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Dissertations / Theses on the topic 'Metal complexes'

Author: Grafiati

Published: 4 June 2021

Last updated: 25 July 2025

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1

Brayshaw, Simon Keith. "Metal complexes bearing pendant alkynes and metal complexes of N-heterocyclic carbenes." University of Western Australia. School of Biomedical and Chemical Sciences, 2004. http://theses.library.uwa.edu.au/adt-WU2005.0017.

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This thesis is comprised of two parts. The first part describes the synthesis of cyclopentadienyltungsten complexes containing a pendant alkyne group (I), and the subsequent photo-induced intramolecular coordination of the alkyne, forming complexes such as II. Compounds containing intramolecularly coordinated alkynes are rare, and this is the first example using cyclopentadiene as the core ligand. The second part describes the synthesis and structural characterisation of a number of novel metal complexes containing N-heterocyclic carbene ligands, some containing particular functionality for ta

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2

Barron, Andrew Ross. "Transition metal aluminohydride complexes." Thesis, Imperial College London, 1986. http://hdl.handle.net/10044/1/37935.

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3

Alem, Nassreen. "Zeolite encapsulated metal complexes." Thesis, University of Reading, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239055.

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4

Jasim, Naseralla. "Transition metal bifluoride complexes." Thesis, University of York, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.323538.

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5

Ho, Kin-ying. "Synthesis, characterization and spectroscopic properties of d6 and d10 metal complexes with pyridyl amine ligands /." Hong Kong : University of Hong Kong, 1999. http://sunzi.lib.hku.hk/hkuto/record.jsp?B20667905.

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6

Jones, Simon C. "Metal-metal coupling in bi- and multimetallic systems : organometallic pentalene and group 14-bridged cyclopentadienyl complexes of transition metals." Thesis, University of Oxford, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270635.

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7

Humphrey, Elizabeth Rebecca. "Tris(pyrazolyl)borate metal complexes : new ligands and metal-metal interactions." Thesis, University of Bristol, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.340301.

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8

Zhao, Ningfeng Eichhorn David M. "Cyano-substituted polypyrazolylborate metal complexes." Diss., Click here for available full-text of this thesis, 2005. http://library.wichita.edu/digitallibrary/etd/2005/d019.pdf.

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Thesis (Ph.D.)--Wichita State University, College of Liberal Arts and Sciences, Dept. of Chemistry.<br>"December 2005." Title from PDF title page (viewed on February 8, 2007). Thesis adviser: David Eichhorn. Includes bibliographic references (leaves 123-128).

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9

Rao, Sumitrananda N. R. "Novel adsorbents using metal complexes." Thesis, Georgia Institute of Technology, 1993. http://hdl.handle.net/1853/10200.

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10

Felsher, Dave. "Electrowinning of metal - DETA complexes." Thesis, McGill University, 2000. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=33329.

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Sludges formed by lime treatment of acidic mine effluents are a widespread environmental hazard. One treatment option is to recover the toxic and potentially valuable contained metals. A method has been reported to selectively recover the metals by leaching with a complexing agent, diethylenetriamine (DETA). In this thesis a novel method has been developed to recover metals from the metal---DETA complexes by direct electrowinning. Copper was studied initially as a test system due to the relative ease with which it is recovered in conventional sulphate electrowinning. The main industrial intere

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11

Tovilla, Cao-Romero Jorge Alberto Francisco. "Molecular recognition with metal complexes." Thesis, Imperial College London, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.436343.

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12

Harrison, Simon. "Metal-arene complexes and clusters." Thesis, University of Nottingham, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.280332.

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13

Jones, P. "Studies of chiral metal complexes." Thesis, Bucks New University, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.373593.

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14

Blackwell, Elizabeth Sarah. "Fluxionality in organonitrogen metal complexes." Thesis, University of Exeter, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.332328.

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15

Harrison, Stephen Anthony. "Novel chiral cyclopentadienyl metal complexes." Thesis, University of Southampton, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.442873.

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16

Veighy, Clifford Robert. "Novel cyclopentadienyl transition metal complexes." Thesis, University of Southampton, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.327366.

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17

Zard, P. W. "Transition metal complexes with pyrimidinethiones." Thesis, Imperial College London, 1988. http://hdl.handle.net/10044/1/47322.

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18

Miles, Philip James. "Metal complexes for cancer chemotherapy." Thesis, University of Manchester, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.627992.

