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Dissertations / Theses on the topic 'Metal complex dyes'

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Published: 4 June 2021

Last updated: 1 February 2022

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1

Kazlauskienė, Eglė. "Sorption of metal complex dyes onto ion exchanger resins." Doctoral thesis, Lithuanian Academic Libraries Network (LABT), 2012. http://vddb.laba.lt/obj/LT-eLABa-0001:E.02~2012~D_20120131_092413-89661.

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Metal complex dyes are a problematic group of substances, present in the negatively charged anion form in mixed industrial wastewater that should be removed. Therefore, a complete removal of these hazardous dyes from wastewaters is necessary to prevent them from release into the environment. Adsorption on activated carbon of dyes has been investigated widely. However some disadvantages using activated carbon in practice were observed, e.g. high regeneration costs and production of fines due to the brittle nature. Since their adsorption capacities, mechanical strength, and other properties need

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2

Kazlauskienė, Eglė. "Metalo kompleksinių dažiklių sorbcija jonitais." Doctoral thesis, Lithuanian Academic Libraries Network (LABT), 2012. http://vddb.laba.lt/obj/LT-eLABa-0001:E.02~2012~D_20120131_092423-21579.

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Pagrindinis aplinkosauginės politikos bruožas yra taršos metalo dažikliais mažinimas gamybos metu ir efektyvių šalinimo iš nuotekų metodų paieška. Regeneruojami, mechaniškai atsparūs ir nekenksmingi gamtai polimeriniai sorbentai naudojami dažikliams valyti yra pranašesni už plačiai paplitusias aktyvintąsias anglis. Ištyrus polimerinių sorbentų sorbcines ir regeneracines savybes, nustačius palankias darbines sąlygas, sorbentai gali būti pritaikomi nuotekų valymui, o išvalytas vanduo grąžinamas atgal į gamybinius procesus. Tokiu būdu, vandens ištekliai gali būti apsaugoti nuo taršos sunkiaisiais

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3

Geary, Elaine A. M. "Transition metal complexes as solar cell dyes." Thesis, University of Edinburgh, 2005. http://hdl.handle.net/1842/12198.

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Dye-Sensitised Solar Cells (DSSC) were first reported in the early 1990’s and function by the sensitisation of a semiconductor using a dye molecule such as organic and transition metal organometallic dyes. This thesis reports the synthesis and characterisation of transition metal dyes with applications as sensitisers in DSSC. Complexes of Ni, Pd and Pt were investigated for use in standard liquid electrolyte cells and Donor-Acceptor type solid-state solar cells. A family of [Pt(II)(diimine)(dithiolate)] complexes of general formula [Pt{X,X’(CO<sub>2</sub>R)<sub>2</sub>-bpy}(mnt)] (where X=3, 4

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4

Linfoot, Charlotte Louise. "First row transition metal complexes for application to dye-sensitised solar cells." Thesis, University of Edinburgh, 2011. http://hdl.handle.net/1842/4870.

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Ruthenium (II) complexes are used extensively in photoelectrochemical and photophysical devices, such as Dye-Sensitized Solar Cells (DSSCs). The use of Cu(I) as a possible replacement for Ru(II) has to date had limited exploration, but has obvious advantages in terms of low cost and high abundance. However, Cu(I) typically undergoes conformational change from tetrahedral towards square planar upon oxidation or MLCT excitation, often leading to reduced stability, reduced electron transfer rates and reduced excited state lifetime, thus impairing useful function. Typically, steric constraints are

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5

Chen, Wei-Hsuan. "Triimine Complexes of Divalent Group 10 Metals for Use in Molecular Electronic Devices." Thesis, University of North Texas, 2010. https://digital.library.unt.edu/ark:/67531/metadc30443/.

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This research focused on the development of new metal triimine complexes of Pt(II), Pd(II), and Ni(II) for use in three types of molecular electronic devices: dye sensitized solar cells (DSSCs), organic light-emitting diodes (OLEDs), and organic field effect transistors (OFETs). Inorganic complexes combine many advantages of their chemical and photophysical properties and are processable on inexpensive and large area substrates for various optoelectronic applications. For DSSCs, a series of platinum (II) triimine complexes were synthesized and evaluated as dyes for nanocrystalline oxide semico

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6

Rosero, Wilmmer Alexander Arcos. "Complexos de rutênio supramoleculares do tipo metal-orgânico e sua aplicação em fotoeletroquimica." Universidade de São Paulo, 2018. http://www.teses.usp.br/teses/disponiveis/46/46136/tde-24092018-153719/.

