed coupling of two C-H bonds." Thesis, McGill University, 2013. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=114441.

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This thesis describes the formation of new C-C bonds from the direct oxidative coupling of two C-H bonds, through the use of metal catalysts for activation. First, three different oxidative Cross-Dehydrogenative-Coupling (CDC) reactions will be presented. Initially, through the use of an organic co-catalyst, N-hydroxyphthalimide (NHPI), oxygen could be utilized as the terminal oxidant for the metal catalyzed alkylation of benzylic C-H bonds with 1,3-dicarbonyls and ketones in Chapter 2. The reaction was found to be feasible for a variety of

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24

Turnbull, Stanhope. "Study of Bis-Imidazol-2-Ylidines as Ligands for Transition Metal Catalyzed Coupling Reactions." ScholarWorks@UNO, 2004. http://scholarworks.uno.edu/td/214.

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Two bis-imidazol-2-ylidine N-heterocyclic carbenes have been employed as ancillary ligands in an attempt to illustrate their utility in the palladium-mediated preparation of aryl ethers from aryl halides. Ullman-type homo-coupling of the aryl halides persistently occurred instead of ether formation. One of the well known N-heterocyclic carbenes, IPr, was employed with the same results. A variety of reaction conditions and reagents were investigated including solvents, N-heterocyclic carbene species, palladium source, alkoxide base, palladium to ligand ratio and reaction time. Reactivity

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25

Srivastava, R. "Activation of small molecules for cycloaddition and coupling reactions over transition metal catalysts." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2005. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2457.

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26

Hopkinson, Matthew Neil. "Transition metal catalysis in the presence of fluorinating reagents." Thesis, University of Oxford, 2011. http://ora.ox.ac.uk/objects/uuid:4f29607a-7aad-473b-aabc-af320ea2b1e5.

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In this thesis, the effect of fluorinating reagents on a selection of transition metal-mediated organic transformations was investigated. The first four chapters are focused on gold-catalysed nucleophilic addition processes performed in the presence of “F⁺” sources. Chapter 1 provides a general introduction to homogeneous gold catalysis and summarises the aims and objectives of the project. The effect of the electrophilic fluorinating reagent Selectfluor (82) on the gold-catalysed rearrangement of propargyl acetates 85 is discussed in Chapter 2. α-Fluoroenones 92 resulting from fluorodeacetyla

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27

Giguère-Bisson, Maxime. "Investigation of transition metal-catalyzed oxidative amidation of aldehydes and aldehyde-alkyne-amine coupling reactions." Thesis, McGill University, 2011. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=103659.

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This thesis describes the investigation of various amino acids derivatives as reagents for copper-catalyzed, silver-catalyzed and iron-catalyzed reactions and the investigation of an enantioselective cobalt-catalyzed aldehyde-alkyne-amine (A3) coupling reaction. The first part focuses on the large-scale optimization of the oxidative amidation of aldehydes in the presence of amine hydrochloride salts as well as our effort to enhance the reaction scope by the use of amino acids derivatives and short peptides. This is then followed by the development of an enantioselective cobalt-catalyzed A3-cou

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28

Shuai, Qi. "Transition-metal-catalyzed functionalization of aryl C-H bonds via a cross-dehydrogenative-coupling process." Thesis, McGill University, 2011. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=104709.

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This thesis is an investigation on the functionalization of aryl C-H bonds in the presence of transition-metal catalysts and oxidants.In the first part of this thesis, an oxidative amidation of 2-arylpyridine derivatives and 1-methylindoles with a variety of amides is described. Copper(I) bromide is used as catalyst and tert-butyl peroxide (TBP) is employed as oxidant. High regioselectivity of this amidation process is achieved through chelation-assisted aryl C-H activation. In the second part of this thesis, a new concept is described for aryl-aryl coupling that involves oxidative decarbonyla

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29

Ashraf, Mohammed Razwan. "Studies relating to coupling of CO₂ and olefins at a Ni(0) metal centre." Thesis, Imperial College London, 1998. http://hdl.handle.net/10044/1/7801.

