Academic literature on the topic 'Metal complexes. Ruthenium. Iron'

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Journal articles on the topic "Metal complexes. Ruthenium. Iron"

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Kim, Junhwan, and Malcolm E. Kenney. "The synthesis and properties of iron, ruthenium, and osmium octabutoxynaphthalocyanine." Journal of Porphyrins and Phthalocyanines 16, no. 09 (September 2012): 1068–71. http://dx.doi.org/10.1142/s1088424612500903.

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New series of iron, ruthenium, and osmium octabutoxynaphthalocyanines were synthesized by inserting corresponding metals into the metal-free octabutoxynaphthalocyanine. Although preparation of axial ligand-free iron octabutoxynaphthalocyanines was reported before, we could not reproduce the synthesis by following the reported method. We attributed the failure to the instability of the iron octabutoxynaphthalocyanines. Bis-ligation increased the stability of the iron complex but only sufficiently for characterization. The application of iron complexes will be limited by their instability. However, ruthenium and osmium formed stable complexes with this macrocycle ring but with significantly lower reaction yields. These new complexes were characterized by NMR, UV-vis, and mass spectrometry.
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Gaiddon, Christian, Isabelle Gross, Xiangjun Meng, Marjorie Sidhoum, Georg Mellitzer, Benoit Romain, Jean-Batiste Delhorme, Aïna Venkatasamy, Alain C. Jung, and Michel Pfeffer. "Bypassing the Resistance Mechanisms of the Tumor Ecosystem by Targeting the Endoplasmic Reticulum Stress Pathway Using Ruthenium- and Osmium-Based Organometallic Compounds: An Exciting Long-Term Collaboration with Dr. Michel Pfeffer." Molecules 26, no. 17 (September 4, 2021): 5386. http://dx.doi.org/10.3390/molecules26175386.

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Metal complexes have been used to treat cancer since the discovery of cisplatin and its interaction with DNA in the 1960’s. Facing the resistance mechanisms against platinum salts and their side effects, safer therapeutic approaches have been sought through other metals, including ruthenium. In the early 2000s, Michel Pfeffer and his collaborators started to investigate the biological activity of organo-ruthenium/osmium complexes, demonstrating their ability to interfere with the activity of purified redox enzymes. Then, they discovered that these organo-ruthenium/osmium complexes could act independently of DNA damage and bypass the requirement for the tumor suppressor gene TP53 to induce the endoplasmic reticulum (ER) stress pathway, which is an original cell death pathway. They showed that other types of ruthenium complexes—as well complexes with other metals (osmium, iron, platinum)—can induce this pathway as well. They also demonstrated that ruthenium complexes accumulate in the ER after entering the cell using passive and active mechanisms. These particular physico-chemical properties of the organometallic complexes designed by Dr. Pfeffer contribute to their ability to reduce tumor growth and angiogenesis. Taken together, the pioneering work of Dr. Michel Pfeffer over his career provides us with a legacy that we have yet to fully embrace.
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Wang, Hai-Xu, Qingyun Wan, Kam-Hung Low, Cong-Ying Zhou, Jie-Sheng Huang, Jun-Long Zhang, and Chi-Ming Che. "Stable group 8 metal porphyrin mono- and bis(dialkylcarbene) complexes: synthesis, characterization, and catalytic activity." Chemical Science 11, no. 8 (2020): 2243–59. http://dx.doi.org/10.1039/c9sc05432d.

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We report the isolation, X-ray crystal structures, reactivity and DFT calculations of iron- and ruthenium-mono(dialkylcarbene) and osmium-bis(dialkylcarbene) porphyrins and diarylcarbene transfer/insertion reactions catalyzed by iron-mono(dialkylcarbene) porphyrin.
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Poursharifi, Mina, Marek T. Wlodarczyk, and Aneta J. Mieszawska. "Nano-Based Systems and Biomacromolecules as Carriers for Metallodrugs in Anticancer Therapy." Inorganics 7, no. 1 (December 20, 2018): 2. http://dx.doi.org/10.3390/inorganics7010002.

