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Journal articles on the topic 'Metal chelate polymers'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Vijay, R. Patel, Patel Vasant, and D. Joshi J. "Synthesis, characterization, thermal, catalytic and antimicrobial aspects of LnIII polymers of phenolic resins." Journal of Indian Chemical Society Vol. 90, Dec 2013 (2013): 2169–79. https://doi.org/10.5281/zenodo.5793655.

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Shri R. K. Parikh Arts & Science College, Petlad-388 450, Gujarat, India Shri Natvarsinhji Arts & Science & S. G. Patel Commerce College, Chhotaudepur-391 165, Gujarat, India Formerly Department of Chemistry, Sardar Patel University, Vallabh Vidyanagar-388 120, Gujarat, India <em>E-mail</em> : jdjoshi314@gmail.com Manuscript received online 19 October 2012, revised 28 December 2012, accepted 04 January 2013 Inorganic compounds of transition and inner transition metal ions play an important role in various chemical reactions. Calcium and lanthanides are similar in their chemical beh

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2

A., S. ASWAR, and N. MUNSHI K. "Preparative, Structural and Thermal Studies on some Chelate Polymers." Journal of Indian Chemical Society Vol. 69, Sep 1992 (1992): 544–46. https://doi.org/10.5281/zenodo.6004893.

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Department of Chemistry, Nagpur University, Nagpur-140 010 <em>Manuscript received 4 November 1991, revised 26 May 1992, accepted 1 July 1992</em> Chelate polymers of bivalent Mn, Co, Ni, Cu and Zn have been prepared from bis-mercaptoacetamide ethylenediamine (BMAED). The analytical data agree with 1 : 1 metal-ligand stoichiometry. Elemental analysis, magnetic, spectral and thermal properties of polycbelates have been studied and probable structures are assigned to the chelate polymers. All the chelates are amorphous powders, insoluble in common organic solvents. The sequence of thermal stabil

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3

Li, Jie, Wenxi Li, Lisi Xie, et al. "A metal–polyphenolic nanosystem with NIR-II fluorescence-guided combined photothermal therapy and radiotherapy." Chemical Communications 57, no. 87 (2021): 11473–76. http://dx.doi.org/10.1039/d1cc04628d.

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A polyphenolic semiconducting polymer was prepared to chelate the high-Z Hf ions, followed by coating of the amphiphilic polymers to form a nanostructure (CPPDA–Hf@Poloxamer nanoparticles) for precise lesion imaging and photothermal therapy.

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4

Virendra, Pal Singh, P. Madnawat S., Kumar Devendra, and Neelam. "Synthesis, spectral and antimicrobial studies of MnII, CoII, NiII and cull metal chelate polymers of poly(metha acryloyl)-N-hydroxamic acid." Journal of Indian Chemical Society Vol. 88, Jul 2011 (2011): 943–46. https://doi.org/10.5281/zenodo.5784941.

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Department of Chemistry, Institute of Basic Sciences, Dr. B. R. Ambedkar University, Khandan, Agra-282 002, Uttar Pradesh, India <em>E-mail</em>: dev_kumar26@indiatimes.com Department of Chemistry, R. B. S. College, Agra-282 002, Uttar Pradesh, India <em>Manuscript rece1ved 13 July 2010, revised 10 December 2010, accepted 13 December 2010</em> Metal chelate polymers of Mn<sup>II</sup>, Co<sup>II</sup>, Ni<sup>II</sup> and Cu<sup>II</sup> with poly(metha acryloyi)-<em>N</em>-hydroxamic acid have been synthesized and characterized by IR and electronic spectral studies. The synthesized poly(metha

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5

Dzhardimalieva, Gulzhian I., and Igor E. Uflyand. "Synthetic methodologies and spatial organization of metal chelate dendrimers and star and hyperbranched polymers." Dalton Transactions 46, no. 31 (2017): 10139–76. http://dx.doi.org/10.1039/c7dt01916e.

