Academic literature on the topic 'Metal complexes – Synthesis'

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Journal articles on the topic "Metal complexes – Synthesis"

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Sethi, Pooja, Rajshree Khare, and Renuka Choudhary. "Complexes of Pyrimidine Thiones: Mechanochemical Synthesis and Biological Evaluation." Asian Journal of Chemistry 32, no. 10 (2020): 2594–600. http://dx.doi.org/10.14233/ajchem.2020.22813.

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A new series of metal complexes with 1-(2-methylphenyl)-4,4,6-trimethyl pyrimidine-2-thione (2-HL1) and 1-(4-methylphenyl)-4,4,6-trimethyl pyrimidine-2-thione (4-HL2) ligands, [M(mppt)2(H2O)n] (M(II) = Cu, Mn, Co; n = 2 and M(II) = Ni, Zn; n = 0) have been synthesized using mechanochemical protocol. The complexes have been framed as [M(mppt)2(H2O)n] due to 1:2 (metal:ligand) nature of these metal complexs. Structures have been further confirmed on the basis of elemental analysis, Magnetic susceptibility measurements, electronic, infrared, far infrared, proton NMR, Mass spectral moment and ther
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Mansoor Ahmed Zi Ning Lei, Mansoor Ahmed Zi Ning Lei, Mohsin Ali Mohsin Ali, Syed Imran Ali Syed Imran Ali, et al. "Synthesis, Characterization and Anticancer Activity of Isonicotinylhydrazide Metal Complexes." Journal of the chemical society of pakistan 41, no. 1 (2019): 113. http://dx.doi.org/10.52568/000706/jcsp/41.01.2019.

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This study focuses characterization of iron (II), iron (III), cobalt (II), copper (II) and nickel (II) complexes of Isoniazid (INH) and studying their spectroscopic as well as physiochemical properties. FTIR studies showed that INH binds the metal from oxygen of carbonyl group and nitrogen of amino group. The proton NMR spectra of the metal complexes confirmed the conversion of ligand molecules into their respective metal complexes. However, pattern of splitting and shapes of peaks was observed but the protons resonated in the expected region. XRD patterns may be concluded that the complexes a
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Nabeshima, Tatsuya, Yusuke Chiba, Takashi Nakamura, and Ryota Matsuoka. "Synthesis and Functions of Oligomeric and Multidentate Dipyrrin Derivatives and their Complexes." Synlett 31, no. 17 (2020): 1663–80. http://dx.doi.org/10.1055/s-0040-1707155.

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The dipyrrin–metal complexes and especially the boron complex 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) have recently attracted considerable attention because of their interesting properties and possible applications. We have developed two unique and useful ways to extend versatility and usefulness of the dipyrrin complexes. The first one is the linear and macrocyclic oligomerization of the BODIPY units. These arrangements of the B–F moieties of the oligomerized BODIPY units provide sophisticated functions, such as unique recognition ability toward cationic guest, associated with cha
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Ortolan, Alexandre O., Giovanni F. Caramori, Renato L. T. Parreira, Renato P. Orenha, Alvaro Muñoz-Castro, and Gernot Frenking. "The bonding situation in heteromultimetallic carbonyl complexes." Dalton Transactions 49, no. 46 (2020): 16762–71. http://dx.doi.org/10.1039/d0dt02916e.

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The description of the metal–metal bonding situation in these complexes provides valuable information, useful to guide the synthesis of unprecedented multimetallic complexes containing coinage metals and other transition metals.
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Sumrra, Sajjad Hussain, Muhammad Ibrahim, Sabahat Ambreen, Muhammad Imran, Muhammad Danish, and Fouzia Sultana Rehmani. "Synthesis, Spectral Characterization, and Biological Evaluation of Transition Metal Complexes of Bidentate N, O Donor Schiff Bases." Bioinorganic Chemistry and Applications 2014 (2014): 1–10. http://dx.doi.org/10.1155/2014/812924.

