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Dissertations / Theses on the topic 'Metal nitrosyl complexes'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Smith, Kevin Michael. "Pi-bonding and reactivity in transition metal nitrosyl complexes." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp03/NQ27249.pdf.

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2

Ansari, Nasrin. "Coordination properties of aminophosphine with first row transition metal nitrosyl complexes." Thesis, University of Ottawa (Canada), 1994. http://hdl.handle.net/10393/6862.

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The synthesis of the new thermolabile ironnitrosylhydride complex FeH(NO)(CO)(dppf) is reported. (dppf = 1,1$\sp\prime$-bisdiphenyl phosphino-ferrocene). The facile decomposition of FeH(NO)(CO)(dppf) is interpreted in terms of a homolysis of the Fe-H bond and of a nitrosyl transfer reaction. The synthesis of the structurally characterized iron complex Fe(O=PPh$\sb2$(2-Py))$\sb3\sp2\sp+\cdot$2BF$\sb4\sp-$, by the reaction of Fe(NO)$\sb2$(THF)$\sb2\sp+$ with PPh$\sb2$(2-Py) is described. The proposed mechanism for the formation of Fe(O=PPh$\sb2$(2-Py))$\sb3\sp2\sp+\cdot$2BF$\sb4\sp-$ involves a

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3

Mougenot, Pierre. "Etude theorique ab initio scf et ci de complexes organometalliques binucleaires." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13025.

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Analyse approfondie du spectre photoelectronique se(fe(c::(5)h::(5)))::(2)(no)::(2). Etude critique des resultats experimentaux anterieurs concernant le diamagnetisme suppose se(co(c::(5)h::(5)))::(2)(no)::(2). Bon accord avec l'experience dans l'etude theorique de l'etat fondamental du cation dirhodium tetraacetate dihydrate. Etude sur la nature de l'interaction metal-metal dans (v(c::(5)h::(5)))::(2) (c::(8)h::(8))

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4

Scheibel, Markus. "Metal-Nitrogen Multiple Bonds with Square-Planar Group 9 Transition Metal PNP Pincer Complexes." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2014. http://hdl.handle.net/11858/00-1735-0000-0023-9944-4.

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5

Hildreth, J. L. "Chemical and biological studies of technetium nitrosyl complexes." Thesis, Loughborough University, 1992. https://dspace.lboro.ac.uk/2134/33014.

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A simple and widely applicable method for the synthesis of technetium nitrosyl complexes containing either [99Tc] or [99mTc] has been developed using hydroxylamine as a reducing agent. A number of readily available complexes such as [TcO4]- or [TcX6]2- (X = Cl, Br, I) may be employed as the starting material.

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6

Fegy, Karine. "Ingénierie de matériaux moléculaires magnétiques : complexes de radicaux libres nitronyl nitroxydes bis-bidentes ; synthèse, structure et magnétisme." Université Joseph Fourier (Grenoble ; 1971-2015), 1997. http://www.theses.fr/1997GRE10197.

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La chimie de coordination des radicaux libres nitronyl nitroxydes est propice aux composes moleculaires magnetiques (aimants moleculaires ou transitions de spin). Cependant le caractere base de lewis faible du groupe nitroxyde >n-o limite dans de nombreux cas leur utilisation aux ions metalliques porteurs de ligands attracteurs. Pour eviter ce probleme, nous avons choisi de substituer les radicaux par des groupes donneurs. Ce travail concerne la synthese, la caracterisation structurale et l'etude des proprietes magnetiques de complexes d'ions metalliques avec les radicaux nitronyl nitroxydes p

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7

Sayers, Stephen F. "Synthetic investigations toward metal nitrosyl complexes." Thesis, 1996. http://hdl.handle.net/2429/6167.

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Reaction of Cp*W(NO)(CH₂SiMe₃)Cl with AgBF4 in MeCN leads to isolation of [Cp*W(NO)(CH₂SiMe₃)(NCMe)₂]BF₄, 2.1. The reactivity of this complex is explored, in particular, the reaction of 2.1 with H₂0 which results in stepwise hydrolysis of the nitrosyl ligand. Labelling studies with D₂0 and H₂¹⁸O are performed which give some insight into the mechanism of the transformation of 2.1 to Cp*W0₂(CH₂SiMe₃) and the fate of the NO ligand. The synthesis and characterisation of a range of carboxylate-containing nitrosyl complexes of the general class Cp*W(NO)(0₂CR')X [X = CH₂SiMe₃ , CI] and attempt

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8

Barr, Mary E. "Syntheses and stereophysical analyses of several metal polyphosphide and triangular iron nitrosyl complexes." 1991. http://catalog.hathitrust.org/api/volumes/oclc/24358734.html.

