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Dissertations / Theses on the topic 'Metal Complexes - Electron Transfer'

Author: Grafiati

Published: 4 June 2021

Last updated: 7 September 2023

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1

Wilson, L. M. "Electron-transfer properties of polynuclear complexes." Thesis, University of East Anglia, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.374277.

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2

Poyraz, Mehmet. "Valence localisation in transition metal cluster complexes." Thesis, University of East Anglia, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.389271.

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3

Delony, Daniel. "Proton Coupled Electron Transfer at Heavy Metal Sites." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2020. http://hdl.handle.net/21.11130/00-1735-0000-0005-1546-5.

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4

Raven, S. J. "One-electron transfer reactions of low-valent transition metal complexes." Thesis, University of Bristol, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.373290.

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5

McDonald, David Robert 1964 Carleton University Dissertation Chemistry. "Photoinduced electron transfer in chromophore-quencher complexes designed for metal centered chemistry." Ottawa.:, 1996.

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6

Koumousi, Evangelia S. "Synthesis and characterization of dinuclear {Fe(μ-CN)Co} complexes exhibiting metal-to-metal electron transfer properties". Thesis, Bordeaux, 2015. http://www.theses.fr/2015BORD0306/document.

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Cette thèse porte sur la synthèse de nouveaux complexes binucléaires à ponts cyanures de type {Fe(μ-CN)Co}, qui reproduisent au sein d'une seule molécule les propriétés originales du réseau de coordination d'analogue de bleu de Prusse AxCo[Fe(CN)6]y•nH2O (A=ions alcalins), i.e. un transfert d'électron intramoléculaire thermo- et photo-induit à l'état solide. Au sein de ce travail, nous nous sommes intéressés à l'étude des propriétés physiques des paires moléculaires Fe/Co, avec l’objectif de comprendre les mécanismes du phénomène de transfert d'électrons. Le chapitre I contient les exemples le

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7

D'Acchioli, Jason S. "On the nature of the electronics structure of metal-metal quadruply bonded complexes." Connect to resource, 2005. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1126621699.

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Thesis (Ph. D.)--Ohio State University, 2005.<br>Title from first page of PDF file. Document formatted into pages; contains xii, 286 p.; also includes graphics (some col.). Includes bibliographical references (p. 273-286). Available online via OhioLINK's ETD Center

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8

Reed, Carly R. "The Photophysical Properties of Multiply Bonded Metal Complexes of Molybdenum, Tungsten, and Rhenium." The Ohio State University, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=osu1309880937.

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9

Chatterjee, Sayandev. "Cooperative Two-Electron Reagents of Lower Transition Metals of Group 10." University of Cincinnati / OhioLINK, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1250266435.

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10

Walker, Glen William, and not available. "Electron Transfer Reactivity, Synthesis, Surface Chemistry and Liquid-Membrane Transport of Sarcophagine-Type Poly-Aza Cage Complexes." The Australian National University, 1997. http://thesis.anu.edu.au./public/adt-ANU20010702.124104.

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[Formulae and special characters can only be approximated here. Please see the pdf version of the Abstract for an accurate reproduction.] The kinetics for outer-sphere electron transfer between a series of cobalt(II) poly-aza cage ligand complexes and the iron(III) sarcophagine-type hexa-aza cage complex, [Fe(sar)]3+ (sar = 3,6,10,13,16,19-hexaazabicyclo[6.6.6]icosane), in aqueous solution have been investigated and the Marcus correlation is used to deduce the electron self-exchange rate constant for the [Fe(sar)]3+/2+ couple from these cross-reactions. The deduced electron self-exchange rate

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11

Finkelmeier, Nils. "Synthesis and Fluorescence Properties of Anthracene Derivatives and their Metal Complexes." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2013. http://hdl.handle.net/11858/00-1735-0000-0023-994A-7.

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12

Ball, Pamilla J. "Investigations of the Electronic Structure and Excited State Processes of Tansition Metal Complexes with Polypyridyl and Schiff Base Ligans." University of Cincinnati / OhioLINK, 2005. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1128805318.

