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Dissertations / Theses on the topic 'Metal-free oxidation'

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1

Schilling, Waldemar [Verfasser]. "Approaches for Transition Metal-Free Photocatalytic Oxidation Reactions / Waldemar Schilling." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2021. http://d-nb.info/1233009001/34.

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2

Crites, Charles-Oneil. "Investigating the Interactions between Free Radicals and Supported Noble Metal Nanoparticles in Oxidation Reactions." Thesis, Université d'Ottawa / University of Ottawa, 2015. http://hdl.handle.net/10393/33404.

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This thesis studies the interaction between free radical species and supported noble metal nanoparticles (silver and gold) in the context of oxidation reactions. The peroxidation of cumene is the first reaction to be discussed and the difference in peroxidation product distribution using silver nanoparticles (AgNP) versus gold nanoparticles (AuNP) is examined. Specifically, cumyl alcohol is obtained as the major product obtained when using supported AuNP, whereas cumene hydroperoxide is favoured for AgNP. Such variations in product distribution are partially explained by the differences in the
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3

Duong-Viet, Cuong. "Synthesis and processing of nitrogen-doped carbon nanotubes as metal-free catalyst for H2S selective oxidation process." Thesis, Strasbourg, 2015. http://www.theses.fr/2015STRAF029/document.

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Les nanotubes de carbone (NTCs) dopés avec différents hétéroéléments tels que l'oxygène et l'azote connaissent un intérêt croissant dans le domaine de la catalyse hétérogène comme leur utilisation en tant que catalyseur sans métaux. L'objectif de cette thèse consiste à la synthèse et la caractérisation de matériaux catalytiques à base de NTC dopés à l'azote supportés sur du carbure de silicium SiC par voie in situ (CVD) et ex-situ méthodes. Une autre approche a été utilisée pour la fonctionnalisation de la surface des nanotubes de carbone et basées sur l'utilisation d'un agent oxydant (HNO3) e
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4

Bansode, A. H. "Synthesis of biologically important molecular and development of synthetic methodologies involving oxidation reaction via visible-light and transition metal-free conditions." Thesis(Ph.D.), CSIR-National Chemical Laboratory Pune, 2021. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/6014.

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5

Yang, Weilu. "Electrochemical advanced oxidation processes for emerging organic contaminants removal with graphene-based modified carbon felt electrode." Thesis, Paris Est, 2019. http://www.theses.fr/2019PESC2025.

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Grâce au développement continu de technologies d'analyse environnementale, certains produits chimiques, qui sont reconnus être nocif, ont récemment attiré l'attention, puisqu'ils constituent un menace pour l'environnement et la santé publique.Parmi ces polluants émergent, les produits pharmaceutiques et de soins personnels (PPSP)sont devenus le cibles dela recherche internationale. La chine est le plus grand producteur et le marché des médicaments dans le monde. Avec le développement de l'économie sociale et l'amélioration du niveau de vie de la population, de la production et de l'utilisation
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6

Zhang, Yu. "Visible Light-Mediated Metal-Free Photocatalytic Oxidative Reactions and Cycloadditions." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2020. http://hdl.handle.net/21.11130/00-1735-0000-0005-14EF-8.

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7

SUAREZ, BERTOA RICARDO. "Sustainable procedures in organic synthesis." Doctoral thesis, Università degli Studi di Milano-Bicocca, 2009. http://hdl.handle.net/10281/7474.

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O-acyl-N-benzyllactamides are obtained in good yield by reaction of 4-benzyl-5-methyl-1,3-oxazolidine-2,4-diones with Grignards reagents and with lithium alkyls. Three alkanes and two ethers were oxidised with ozone in dichloromethane solution or in aqueous pH 3 suspension. Cyclodecane and cyclododecane were converted into the corresponding cycloalkanones. n-decane was converted into a mixture of isomeric n-decanones and carboxylic acids. An ester was formed from the ethers. Hence, one of the methylene groups of these substrates is generally converted into a carbonyl group. Some of these react
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8

Duan, Xiaoguang. "Catalytic Oxidative Degradation of Hydrocarbons Using Novel Metal-Free Nanocarbon Catalysts." Thesis, Curtin University, 2015. http://hdl.handle.net/20.500.11937/1951.