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Since the discovery of cisplatin and its potency in anticancer therapy, the development of metallodrugs has been an active area of research. The large choice of transition metals, oxidation states, coordinating ligands, and different geometries, allows for the design of metal-based agents with unique mechanisms of action. Many metallodrugs, such as titanium, ruthenium, gallium, tin, gold, and copper-based complexes have been found to have anticancer activities. However, biological application of these agents necessitates aqueous solubility and low systemic toxicity. This minireview highlights the emerging strategies to facilitate the in vivo application of metallodrugs, aimed at enhancing their solubility and bioavailability, as well as improving their delivery to tumor tissues. The focus is on encapsulating the metal-based complexes into nanocarriers or coupling to biomacromolecules, generating efficacious anticancer therapies. The delivery systems for complexes of platinum, ruthenium, copper, and iron are discussed with most recent examples.
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Murahashi, Shun-Ichi, Naruyoshi Komiya, Yukiko Hayashi, and Tatsuyuki Kumano. "Copper complexes for catalytic, aerobic oxidation of hydrocarbons." Pure and Applied Chemistry 73, no. 2 (January 1, 2001): 311–14. http://dx.doi.org/10.1351/pac200173020311.

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Catalytic oxidation of hydrocarbons can be performed efficiently upon treatment with tert-butylhydroperoxide or peracetic acid in the presence of a low-valent ruthenium catalyst. Furthermore, aerobic oxidation of hydrocarbons can be performed in the presence of acetaldehyde using ruthenium, iron, and copper catalysts. Copper derived from copper chloride/crown ether or copper chloride/crown ether/alkaline metal salts have proved to be efficient catalysts. Further study revealed that specific copper complexes formed from copper salts and acetonitrile are convenient and highly useful catalysts for the aerobic oxidation of unactivated hydrocarbons.
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Ford, Peter C. "Photochemical reactions of metal nitrosyl complexes. Mechanisms of NO reactions with biologically relevant metal centers." International Journal of Photoenergy 3, no. 3 (2001): 161–69. http://dx.doi.org/10.1155/s1110662x01000204.

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The discoveries that nitric oxide (a.k.a. nitrogen monoxide) serves important roles in mammalian bioregulation and immunology have stimulated intense interest in the chemistry and biochemistry of NO and derivatives such as metal nitrosyl complexes. Also of interest are strategies to deliver NO to biological targets on demand. One such strategy would be to employ a precursor which displays relatively low thermal reactivity but is photochemically active to release NO. This proposition led us to investigate laser flash and continuous photolysis kinetics of nitrosyl complexes such as the Roussin's iron-sulfur-nitrosyl cluster anionsFe2S2(NO)42−andFe4S3(NO)7−and several ruthenium salen and porphyrin nitrosyls. These include studies using metal-nitrosyl photochemistry as a vehicle for delivering NO to hypoxic cell cultures in order to sensitizeγ-radiation damage. Also studied were the rates and mechanisms of NO “on” reactions with model water soluble heme compounds, the ferriheme protein met-myoglobin and various ruthenium complexes using ns laser flash photolysis techniques. An overview of these studies is presented.
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Rocha, Reginaldo C., and Henrique E. Toma. "Intervalence transfer in a new benzotriazolate bridged ruthenium-iron complex." Canadian Journal of Chemistry 79, no. 2 (February 1, 2001): 145–56. http://dx.doi.org/10.1139/v00-195.