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6

Amarasekara, Ananda S., and Ashfaqur Razzaq. "Vanillin-Based Polymers—part II: Synthesis of Schiff Base Polymers of Divanillin and Their Chelation with Metal Ions." ISRN Polymer Science 2012 (November 1, 2012): 1–5. http://dx.doi.org/10.5402/2012/532171.

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Condensation of renewable resources-based monomer divanillin with alkyl diamines gives Schiff base polymers with degree of polymerization (DP) ~25–32 in 88–95% yield. These yellow polymers are insoluble in water and common organic solvents, slightly soluble in warm DMSO, DMF and dissolves in aqueous NaOH. The polymers were characterized using FT-IR, 1H, and 13C NMR spectroscopy and by comparison with the model compound N,N′-bis(vanillidene)-1,3-propanediamine. Polymer prepared by condensation of divanillin and 1,6-diaminohexane is shown to chelate with Cu(II), Fe(II), and Co(II) metal ions in

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7

Kurnoskin, A. V. "Heat resistance of metal-containing epoxy chelate polymers." Polymer Degradation and Stability 37, no. 1 (1992): 51–59. http://dx.doi.org/10.1016/0141-3910(92)90091-i.

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8

D., PRAKASH., N. SINGH R., L. VERMA R., and PRAKASH GUPTA OM. "Alkaline Earth Metal Chelate Polymers with Naturally occurring Substrate." Journal of Indian Chemical Society Vol. 68, Sep 1991 (1991): 518–19. https://doi.org/10.5281/zenodo.6154017.

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Department of Chemistry, Patna University, Patna-800 005 <em>Manuscript received 4 March 1991, revised 31 July 1991, accepted 3 September 1991</em> Alkaline Earth Metal Chelate Polymers with Naturally occurring Substrate<em>.</em>

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9

Wenzel, Thomas J., Lawrence W. Yarmaloff, Lorraine Y. St. Cyr, Laura J. O'Meara, Michael Donatelli, and Richard W. Bauer. "Metal chelate polymers as selective sorbents for gas chromatography." Journal of Chromatography A 396 (January 1987): 51–64. http://dx.doi.org/10.1016/s0021-9673(01)94042-7.

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10

Mattiasson, Bo, Ashok Kumar, Alexander E. Ivanov, and Igor Y. Galaev. "Metal-chelate affinity precipitation of proteins using responsive polymers." Nature Protocols 2, no. 1 (2007): 213–20. http://dx.doi.org/10.1038/nprot.2006.440.

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11

Pu, Jian, and Kensuke Fukushi. "Measurement of Cadmium Ion in the Presence of Metal-Binding Biopolymers in Aqueous Sample." Scientific World Journal 2013 (2013): 1–6. http://dx.doi.org/10.1155/2013/270478.

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In aqueous environment, water-soluble polymers are effectively used to separate free metal ions from metal-polymer complexes. The feasibilities of four different analytical techniques, cadmium ion-selective electrode, dialysis sack, chelate disk cartridge, and ultrafiltration, in distinguishing biopolymer-bound and nonbound cadmium in aqueous samples were investigated. And two different biopolymers were used, including bovine serum albumin (BSA) and biopolymer solution extracted from cultivated activated sludge (ASBP). The ISE method requires relatively large amount of sample and contaminates

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12

Kuru, Cansu İlke, Fulden Ulucan-Karnak, and Sinan Akgol. "Metal-Chelated Polymeric Nanomaterials for the Removal of Penicillin G Contamination." Polymers 15, no. 13 (2023): 2832. http://dx.doi.org/10.3390/polym15132832.