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30

Clavadetscher, Jessica Veronica. "Transition metal catalysis : a new paradigm in bioorthogonal drug activation." Thesis, University of Edinburgh, 2017. http://hdl.handle.net/1842/29580.

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Powerful tools have emerged in the past few years to allow the sensing, imaging and modulation of biological processes in living systems. Bioorthogonal organometallic reactions are transformations catalysed by transition metals, which are compatible within a biological environment. Palladium-mediated cross-coupling and decaging reactions, for example, have been successfully applied to catalyse non-natural chemical transformations within a biological milieu. Up until now, copper-catalysed cycloaddition reactions have been used extensively for the conjugation, immobilisation, and purification of

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31

Zhang, Ye. "Development of amide-derived P,O-ligands for Suzuki cross-coupling of aryl chlorides and the asymmetric version /." View abstract or full-text, 2005. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202005%20ZHANG.

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32

Chen, Jinshui. "Studies on Transition Metal-catalyzed Carbon－Carbon Bond Forming Reactions through Intramolecular Activation of Organosilicon Compounds." 京都大学 (Kyoto University), 2008. http://hdl.handle.net/2433/57272.

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Kyoto University (京都大学)<br>0048<br>新制・課程博士<br>博士(工学)<br>甲第13828号<br>工博第2932号<br>新制||工||1433(附属図書館)<br>26044<br>UT51-2008-C744<br>京都大学大学院工学研究科材料化学専攻<br>(主査)教授檜山爲次郎, 教授大嶌幸一郎, 教授松原誠二郎<br>学位規則第4条第1項該当

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Patil, Pratap Tukaram. "Nanoscopic metal fluoride based novel solid catalysts." Doctoral thesis, Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät I, 2009. http://dx.doi.org/10.18452/16021.

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Metallfluoride sind dank ihrer hohen chemischen und thermischen Stabilität, insbesondere bei Reaktionen unter Beteiligung von hoch korrosiven Gasen (HF, HCl, Cl2, F2) den entsprechenden Oxiden überlegen. Über den Sol-Gel Prozess synthetisierte Produkte weisen oft spezifische, zum Teil sehr unterschiedliche Eigenschaften im Vergleich zu klassisch hergestellten Verbindungen auf. In dieser Arbeit wurde der Sol-Gel Prozess zur Herstellung von binären Fluoriden (AlF3, MgF2, CaF2, CuF2 und FeF3) genutzt und zum Teil weiter entwickelt sowie das Synthesepotential dieser Methode als Zugang für komplex

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Becica, Joseph. "Mechanism and application of Lewis and Brønsted acid effects in organotransition metal catalysis." Diss., Temple University Libraries, 2019. http://cdm16002.contentdm.oclc.org/cdm/ref/collection/p245801coll10/id/570159.

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Chemistry<br>Ph.D.<br>The essential questions of the dissertation research described here address concepts in homogeneous catalysis and organometallic chemistry, with a focus on method development for catalytic reaction applications in organic synthesis. The unifying theme throughout the research is the development of rational design principles for cooperative catalysis through both mechanistic and empirical study. Cooperative catalysis – in which multiple catalysts enable increased activity or selectivity versus a single catalyst system – can involve some combination of a transition metal, L

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Manolikakes, Georg. "Transition-Metal Catalyzed Cross-Coupling Reactions of Functionalized Organometallic Reagents, Nickel-Catalyzed Amination of Aryl Chlorides and Preparation and Reactions of Organozinc Reagents." Diss., lmu, 2009. http://nbn-resolving.de/urn:nbn:de:bvb:19-139921.

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Hänni, Kevin D. "Mechanically interlocked architectures via active-metal template strategies." Thesis, University of Edinburgh, 2009. http://hdl.handle.net/1842/3802.