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This research presents novel nanocarbon materials as green and metal-free carbocatalysts for advanced oxidative processes toward environmental remediation. Various nanocarbons exhibit high catalytic activity in activation of sulfate oxidants for degradation of water contaminants. The tailored surface chemistry of nanocarbons and insightful mechanistic studies for catalytic activation of superoxides were revealed via deliberate materials design, advanced characterization techniques and theoretical calculations.The findings would significantly contribute to materials chemistry, environmental sc
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9

Zhang, Yu [Verfasser]. "Visible Light-Mediated Metal-Free Photocatalytic Oxidative Reactions and Cycloadditions / Yu Zhang." Göttingen : Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2020. http://d-nb.info/1221802372/34.

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10

Ayoub, Nadim. "Synthèse et valorisation des dérivés furaniques issus de la biomasse par oxydations sélectives." Electronic Thesis or Diss., Compiègne, 2022. http://www.theses.fr/2022COMP2677.

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La biomasse fait partie des ressources renouvelables qui peuvent répondre durablement à nos besoins de production de carburants, de produits chimiques et de matériaux. En effet, la biomasse non comestible telle que la lignocellulose a attiré l'attention des chercheurs et des scientifiques au cours des dernières décennies en tant qu'alternative renouvelable. Le furfural et le 5-hydroxyméthylfurfural (HMF), dérivés de la déshydratation des pentoses et des hexoses respectivement, sont produits à plusieurs millions de tonnes par an. Ces derniers composés sont donc des molécules plateformes et repr
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11

Lamani, Manjunath. "Design And Development Of Synthetic Methods Using Metal-Mediated And Metal Free Redox Reactions : Novel C-H Activations, Reductions And Oxidative Transformations." Thesis, 2012. https://etd.iisc.ac.in/handle/2005/2501.

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The thesis entitled “Design and Development of Synthetic Methods using Metal-mediated and Metal-free Redox Reactions: Novel C-H Activations, Reductions and Oxidative Transformations” is presented in 4 chapters Chapter 1; Iodine catalyzed amination of benzoxazoles: efficient metal free route to 2-aminobenzoxazoles under mild conditions. The Chapter 1 of this thesis describes iodine catalyzed C-H activation of benzoxazole with primary and secondary amines to form oxidative aminated products. Selective C-H oxidation is a frontline area of modern chemical research as it offers the opportunitie
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12

Lamani, Manjunath. "Design And Development Of Synthetic Methods Using Metal-Mediated And Metal Free Redox Reactions : Novel C-H Activations, Reductions And Oxidative Transformations." Thesis, 2012. http://hdl.handle.net/2005/2501.

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The thesis entitled “Design and Development of Synthetic Methods using Metal-mediated and Metal-free Redox Reactions: Novel C-H Activations, Reductions and Oxidative Transformations” is presented in 4 chapters Chapter 1; Iodine catalyzed amination of benzoxazoles: efficient metal free route to 2-aminobenzoxazoles under mild conditions. The Chapter 1 of this thesis describes iodine catalyzed C-H activation of benzoxazole with primary and secondary amines to form oxidative aminated products. Selective C-H oxidation is a frontline area of modern chemical research as it offers the opportunities
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13

Kao, Wei-Huan, and 高偉桓. "Density functional theory calculations on boron-doped carbon nanotubes as a potential metal-free catalyst for CO oxidation." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/vqv3zc.

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碩士<br>中原大學<br>化學研究所<br>106<br>By means of density functional theory (DFT) calculation, we used the carbon nanotubes with different content of doped boron as potential metal-free catalysts for the CO oxidation. In order to find the possible active sites for CO oxidation, we investigated the O2 -adsorption behavior on different position of 1 and 2 B-doped carbon nanotubes and find the most stable structures of adsorbed O2 are flat on C-B site of both nanotubes with the adsorption energies of -0.85 and -1.29 eV, respectively. Then we investigated the catalytic reaction paths of CO oxidation,
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14

Lin, I.-Hsiang, and 林逸庠. "A density functional theory study on nitrogen-doped carbon nanomaterials as a potential metal-free catalyst for CO oxidation." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/51638935078240872881.