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New series of three bidentate N, O donor type Schiff bases(L1)–(L3)were prepared by using ethylene-1,2-diamine with 5-methyl furfural, 2-anisaldehyde, and 2-hydroxybenzaldehyde in an equimolar ratio. These ligands were further complexed with Co(II), Cu(II), Ni(II), and Zn(II) metals to produce their new metal complexes having an octahedral geometry. These compounds were characterized on the basis of their physical, spectral, and analytical data. Elemental analysis and spectral data of the uncomplexed ligands and their metal(II) complexes were found to be in good agreement with their structures
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Rais, Eduard, Ulrich Flörke, and René Wilhelm. "Synthesis and investigation of new cyclic haloamidinium salts." Zeitschrift für Naturforschung B 71, no. 6 (2016): 667–76. http://dx.doi.org/10.1515/znb-2016-0011.

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AbstractThe presented work describes the synthesis of new six- and seven-membered haloamidinium salts and their reaction with different metals. The isolated metal complexes were tested in a catalytic reaction. Two different synthetic routes were applied to prepare five different salts. Chloroamidinium salts were very water-sensitive in comparison to their corresponding bromoamidinium salts. Hence, the preparation of the less sensitive bromoamidinium salts was higher prioritized. The formed salts were converted with metal sources to N-heterocyclic carbene (NHC) metal complexes through an oxidat
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Zhang, Zaihui, T. L. Thomas Hui, and Chris Orvig. "One-pot synthesis of N-substituted-3-hydroxy-4-pyridinone chelate complexes of aluminum, gallium, and indium." Canadian Journal of Chemistry 67, no. 11 (1989): 1708–10. http://dx.doi.org/10.1139/v89-263.

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A series of tris(3-hydroxy-2-methyl-4-pyridinonato)metal(III) and tris(3-hydroxy-6-hydroxymethyl-4-pyridinonato)metal(III) complexes have been prepared in water by one-pot synthesis directly from maltol and kojic acid, respectively, and the metal ion (M = Al, Ga, In) with an appropriate amine. The pyridinones have substituents at the ring nitrogen atom (CH3, C2H5). The tris(3-hydroxy-4-pyronato)metal(III) complexes are formed insitu and these undergo nucleophilic attack by the primary amine; the appropriate tris(3-hydroxy-4-pyridinonato)metal(III) complexes are obtained. This method bypasses t
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Gonzalez, A., J. Marquet, and M. Moreno-Mañas. "Metal complexes in organic synthesis." Tetrahedron 42, no. 15 (1986): 4253–57. http://dx.doi.org/10.1016/s0040-4020(01)87650-x.

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Maurya, Chandan, and Sangeeta Bajpai. "Biological Applications of Metal Complexes of Dithiocarbamates." Journal of Applied Science and Education (JASE) 2, no. 1 (2022): 1–16. http://dx.doi.org/10.54060/jase/002.01.002.

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Dithiocarbamates are organosulphur ligands and form chelate compounds with metals. Their uses are reported in the field of accelerating vulcanization, pesticide, material science, organic synthesis, etc. Recent research demonstrated the potential of metal complexes of these ligands as good antifungal, antibacterial, and antitumor agents. Dithiocarbamate complexes have also been reported to use as a plasmonic sensor, as an inhibitor of proteasome, and for antioxidant and antileishmanial activity. This brief review presents the biological activities of metal complexes of dithiocarbamate.
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Sethi, Pooja, Rajshree Khare, Jyoti Sharma, Anjana Kumari, and Simrat Kaur. "Mechanochemical Synthesis, Characterization and Biological Exploration of Pyrimidinethione based ligands." Research Journal of Chemistry and Environment 26, no. 9 (2022): 12–20. http://dx.doi.org/10.25303/2609rjce12020.

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The mechanochemical synthesis of 1-(4-Nitro phenylamino)-4,4,6-trimethyl-3,4-dihydro pyrimidine-2-(1H)- thione (Hnppt) based ligand and its metal complexes with Cu(II), Co(II), Ni(II), Mn(II), Cd(II), Pd(II) has been achieved. The synthesized ligand and its coordination complexes were evaluated for antibacterial ability and DNA photocleavage potential by using plasmid DNA. Ligand(Hnppt) was prepared and then it was allowed to chelate with different transition metals in 1:2 metal ligand ratio. All the complexes were then characterized by IR, Mass, NMR, magnetic moment, electronic spectra like s
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Dissertations / Theses on the topic "Metal complexes – Synthesis"

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Mobbs, B. E. "Arene transition metal complexes in synthesis." Thesis, University of Oxford, 1985. http://ora.ox.ac.uk/objects/uuid:4c7030d4-297e-4af8-a622-d5b4963fc0a3.