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O presente trabalho tem como objetivo contribuir para o conhecimento, entendimento e desenvolvimento das células solares sensibilizadas por corantes. Assim foram abordadas rotas sintéticas com o fim de obter novas espécies supramoleculares constituídos por fragmentos que apresentam separadamente ótimas propriedades eletrônicas e eletroquímicas. A abordagem sintética feita é muito importante dado que dá as bases para sistemas supramoleculares como o apresentado nas perspectivas, nos quais estase visando diminuir os processos de recombinação e melhor aproveitamento do espectro solar através da e

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7

Gresser, Roland, Alexander Hoyer, Markus Hummert, Horst Hartmann, Karl Leo, and Moritz Riede. "Homoleptic Co(II), Ni(II), Cu(II), Zn(II) and Hg(II) complexes of bis-(phenyl)-diisoindol-aza-methene." Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2014. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-138691.

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The synthesis of five homoleptic transition metal complexes of bis-(phenyl)-diisoindol-aza-methene is described together with the optical, electrochemical and thermal properties of these compounds. Additionally, crystal structures for the Co and the Zn complex are reported<br>Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich

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8

Gresser, Roland, Alexander Hoyer, Markus Hummert, Horst Hartmann, Karl Leo, and Moritz Riede. "Homoleptic Co(II), Ni(II), Cu(II), Zn(II) and Hg(II) complexes of bis-(phenyl)-diisoindol-aza-methene." Royal Society of Chemistry, 2011. https://tud.qucosa.de/id/qucosa%3A27773.

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The synthesis of five homoleptic transition metal complexes of bis-(phenyl)-diisoindol-aza-methene is described together with the optical, electrochemical and thermal properties of these compounds. Additionally, crystal structures for the Co and the Zn complex are reported.<br>Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.

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9

Hudson, Joshua M. "Photophysical studies of silver(I), platinum(II), palladium(II), and nickel(II) complexes and their use in electronic devices." Thesis, University of North Texas, 2007. https://digital.library.unt.edu/ark:/67531/metadc5165/.

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This dissertation deals with two major topics that involve spectroscopic studies of (a) divalent group 10 metals and (b) silver(I)-phosphine complexes. The scope of the work involved the delineation of the electronic structure of these complexes in different environments and their use in electronic devices. The first topic is a look at the luminescence of tetrahedral silver(I)-phosphine complexes. Broad unstructured emissions with large Stokes shifts were found for these complexes. Computational analysis of the singlet and triplet state geometries suggests that this emission is due to a Jahn-T

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10

Lindblad, Rebecka. "Electronic Structures and Energy Level Alignment in Mesoscopic Solar Cells : A Hard and Soft X-ray Photoelectron Spectroscopy Study." Doctoral thesis, Uppsala universitet, Molekyl- och kondenserade materiens fysik, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-221450.

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Photoelectron spectroscopy is an experimental method to study the electronic structure in matter. In this thesis, a combination of soft and hard X-ray based photoelectron spectroscopy has been used to obtain atomic level understanding of electronic structures and energy level alignments in mesoscopic solar cells. The thesis describes how the method can be varied between being surface and bulk sensitive and how to follow the structure linked to particular elements. The results were discussed with respect to the material function in mesoscopic solar cell configurations. The heart of a solar cell

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11

Rico, Santacruz Marisa. "Band gap control in hybrid titania photocatalysts." Doctoral thesis, Universidad de Alicante, 2014. http://hdl.handle.net/10045/42201.

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12

Arias, Olivares David. "Relation Among Localization, Delocalization and Physicochemical Properties. From Electron Density Databases to Magnetic Properties Eﬀects of the acceptor unit in dyes with acceptor–bridge–donor architecture on the electron photo-injection mechanism and aggregation in DSSCs The role of Cr, Mo and W in the electronic delocalization and the metal–ring interaction in metallocene complexes". Thesis, Sorbonne université, 2019. http://www.theses.fr/2019SORUS015.