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The unsymmetrical dinuclear ruthenium–iron complexes [(NH3)5Ru–bta–Fe(CN)5]n (where bta = benzotriazolate; n = –2, –1, 0) were prepared as solid sodium salts from [RuII(NH3)5(bta)]+ or [RuIII(NH3)5(bta)]2+ and [FeII(CN)5(H2O)]3– and characterized in aqueous solution by means of electrochemical and spectroelectrochemical methods. UV-vis, near-infrared, IR, and cyclic and differential pulse voltammetry data suggest that the related mixed valent species belong to a valence trapped formulation, featuring localized Ru(III) and Fe(II) oxidation states. In spite of the class II categorization in the Robin and Day scheme, this system shows a remarkable metal–metal electronic coupling, as deduced from an intense, low-energy, and very broad intervalence band in the near-IR region. In addition, the mixed valence state displays enhanced stabilization in relation to the isovalent state. The intervalence transfer properties are discussed on the basis of Hush's theory.Key words: ammineruthenium complexes, cyanoiron complexes, mixed valence, intervalence, benzotriazole, benzotriazolate.
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Prasad, Sahdeo, Dan DuBourdieu, Ajay Srivastava, Prafulla Kumar, and Rajiv Lall. "Metal–Curcumin Complexes in Therapeutics: An Approach to Enhance Pharmacological Effects of Curcumin." International Journal of Molecular Sciences 22, no. 13 (June 30, 2021): 7094. http://dx.doi.org/10.3390/ijms22137094.

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Curcumin, an active component of the rhizome turmeric, has gained much attention as a plant-based compound with pleiotropic pharmacological properties. It possesses anti-inflammatory, antioxidant, hypoglycemic, antimicrobial, neuroprotective, and immunomodulatory activities. However, the health-promoting utility of curcumin is constrained due to its hydrophobic nature, water insolubility, poor bioavailability, rapid metabolism, and systemic elimination. Therefore, an innovative stride was taken, and complexes of metals with curcumin have been synthesized. Curcumin usually reacts with metals through the β-diketone moiety to generate metal–curcumin complexes. It is well established that curcumin strongly chelates several metal ions, including boron, cobalt, copper, gallium, gadolinium, gold, lanthanum, manganese, nickel, iron, palladium, platinum, ruthenium, silver, vanadium, and zinc. In this review, the pharmacological, chemopreventive, and therapeutic activities of metal–curcumin complexes are discussed. Metal–curcumin complexes increase the solubility, cellular uptake, and bioavailability and improve the antioxidant, anti-inflammatory, antimicrobial, and antiviral effects of curcumin. Metal–curcumin complexes have also demonstrated efficacy against various chronic diseases, including cancer, arthritis, osteoporosis, and neurological disorders such as Alzheimer’s disease. These biological activities of metal–curcumin complexes were associated with the modulation of inflammatory mediators, transcription factors, protein kinases, antiapoptotic proteins, lipid peroxidation, and antioxidant enzymes. In addition, metal–curcumin complexes have shown usefulness in biological imaging and radioimaging. The future use of metal–curcumin complexes may represent a new approach in the prevention and treatment of chronic diseases.
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Swamy, S. J., B. Veera Pratap, P. Someshwar, K. Suresh, and D. Nagaraju. "Synthesis and Spectral Studies of Iron(III), Ruthenium(III) and Rhodium(III) Complexes with New Tetraaza Macrocyclic Ligands." Journal of Chemical Research 2005, no. 5 (May 2005): 313–15. http://dx.doi.org/10.3184/0308234054323986.

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Complexes of iron(III), ruthenium(III) and rhodium(III) with three new tetraaza macrocyclic ligands, oxo4bzo3[14]triene-N4 [TBTAC14Tone], oxo4bzo2[14]diene-N4 [DBTAC14Tone] and oxo4bzo2[15]diene-N4 [DBTAC15Tone] have been prepared and characterised. The complexes are found to have the formulae [FeLCl2]Cl. 2H2O, [RuLCl2]Cl. 3H2O and [RhLCl2]Cl. 2H2O. The cations adopt a trans-dichloro configuration with the six-coordinated trivalent metal ions in a pseudo-octahedral geometry.
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KIENAST, ARNE, LUTZ GALICH, KEITH S. MURRAY, BOUJEMA MOUBARAKI, GEORGE LAZAREV, JOHN D. CASHION, and HEINER HOMBORG. "μ-Carbido Diporphyrinates and Diphthalocyaninates of Iron and Ruthenium." Journal of Porphyrins and Phthalocyanines 01, no. 02 (April 1997): 141–57. http://dx.doi.org/10.1002/(sici)1099-1409(199704)1:2<141::aid-jpp18>3.0.co;2-m.