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This thesis deals with the applications of organopalladium and organochromium chemistry to the functionalisation of the benzopyran ring system, at a variety of oxidation levels. Section I demonstrates the functionalisation of 3-, 6-, and 8-bromochromones via palladium (0) insertion into the C-Br bond. The resultant arylpalladium species are shown to undergo addition to the least substituted end of a variety of olefins including methyl acrylate, acrylonitrile and styrene. Subsequent palladium-hydride elimination leads to overall palladium catalysed vinylation of the chromone and the synthesis o
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Atkins, Andrew J. "Studies on transition metal macrocyclic complexes." Thesis, University of Edinburgh, 1993. http://hdl.handle.net/1842/11664.

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Ho, Kin-ying. "Synthesis, characterization and spectroscopic properties of d6 and d10 metal complexes with pyridyl amine ligands /." Hong Kong : University of Hong Kong, 1999. http://sunzi.lib.hku.hk/hkuto/record.jsp?B20667905.

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Landman, Marile. "Synthesis of metal complexes with thiophene ligands." Thesis, Access to E-Thesis, 2000. http://upetd.up.ac.za/thesis/available/etd-12042006-143722/.

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Ballisai, Antonio. "Synthesis of rigid-rod metal-alkynyl complexes." Thesis, Imperial College London, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.433302.

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Warner, P. "Asymmetric synthesis via transition metal acyl complexes." Thesis, University of Oxford, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.355823.

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Buffet, Jean-Charles. "Homochiral metal complexes for biodegradable polymer synthesis." Thesis, University of Edinburgh, 2010. http://hdl.handle.net/1842/4618.

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Chapter One introduces the principle of alkoxide and phosphine oxide as ligands for lanthanides and electropositive metals, ligand self-recognition, stereoselective polymerisation of lactide, fixation of CO2 and finally copolymerisation of CO2 and epoxide. Chapter Two shows the synthesis of the proligands rac-HLR (a racemic phosphine oxide-alkoxide, A, where R = tBu, Ph or C6H3-Me-3,5) and explores the resolution into diastereomeric RRR- and SSS-M(LR)3 to afford C3–symmetric M(LR)3 complexes, B (where M = Sc, Lu, Y, In, Bi or La). It also demonstrates that the process is under thermodynamic co
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Cooksey, John Paul. "Asymetric synthesis using (pi-allyl) metal complexes." Thesis, University of Leeds, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.445378.

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Jervis, Helen Beverley. "Synthesis and application of surfactant metal complexes." Thesis, University of Exeter, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.288023.

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Worayingyong, Attera O. "Metal complexes as catalysts for stereoselective synthesis." Thesis, University of Aberdeen, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.294145.

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Metal complexes have been used as catalysts for stereoselective syntheses in CC bond formation reactions, namely, alkyl- and allyl- additions to aldehydes. The enantiomeric alkylations involved reactions between Et<sub>2</sub>Zn and arylaldehydes in the presence of chiral templates, e.g. zinc-, titanium- and boron-complexes of (<I>S</I>)-(-)-2-amino-3-(<I>p</I>-hydroxyphenyl)-1,1-diphenylpropanol. The reaction has been proved to be catalytic, using 3-5 mol% of the chiral ligand in the addition of Et<sub>2</sub>Zn to <I>p</I>-tolualdehyde. Study of the substituent effects in arylaldehydes showe
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Books on the topic "Metal complexes – Synthesis"

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1939-, Wöhrle Dieter, and Pomogaĭlo A. D, eds. Metal complexes and metals in macromolecules: Synthesis, structure, and properties. Wiley-VCH, 2003.

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name, No. Metal complexes and metals in macromolecules: Synthesis, structure and properties. Wiley-VCH, 2003.

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Karu, Elisha. Synthesis and kinetic studies of some trinuclear metal complexes. University of East Anglia, 1990.

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Obuzor, Gloria U. Synthesis of new cyclopentadienyl and indenyl transition metal complexes. UMIST, 1998.

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Peter, Kündig E., and Böttcher A, eds. Transition metal arene [pi]-complexes in organic synthesis and catalysis. Springer-Verlag, 2004.