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13

Brown-Xu, Samantha E. "Photophysical and Photosensitizing Properties of Dimetal Quadruply Bonded Paddlewheel Complexes Probed Through Ultrafast Spectroscopy." The Ohio State University, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=osu1405491729.

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14

Nazemi, Azadeh. "Study the pKa of C–H Bonds and Proton-Coupled Electron Transfer Process by Transition Metal Complexes via Computational Methods." Thesis, University of North Texas, 2020. https://digital.library.unt.edu/ark:/67531/metadc1703312/.

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Computational techniques, mostly density functional theory (DFT), were applied to study metal-based catalytic processes for energy conversion reactions. In the first and second projects, the main focus was on activation of the light alkanes such as methane, which have thermodynamically strong and kinetically inert C–H bonds plus very low acidity/basicity. Two Mo-oxo complexes with the different redox non-innocent supporting ligands, diamide-diimine and ethylene-dithiolate, were modeled. These Mo-oxo complexes are modeled inspired by active species of a metalloenzyme, ethylbenzene dehydrogenase

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15

Munisamy, Thiruvengadam Gipson Stephen L. "Electrochemistry and electron transfer induced substitution reactions of methylcyclopentadienylmolybdenum tricarbonyl complexes and electrospray ionization mass spectrometry and x-ray crystallographic characterization of related molybdenum complexes." Waco, Tex. : Baylor University, 2007. http://hdl.handle.net/2104/5234.

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16

Abbenseth, Josh. "Synthesis of Terminal Transition Metal Pnictide Complexes by Activation of Small Molecules." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2019. http://hdl.handle.net/21.11130/00-1735-0000-0003-C18F-2.

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17

Soper, Jake D. "Reactions at nitrogenous ligands on oxidizing group 8 metal centers /." Thesis, Connect to this title online; UW restricted, 2003. http://hdl.handle.net/1773/8589.

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18

Hankache, Jihane [Verfasser], Oliver [Akademischer Betreuer] Wenger, Franc [Akademischer Betreuer] Meyer, Dietmar [Akademischer Betreuer] Stalke, and Jörg [Akademischer Betreuer] Schroeder. "Photoinduced electron transfer in dyads and triads with d6 metal complexes and anthraquinone / Jihane Hankache. Gutachter: Franc Meyer ; Dietmar Stalke ; Jörg Schroeder. Betreuer: Oliver Wenger." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2012. http://d-nb.info/1043938516/34.

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19

Pathirathne, Thusitha. "Theoretical modeling of electron transfer rates between cytochrome c and small transition metal complexes a thesis presented to the faculty of the Graduate School, Tennessee Technological University /." Click to access online, 2009. http://proquest.umi.com/pqdweb?index=0&did=1760001881&SrchMode=1&sid=2&Fmt=6&VInst=PROD&VType=PQD&RQT=309&VName=PQD&TS=1268409541&clientId=28564.

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20

Calancea, Sergiu. "Synthèse et caractérisations de nouveaux complexes binucléaires à transfert d’électron de type {Fe(µ-CN)M} (M = Fe, Mn, Co)." Thesis, Bordeaux 1, 2013. http://www.theses.fr/2013BOR14802/document.

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L’une des grandes directions de recherche dans la chimie moderne est la synthèse et l’étude denouveaux composés « commutables » capables de modifier leurs propriétés sous l’effet de stimuli extérieurs (température, lumière, champ magnétique ou électrique…). Ces systèmes peuvent stocker une information à l’échelle moléculaire. Dans ce contexte, parmi les systèmes les plus étudiés en chimie de coordination figurent les réseaux et les analogues moléculaires du bleu de Prusse. Cette thèse est dédiée à la synthèse et aux caractérisations de nouveaux analogues moléculaires du bleu de Prusse à transf

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21

Miesel, Dominique. "Beeinflussung der Metall-Metall-Interaktionen in Ferrocenyl-funktionalisierten Phospholen." Doctoral thesis, Universitätsbibliothek Chemnitz, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-198963.