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μ-Carbido diporphyrinates and diphthalocyaninates of general formula [{ Mp 2−}2(μ- C )] ( p 2− = tpp ( M = Fe ), oep ( Fe ), pc ( Fe , Ru ); H 2 tpp : 21H,23H-5,10,15,20-tetraphenylporphine; H 2 oep : 21H,23H-2,3,4,8,12,13,17,18-octaethylporphine; H 2 pc : 29H,31H-phthalocyanine) of formally Fe IV and Ru IV are prepared by a new and improved ‘one-pot’ synthesis. The corresponding chloro complexes of the tervalent metal ions react successively with potassium hydroxide in boiling 2-propanol and then with trichloromethane. Potassium hydroxide is proven to be a very versatile and powerful reductant in tetrapyrrolic chemistry. As evidenced from electron spin resonance and UV vis spectral measurements, the precursor is reduced primarily to an ate-complex of type [ M I p 2−]− of a formally monovalent metal ion. This active species is assumed to react with trichloromethane via a dichlorocarbene complex of type [ M II( CCl 2) p 2−] to yield the actual -carbido complex. [{ Feoep 2−}2(μ- C )] is crystallographically characterized. It is monoclinic, space group C12/c1 (15), with a = 18.279(3) Å, b = 15.005(2) Å, c = 23.392(7) Å, β = 107.12(2)°, Z = 4, R1 = 0.0773. The iron atom is displaced by 0.192(3) Å out of the centre ( Ct ) of the ( N p )4 plane toward the (μ- C ) atom. Average d ( Fe - N p ) is 1.986(5) Å; d ( Fe -(μ- C )) is 1.6638(9) Å. The Fe - C - Fe skeleton is linear (179.5(3)°). The two slightly waving porphyrinato cores are in a staggered conformation, the ( N p - Fe - Fe ″- N p ″) torsion angle being 21.0(3)°. Solutions of each μ-carbido complex in pyridine/dichloromethane show four distinct quasi-reversible redox processes in their differential-pulse voltammograms and these are assigned to the successive one-electron reduction and oxidation of the macrocyclic ligands. 13 C CP MAS NMR spectra indicate effective four-fold symmetry within the series of the μ-carbido complexes with isotropic shifts occurring at similar fields to those of the corresponding macrocyclic complex of a closed-shell metal ion. Resonances of the bridging carbon atom are not detected. A characteristic increase of line broadening within the series tpp 2− > oep 2− > pc 2− may be due to Fermi contact interactions with the strongly coupled low-spin M IV centres. The magnetic susceptibility studies show that the complexes all display non-zero μ values at 295 K increasing from pc 2− to tpp 2−. Mössbauer spectra confirm the low-spin Fe IV oxidation state for the iron centres. Isomer shift, δ, and quadrupole splitting, ΔE Q , for [{ Fepc 2−}2(μ- C )] and [{ Fetpp 2−}2(μ- C )] are identical to those previously reported. Data for [{ Feoep 2−}2(μ- C )] are essentially the same as for the pc and tpp complex. Thus the order of δ is tpp ≈ oep > pc whilst that of Δ E Q is pc >> oep > tpp . Small impurity lines are observed which help explain the magnetic data. UV vis/NIR spectra of the μ-carbido complexes show the characteristic π-π* transitions. These are shifted with respect to the corresponding mononuclear complexes to higher energy because of excitonic interactions. Vibrational spectra are discussed in detail ν as ( M - C - M ) (in cm−1) is at 937 ( M = Fe ; tpp ) < 976 ( Fe / oep ) < 997 ( Fe / pc ) < 1050 ( Ru / pc ), ν s ( M - C - M ) (in cm−1 at 433 ( Fe / tpp ) < 460 ( Fe / oep ) < 477 ( Fe / pc ). Hence, valence force constants increase significantly in the order tpp < oep < pc . ν s ( Fe - C - Fe ) of [{ Fepc 2−}2(μ- C )] is selectively resonance Raman enhanced. As evidenced from the excitation profile a C → Fe charge transfer, not detected in the vis spectrum, is assumed to be present at 22 000 > ν > 25 000 cm −1.
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Dissertations / Theses on the topic "Metal complexes. Ruthenium. Iron"