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We developed selective and relatively low-cost metal-chelated nanoparticle systems for the removal of the penicillin G (Pen G) antibiotic, presented for the first time in the literature. In the nanosystem, poly(glycidyl methacrylate) nanoparticles were synthesized by a surfactant-free emulsion polymerization method and covalently bound with a tridentate-chelating ligand, iminodiacetic acid, based on the immobilized metal chelate affinity technique. It was modified with Cu2+, a chelating metal, to make Pen G specific. Metal-chelated nanoparticles were characterized by Fourier-transform infrared

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13

Ali, Dr Firyal M., and Haider H. Rashed. "Poly-Condensation of CDTA with Some Diamines." Journal of Petroleum Research and Studies 4, no. 1 (2013): 58–70. http://dx.doi.org/10.52716/jprs.v4i1.89.

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In this research, new condensed polymers (A1-A8) were prepared by poly condensation between 1, 2-cyclohexyl diamine tetraacetic acid CDTA with different diamines such as 1, 6-Diamino hexane, Melamine, 3,3-,5,5--Tetramethyl benzidine, Benzidine and Cystine. These prepared chelate polymers could be used to remove heavy metals and toxic metal ions in many industrial processes as well as acting as sequestrate for metal ions. The all prepared polymers were characterized by 1H-NMR and FT-IR spectra. The thermal analyses (TGA, DSC) were studied, the intrinsic viscosities were calculated at 30 ˚C usin

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14

Smith, Graham. "Two-Dimensional Coordination Polymers in Rubidium and Caesium Complexes with Orthanilic Acid." Australian Journal of Chemistry 65, no. 7 (2012): 750. http://dx.doi.org/10.1071/ch11503.

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The crystal structures of the rubidium and caesium complexes with 2-aminobenzenesulfonic acid (orthanilic acid), [Rb4(C6H6NO3S)4(H2O)]n(1) and [Cs(C6H6NO3S)]n(2), have been determined at 200 K. Complex 1 has a repeating unit comprising four independent and different Rb coordination centres, (RbO8), (RbO7), (RbN2O4) and (RbO10), each having irregular stereochemistry and involving several bidentate chelate sulfonate-O,O′-metal and bridging interactions, giving a two-dimensional polymeric layered structure. Anhydrous complex 2 is also polymeric with the irregular (CsO7) coordination polyhedron co

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15

Belmont-Sánchez, Jeannette Carolina, María Eugenia García-Rubiño, Antonio Frontera, Antonio Matilla-Hernández, Alfonso Castiñeiras, and Juan Niclós-Gutiérrez. "Novel Cd (II) Coordination Polymers Afforded with EDTA or Trans-1,2-Cdta Chelators and Imidazole, Adenine, or 9-(2-Hydroxyethyl) Adenine Coligands." Crystals 10, no. 5 (2020): 391. http://dx.doi.org/10.3390/cryst10050391.

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Three mixed-ligands of Cd(II) coordination polymers were unintentionally obtained: {[Cd(µ3-EDTA)(Him)·Cd(Him)(H2O)2]·H2O}n (1), {[Cd(µ4-CDTA)(Hade)·Cd(Hade)2]}n (2), and {[Cd(µ3-EDTA)(H2O)·Cd(H9heade)(H2O)]·2H2O}n (3), having imidazole (Him), adenine (Hade) or 9-(2-hydroxyethyl)adenine (9heade) as the N-heterocyclic coligands. Compounds 2 and 3 were obtained by working with an excess of corresponding N-heterocyclic coligands. The single-crystal X-ray diffraction structures and thermogravimetric analyses are reported. The chelate moieties in all three compounds exhibit hepta-coordinated Cd cent

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16

Pan, Chengjun, Luhai Wang, Wenqiao Zhou, et al. "Preparation and Thermoelectric Properties Study of Bipyridine-Containing Polyfluorene Derivative/SWCNT Composites." Polymers 11, no. 2 (2019): 278. http://dx.doi.org/10.3390/polym11020278.