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Tout d'abord, nous évoquerons un aperçu général de l'analyse topologique basée sur la densité d'électronique, le trou d'échange-corrélation et la densité de paires. Une fois la densité électronique rappelée, l'analyse topologique de la densité électronique est expliquée, ainsi que la procédure de calcul des points critiques de la densité électronique, le calcul de la matrice hessienne de la densité électronique et la définition des points critiques à la surface. Tous ces outils topologiques permettent de caractériser la nature des liaisons chimiques parallèlement à l'indice basé sur la délocal

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13

Zhou, Yu De, and 周育德. "Synthesis and properties of 2:1 metal complex dyes." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/01100628467097048248.

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14

Chou, Yuh Der, and 周育德. "Synthesis and Properties of 2:1 Metal Complex Dyes." Thesis, 1994. http://ndltd.ncl.edu.tw/handle/85029720100940186610.

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碩士<br>國立臺灣科技大學<br>纖維工程技術系<br>82<br>2:1 metal complex dyes were synthesized by the reaction of o- Phenylenediamine, o-Aminophenol and o-Dihydroxybenzene with Nickel Chloride and Cobalt Chloride. Their chemical structure were confirmed as 2:1 metal complex dyes by UV／Visible spectra, infrared spectra, elemental analysis, and titration method. The dyes were characterized by thermal analysis, conductivity measurement, X-ray powder diffraction, and photofading. These dyes that from o-Phenylenedi

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15

Li, Chao Cheng, and 趙成禮. "Synthesis and Photofading Properties of Pyridone Metal Complex Azo Dyes." Thesis, 1993. http://ndltd.ncl.edu.tw/handle/11357040861416080279.

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16

Hsueh, Chih-Yuan, and 薛智遠. "Synthetic Studies on Azo Metal Complex Dyes for High Density Optical Recording Media." Thesis, 2007. http://ndltd.ncl.edu.tw/handle/45113540562329374647.

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碩士<br>朝陽科技大學<br>應用化學系碩士班<br>95<br>The difference between HD DVD-R and DVD-R is that the memory capacity of HD DVD-R is 3 to 5 times larger than DVD-R. The increase in meaning capacity is caused by the reduction of track width and distance between tracks. Thus, for the same size compact disk, HD DVD-R provides more memory tracks. With regards to such a thinness of the memory track, the laser dye layer plays a very critical role to absorb the blue-ray laser with higher energy. The principle of the barning process form the memory data on disc is caused by laser dye to pits and lands when it abs

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17

Lu, Jun-Jie, and 盧俊傑. "PART 1.Synthetic Studies on Azo Metal Complex Dyes for High Density Optical Recording MediaPART 2. Synthetic Studies on Temperature Sensitive Dyes." Thesis, 2008. http://ndltd.ncl.edu.tw/handle/86402177743824683572.

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碩士<br>朝陽科技大學<br>應用化學系碩士班<br>96<br>part1 The difference between HD-DVD and DVD-R is that the memory capacity of HD-DVD is 3 to 5 times of DVD-R. The increase of recerdting capatity is due to the track width of swaerding spot seduced form 0.74μm of DVD-R to 0.32μm of HD-DVD。Thus, for the same size compact disk, HD-DVD provides more memory tracks. With regards to such a thin the memory track, the laser dye layer plays a very important role to absorb the blue-ray laser with higher energy. The principle of the barning process form the memory data on disc is caused by laser dye to pits and lands wh

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18

Ching, Liao Tzu, and 廖姿菁. "Conductance-metal complex dye PU Resin." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/69624142688067780550.

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碩士<br>中國文化大學<br>應用化學研究所<br>90<br>英文摘要 The reaction of various metal-complex dye with toluene diisocyanate and other additives to from the structure of the metal-complex dye polyurethane resin has been proven by FT-IR spectra. Experimental results show that, for the conductive type of metal-complex dye polyurethane resin in organic solvent, the surface tension for this resin molecule appears not to change with increased the concentration of special type siloxane and carbon black, respectively. The reason because increased adsorption of hydrophilic groups at the surface of the organic

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19

Chen, Bo-So, and 陳柏壽. "Ruthenium metal complex and organic dye based dye-sensitized solar cell studies." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/99478919107678134820.

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20

Lo, Wei-Chen, and 羅偉誠. "On the study of metal-complex dye polyurethane ionomer." Thesis, 2001. http://ndltd.ncl.edu.tw/handle/67474805466374744369.