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Guest, Ruth Winifred. "Synthesis and reactions of iron and rutheniuim dinitrogen complexes." Connect to full text, 2008. http://ses.library.usyd.edu.au/handle/2123/3533.

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Thesis (Ph. D.)--University of Sydney, 2008.
Includes tables. Includes list of publications: leaves i-ii. Title from title screen (viewed October 30, 2008). Submitted in fulfilment of the requirements for the degree of Doctor of Philosophy to the School of Chemistry, Faculty of Science. Includes bibliographical references. Also available in print form.
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Walters, Stephen John. "Acyl(oxy) carbene and vinylidene chemistry of iron and ruthenium half-sandwich complexes." Thesis, University of Sheffield, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.245691.

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Xie, Jin. "Synthesis, structures and spectroscopic properties of primary and secondary phosphine complexes of iron, ruthenium and osmium porphyrins." Click to view the E-thesis via HKUTO, 2007. http://sunzi.lib.hku.hk/HKUTO/record/B39556876.

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Xie, Jin, and 解錦. "Synthesis, structures and spectroscopic properties of primary and secondary phosphine complexes of iron, ruthenium and osmiumporphyrins." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2007. http://hub.hku.hk/bib/B39556876.

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鄧煒堂 and Wai-tong Tang. "Homogeneous oxidation of organic substrates by ruthenium, iron and manganese tertiary amine complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1989. http://hub.hku.hk/bib/B31231706.

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Tang, Wai-tong. "Homogeneous oxidation of organic substrates by ruthenium, iron and manganese tertiary amine complexes /." [Hong Kong : University of Hong Kong], 1989. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12355203.

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Burgun, Alexandre. "Oxidative activation of iron- and ruthenium-alkynyl complexes : toward square-shaped molecules with four redox-active metal centres." Rennes 1, 2011. http://www.theses.fr/2011REN1S081.

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Turner, David Benjamin. "Photochemistry of Group 8 Metal Complexes of Type [M(bpy)2(CN)2] (M = Fe, Ru). Photosynthesis of Heteroleptic Iron(II) Compounds and Photoionization of Ruthenium(II) Compounds." The Ohio State University, 2009. http://rave.ohiolink.edu/etdc/view?acc_num=osu1253238745.

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Buitrago, Elina. "Transition metal-catalyzed reduction of carbonyl compounds : Fe, Ru and Rh complexes as powerful hydride mediators." Doctoral thesis, Stockholms universitet, Institutionen för organisk kemi, 2012. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-75795.