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Thesis (Ph. D.)--University of Wisconsin--Madison, 1991.<br>Vita. Typescript. eContent provider-neutral record in process. Description based on print version record. Includes bibliographical references.

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9

Menglet, Dmitri. "Nitrosyl halides and bis-acetylacetonates of ruthenium and osmium : synthetic and spectro-electrochemical investigation of ligand addivity in redox-active transition metal complexes." Phd thesis, 1996. http://hdl.handle.net/1885/144252.

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10

Polaczek, Justyna. "NO versus HNO chemistry : studies on the formation, stability and reactivity of nitrosylcobalamin and model complexes." Praca doktorska, 2019. https://ruj.uj.edu.pl/xmlui/handle/item/74789.

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11

Weng, Hong-Yue, and 翁宏岳. "The Preparation and Magnetic Studies Metal Complexes with Nitronyl Nitronyl Ligand." Thesis, 1995. http://ndltd.ncl.edu.tw/handle/44172688795344560054.

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碩士<br>淡江大學<br>化學學系<br>83<br>The magnetic properties of the metal complexes are most originated from the electronic spin ststes of the metal ions.We can predict the different magnetic properties from the complexes through the moleculars. In present thesis,the organic radical,NITpPy,reacts with different metal complexes of acetylacetonates,hexafluoac- etylacetonates and chlorides. We hope to get ferromagnetic molecular-base materials with strong inter- or intramolecular interaction and high c

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12

Huang, Chian-Feng, and 黃乾峰. "The Preparation and Magnetic Studies of Metal Complexes with Pyridine-Substituted Nitronyl Nitroxide Ligands." Thesis, 1996. http://ndltd.ncl.edu.tw/handle/85705556201483969888.

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碩士<br>淡江大學<br>化學學系<br>84<br>Two nitronyl nitroxide ligands NIToPy (2-(2-pyridyl)-4,4,5,5- tetramethyl-4,5-dihydro-1H-imidazolyl-oxy-3-oxide) and NITmPy (2-(3-pyridyl)-4,4,5,5-tetramethyl- 4,5-dihydro-1H-imidazolyl- oxy-3-oxide) and some new compoundsof formula Cd3Cl6(NIToPy)2( ETOH)2, HgBr2(NIToPy), Co(NIToPy)3(ClO4)2, CoCl2(NIToPy)2, Co( hfac)2(NIToPy), Ni(NIToPy)2(ClO4)2(H2O)7/2, Cu(NIToPy)2(ClO4)2( H2O), CuCl2(NIToPy)2 and HgBr2[HgBr2(NITmPy)]2 are magnetically characterized. The NIToP

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13

Huang, Gan Feng, and 黃乾峰. "The preparation and magnetic studies of metal complexes with pyridine-substituted nitronyl nitroxide ligands." Thesis, 1996. http://ndltd.ncl.edu.tw/handle/88520768010335909114.

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14

Lin, Hsin-Huang, and 林信宏. "Structures and Magnetic Properties of Imino/Nitronyl Nitroxide Radicals and Their Metal Complexes and Cyano-Bridged of Lanthanide Complexes." Thesis, 2005. http://ndltd.ncl.edu.tw/handle/98233878494598093557.

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博士<br>淡江大學<br>化學學系博士班<br>93<br>The present thesis has been divided into two parts: PartⅠ: Preparations, structures and magnetic properties of the free radicals of nitronyl nitroxide and imino nitroxide and their metal complexes have been reported. The temperature dependence of magnetic properties of these free radicals and their metal complexes are measured, the magneto-structural correlations also have been discussed . At first, twelve nitronyl/imino nitroxide derivatives are prepared, in which the crystal structures of the free radical ligands of NITpPy、NITmPy、NITpBA、IM-pBA、NITmBA、NITpAH h

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15

Bo-ShengWang and 王柏升. "On the electrocatalytic activity of transition metal nitroso-R complexes towards the reduction of CO2." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/cxnb6j.

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碩士<br>國立成功大學<br>化學工程學系<br>104<br>In this study, the electrochemical reduction of CO2 using the electrocatalytic systems, which consists of four types of surface-modified fluorine-doped tin oxide coated glass electrodes (FTO) and three kinds of transition metal (Co2+, Ni2+, Fe2+) nitroso–R complexes was investigated. By reducing the CO2 into methanol, it can not only eliminate the excess emission of CO2 in atmosphere but also generate an alternative energy to solve both severe greenhouse effect and the energy crisis. The four types of surface-modified FTO electrodes include bare FTO, Prussian b

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