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Polymer/inorganic thermoelectric composites have witnessed rapid progress in recent years, but most of the studies have focused on the traditional conducting polymers. The limited structures of traditional conducting polymers restrain the development of organic thermoelectric composites. Herein, we report the preparation and thermoelectric properties of a series of composites films based on SWCNTs and bipyridine-containing polyfluorene derivatives. The value of the power factor around 12 μW m−1 K−2 was achieved for the composite F8bpy/SWCNTs with a mass ratio of 50/50, and the maximum value of

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17

Gillis, John N., Robert E. Sievers, and Glenn E. Pollock. "Selective retention of oxygen using chromatographic columns containing metal chelate polymers." Analytical Chemistry 57, no. 8 (1985): 1572–77. http://dx.doi.org/10.1021/ac00285a017.

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18

Dzhardimalieva, Gulzhian I., and Igor E. Uflyand. "Metal Chelate Monomers as Precursors of Polymeric Materials." Journal of Inorganic and Organometallic Polymers and Materials 26, no. 6 (2016): 1112–73. http://dx.doi.org/10.1007/s10904-016-0418-3.

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19

Uflyand, I. E., and A. D. Pomogailo. "Polymers containing metal chelate units. I. Immobilized mono- and binuclear chelates of nickel(II) and cobalt(II)." Journal of Inorganic and Organometallic Polymers 2, no. 4 (1992): 373–86. http://dx.doi.org/10.1007/bf00701112.

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20

Uflyand, I. E., A. G. Starikov, N. D. Golubeva, and A. D. Pomogailo. "Polymers containing metal chelate units II. Synthesis, structure and use of polymer-supported heterometallic complexes." Reactive Polymers 13, no. 1-2 (1990): 139–44. http://dx.doi.org/10.1016/0923-1137(90)90048-9.

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21

Uflyand, I. E., I. A. Ilchenko, V. N. Sheinker, and V. S. Savostyanov. "Polymers containing metal chelate units. VI. Post-graft polymerization of metal chelate monomers based on 1-phenyl-4-methylpent-4-en-1,3-dione." Reactive Polymers 17, no. 3 (1992): 289–96. http://dx.doi.org/10.1016/0923-1137(92)90275-7.

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22

De Abreu, Heitor, Renata Diniz, and Filipe De Almeida. "Crystallographic Study of a coordination polymer based on Zn2+ion." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C647. http://dx.doi.org/10.1107/s2053273314093528.

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Several studies have aimed to better understand coordination polymers, which are structures based on a connection between a metal ion and an organic ligand that extends infinitely, forming a macro-structure1. The interest in this type of structure is mainly due to its properties, such as its pore-forming ability, presenting many potential applications2 like selective separations, catalysis and gas storage. It is interesting to study the structure of coordination polymers to focus in some particular future application. In these way, a coordination polymer was synthetized by simple mixture with

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23

Kurnoskin, A. V. "Reaction mechanisms of the metal chelates with epoxy oligomers and the structures of the epoxy—chelate metal-containing matrixes." Journal of Applied Polymer Science 46, no. 9 (1992): 1509–30. http://dx.doi.org/10.1002/app.1992.070460901.

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24

Yen, Chih-Chao, Chueh-Jung Huang, and Teh-Chou Chang. "Studies on the preparation and properties of conductive polymers. V. Analysis of metallized polyamide complex metal chelate films and precipitates in metal chelate solution." Journal of Applied Polymer Science 46, no. 9 (1992): 1677–89. http://dx.doi.org/10.1002/app.1992.070460917.

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25

Uflyand, I. E., I. A. Ilchenko, V. N. Sheinker, and A. V. Bulatov. "Polymers containing metal chelate units. V Modification of a polyethylene surface by post-grafting polymerization of palladium(II) chelate monomers." Reactive Polymers 14, no. 1 (1991): 41–47. http://dx.doi.org/10.1016/0923-1137(91)90246-k.

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26

Cazacu, Maria, Mihai Marcu, Angelica Vlad, and Monica Vasiliu. "Chelate Polymers. V. Novel Alternating Copolymers Based on Transition Metal–Azomethine Complexes and Siloxanes." Journal of Macromolecular Science, Part A 41, no. 5 (2004): 565–75. http://dx.doi.org/10.1081/ma-120030925.