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A detailed mechanistic investigation of the previously reported ruthenium pseudo-dipeptide-catalyzed asymmetric transfer hydrogenation (ATH) of aromatic ketones was performed. It was found that the addition of alkali metals has a large influence on both the reaction rate and the selectivity, and that the rate of the reaction was substantially increased when THF was used as a co-solvent. A novel bimetallic mechanism for the ruthenium pseudo-dipeptide-catalyzed asymmetric reduction of prochiral ketones was proposed. There is a demand for a larger substrate scope in the ATH reaction, and heteroaromatic ketones are traditionally more challenging substrates. Normally a catalyst is developed for one benchmark substrate, and a substrate screen is carried out with the best performing catalyst. There is a high probability that for different substrates, another catalyst could outperform the one used. To circumvent this issue, a multiple screen was executed, employing a variety of ligands from different families within our group’s ligand library, and different heteroaromatic ketones to fine-tune and to find the optimum catalyst depending on the substrate. The acquired information was used in the formal total syntheses of (R)-fluoxetine and (S)-duloxetine, where the key reduction step was performed with high enantioselectivities and high yield, in each case. Furthermore, a new iron-N-heterocyclic carbene (NHC)-catalyzed hydrosilylation (HS) protocol was developed. An active catalyst was formed in situ from readily available imidazolium salts together with an iron source, and the inexpensive and benign polymethylhydrosiloxane (PMHS) was used as hydride donor. A set of sterically less demanding, potentially bidentate NHC precursors was prepared. The effect proved to be remarkable, and an unprecedented activity was observed when combining them with iron. The same system was also explored in the reduction of amides to amines with satisfactory results.

At the time of doctoral defense, the following paper was unpublished and had a status as follows: Paper 2: Manuscript.

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Orth, Nicole [Verfasser], Ivana [Akademischer Betreuer] Ivanovic-Burmazovic, and Ivana [Gutachter] Ivanovic-Burmazovic. "Development of a Novel Inorganic Enzyme Mimetic with Dual Functionality and Characterization of Catalytically Active Copper, Iron and Ruthenium Complexes and Metal Based Self-Assemblies by Cryospray-Ionization Mass Spectrometry / Nicole Orth ; Gutachter: Ivana Ivanovic-Burmazovic ; Betreuer: Ivana Ivanovic-Burmazovic." Erlangen : Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 2021. http://d-nb.info/1237107652/34.

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Books on the topic "Metal complexes. Ruthenium. Iron"

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Baulieu, Etienne, Donald T. Forman, Magnus Ingelman-Sundberg, Lothar Jaenicke, John A. Kellen, Yoshitaka Nagai, Georg F. Springer, Lothar Träger, Liane Will-Shahab, and James L. Wittliff, eds. Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy. Berlin, Heidelberg: Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-642-74760-1.

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Carbon-carbon and carbon-hydrogen coupling reactions on iron and ruthenium [alpha]-diimine complexes. [Amsterdam]: Universiteit van Amsterdam, 1992.

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Farrell, Michael A. Highly polarisable derivatives of bridging carbene and carbyne di-iron complexes. Dublin: University College Dublin, 1998.

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Kellen, John A., Etienne Baulieu, Lothar Jaenicke, Donald T. Forman, Magnus Ingelman-Sundberg, Yashitaka Nagai, Georg F. Springer, Lothar Träger, Liane Will-Shahab, and James L. Wittliff. Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy. Springer, 2011.

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E, Alessio, Clarke M. J, Società chimica italiana, Università degli studi di Trieste., and Symposium on Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy., eds. Ruthenium and other non-platinum metal complexes in cancer chemotherapy. Berlin: Spriger Verlag, 1989.

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Muller, Frederik. Reactions of dinuclear iron and ruthenium carbonyl [alpha] -diimine complexes with alkynes. 1988.

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Omrcen, Tatjana. Syntheses and ring-opening reactions of alpha-fluorocyclopropyl sigma-complexes of iron: Syntheses and fluxionality studies of iron and ruthenium cyclic allenes. 1992.

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Progress in Clinical Biochemistry and Medicine: Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy (Progress in Clinical Bioche). Springer, 1989.

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Crowther, Donna Jean. Ring-opening reactions of cyclopropyl and cyclobutyl complexes of manganese and iron. 1989.

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Hinman, Justin Grant. Acidity of neutral transition metal polyhydride complexes and the study of anionic rhenium and ruthenium polyhydride dimers. 2001.

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Book chapters on the topic "Metal complexes. Ruthenium. Iron"

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Bullock, Jimmie L., and Alvin A. Holder. "Photodynamic Therapy in Medicine with Mixed-Metal/Supramolecular Complexes." In Ruthenium Complexes, 139–60. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2017. http://dx.doi.org/10.1002/9783527695225.ch7.

