Academic literature on the topic 'Metal-ligand stability constants'

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Journal articles on the topic "Metal-ligand stability constants"

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N., DALLALI, and K. AGRAWAL Y. "Metal-Ligand Stability Constants of Heterocyclic Hydroxamic Acids." Journal of Indian Chemical Society Vol. 69, Apr 1992 (1992): 219–20. https://doi.org/10.5281/zenodo.6089206.

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Analytical Laboratory, Pharmacy Department, Faculty of Technology and Engineering, M. S. University of Baroda, Kalabhavan, Baroda-390 001 <em>Manuscript received 15 March 1991, revised 17 March 1992, accepted 19 March 1992</em> Metal-Ligand Stability Constants of Heterocyclic Hydroxamic Acids.
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T., A. Patekar, and Abdul Rahim Shaikh. "Coordination studies of Ritodrine Hydrochloride with selected transition Metal ions." International Journal of Current Science Research and Review 07, no. 12 (2025): 9424–26. https://doi.org/10.5281/zenodo.14584076.

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Abstract : The stability constants of binary complexes of metal ions &nbsp;&nbsp;Cu&sup2;⁺, Ni&sup2;⁺, Co&sup2;⁺, Cr&sup3;⁺ and Zn<sup>2+</sup>&nbsp;with Ritodrine Hydrochloride ligand were studied in aqueous media at 28<sup>0</sup>&nbsp;C temperature. The Protonation constant and metal ligand stability constants were determined by Calvin Bjerrum titrations in combination with Microsoft excel software programme. 1 N NaNO<sub>3&nbsp;</sub>used to maintain ionic strength. Metal ligand ratio kept was 1: 1. The Protonation constant and metal ligand stability constants calculated by half integral a
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PRITAM, VERMA, FULWADHVA USHA, and B. LAXMESHWAR N. "Potentiometric Studies in Solution of some Transitional Metal Ion and Rare Earth Metal Ion Complexes of 5-Benzal-3-methyl-2-thiohydantoin( 5-benzal-3-methyl-4-imidozolinone-2-thioxo)." Journal of Indian Chemical Society Vol. 62, Jul 1985 (1985): 502–3. https://doi.org/10.5281/zenodo.6321646.

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Physical Chemistry Laboratory, Institute of Science, Bombay-400 032 <em>Manuscript received 26 December 1984, revised 26 June 1985, accepted 31 July 1985</em> The stepwise stability constants of complexes of 5-benzal-3-methyl-2-thiohydantoin with transition metal ions and rare earth metal ions are determined by Calvin-Bjerrum potentiometric titration method. The work is conducted in 3 : 1 (v/v) dioxane-water medium of ionic strength 0.1 <em>N</em> and at temperature 27&plusmn;1&deg;. The order of stability cons&shy;tants is found to be in agreement with the order reported by earlier workers. I
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Nleonu, E.C., E.R. Enemo, and T.E. Ezenwa. "Conductometric Study on the Stability Constants and Thermodynamic Parameters of Fe3+ Complexes with some Ligands." Chemistry Research Journal 6, no. 3 (2021): 112–16. https://doi.org/10.5281/zenodo.11665158.

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<strong>Abstract </strong>The stability constants and theymodynamic parameters of Fe<sup>3+</sup> complexes with cyanide, thiocyanide, ethylene diamine tetraacetic acid, methylamine and ethylamine were studied by conductometric method in aqueous medium at different temperatures (302, 308, 313 &amp; 318K). The stability constants and thermodynamic parameters of the metal-ligand complexes were studied at low concentration of the metal and ligand. The results indicated that, the complex formation is spontaneous, exothermic and entropically favourable. The complexes were observed to be stable at l
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Menon,, Sobhana K., and Yadvendra K. Agrawal,. "Proton-Ligand and Metal-Ligand Stability Constants of Hydroxamic Acids." Reviews in Inorganic Chemistry 16, no. 1 (1996): 1–90. http://dx.doi.org/10.1515/revic.1996.16.1.1.