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21

Yu-Ray, Wang, and 王育瑞. "A Study of the effect about Surfactant to Metal-complex Rective Dye." Thesis, 1996. http://ndltd.ncl.edu.tw/handle/06613289613320167498.

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22

Liu, Hsin-Lan, and 劉秀蘭. "On the Study of Metal-complex dye Polyurethane Ionomers Their Physical Properties." Thesis, 2001. http://ndltd.ncl.edu.tw/handle/23261406953743465888.

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碩士<br>中國文化大學<br>應用化學研究所<br>89<br>Abstract The reaction of toluene diisocyanate (TDI) with polyester and metal-complex dye forms metal-complex dye polyurethane (PU) ionomers, and their structures have been proven by FT-IR spectra. Experimental results show that the viscosity are seen to increase with increasing the concentration of metal-complex dye. This is the result of increased free volume of PU ionomer molecule. For yellow metal-complex dye PU ionomer solution, the surface tension are seen to decrease with increasing the concentration of yellow metal-complex dye. This

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23

蔡俊隆. "Synthesis and properties of metal complexes of an o, o�-dihydroxy azo pyridone dyes." Thesis, 1992. http://ndltd.ncl.edu.tw/handle/18298932337414714910.

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24

Lai, Hsi-Chou, and 賴錫洲. "On the study of the Electronic Conductivity of the Metal-complex Dye Polyurethane Ionomer." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/53591507119918584077.

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碩士<br>中國文化大學<br>應用化學研究所<br>90<br>Abstract The organic solvent used as a diluent for the resin industry is gradually being replaced by a nonpollutant water. The reaction of toluene diisocyanate with polyester, dimethylol proionic acid, metal-complex dye and other additives to form the structure of metal-complex dye polyurethane ionomer molecule has been proven by FT-IR spectra. The number average particle size of metal-complex dye polyurethane ionomer molecule in aqueous solution appears to steadily increase with an increase of the concentration of meta

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25

HSU, CHIA-HSUAN, and 許嘉軒. "Synthesis of new metal-salen complexes of dye-sensitized solar cells." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/44954729911496399118.

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碩士<br>國立中央大學<br>化學研究所<br>98<br>With increasing renewable energy demands, dye-sensitized solar cells (DSSCs) are being explored extensively for photovoltaic applications because of their versatility and low cost of manufacture. In these cells the sensitizer is one of the key components, harvesting the solar radiation and converting it to electric current. To date, the only ruthenium sensitizers for DSSC applications that have been described in the literature are those bearing bipyridine or polypyridine ligands. But ruthenium metal is not full in the earth，therefore enhances the cost of manufact

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26

林佑霖. "On the study of the effect of silica on the metal-complex dye polyurethane ionomers." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/24981928814750510200.

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碩士<br>中國文化大學<br>應用化學研究所<br>90<br>The addition of siloxane into metal-complex red、yellow and black dye react with toluene diisocyanate and other ingredients to form the structure of siloxane with metal-complex dye polyurethane ionomer has been proven by FT-IR spectrum. Experimental results show that viscosity for siloxane with metal-complex dye polyurethane ionomer in aqueous solution appear to increase with increasing the concentration of siloxane because of increasing free volume of the polyurethane ionomer molecule. As for the surface tension of siloxane with metal-com

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27

CHUANG, YI-JU, and 莊易儒. "On the study of the Synthesis of Application of Metal-complex Dye Photosenitive Polyurethane Ionomers." Thesis, 2001. http://ndltd.ncl.edu.tw/handle/41429448893238387315.

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碩士<br>中國文化大學<br>應用化學研究所<br>89<br>The reaction of toluene diisocyanate with polyester, metal-complex dye, dimethylol propionic acid, hydroxypropyl acrylate and other additives froms metal-cpmplex dye photosenitive polyurethane ionomers, and their structures have been proven by FT-IR spectra.. The surface tension of metal-cpmplex dye photosenitive polyurethane ionomer molecule increase slightly with increasing concentration of metal-complex dye , hydroxypropyl acrylate and benzophenone, respectively. This is because the adsorption of htdrophobics of ionomer molecules at the surface of

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28

Chun-Hsiung, Chiu, and 邱俊雄. "On the Study of Effect of Metal-Complex Dye on the Electronic Conductivity of Polyurethane Ionomer." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/79904567236459009950.