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In contrast to the classic ‘passive template’ approach, an ‘active-metal’ template strategy involves a metal centre which acts as both a template and the catalyst for covalent bond formation in the construction of mechanically interlocked architectures. The crucial formation of a covalent bond between two ‘half-threads’ is promoted by the catalyst and directed through the cavity of the macrocycle by the catalyst’s coordination requirements. The main attractive features of such a synthetic approach are the efficiency (as one step is required instead of two), the rapid assembly of inaccessible s

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Payard, Pierre-Adrien. "Mechanistic studies of metal-catalyzed reactions : predicting tools for reaction optimization." Thesis, Paris Sciences et Lettres (ComUE), 2019. http://www.theses.fr/2019PSLEE009/document.

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Cette thèse est consacrée à l’étude de mécanismes de réactions catalysées par des métaux ainsi qu’au développement de nouveaux outils pour la rationalisation et la prévision du comportement catalytique. L’étape de transmétallation entre le bore et le nickel a été étudiée en détail à l’aide de méthodes expérimentales variées (electrochimie, RMN, cinétiques) et par DFT, permettant d’expliquer certaines limitations rencontrées par les experimentateurs. La seconde partie de cette thèse est dédiée à la rationalisation du comportement d’une famille d’acides de Lewis : les sels de triflate et de trif

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38

Sun, Duo. "Studies towards the synthesis of functionalized aryl fluorides : transition metal catalyzed cross-coupling and fluorination of organoboron reagents." Thesis, University of British Columbia, 2013. http://hdl.handle.net/2429/43839.

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This thesis covers several synthetic approaches to the generation of highly functionalized aryl fluorides. PtCl₂(SMe₂)₂ and PtCl₂(DMSO)₂ have been applied to catalytic methylation of polyfluoroaryl imines as user-friendly precatalysts. These complexes have demonstrated high selectivity for ortho C-F activation and subsequent functionalization, exhibiting high functional group tolerance while proving more thermal, moisture and air stable than our original catalyst, [PtMe₂(SMe₂)]₂. Nickel-catalyzed Suzuki-Miyaura and Negishi cross-coupling reactions allow rapid functionalized of C-F bonds; we ha

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White, James Robert. "Transition metal catalysis for novel syntheses and applications of arylboronic acids and their derivatives." Thesis, University of Bath, 2012. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.577146.

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The research investigations presented herein are concerned with the syntheses and applications of arylboronic acids and their derivatives; with a particular focus on their accessibility or utility in certain of the most significant modern transition metal-catalysed reactions to involve organoborons. Chapter 1 provides an introduction to the field of organoboron chemistry, from its roots employing borane and related highly reactive derivatives for uncatalysed hydroboration of olefins and acetylenes, to the modern classes of organoboron reagents of the greatest significance to the related contem

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40

Kokate, G. D. "Supported transition metal catalysts for carbon - carbon, carbon - heteroatom cross coupling and selective oxidation of organic molecules." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2011. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/3798.

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Melzig, Laurin. "Sulfoxide-Controlled Functionalization of Arenes and Heterocycles Transition Metal-Catalyzed Cross-Coupling Reactions of Thioethers Chlorine-Zinc Exchange Reactions." Diss., lmu, 2011. http://nbn-resolving.de/urn:nbn:de:bvb:19-129202.

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42

Chauder, Brian Andrew. "Combined directed ortho metalation-transition metal catalyzed coupling reactions for the synthesis of chromenes, ergot alkaloids, and biaryl macrocycles." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/NQ63410.pdf.

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Andrella, Nicholas Orlando. "Synthesis of Organo-fluorine Compounds by Metal Complex-mediated and -Catalyzed Transformations of Fluoro-alkenes and Fluoro-arenes." Thesis, Université d'Ottawa / University of Ottawa, 2019. http://hdl.handle.net/10393/39509.