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Beynek, N. Metal-ion control in the template synthesis of helical complexes. UMIST, 1997.

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Omar, Hadi A. A. Synthesis and studies of metal complexes of new azamacrocyclic ligands. typescript, 1987.

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Kündig, E. Peter, ред. Transition Metal Arene π-Complexes in Organic Synthesis and Catalysis. Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/b76615.

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J, Stillman Martin, Shaw C. Frank, and Suzuki Kazuo T, eds. Metallothionein: Synthesis, structure, and properties of metallothioneins, phytochelatins, and metal-thiolate complexes. VCH Publishers, 1992.

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Reader, Charles James. Synthesis and study of new macrocycles and some of their transition metal complexes. typescript, 1988.

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Book chapters on the topic "Metal complexes – Synthesis"

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Voloshin, Yan, Irina Belaya, and Roland Krämer. "Synthesis and Reactivity of Cage Metal Complexes." In Cage Metal Complexes. Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-56420-3_2.

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Pomogailo, Anatolii D., and Dieter Wöhrle. "Synthesis and Structure of Macromolecular Metal Complexes." In Macromolecule-Metal Complexes. Springer Berlin Heidelberg, 1996. http://dx.doi.org/10.1007/978-3-642-60986-2_2.

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Pfaltz, A. "Enantioselective Catalysis with Chiral Metal Complexes." In Stereoselective Synthesis. Springer Berlin Heidelberg, 1994. http://dx.doi.org/10.1007/978-3-642-78496-5_2.

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Brunner, Henri. "Enantioselective Catalysis with Transition Metal Complexes." In Chemical Synthesis. Springer Netherlands, 1996. http://dx.doi.org/10.1007/978-94-009-0255-8_7.

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Chaloner, Penny A., Miguel A. Esteruelas, Ferenc Joó, and Luis A. Oro. "Homogeneous Hydrogenation in Organic Synthesis." In Catalysis by Metal Complexes. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-017-1791-5_4.

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Maiorana, S., C. Baldoli, and E. Licandro. "Carbonylchromium(O) Complexes in Organic Synthesis." In Catalysis by Metal Complexes. Springer Netherlands, 1991. http://dx.doi.org/10.1007/978-94-011-3408-8_13.

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Lindsey, Jonathan S. "The Synthesis of Meso-Substituted Porphyrins." In Catalysis by Metal Complexes. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-017-2247-6_2.

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Lane, J. D., C. J. Pickett, and D. R. Stanley. "Synthesis of Metal-Nitrido Complexes." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145227.ch67.

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Demonceau, A., A. J. Hubert, and A. F. Noels. "Basic Principles in Carbene Chemistry and Applications to Organic Synthesis." In Catalysis by Metal Complexes. Springer Netherlands, 1991. http://dx.doi.org/10.1007/978-94-011-3408-8_12.

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Grubbs, Robert H., and Laura Gilliom. "Metal Carbene Complexes in Polymer Synthesis." In Recent Advances in Mechanistic and Synthetic Aspects of Polymerization. Springer Netherlands, 1987. http://dx.doi.org/10.1007/978-94-009-3989-9_27.

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Conference papers on the topic "Metal complexes – Synthesis"

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Pietschnig, Rudolf, Carmen Moser, Stefan Spirk, and Sven Schäfer. "Synthesis and Structure of Transition Metal Bisalkinylselenolato Complexes." In The 9th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2005. http://dx.doi.org/10.3390/ecsoc-9-01518.

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Palopoli, Stephen F., and Thomas B. Brill. "Synthesis And Thermolysis Of Metal Complexes Containing Energetic Ligands." In 1988 Los Angeles Symposium--O-E/LASE '88, edited by Joseph Flanagan. SPIE, 1988. http://dx.doi.org/10.1117/12.943744.

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Vrabel, Milan, and Michal Hocek. "Synthesis of modified nucleosides, nucleotides and oligonucleotides bearing metal complexes." In XIVth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2008. http://dx.doi.org/10.1135/css200810182.

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Bulavka, Vladimir, and Vladimir Abaev. "Synthesis of some 5,9,14,18,23,27,32,36-octabutoxynaphthalocyanine metal complexes in modified microwave oven." In The 13th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2009. http://dx.doi.org/10.3390/ecsoc-13-00162.