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Die vorliegende Arbeit beschreibt die Synthese Ferrocenyl-funktionalisierter Phosphole und deren elektrochemische sowie spektroelektrochemische Charakterisierung zur Bestimmung der Stärke der Metall-Metall-Wechselwirkungen. Aufgrund der mangelnden Aromatizität stehen das freie Elektronenpaar am Phosphoratom und das dienische System für weitere Reaktionen zur Verfügung. Somit konnten gezielt Modifikationen am heterozyklischen Grundgerüst vorgenommen werden, um dessen elektronische Eigenschaften zu beeinflussen. Ein Schwerpunkt der Arbeit lag im Aufbau eines Phospholsystems mit Ferrocenyl-subst

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22

Gosavi, Shachi S. Kuppermann Aron Marcus R. A. "Electron transfer at metal surfaces /." Diss., Pasadena, Calif. : California Institute of Technology, 2003. http://resolver.caltech.edu/CaltechETD:etd-03192003-095722.

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23

Singh, Priti. "The electron transfer chemistry of nitrosyl complexes." [S.l. : s.n.], 2008. http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-34223.

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24

Casale, Mariana Romano Camilo. "Desenvolvimento de processos químicos seguindo os princípios adotados pela química verde: redução e conversão de CO2 usando compostos de Mn(I)." Universidade Federal de São Carlos, 2014. https://repositorio.ufscar.br/handle/ufscar/6319.

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Made available in DSpace on 2016-06-02T20:34:56Z (GMT). No. of bitstreams: 1 6264.pdf: 6241491 bytes, checksum: c10b9312872f17d86e9c24ccd25b2508 (MD5) Previous issue date: 2014-10-09<br>Universidade Federal de Minas Gerais<br>Due to its versatile chemistry and ability to stabilize metals with low oxidation states, carbonyl compounds of transition metals play an important role in various fields of organometallic chemistry. In our research group, we have studied carbonyl compounds of manganese (I) over time and investigated their photochemical and spectroscopic properties. We carried out studi

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25

Londergan, Casey H. "Electron transfer and delocalization in mixed-valence complexes /." Diss., Connect to a 24 p. preview or request complete full text in PDF format. Access restricted to UC campuses, 2003. http://wwwlib.umi.com/cr/ucsd/fullcit?p3091312.

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26

Schneck, Felix. "Proton-Coupled Electron Transfer at Nickel Pincer Complexes." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2019. http://hdl.handle.net/11858/00-1735-0000-002E-E64C-9.

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27

Kumari, Sudesh. "ELECTRON AND ION SPECTROSCOPY OF METAL HYDROCARBON COMPLEXES." UKnowledge, 2014. http://uknowledge.uky.edu/chemistry_etds/30.

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Metal-hydrocarbon complexes were prepared in a laser-vaporization molecular beam source and studied by single-photon zero electron kinetic energy (ZEKE) and mass-analyzed threshold ionization (MATI) spectroscopy. The ionization energies and vibrational frequencies of the metal complexes were measured from the ZEKE and MATI spectra. Metal-ligand bonding and low-lying electronic states of the neutral and ionized complexes were analyzed by combining the spectroscopic measurements with quantum chemical calculations and spectral simulations. In this dissertation, the metal complexes of mesitylene,

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28

Khandelwal, B. "Metal complexes of electron-rich arsenic-sulphur ligands." Thesis, University of Exeter, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.378245.

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29

He, Dian. "CHIRALITY TRANSFER AND ELECTRON TRANSFER IN DENDRITIC COMPLEXES WITH STABLE SECONDARY STRUCTURE." The Ohio State University, 2008. http://rave.ohiolink.edu/etdc/view?acc_num=osu1222186119.

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30

Quarmby, I. C. "Electron-transfer reactions of octahedral manganese (I) carbonyl complexes." Thesis, University of Bristol, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.233742.