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19

Jones, Michael David. "Trimethylenemethane and oxodimethylenemethane metal complexes." Thesis, University of Leicester, 1986. http://hdl.handle.net/2381/33764.

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Chapter 1 reviews the literature concerning trimethylenemethane and oxodimethylenemethane metal complexes and their r?le in organic synthesis. The preparation and characterisation of ?4-trimethylenemethane metal complexes of iridium, rhodium, osmium and ruthenium are presented in Chapter 2, together with the molecular structure of three of these complexes which establishes the presence of the ?4-trimethylenemethane ligand. The room temperature 1H n.m.r. spectra show the expected features for a static structure and no sign of rotation of the trimethylenemethane ligand was observed at higher tem

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20

Greig, John A. "Studies on metal macrocyclic complexes." Thesis, University of Edinburgh, 1991. http://hdl.handle.net/1842/13953.

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21

Johnson, Donald Martin. "Cyanoscorpionates and Transition Metal Complexes." Digital Commons @ East Tennessee State University, 2010. https://dc.etsu.edu/etd/1725.

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The new dihydrobis(4-cyano-3-tert-butylpyrazolylborate) ligand has been synthesized. Isolated crystals of the thallium complex were collected and structurally characterized by X-ray diffraction. Transition metal complexes of the ligand are currently under investigation.

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22

VALLETTA, ELISA. "Metal complexes with biological activity." Doctoral thesis, Università degli Studi di Cagliari, 2016. http://hdl.handle.net/11584/266768.

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Cancer is a group a diseases that involves abnormal cell growth with potential to invade or spread to other parts of the body, and it represents the second leading cause of death in developed countries. Cisplatin is one of the most chemotherapeutic drug. In spite of its great efficacy, it shows several side effects and most patients develop a resistance to cisplatin. To overcome the cisplatin resistance, drugs are often administered in combination in order to exploit the drug synergy. After discovery of cisplatin, the research focused on metal complexes less toxic, more effective and that exp

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23

Rais, Daniela. "Supramolecular chemistry of metal anynyl and metal phenanthroline complexes." Thesis, Imperial College London, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.271988.

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24

Plowright, Richard J. "Spectroscopy and interactions of metal and metal cation complexes." Thesis, University of Nottingham, 2010. http://eprints.nottingham.ac.uk/11448/.

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The work in this thesis looks at the spectroscopy and interactions of metals and metal cation complexes. There are two aspects of this vast subject that are considered: the electronic spectroscopy of Au-RG complexes and the ion-molecule chemistry of metals important in the mesosphere-lower thermosphere (MLT) region of the atmosphere. The spectroscopy of the molecular states in the vicinity of the strong Au 2P3/2, 1/2 ← 2S1/2 atomic transition, have been studied for the Au-RG (RG = Ne, Ar, Kr, Xe) series using resonance enhanced multiphoton ionization (REMPI). The spectroscopy of these systems

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25

Bradley, Patricia Marie. "Photochemistry and photophysical properties of metal-metal dimer complexes /." The Ohio State University, 2002. http://rave.ohiolink.edu/etdc/view?acc_num=osu1486461246814571.

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26

何建英 and Kin-ying Ho. "Synthesis, characterization and spectroscopic properties of d6 and d10metal complexes with pyridyl amine ligands." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1999. http://hub.hku.hk/bib/B31220885.

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27

Chan, Hoi-shan. "Syntheses, reactivity and coordination chemistry of d10 metal complexes of phosphorus and nitrogen donating polydentate ligands /." Hong Kong : University of Hong Kong, 1999. http://sunzi.lib.hku.hk/hkuto/record.jsp?B2079289X.

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28

Chamayou, Anne-Christine [Verfasser], and Christoph [Akademischer Betreuer] Janiak. "Chiral metal-Schiff base complexes = Chirale Metal-Schiff-Base-Komplexe." Freiburg : Universität, 2011. http://d-nb.info/1115490567/34.

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29

Barthram, Anita Marie. "Metal-metal interactions in polynuclear complexes of ruthenium and osmium." Thesis, University of Bristol, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.326683.

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30

Ziehm, Christopher Joseph. "ENHANCEMENT OF ELECTRONIC COUPLING IN METAL-METAL QUADRUPLY BONDED COMPLEXES." The Ohio State University, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=osu1416315259.