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Malisch, Wolfgang, Klaus Grün, Heinrich Jehle, Joachim Reising, Stephan Möller, Oliver Fey, and Christa Abdelbaky. "Metal Mediated Synthesis of Chiral Secondary Phosphane Ligands via the Organophosphenium Complexes Cp(OC)(L)M=P(H)R (M = Mo, W; L = OC, Me3P; R = t-Bu, Mes). Regiospecific Functionalization of Iron and Ruthenium Substituted Disilanes." In Selective Reactions of Metal-Activated Molecules, 257–63. Berlin, Heidelberg: Springer Berlin Heidelberg, 1998. http://dx.doi.org/10.1007/978-3-662-00975-8_39.

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Mlodnicka, Teresa, and Brian R. James. "Oxidations Catalyzed by Ruthenium Porphyrins." In Catalysis by Metal Complexes, 121–48. Dordrecht: Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-017-2247-6_4.

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Griffith, William P. "The Chemistry of Ruthenium Oxidation Complexes." In Catalysis by Metal Complexes, 1–134. Dordrecht: Springer Netherlands, 2009. http://dx.doi.org/10.1007/978-1-4020-9378-4_1.

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Roper, W. R. "Carbyne Complexes of Ruthenium and Osmium." In Transition Metal Carbyne Complexes, 155–68. Dordrecht: Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4_20.

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Süss-Fink, Georg. "Multicenter Ligand Transformations of Tetramethyl-Thiourea on Ruthenium Clusters." In Transition Metal Carbyne Complexes, 151–53. Dordrecht: Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4_19.

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Farrell, Nicholas. "Metal Complexes as Radiosensitizers." In Ruthenium and Other Non-Platinum Metal Complexes in Cancer Chemotherapy, 89–109. Berlin, Heidelberg: Springer Berlin Heidelberg, 1989. http://dx.doi.org/10.1007/978-3-642-74760-1_5.

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Funabiki, Takuzo. "Iron Model Studies on Dioxygenases." In Catalysis by Metal Complexes, 105–55. Dordrecht: Springer Netherlands, 1997. http://dx.doi.org/10.1007/978-94-011-5442-0_3.

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Nishinaga, Akira. "Non-Iron Model Studies on Dioxygenases." In Catalysis by Metal Complexes, 157–94. Dordrecht: Springer Netherlands, 1997. http://dx.doi.org/10.1007/978-94-011-5442-0_4.

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Hill, A. F. "Diversions En Route to Alkylidyne Complexes of Iron." In Transition Metal Carbyne Complexes, 239–48. Dordrecht: Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1666-4_27.

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Conference papers on the topic "Metal complexes. Ruthenium. Iron"

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Rebane, Aleksander K., Charles Stark, Juri Pahapill, Alexander Mikhaylov, and Matt Rammo. "Probing metal-to-ligand charge transfer transitions in ruthenium complexes by quantitative two-photon absorption spectroscopy." In Organic Photonic Materials and Devices XX, edited by Christopher E. Tabor, François Kajzar, Toshikuni Kaino, and Yasuhiro Koike. SPIE, 2018. http://dx.doi.org/10.1117/12.2290363.

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Záliš, S., R. S. Winter, M. Linseis, A. Kaim, B. Sarkar, I. Kratochvílová, George Maroulis, and Theodore E. Simos. "DFT modeling of Spectral and Redox Properties of Di-and Tetranuclear Ruthenium Transition Metal Complexes with Bridging Ligands." In COMPUTATIONAL METHODS IN SCIENCE AND ENGINEERING: Advances in Computational Science: Lectures presented at the International Conference on Computational Methods in Sciences and Engineering 2008 (ICCMSE 2008). AIP, 2009. http://dx.doi.org/10.1063/1.3225297.

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Khalil, Sarah, and Tarek M. Hatem. "Hydrogen Embrittlement Characteristics in Irradiated Stainless Steel." In ASME 2020 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2020. http://dx.doi.org/10.1115/imece2020-24081.