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31

Galan, Elena. "Catalysis of phosphoryl transfer reactions by metal complexes." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape3/PQDD_0012/MQ52900.pdf.

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32

Hamilton, Charles W. Ph D. Massachusetts Institute of Technology. "Nitrene transfer reactions by late transition metal complexes." Thesis, Massachusetts Institute of Technology, 2007. http://hdl.handle.net/1721.1/38618.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2007.<br>Vita.<br>Includes bibliographical references.<br>This thesis presents nitrene transfer reactions that are catalyzed or mediated by late transition metal complexes. Sterically large, fluorinated supporting ligands are used to minimize potential side reactions. A new 1,10-phenanthroline ligand has been synthesized with 2,4,6-(CF3)3C6H2- groups in the 2- and 9-positions (1). A cationic copper(l) complex of 1 catalyzes nitrene transfer from N-(p-toluenesulfonylimino)phenyliodinane (PhlNTs) to the C-H bonds of 1,3-

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33

Barthram, Anita Marie. "Metal-metal interactions in polynuclear complexes of ruthenium and osmium." Thesis, University of Bristol, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.326683.

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34

Zalich, Michael Andrew. "Physical Properties of Magnetic Macromolecule-Metal and Macromolecule-Metal Oxide Nanoparticle Complexes." Diss., Virginia Tech, 2005. http://hdl.handle.net/10919/27528.

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Magnetic nanoparticles are of considerable interest owing to their potential applications in biotechnology and the magnetic recording industry. Iron oxides have received much attention owing to their oxidative stability and biocompatibility; however, other transition metals and their alloys are also under investigation. Cobalt has one of the largest magnetic susceptibilities of these materials, but it readily oxidizes upon exposure to air resulting in antiferromagnetic oxide. Hence, coating cobalt nanoparticles with an oxygen-impermeable sheath would confer numerous benefits. Cobalt nanopa

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35

Butson, Jeffery M. "Electron Transfer and Other Reactions Using Atomic Metal Anions." Thèse, Université d'Ottawa / University of Ottawa, 2014. http://hdl.handle.net/10393/30561.

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The atomic metal anions Rb-, Cs-, Cu-, Ag- and Fe- have been generated in the gas phase and reacted with various neutral reactants in a triple quadrupole mass spectrometer. The metal anions were formed via electrospray ionization of the metal-oxalate solutions and form in gas phase between the capillary and the first quadrupole. Neutral gas phase reactants investigated include NO, NO2, SO2, C6F5OH, C6F5NH2, C6F6, E-octafluoro-butene and 1,2,3/1,2,4/1,3,5 trifluoro-benzene. When possible, CBS-4M methods were used to suggest the lowest energy products based on relative energy. Observed reactions

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36

Gnandt, David [Verfasser], Thorsten [Akademischer Betreuer] Koslowski, and Oliver [Akademischer Betreuer] Einsle. "A multi-scale approach to electron transfer in protein complexes." Freiburg : Universität, 2020. http://d-nb.info/1226656978/34.

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37

Liang, Shengwen. "Nitrene Transfer Reactions Mediated by Transition Metal Scorpionate Complexes." Ohio University / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1339005115.

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38

Cooper, Glyn. "Photoelectron spectroscopy of transition metal complexes." Thesis, University of Oxford, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.670392.

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39

Addy, David A. "Borane, boryl and borylene complexes of electron rich metal centres." Thesis, University of Oxford, 2012. http://ora.ox.ac.uk/objects/uuid:211632be-dd28-439c-9dee-0a214a7dc660.