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碩士<br>中國文化大學<br>應用化學研究所<br>90<br>Abstract The reaction of toluene diisocyanate with different metal-complex dye and other ingredients to form the structure of the metal-complex dye polyurethane ionomer has been proven by FT-IR spectra. Experimental results show that the viscosity for various metal-complex dye polyurethane ionomer in aqueous solution appears to increase with increasing the concentration of the metal-complex dye . As for the surface tension of the metal-complex dye polyurethane ionomer in water, it was found not to change with increasing the concentration of the metal

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29

WANG, WUN-SHIUAN, and 王文璇. "Reduced Graphene Oxide/Macrocyclic Metal Complex Hybrid Materials as Counter Electrodes for Dye-Sensitized Solar Cells." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/vs7npd.

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碩士<br>輔仁大學<br>化學系<br>105<br>Dye-sensitized solar cells (DSSCs) have the advantages of simple process, high efficiency, and low cost. DSSCs have been investigated extensively due to their various features and merits for applications in renewable energy. A typical DSSC consists of a transparent conductive substrate, TiO2 nanoparticles, dyes, an electrolyte, and a platinum (Pt) counter electrode (CE). However, Pt is a rare and expensive metal element and may limit the DSSC applications. As such, replacing the expensive Pt with other materials having the required electrochemical properties for the

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30

Huang, Chun-Min, and 黃群閔. "On the Study of the Physical Properties Doped with Conductive Polymers , Metal-complex Dye in Water-soluble PU." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/81234034981150759318.

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碩士<br>中國文化大學<br>應用化學研究所<br>90<br>Abstract The conductivity polymers of polyaniline consists of alternating single and double bonds, called conjugate double bonds, which make its electrons free to move and becomes electrically conductive. To raise its conductivity, PAn is doped with proton acid and then adds metal-complex dye polyurethane ionomer in aqueous solution into it. By stirring it, particles of PAn dispersed in metal-complex dye polyurethane ionomer in aqueous solution. After shaped, its conductivity, EMI and physical properties was measured by ohmmeter and networ

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31

Lin, Chia-Hao, and 林家豪. "Design and Synthesis of a New Type Metal Complex with Dipyridylpyrrole Ligands for Dye-Sensitized Solar Cell Applications." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/hca428.

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碩士<br>國立中央大學<br>化學學系<br>105<br>In dye-sensitized solar cells (DSSCs), the dye which located in absorb layer have been considered as a important role for their power conversion efficiency. In this thesis, I used the dipyridylpyrrole as my Ligand, and I modified it for longer conjugation then reacts with Zinc. Finally, I make it a suitable dye structure, and measure the optical properties. So far, there are no any reports about the metal complex of dipyridylpyrrole ligands in DSSCs. In future, the special metal complex may be a very potential dyes in DSSCs.

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Chang, Li-Wei, and 張立瑋. "Metal-chelating character of wastewater generated from metal-complex dye manufacturing processes: Using chelated iron concentration to evaluate the removal efficiency of chelating functional group and treatment options." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/16289395682446665980.

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碩士<br>淡江大學<br>水資源及環境工程學系碩士班<br>100<br>In this study, Dye manufacturing processes wastewater (DMPW) is the effluent generated from synthesizing process of dyes, consisting of intermediated compounds, monomer structure, and dyes molecules. Coagulation is found to be an inefficient process for removing organic matters. Color of treated water is increased with the decreasing coagulation pH. Measured dissolved iron after coagulation allowed one to evaluate the content of functional groups of organics which can chelate iron from coagulant. Organic removal efficiency is also not very well when pre-pr

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Chiang, Shun-Chi, and 江舜琦. "Design and Synthesis of pyridyl thieno[3,4-d]imidazole Based Metal Complexes for Dye Sensitized Solar Cell Applications." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/50744148033867889330.

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碩士<br>國立中央大學<br>化學學系<br>105<br>Dye-Sensitized Solar Cells (DSSCs) have been one of the mostly studied technologies because of their advantages like simple fabrication process, low cost, and flexibility, etc. Metal complexes and organic dyes have their own advantages; therefore, combining them together might afford a novel and efficient sensitizer, has become our goal of research. We designed a series of organic-inorganic dyes consisting pyridyl thieno[3,4-d]imidazole ligand. The pure organic sensitizer can coordinate with metal and form transition metal complex to be a hybrid sensitizer. Our n

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