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27

Vasiliu, M., M. Cazacu, M. Marcu, C. Racles, and A. Vlad. "Chelate polymers. IV. siloxanes functionalized with chelating groups derived from hydroxy-ketones, their metal complexes and some polymers." Applied Organometallic Chemistry 19, no. 5 (2005): 614–20. http://dx.doi.org/10.1002/aoc.873.

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28

T., RAMKISHAN RAO, RAGHUNATH RAO P., LINGAIAH P., and SIR DESHMUKH LALITHA. "Synthesis, Dielectric and X-Ray Powder Diffraction Studies of lron(III), Cobalt(II) and Nickel(II) Chelate Polymers with 2,5- Dihydroxy-p-benzoquinone." Journal of Indian Chemical Society Vol. 68, Aug 1991 (1991): 458–59. https://doi.org/10.5281/zenodo.6196145.

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Department of Chemistry, Department of Physics. Kakatiya University, Warangal-506 009 <em>Manuscript received 10 January 1990, revised 5 September 1990, accepted 25 July 1991</em> Synthesis, Dielectric and X-Ray Powder Diffraction Studies of lron(III), Cobalt(II) and Nickel(II) Chelate Polymers with 2,5- Dihydroxy-<em>p</em>-benzoquinone.

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29

Czech, Zbigniew, and Marta Wojciechowicz. "The crosslinking reaction of acrylic PSA using chelate metal acetylacetonates." European Polymer Journal 42, no. 9 (2006): 2153–60. http://dx.doi.org/10.1016/j.eurpolymj.2006.03.022.

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30

Uflyand, I. E., I. V. Kokoreva, A. G. Starikov, V. N. Sheinker, and A. D. Pomogailo. "Polymers containing metal chelate units. IV. Immobilised complexes of transition metal acrylates with 2,2′-dipyridyl and 1,10-phenanthroline." Reactive Polymers 11 (January 1989): 221–26. http://dx.doi.org/10.1016/0923-1137(89)90107-3.

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31

Kurnoskin, A. V. "Structure of the epoxy–chelate metal-containing matrices: Theoretical aspects." Journal of Applied Polymer Science 48, no. 4 (1993): 639–56. http://dx.doi.org/10.1002/app.1993.070480407.

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32

Salih, Bekir, Nursel Pekel, and Olgun Güven. "A new metal chelate sorbent for glucose oxidase: Cu(II)- and Co(II)-chelated poly(N-vinylimidazole) gels." Journal of Applied Polymer Science 82, no. 2 (2001): 446–53. http://dx.doi.org/10.1002/app.1870.

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33

Pastuhov, P., V. Petrovskii, O. Lavrenyuk, and B. Mykhalitchko. "EFFICIENT FLAME RETARDANTS FOR EPOXY RESINS: SYNTHESIS, STRUCTURE, PROPERTIES." Fire Safety 36 (July 23, 2020): 101–7. http://dx.doi.org/10.32447/20786662.36.2020.11.

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Introduction. In modern conditions, the combustibility of polymers plays a dominant role in the process of the appearance and spread of fires. This is because the extremely wide use of polymeric materials in all areas of the national economy. Due to the organic structure, the high content of carbon and hydrogen that make up the macromolecules of the polymers, they are extremely combustible. Combustion of polymers is accompanied by high temperature and flame propagation rate, as well as significant smoke generation and the release of a large number of toxic combustion products. Therefore, the s

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34

Ukey, Vaishali V., H. D. Juneja, S. D. Borkar, R. S. Ghubde, and S. Naz. "Preparation, characterization, magnetic and thermal studies of some chelate polymers of first series transition metal ions." Materials Science and Engineering: B 132, no. 1-2 (2006): 34–38. http://dx.doi.org/10.1016/j.mseb.2006.02.007.