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碩士<br>中原大學<br>化學研究所<br>104<br>We use density functional theory (DFT) calculation to investigate nitrogen-doped carbon nanomaterials as a potential metal-free catalyst for CO oxidation. The possible structures and reaction mechanisms, of CO oxidation are illustrated by using the same method. First, we consider the O2 adsorption and use Bader charge to analysis, the favorable adsorption sites are C-N site and C-C-1 site. The calculation results show that most stable adsorption energy are -0.82 and -1.63eV for NCNTs, and -0.84 and -0.99eV for N-C60. Then we use nudged elastic band (NEB) method to
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15

Ruz, Sichem Guerrero. "Activity in-situ IR and EXAFS spectroscopy studies, and Monte Carlo simulation of the preferential oxidation of carbon monoxide on Nb-promoted Pt/A12O3 catalysts and Pt-free metal oxides catalysts." 2007. http://etd.nd.edu/ETD-db/theses/available/etd-12202007-161930/.

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Thesis (Ph. D.)--University of Notre Dame, 2007.<br>Thesis directed by E. E. Wolf for the Department of Chemical and Biomolecular Engineering. "December 2007." Includes bibliographical references (leaves 196-214).
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16

Zhen-YuLin and 林真宇. "Metal ions mediated oxidative free radical reaction of 1,4-quinones." Thesis, 2010. http://ndltd.ncl.edu.tw/handle/65209540702165189310.

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碩士<br>國立成功大學<br>化學系碩博士班<br>98<br>The metal salts mediated radical reaction of quinones for constructing carbon-carbon bonds are described. Radical intermediates which created by Ag(II) or Mn(III) then underwent intermolecular and intramolecular cyclizations. The study was initiated by the methodolgy. There are two parts in this thesis: (1) Acyl and carbon radicals generated by the oxidative decarboxylation of α-ketone acid and α-amino acid respectively with silver(I) nitrate and persulfate. Besides, Acyl radicals also produced by β-ketone ester with manganese(III) and O2. Each of the radicals
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17

Tsai, An-I., and 蔡安益. "Metal ions mediated oxidative free radical reactions of 1,4-quinones and heterocycles." Thesis, 2008. http://ndltd.ncl.edu.tw/handle/37001122243101517445.

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博士<br>國立成功大學<br>化學系碩博士班<br>96<br>The use of radicals in organic synthesis has increased dramatically within the last decades. Radical carbon-carbon bond-forming reactions have grown in importance to the point where chemists are now routinely considered in strategy planning of complex targets. A typical, widely used radical cyclization involves the reduction of a halide or other functional group to a radical with R3SnH, followed by cyclization and reduction of the resulting radical to a hydrocarbon in the chain propagation steps. While this sequence often gives high yields of products, this app
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18

Chung-YiChou and 周忠毅. "Metal ions mediated oxidative free radical reactions of 1,4-quinones and heterocycles." Thesis, 2012. http://ndltd.ncl.edu.tw/handle/30746492538623197619.

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碩士<br>國立成功大學<br>化學系碩博士班<br>100<br>Free-radical reaction has been applied to formation of carbon-carbon bond for decades and it plays an important role for synthesis of heterocyclic compounds. Manganese (Ⅲ) acetate and Silver (Ⅱ) are the most common reagents for the oxidative free-radical reaction. The study was initiated by the methodology. There are two parts in this thesis: (1)The oxidative free radical reactions of 2-anilino-1,4-naphthoquinones 62 with Silver (Ⅱ) produce benzo[b]acridines 63 effectively. (2)The oxidative free radical reactions of 2-(Allylsulfonyl)-N-benzyl-N-(4’-methoxybi
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