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Arakelian, S., S. Kutrovskaya, A. Kucherik, et al. "Laser-induced synthesis of a nanostructured polymer-like metal-carbon complexes." In SPIE Photonics Europe, edited by David L. Andrews, Jean-Michel Nunzi, and Andreas Ostendorf. SPIE, 2016. http://dx.doi.org/10.1117/12.2225452.

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Mikheeva, L. A., S. A. Shchelkaev, and A. V. Mikheeva. "Preparation of copper pectate preparation for use in medical practice." In VIII Vserossijskaja konferencija s mezhdunarodnym uchastiem «Mediko-fiziologicheskie problemy jekologii cheloveka». Publishing center of Ulyanovsk State University, 2021. http://dx.doi.org/10.34014/mpphe.2021-147-150.

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Currently, the processes of complexation of various ligands, including biopolymers with metals, attract the attention of scientists from different countries not only in order to obtain new data on the methods of synthesis and properties of metal complexes, but also in connection with the search for ways to obtain new effective biologically active drugs among them.&#x0D; Since the life around us is oversaturated with various artificially produced drugs that have a negative effect on the human body, today, more than ever before, the question arises of using natural, environmentally friendly ingr
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Gude, Lourdes, Katerina Duskova, Sara Sierra, María-José Fernández, and Antonio Lorente. "Synthesis of 2,2'-bipyridine metal complexes as potential G-quadruplex DNA ligands." In XVth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2011. http://dx.doi.org/10.1135/css201112330.

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Duprez, Virginie, Matteo Biancardo, and Frederik C. Krebs. "Synthesis of conjugated polymers containing terpyridine metal complexes: application in organic solar cells." In Optics & Photonics 2005, edited by Zakya H. Kafafi and Paul A. Lane. SPIE, 2005. http://dx.doi.org/10.1117/12.613437.

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Kanchanadevi, S., S. Parveen, and V. Mahalingam. "Synthesis, characterization, crystal structure and DNA-binding studies of transition metal hydrazone complexes." In 9TH NATIONAL CONFERENCE ON THERMOPHYSICAL PROPERTIES (NCTP-2017). Author(s), 2018. http://dx.doi.org/10.1063/1.5031734.

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Al-Amiery, Ahmed, Mahdi Radi, and Redha AL-Bayati. "Synthesis, spectroscopic and antimicrobial studies of transition metal complexes of N-amino quinolone derivatives." In The 14th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2010. http://dx.doi.org/10.3390/ecsoc-14-00435.

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Reports on the topic "Metal complexes – Synthesis"

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Rubin, Yves F. Total Synthesis of Buckminsterfullerene (C60) and Endohedral Metal Complexes. Defense Technical Information Center, 1997. http://dx.doi.org/10.21236/ada328578.

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Evans, W. J. Synthesis and chemistry of yttrium and lanthanide metal complexes. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/6267724.

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Jordan, R. F. Synthesis and chemistry of cationic d sup 0 metal alkyl complexes. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/6020649.

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Jordan, R. F. Synthesis and chemistry of cationic d sup 0 metal alkyl complexes. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/6179256.

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Jordan, R. Synthesis and chemistry of cationic d sup O metal alkyl complexes. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/7246016.

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Klein, D. The synthesis and reactivity of organoiridium complexes containing metal-heteroatom bonds. Office of Scientific and Technical Information (OSTI), 1989. http://dx.doi.org/10.2172/7249432.

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Reinig, Regina Rose. Synthesis and reactivity of paramagnetic late transition metal complexes supported by tris(oxazolinyl)phenylborate. Office of Scientific and Technical Information (OSTI), 2018. http://dx.doi.org/10.2172/1505192.

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Yan, Ka King. Synthesis of main group, rare-earth, and d{sup 0} metal complexes containing beta-hydrogen. Office of Scientific and Technical Information (OSTI), 2013. http://dx.doi.org/10.2172/1082979.

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Evans, W. J. Synthesis and chemistry of yttrium and lanthanide metal complexes. Progress report, March 15, 1991--March 14, 1992. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/10104789.

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Jordan, R. F. Synthesis and chemistry of cationic d{sup 0} metal alkyl complexes. Progress report, July 1988--May 1991. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/10110882.

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