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35

Prasad, T. L., P. K. Tewari, and D. Sathiyamoorthy. "Sorption kinetic studies using metal chelate embedded polymers for recovery of heavy metals from desalination effluents." International Journal of Nuclear Desalination 4, no. 3 (2011): 261. http://dx.doi.org/10.1504/ijnd.2011.040127.

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36

Barton, John M., Ian Hamerton, Brendan J. Howlin, John R. Jones, and Shuyuan Liu. "The development of controllable metal-chelate curing agents with improved storage stability." Polymer Bulletin 33, no. 3 (1994): 347–53. http://dx.doi.org/10.1007/bf00314273.

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37

Özkara, Serpil, Handan Yavuz, and Adil Denizli. "Purification of immunoglobulin G from human plasma by metal-chelate affinity chromatography." Journal of Applied Polymer Science 89, no. 6 (2003): 1567–72. http://dx.doi.org/10.1002/app.12312.

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38

Denizli, Adil, Handan Yavuz, Bora Garipcan, and M. Yakup Arica. "Nonporous monosize polymeric sorbents: Dye and metal chelate affinity separation of lysozyme." Journal of Applied Polymer Science 76, no. 2 (2000): 115–24. http://dx.doi.org/10.1002/(sici)1097-4628(20000411)76:2<115::aid-app1>3.0.co;2-m.

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39

Nikiforova, Tatiana, Vladimir Kozlov, Pavel Razgovorov, et al. "Heavy Metal Ions(II) Sorption by a Cellulose-Based Sorbent Containing Sulfogroups." Polymers 15, no. 21 (2023): 4212. http://dx.doi.org/10.3390/polym15214212.

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This article concerns the effect of the chemical modification of short flax fiber on its sorption properties for heavy metal ions. The main purpose of the modification was to achieve the oxidation of flax cellulose with sodium metaperiodate to form dialdehyde cellulose. Additionally, the research shows the subsequent interaction of dialdehyde cellulose with 1-amino-8-hydroxynaphthalene-3,6-disulfonic acid and its transformation into a derivative capable of forming chelate complexes with heavy metal ions. Additionally, this article presents the results of equilibrium and kinetics studies of the

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40

Cazacu, Maria, Mihai Marcu, Angelica Vlad, András Tóth, and Carmen Racles. "Chelate polymers. III. New polyazomethines of 5,5′-methylene-bissalicylaldehyde with siloxane diamines and their divalent metal complexes." Journal of Polymer Science Part A: Polymer Chemistry 41, no. 20 (2003): 3169–79. http://dx.doi.org/10.1002/pola.10911.

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41

Zu, Jianhua, Long Tong, Xinwen Liu, and Guisheng Sun. "HDPE chelate membranes prepared by preirradiation grafting for adsorption of heavy metal ions." Journal of Applied Polymer Science 107, no. 2 (2007): 1252–56. http://dx.doi.org/10.1002/app.27161.

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42

Stamatatos, Theocharis C., and Eva Rentschler. "Organic chelate-free and azido-rich metal clusters and coordination polymers from the use of Me3SiN3: a new synthetic route to complexes with beautiful structures and diverse magnetic properties." Chemical Communications 55, no. 1 (2019): 11–26. http://dx.doi.org/10.1039/c8cc08854c.

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A new synthetic route to structurally novel and magnetically interesting 3d-metal azido clusters and coordination polymers is presented; the key reagent for the preparation of solely azido-bridged molecule-based species is the organic azide precursor Me<sub>3</sub>SiN<sub>3</sub>.

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43

Uflyand, Igor E., Irina V. Kokoreva, Victor N. Sheinker, and Alexander S. Kuzharov. "Metal-containing monomers. Part 2. Preparation of polytetrafluoroethylene-grafted copper(II) chelate polymers and their use as lubricants." Transition Metal Chemistry 17, no. 4 (1992): 360–63. http://dx.doi.org/10.1007/bf02910909.