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Agrawal, Y. K., R. Giridhar, and S. K. Menon. "Sulfa Drugs: Thermodynamic Proton—Ligand and Metal—Ligand Stability Constants." Journal of Pharmaceutical Sciences 76, no. 12 (1987): 903–6. http://dx.doi.org/10.1002/jps.2600761212.

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Leena, Gandhi, and S. Sekhon B. "Complexation equilibria of sulfisoxazole with proton and some metal ions in aqueous-organic solvents." Journal of Indian Chemical Society Vol. 83, Sep 2011 (2006): 868–70. https://doi.org/10.5281/zenodo.5829759.

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Department of Biochemistry and Chemistry, Punjab Agricultural University, Ludhiana-141 004, Punjab, India <em>E-mail :</em> sekhon224@yahoo.com <em>Manuscript received 4 January 2006, revised 4 May 2006, accepted 6 June 2006</em> The proton-ligand stability constant (log K\(_I^{II}\) i.e. p<em>K</em><sub>a</sub>) of sulfisoxazole in 50 : 50 (% v/v) aqueous ethanol and 50 : 50 (% v/v) aqueous-dioxane mixtures at different ionic strengths (0.05, 0.10 and 0.15 mol dm<sup>-3</sup>) and its stability constanlq with some metal ions were determined in 50 : 50 (% v/v) aqueous ethanol and aqueous-dioxa
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S.N., Jatolia, Verma S.K., Bhandari H.S., and Rathore Uma. "Potentiometric Study of Ni(II)-Thiosemicarbazone Systems in Micellar Medium." Chemistry Research Journal 5, no. 2 (2020): 195–201. https://doi.org/10.5281/zenodo.12493800.

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<strong>Abstract </strong>Ligand 2,6-Dihydroxyacetophenonethiosemicarbazone<sub> </sub>[2, 6 DHAT] has been synthesized.&nbsp; The present work describes the synthesis, characterization, solution, and biological investigations on Ni (II)-thiosemicarbazone complexes. Solution studies on the complexes have also been carried out in different micellar [HTAB, SDS, TX-100] systems at 25&deg;C and data have been compared with ethanol water mixture. Stability constants and molar ions in 60% ethanol were determined. Proton ligand stability constant and metal-ligand stability have been determined potent
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El-Bindary, Ashraf A., Adel Z. El-Sonbati, and Hanan M. Kera. "Thermodynamics of substituted pyrazolone. V: Potentiometric and conductometric studies of complexes of some transition metals with 4-(4-acetophenyl)hydrazono-3-methyl-2-pyrazolin-5-one." Canadian Journal of Chemistry 77, no. 7 (1999): 1305–9. http://dx.doi.org/10.1139/v99-122.

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Proton-ligand dissociation constants of 4-(4-acetophenyl)hydrazono-3-methyl-2-pyrazolin-5-one (AHMP) and metal-ligand stability constants of its complexes with some transition metal ions were calculated potentiometrically in 0.1 M KCl and 50% (v/v) ethanol-water mixture. The order of stability constants was found to be Th4+ &gt; UO22+ &gt; Ce3+ &gt; La3+ &gt; Mn2+ &lt; Co2+ &lt; Ni2+ &lt; Cu2+ &gt; Zn2+. The dissociation constant, pK1H, of AHMP and the stability constants, log K, of their complexes were determined at different temperatures (298, 308, and 318 K). The corresponding thermodynamic
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V., V. RAMANA, YAMUNA K., and SARASWATHI K. "Stability Constants of Metal Complexes of 1,2,4-Triazoles." Journal of Indian Chemical Society Vol. 68, Dec 1991 (1991): 666–67. https://doi.org/10.5281/zenodo.6135029.