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31

Young, George Hansen. "Reactions of transition-metal propargyl complexes with polynuclear metal carbonyls /." The Ohio State University, 1989. http://rave.ohiolink.edu/etdc/view?acc_num=osu1487672631602474.

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32

Lam, Chong Ho. "Metal complexes containing oxygen tripod ligands : models of metal oxides /." View Abstract or Full-Text, 2003. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202003%20LAMC.

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Thesis (Ph. D.)--Hong Kong University of Science and Technology, 2003.<br>Includes bibliographical references (leaves 275-290). Also available in electronic version. Access restricted to campus users.

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33

Iskra, Andreas. "Photofragmentation studies of metal ion-molecule complexes and metal oxides." Thesis, University of Oxford, 2017. https://ora.ox.ac.uk/objects/uuid:d3663b37-7954-47a3-83e3-4a9ad7b9e3e7.

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Gas phase metal-containing complexes provide suitable systems in which to study fundamental binding motifs between a metal ion and molecules in the absence of any solvent, support or competing charge effects. In this thesis, metal-containing species are explored experimentally using infrared resonance enhanced photodissociation (IR-REPD) spectroscopy and velocity map imaging (VMI). The experimental results are further interpreted with the aid of spectral simulations based on density functional theory (DFT). These are the first studies reported using a newly built IR-REPD spectrometer equipped

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34

Holder, Alan John. "Studies on transition metal macrocyclic complexes." Thesis, University of Edinburgh, 1987. http://hdl.handle.net/1842/10961.

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35

Onyiriuka, Emmanuel C. "Pyrazolyl ligands in mixed metal complexes." Thesis, University of British Columbia, 1986. http://hdl.handle.net/2429/27178.

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The anions LMo(CO)₃⁻ (L = MeGapz₃ or MeGa(3,5-Me₂pz)₃) have been isolated as the Na⁺, Et₄N⁺ or HAsPh₃⁺ salts and the solution structures of the Na⁺ salts in THF have been defined by analysis of the v[sub CO] ir spectra. Ion-pair interaction of the LMo(CO)₃⁻ anion with Na⁺cation in THF solution is apparent from the spectroscopic evidence obtained. The MeGapz₃Mo(CO)₃ ⁻anion reacted with HCl or EtBr to give the seven-coordinate [MeGapz₃]-Mo(CO)₃R (R = H or Et) complexes. However, with Mel or PhCOCl complexes of the type [MeGapz₃]Mo(CO)₂(n₂-COR) (R = Me or Ph) were obtained. The reactions of the

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36

Ndamyabera, Christophe Adrien. "Porous metal complexes for CO2 capturing." University of the Western Cape, 2017. http://hdl.handle.net/11394/5739.

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Magister Scientiae - MSc (Chemistry)<br>The need in energy has resulted in the burning of fossil fuels at an increasingly high level. The consequence is a release of high volumes of carbon dioxide gas (CO2) in the atmosphere. This gas is a major greenhouse gas which causes global warming. There is therefore a great need to efficiently sequestrate this gas (CO2) for a sustainable economic development and environment. A new class of metal organic frameworks (MOFs) is a promising high potential application in carbon dioxide capture. In the current study, synthetic methods were developed for the d

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37

Cheung, Wai Man. "Transition metal complexes with dichalcogenoimidodiphosphinate ligands /." View abstract or full-text, 2007. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202007%20CHEUNG.

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38

Smith, Amanda Michelle. "Metal complexes of xylylene-bridged pyridiones." Thesis, Imperial College London, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.362871.

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39

Dubberley, Stuart R. "New calix[4]arene metal complexes." Thesis, University of Oxford, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.365290.

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40

Redfern, C. M. "Electronic structure of transition metal complexes." Thesis, University of Oxford, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.235094.

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41

Casely, Ian J. "Electropositive metal N-heterocyclic carbene complexes." Thesis, University of Edinburgh, 2009. http://hdl.handle.net/1842/3873.

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The first chapter is an introduction to the f-elements, with a focus on the synthesis and chemistry of tetravalent cerium complexes. The synthesis, characterisation and reactivity of carbenes, particularly N-heterocyclic carbenes (NHCs), and anionic-functionalised NHC ligands is discussed. The synthesis and reactivity of s-block, Group three and fblock NHC complexes is reviewed. The synthesis of the alcohol-functionalised unsaturated imidazolium proligand, [H2L]I [H2L = HOCMe2CH2(1-CH{NCHCHNiPr})], is extended to saturated imidazolinium analogues, [H2LR]X, [HOCMe2CH2(1-CH{NCH2CH2NR})]X (R = iP

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42

Hollingsworth, Nathan. "Metal complexes of amino-functionalised alkoxides." Thesis, University of Bath, 2010. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.528128.