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Abstract Hydrogen is produced in nuclear reactors as a by-product of the corrosion reaction between the pressure vessel and the cooling water, where hydrogen produced may enter the metal in atomic form. During operation a reactor vessel is exposed to avalanche of neutron irradiation fluxes, in addition to corrosion from cooling water. A novel cluster dynamics model that accounts for off-stoichiometry of clusters and matrix was developed and applied to investigate the clustering behavior of Hydrogen-vacancy and Hydrogen-interstitial clusters in proton irradiated stainless steel has been developed. The differences in point defect migration energies and binding energy of H to lattice defects, makes it possible to have vacancy and interstitial clusters having compositions different from those of pure iron. The model predicts populations of Defect-Hydrogen complexes in iron. The model is applied to the early stage formation of voids and dislocation loops in stainless steel in the presence of atomic hydrogen. This study investigates the effect of irradiation dose and temperature on the concentration of vacancy-Hydrogen (VmHn) and Intersitial Fe-H (FemHn) complexes on bulk α-Iron. The re
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Cantrel, Laurent, Thierry Albiol, Loïc Bosland, Juliette Colombani, Frédéric Cousin, Anne-Cécile Grégoire, Olivia Leroy, et al. "IRSN R&D Actions on FP Behaviour for RCS, Containment and FCVS in Severe Accident Conditions." In 2016 24th International Conference on Nuclear Engineering. American Society of Mechanical Engineers, 2016. http://dx.doi.org/10.1115/icone24-61104.

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This paper deals with near past, ongoing and planned R&D works on fission products (FPs) behaviour in Reactor Cooling System (RCS), containment building and in Filtered Containment Venting Systems (FCVS) for severe accident (SA) conditions. For the last topic, in link with the Fukushima post-accident management and possible improvement of mitigation actions for such SA, the FCVS topic is again on the agenda (see Status Report on Filtered Containment Venting, OECD/NEA/CSNI, Report NEA/CSNI/R(2014)7, 2014.) with a large interest at the international scale. All the researches are collaborative works; the overall objective is to develop confident models to be implemented in ASTEC SA simulation software. After being initiated in the International Source Term Program (ISTP), researches devoted to the understanding of iodine transport through the RCS are still ongoing in the frame of a bilateral agreement between IRSN and EDF with promising results. In 2017, a synthesis report of the last 10 years of researches, which have combined experimental and fundamental works based on the use of theoretical chemistry tools, will be issued. For containment, the last advances are linked to the Source Term Evaluation and Mitigation (STEM) OECD/NEA project operated by IRSN. The objective of the STEM project was to improve the evaluation of Source Term (ST) for a SA on a nuclear power plant and to reduce uncertainties on specific phenomena dealing with the chemistry of two major fission products: iodine and ruthenium. More precisely, the STEM project provided additional knowledge and improvements for calculation tools in order to allow a more robust diagnosis and prognosis of radioactive releases in a SA. STEM data will be completed by a follow-up, called STEM2, to further the knowledge concerning some remaining issues and be closer to reactor conditions. Two additional programmes deal with FCVS issues: the MItigation of outside Releases in the Environment (MIRE) (2013–2019) French National Research Agency (NRA) programme and the Passive and Active Systems on Severe Accident source term Mitigation (PASSAM) (2013–2016) European project. For FCVS works, the efficiencies for trapping iodine with various FCVS, covering scrubbers and dry filters, are examined to get a clear view of their abilities in SA conditions. Another part, performed in collaboration with French universities (Lorraine and Lille 1), is focused on the enhancement of the performance of these filters with specific porous materials able to trap volatile iodine. For that, influence of zeolites materials parameters (nature of the counter-ions, structure, Si/Al ratio …) will be tested. New kind of porous materials constituted by Metal organic Frameworks (MOF) will also be looked at because they can constitute a promising way of trapping.
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