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Department of Chemistry. S. V. University, Tirupati-517 502 <em>Manuscript received 21 May 1990, revised 2 December 1991, accepted 6 December 1991</em> The present study reports the stability constants of the metal complexes using bivalent Mn, Fe, Co, Ni, Cu and Zn with 4-amino-3-(methylphenyl)-5- mercapto-1 ,2,4-triazole (1), 4-amino-3-phenyl-5-mercapto-1,2,4-triazole (2), 4-amino-3-(p-cblorophenoxymethyl)-5-mercapto-1,2,4-triazole (3), 4-amino-3&middot; (phenoxymethyl)-5-mercapto-1,2,4-triazole (4).
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Dissertations / Theses on the topic "Metal-ligand stability constants"

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Zineddine, Hamid. "Contribution a l'etude de complexes de cations de transition et de lanthanides avec des peptides fonctionnels, synthese, electrochimie, spectrometrie structurale." Aix-Marseille 1, 1987. http://www.theses.fr/1987AIX11104.

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Metabanzoulou, Jean-Pierre. "Mecanisme de la complexation de l'ion uo : :(2)**(2+) par des di(acyl-4 pyrazolones-5), des ethers-couronnes, des diazapolyoxamacrocycles et des ligands apparentes." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13146.

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Etude spectrophotometrique de la stabilite des complexes de l'ion uo::(2)**(2+) et de l'ion cu**(2+), dans l'eau et eau-acetonitrile. Structures possibles des complexes 1:1, 1:2 et 2:1. Mecanismes de formation des complexes
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Bouet, Gilles. "Etude structurale et analytique de complexes d'halogénures d'éléments 3D : mx::(2) (M = co,ni,cu; X = cl,br) et de diverses aldoximes furanniques." Angers, 1987. http://www.theses.fr/1987ANGE0009.

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Vingt-quatre nouveaux complexes d'halogénures de métaux 3 D : mx::(2) (m = co,ni,cu; x = cl,br) sont préparés et caractérisés. Leurs structures sont déterminées par diffraction des rayons X pour deux des composés et, à partir de celles-ci, pour l'ensemble des complexes grâce à la spectroscopie infrarouge et à la spectroscopie électronique. Le calcul des constantes de stabilité et des paramètres thermodynamiques correspondants par titrimétrie thermométrique est décrit.
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Aous, Soad. "Synthèse de cyclopendants aminophosphorés : complexes d'ions paramagnétiques à finalité biomédicale." Université Joseph Fourier (Grenoble), 1998. http://www.theses.fr/1998GRE10057.

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Les resultats de ce travail a finalite biomedicale s'organisent selon trois axes : - synthese de nouveaux cyclopendants et de complexes polyfonctionnels de gd iii, en serie macrocyclique et bismacrocyclique, les podants etant organophosphores. Nous avons ainsi obtenu le dotmp -acide 10,13-dioxo-1,4,7-triazacyclopentadecane-4,7,10-tri(methylenephosphonique) avec un cycle bifonctionnel dioxo-triaza et des composes modeles, precurseurs de dendrimeres : le ttap, -acide 1,4,8,11-tetraazacyclotetradecane-1-acetique-4,8,11-tri(methylenephosphonique) cyclopendant a podants mixtes phosphonique et carbo
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Boyle, David. "Surface Complexation Modelling of the Adsorption of Cd(II), Cu(II), and Ni(II) to the Roots of Triticum turgidum." Thesis, 2012. http://hdl.handle.net/10214/5315.

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The goal of this study was to characterize the binding sites on the surface of wheat roots, Triticum turgidum, involved in the adsorption of protons and metals, and quantify the thermodynamic constants needed for a surface complexation model to predict metal binding. The adsorption of protons, Cd(II), Cu(II), and Ni(II) to the root surface as a function of pH and ionic strength in single metal exposure scenarios was quantitatively described using potentiometric titrations, batch metal adsorption experiments, and the least squares fitting program FITEQL. Model predictions from single metal ex
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Book chapters on the topic "Metal-ligand stability constants"

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Kanzaki, Ryo. "Acid Dissociation Constants, Formation Constants, and Other Thermodynamic Parameters." In Instrumental Analysis of Coordination Compounds. Royal Society of Chemistry, 2024. http://dx.doi.org/10.1039/9781837674978-00065.