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The synthesis and characterisation of a series of novel borane, boryl and borylene complexes of electron rich group 8 and 9 metal centres are described in this thesis. Chapter 3 reports on the properties of a highly nucleophile tolerant borylene system, [CpFe(dmpe)(BNMe₂)]⁺, together with its surprising formation via an unprecedented spontaneous halide ejection process. The incorporation of strongly electron releasing ancillary phosphine ligands is reflected by an Fe-B distance (ca. 1.80 Å) which is more akin to alkyl/aryl substituted borylene complexes, and perhaps more strikingly, by the ver

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40

Vidayaratne, Indu. "Metal to ligand electron transfer for molecular activation and catalysis." Thesis, University of Ottawa (Canada), 2010. http://hdl.handle.net/10393/28735.

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The ultimate goal of this thesis was to elucidate the metal oxidation state of the active species in the catalytic cycle for ethylene oligo- and polymerization, and understanding the nature of the catalyst/co-catalyst interaction. Central to achieving these goals is of course the judicious choice of the metal and ligand system enabling the isolation and characterization of species arising from the interaction catalyst precursor/activator, and an investigation of their catalytic behaviour. Two families of ligands (bis-iminopyridine) and pyrrolide anions have been used for different sets of reas

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41

Delony, Daniel [Verfasser]. "Proton Coupled Electron Transfer at Heavy Metal Sites / Daniel Delony." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2021. http://d-nb.info/1225121620/34.

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42

Liu, Peng. "Oxidation and nitrene transfer reactions catalyzed by iron-oligopyridine complexes." Click to view the E-thesis via HKUTO, 2009. http://sunzi.lib.hku.hk/hkuto/record/B42664275.

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43

Mhinzi, Gaspar Stephen. "Three-centre, two-electron interactions in Pt(II) diphosphine complexes." Thesis, University of Salford, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.305885.

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44

Berglund, Baudin Helena. "Electron and Energy Transfer in Supramolecular Complexes Designed for Artificial Photosynthesis." Doctoral thesis, Uppsala : Acta Universitatis Upsaliensis : Univ.-bibl. [distributör], 2001. http://publications.uu.se/theses/91-554-5033-4/.

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45

Petersson, Jonas. "Ultrafast, Non-Equilibrium Electron Transfer Reactions of Molecular Complexes in Solution." Doctoral thesis, Uppsala universitet, Fysikalisk kemi, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-235461.

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Photoinduced electron transfer is a fundamentally interesting process; it occurs everywhere in the natural world. Studies on electron transfer shed light on questions about the interaction between molecules and how the dynamics of these can be utilized to steer the electron transfer processes to achieve a desired goal. The goal may be to get electrons to the electrode of a solar cell, or to make the electrons form an energy rich fuel such as hydrogen, and it may also be an input or output for molecular switches. The importance of electron transfer reactions will be highlighted in this thesis,

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46

Davies, Stephen Robert. "Synthesis and characterisation of charge transfer complexes of new electron acceptors." Thesis, Durham University, 1989. http://etheses.dur.ac.uk/6507/.

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New electron acceptors, possessing various skeletal frameworks have been prepared and characterised. Complexation with a range of metal and organic cations reveal the suitability of the electron acceptors in the field of conducting charge-transfer complexes. Unsuccessful attempts to synthesise sterically demanding TCNQ derivatives, directly from the corresponding p-benzoquinone in the presence of titanium tetrachloride, provided a convenient route to a range of mono (dicyanomethylated)alkyl-p-benzoquinones, which were converted into N,7,7-tricyanoquinomethaneimine derivatives. Semi conducting

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47

Liu, Peng, and 劉鵬. "Oxidation and nitrene transfer reactions catalyzed by iron-oligopyridine complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2009. http://hub.hku.hk/bib/B42664275.

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48

Madduma-Liyanage, Kumudu C. "Reactions of Pt(IV) and Pd(IV) Complexes with Multi-Electron Substrates." University of Cincinnati / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1416570506.

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49

Pitts, Michael Robert. "Selective reductions with indium metal." Thesis, University of Exeter, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.324718.

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50

唐素明 and So-ming Glenna Tong. "Theoretical studies of transition metal containing diatomics and DNA electron transfer." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2002. http://hub.hku.hk/bib/B31244828.

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