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The prevalence of fluorine in natural products is scarce. There are but a handful of compounds that have been discovered to date. This could be largely attributable to the occurrence of fluorine in nature as fluoride (F-). — One might recognize such nomenclature from the ingredients list on a toothpaste tube — In fact, naturally occurring fluoride is most commonly found as fluorite (CaF2) or cryolite (Na3AlF6). As such, the introduction of fluorine via biological pathways has been limited to use of aqueous F- (a very poor nucleophile). This fact — coupled with its naturally low concentration i

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Akanksha, Tyagi. "Development of novel hybrid catalysis for carbon-carbon couplings by titanium oxide photocatalyst and metal cocatalyst." Kyoto University, 2018. http://hdl.handle.net/2433/232379.

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Kyoto University (京都大学)<br>0048<br>新制・課程博士<br>博士(人間・環境学)<br>甲第21178号<br>人博第850号<br>新制||人||203(附属図書館)<br>29||人博||850(吉田南総合図書館)<br>京都大学大学院人間・環境学研究科相関環境学専攻<br>(主査)教授吉田寿雄, 教授内本喜晴, 教授田部勢津久<br>学位規則第4条第1項該当

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Xue, Weichao [Verfasser], Martin [Akademischer Betreuer] Oestreich, Martin [Gutachter] Oestreich, and Werz [Gutachter] Daniel. "Metal-catalyzed radical C(sp3)–Si/Ge cross-coupling reactions / Weichao Xue ; Gutachter: Martin Oestreich, Werz Daniel ; Betreuer: Martin Oestreich." Berlin : Technische Universität Berlin, 2019. http://d-nb.info/1191256707/34.

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Manolikakes, Georg Verfasser], and Paul [Akademischer Betreuer] [Knochel. "Transition-Metal Catalyzed Cross-Coupling Reactions of Functionalized Organometallic Reagents, Nickel-Catalyzed Amination of Aryl Chlorides and Preparation and Reactions of Organozinc Reagents / Georg Manolikakes. Betreuer: Paul Knochel." München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2009. http://d-nb.info/1019930152/34.

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Langgaard, Kristensen Jesper. "Metalation, halogen-metal exchange and Pd(0) catalyzed cross-coupling reactions : application to the synthesis of substituted aromatic and heteroaromatic systems /." [Cph.] : Department of Medicinal Chemistry, Royal Danish School of Pharmacy, 2001. http://www.dfh.dk/phd/defences/previous2002.htm.

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Escárcega, Bobadilla Martha Verónica. "Organometallic compounds and metal nanoparticles as catalysts in low environmental impact solvents." Doctoral thesis, Universitat Rovira i Virgili, 2011. http://hdl.handle.net/10803/9114.

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Durant les darreres dècades, el disseny de processos en el marc de la química sostenible ha anat creixent de forma exponencial. La recerca constant de processos mes benignes amb el medi ambient ha implicat un gran esforç per obtenir millors rendiments mitjançant l'activació de llocs específics, i possant especial èmfasi amb el control de la quimio-, la regio- i la enantioselectivitat, punts crucials per a l'economia atómica. En aquest sentit, els dissolvents juguen un paper crític, i com podrà veure's al llarg d'aquesta memòria..<br/>Aquesta Tesi s'enfoca en l'ús de mitjans de reacció alternat

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Satou, Motoi. "Synthesis of Ligands Bearing Poly(ethylene glycol) Chains and Their Application in Catalysis." Kyoto University, 2018. http://hdl.handle.net/2433/232048.

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Bonnefoy, Jonathan. "Conception de nouveaux matériaux hybrides types MOFs bio-inspirés à fonctionnalités avancées pour la catalyse." Thesis, Lyon 1, 2015. http://www.theses.fr/2015LYO10195/document.

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Les MOFs sont des solides à la structure cristalline poreuse à base de clusters métalliques et de ligands organiques qui font l'objet de très nombreuses études, dans des champs d'applications très variés, qui vont de la catalyse au « drug delivery », en passant par le stockage de gaz et, plus récemment, en tant que senseurs biologiques. Les ligands organiques, qui les constituent, peuvent lorsqu'ils possèdent un point d'ancrage, comme des groupements amino, être fonctionnalisés grâce à des réactions chimiques. Les travaux présentés dans cette thèse reportent la fonctionnalisation de MOFs, via

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