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In metal–ligand mixture solutions, more than one complex species with different coordination numbers coexist, and each complex behaves as a distinct chemical species. Hence, the first step in characterizing and synthesizing metal complexes is to know the type and concentration of each complex. Stability constants enable us to determine the formation distribution of the metal complexes. In this chapter, complex formation (complexation) equilibria and their equilibrium constants (stability constants) are described. The experimental procedures to determine the thermodynamic parameters of these co
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Inomata, T. "Stability of Metal Complexes and Ligand Substitution Reactions." In Coordination Chemistry. Royal Society of Chemistry, 2024. http://dx.doi.org/10.1039/9781837673254-00148.

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In this chapter, the necessary basics (solvents, chemical equilibria, and definitions of acids and bases) are briefly explained before the stability of metal complexes and ligand substitution reactions are discussed. Then, the formation and stepwise formation constants, which are indicators of the stability of metal complexes, are explained. The effects of the Irving–Williams series and chelate effects, which are necessary for discussing the stability of metal complexes, are also explained. Finally, ligand substitution reactions are introduced as one of the most typical reactions of metal comp
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Kanzaki, Ryo. "Thermodynamic Measurements: Potentiometry, UV/Vis Spectrometry and Calorimetry." In Metal Ions and Complexes in Solution. Royal Society of Chemistry, 2023. http://dx.doi.org/10.1039/bk9781839169601-00001.

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General information about metal complex formation equilibria, the definition of the stability constants, and the calculation of the formation distribution of metal complexes are presented. Acid–base dissociation of the ligand species is also covered. Then, the procedure to determine the stability constants of metal complexe by means of potentiometric, spectroscopic, and calorimetric titrations, as well as the experimental attention, is explained. The physical meaning and interpretation of the simultaneously obtained thermodynamic parameters are also discussed.
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Conference papers on the topic "Metal-ligand stability constants"

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Wang, Hao, Anh Nguyen, Tao Wang, Ryosuke Okuno, Vitor Felipe Hage Serra, and Pedro Tupã Pandava Aum. "Enhanced CO2 Mineralization in Stromatolite and Magnesium and Calcium Silicates Using Formate Ligands." In SPE International Conference on Oilfield Chemistry. SPE, 2025. https://doi.org/10.2118/224315-ms.

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Abstract Carbon dioxide (CO2) mineralization in (ultra)mafic rock formations has gained increasing attention as a potential method for secure CO2 sequestration compared to structural and capillary trapping mechanisms. The CO2 mineralization process consists of two main stages: mineral dissolution and CO2 mineralization. This paper presents an experimental study on enhanced CO2 mineralization using sodium formate solutions, where formate ions serve an effective catalytic role. The experimental program began with the characterization of rock samples and fundamental property measurements (pH, den
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Reports on the topic "Metal-ligand stability constants"

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Crowley, David, Yitzhak Hadar, and Yona Chen. Rhizosphere Ecology of Plant-Beneficial Microorganisms. United States Department of Agriculture, 2000. http://dx.doi.org/10.32747/2000.7695843.bard.

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Rhizoferrin, a siderophore produced by Rhizopus arrhizus, has been shown in previous studies to be an outstanding Fe carrier to plants. However, calculations based on stability constants and thermodynamic equilibrium lead to contradicting conclusions. In this study a kinetic approach was employed to elucidate this apparent contradiction and to determine the behavior of rhizoferrin under conditions representing soil and nutrient solutions. Stability of Fe3+ complexes in nutrient solution, rate of metal exchange with Ca, and rate of Fe extraction by the free ligand were monitored for rhizoferrin
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