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44

Ukey, Vaishali V., and Harjeet D. Juneja. "Synthetic and spectroscopic studies of chelate polymers involving azelaoyl bis-N-phenyl hydroxamic acid with transition metal ions." Journal of Applied Polymer Science 99, no. 1 (2005): 273–78. http://dx.doi.org/10.1002/app.22474.

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45

Abbas Omran, Khalida. "The Construct and Interpretation of Chelated Coordination Polymers and Their Use in Nanomaterials Research." Journal of Environmental and Public Health 2022 (August 10, 2022): 1–13. http://dx.doi.org/10.1155/2022/3937375.

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Presently, an important step from basic research to practical applications is synthesizing nanostructured materials. Metal-organic structures, as well as coordination polymers, are a diverse group of materials with a wide range of potential and properties applications. It has been difficult to get these materials into commercial use because of many drawbacks. Polymers containing chelated units are described and assessed for their advancements and problems in preparation, properties, and structure. Here, a proposed approach based on designing coordination polymeric materials with chelated units

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46

Akgöl, Sinan, Deniz Türkmen, and Adil Denizli. "Cu(II)-incorporated, histidine-containing, magnetic-metal-complexing beads as specific sorbents for the metal chelate affinity of albumin." Journal of Applied Polymer Science 93, no. 6 (2004): 2669–77. http://dx.doi.org/10.1002/app.20757.

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47

Zhou, Lin-Cheng, Yan-Feng Li, Shu-Jiang Zhang, Xi-Jun Chang, Ying-Feng Hou, and Hai-Xia Yang. "Synthesis of chelate resins derived from furfural and their adsorption properties for metal ions." Journal of Applied Polymer Science 99, no. 4 (2005): 1620–26. http://dx.doi.org/10.1002/app.22528.

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48

Odaba?i, Mehmet, Bora Garipcan, and Adil Denizli. "Preparation of a novel metal-chelate affinity beads for albumin isolation from human plasma." Journal of Applied Polymer Science 90, no. 10 (2003): 2840–47. http://dx.doi.org/10.1002/app.12993.

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49

Sasikala T, Greeshma KP, Gnana Priya K, Muthulingam S, and Nandhakumar C. "Synthesis, characterization and chelating properties of tannin-8-hydroxy quinoline - formaldehyde polymer." GSC Advanced Research and Reviews 5, no. 2 (2020): 019–23. http://dx.doi.org/10.30574/gscarr.2020.5.2.0083.

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Tannin obtained from Eucalyptus plant, condensed with formaldehyde and then 8-hydroxy quinoline. The so called obtained polymer designated as TFQ was used for metal chelate formation. Thus Transition metal chelates of TFQ with Zn+2, Co+2, Cu+2, Ni+2 and Mn+2 metal ions were prepared. The ligand TFQ and its all five metal chelates were characterized by nitrogen content, IR, UV-Visible spectral studies, magnetic moments and thermogravimetry. The antimicrobial activity of all the samples has also been monitored against common microbes.

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Blasi, Delia, Pierluigi Mercandelli та Lucia Carlucci. "Supramolecular Frameworks and a Luminescent Coordination Polymer from New β-Diketone/Tetrazole Ligands". Inorganics 10, № 4 (2022): 55. http://dx.doi.org/10.3390/inorganics10040055.

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Abstract:

Mixed multidentate linkers with donor groups of different types can be fruitfully exploited in the self-assembly of coordination polymers (CPs) and Metal-Organic Frameworks (MOFs). In this work we develop new ligands containing a β-diketone chelating functionality, to better control the stereochemistry at the metal center, and tetrazolyl multidentate bridging groups, a combination not yet explored for networking with metal ions. The new ligands, 1,3-bis(4-(1H-tetrazol-5-yl)phenyl)-1,3-propanedione (H3L1) and 1-phenyl-3-(4-(1H-tetrazol-5-yl)phenyl)-1,3-propanedione (H2L2), are synthesized from

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