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43

O'Sullivan, Julie Ann. "Metal complexes of trimethylsilyl substituted cyclooctatetraenes." Thesis, University of Sussex, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.361361.

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44

Davoile, Ryan J. "New reactions of metal-alkyne complexes." Thesis, Loughborough University, 2003. https://dspace.lboro.ac.uk/2134/12908.

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This thesis describes the use of bimetallic alkyne complexes for use in variants of the Nicholas reaction. The heterobimetallic core provides a source of chiral control unlike previous protocols reported in the literature, as stereocontrol arises from the inherently chiral cobalt-molybdenum core of these complexes and not from an external source. The inherently chiral heterobimetallic complexes were utilised as efficient chiral auxiliaries for nucleophilic additions to both propargylic alkene and Nicholas salt complexes with a degree of stereocontrol also extending to intramolecular addition.

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45

Mobbs, B. E. "Arene transition metal complexes in synthesis." Thesis, University of Oxford, 1985. http://ora.ox.ac.uk/objects/uuid:4c7030d4-297e-4af8-a622-d5b4963fc0a3.

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This thesis deals with the applications of organopalladium and organochromium chemistry to the functionalisation of the benzopyran ring system, at a variety of oxidation levels. Section I demonstrates the functionalisation of 3-, 6-, and 8-bromochromones via palladium (0) insertion into the C-Br bond. The resultant arylpalladium species are shown to undergo addition to the least substituted end of a variety of olefins including methyl acrylate, acrylonitrile and styrene. Subsequent palladium-hydride elimination leads to overall palladium catalysed vinylation of the chromone and the synthesis o

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46

Foster, Clive Edwin. "Tailored metal complexes for imaging applications." Thesis, Durham University, 1996. http://etheses.dur.ac.uk/5223/.

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The short-lived PET radionuclide (^134)La(t(_1/2)=6.7 minutes) is well suited to the repeated evaluation of blood perfusion, thus providing a method of following changes in tumour behaviour, in response to therapy. Ligands, both acyclic and macrocyclic, have been synthesised, and the complexes formed with (^134)La(^3+) evaluated in vitro and in vivo. Other lanthanide complexes have also been evaluated for potential use in magnetic resonance imaging and photoimmunoassay studies. A preliminary crystal structure determination of a lanthanum tetrabenzylphosphinate complex reveals the presence of o

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47

Bridgewater, Brian Michael. "Sterically hindered chiral transition metal complexes." Thesis, Durham University, 1998. http://etheses.dur.ac.uk/5022/.

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This thesis describes the synthesis, characterization and study of a series of organometallic compounds which all contain the same new ligand, l-phenyl-3-methyl-4,5,6,7-tetrahydroindenyl. The ligand forms a chiral complex once coordinated, and is relatively bulky when compared with ligands such as cyclopentadienyl or 4,5,6,7-tetrahydroindenyl.Chapter one of this thesis introduces cyclopentadienyl ligand chirality, cyclopentadienyl metal complex chirality and sterically demanding cyclopentadienyl systems. The synthesis and chemistry of tetrahydroindenes and some applications of chiral cyclopent

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48

Williams, James Anthony Gareth. "Luminescence behaviour of macrocycle metal complexes." Thesis, Durham University, 1995. http://etheses.dur.ac.uk/5313/.

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Luminescent complexes of lanthanide ions are of growing interest because the long lifetime of emission allows time-resolved detection procedures to be employed. A key step in the development of such systems lies in the preparation of highly luminescent complexes which display high stability in aqueous solution. A series of ligands based on 1,4,7,10-tetraazacyclododecane have been prepared, in which the nitrogen atoms are appended with coordinating phosphinate or amide groups, or a combination of both. The compounds obtained are octadentate ligands which form water-soluble lanthanide complexes

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49

Norbert, Waranakulaarachchiralalage D. J. A. "Metal complexes as potential pH sensors." Thesis, Queen's University Belfast, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.336008.

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50

Baiada, A. "Novel tricoordinate univalent coinage metal complexes." Thesis, University of East London, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.375666.

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