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Journal articles on the topic 'Metal-organic complex'

Author: Grafiati

Published: 3 June 2025

Last updated: 31 July 2025

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1

Hang, Tian, Wen Zhang, Heng-Yun Ye, and Ren-Gen Xiong. "Metal–organic complex ferroelectrics." Chemical Society Reviews 40, no. 7 (2011): 3577. http://dx.doi.org/10.1039/c0cs00226g.

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2

Vairaprakash, Pothiappan, Hisanori Ueki, Kentaro Tashiro, and Omar M. Yaghi. "Synthesis of Metal−Organic Complex Arrays." Journal of the American Chemical Society 133, no. 4 (2011): 759–61. http://dx.doi.org/10.1021/ja1097644.

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3

Pérez, O., F. Porcher, J. Jaud, and J. M. Rueff. "Complex ordering in metal–organic frameworks." Acta Crystallographica Section A Foundations of Crystallography 68, a1 (2012): s63. http://dx.doi.org/10.1107/s0108767312098790.

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4

Budnikova, Yulia H. "Metal complex catalysis in organic electrosynthesis." Russian Chemical Reviews 71, no. 2 (2002): 111–39. http://dx.doi.org/10.1070/rc2002v071n02abeh000697.

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5

Fracaroli, Alejandro M., Kentaro Tashiro, and Omar M. Yaghi. "Isomers of Metal–Organic Complex Arrays." Inorganic Chemistry 51, no. 12 (2012): 6437–39. http://dx.doi.org/10.1021/ic300744x.

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6

Hang, Tian, Wen Zhang, Heng-Yun Ye, and Ren-Gen Xiong. "ChemInform Abstract: Metal-Organic Complex Ferroelectrics." ChemInform 42, no. 42 (2011): no. http://dx.doi.org/10.1002/chin.201142221.

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7

Mamedova, Shafa Agаеvna. "METAL COMPLEX CATALYSIS." Globus 7, no. 5(62) (2021): 31–33. http://dx.doi.org/10.52013/2658-5197-62-5-7.

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Complexes of transition metals with chiral ligands are considered as catalysts. Among metal-containing organic complexes with semiconducting properties, compounds of the porphin series occupy a special place in electrocatalytic studies. The properties of the porphyrin macrocycle, their role in catalysis, and the influence of the nature of the metal on the catalytic properties of the complex are considered.

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8

Timofeeva, Maria V., Semyon V. Bachinin, and Valentin A. Milichko. "Tuneable photoluminescence of TBAPY-based Metal-Organic Complex." Journal of Physics: Conference Series 2015, no. 1 (2021): 012151. http://dx.doi.org/10.1088/1742-6596/2015/1/012151.

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Abstract We report the synthesis of crystals of an organic metal complex based on a large redox-active ligand (tbapy) exhibiting luminescent properties. We have demonstrated the tuning of the luminescence of a Zn-based metal-organic complex, soaked in advance in dimethylformamide, with pumping light.

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9

Hong, Dongfeng, Linlin Shi, Xianghui Liu, Huiyuan Ya, and Xin Han. "Photocatalysis in Water-Soluble Supramolecular Metal Organic Complex." Molecules 28, no. 10 (2023): 4068. http://dx.doi.org/10.3390/molecules28104068.

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As an emerging subset of organic complexes, metal complexes have garnered considerable attention owing to their outstanding structures, properties, and applications. In this content, metal-organic cages (MOCs) with defined shapes and sizes provide internal spaces to isolate water for guest molecules, which can be selectively captured, isolated, and released to achieve control over chemical reactions. Complex supramolecules are constructed by simulating the self-assembly behavior of the molecules or structures in nature. For this purpose, massive amounts of cavity-containing supramolecules, suc

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10

KANEDA, Kiyotomi, and David E. BERGBREITER. "Development of Organic Polymer-bound Metal Complex Catalysts." Journal of The Japan Petroleum Institute 36, no. 4 (1993): 268–81. http://dx.doi.org/10.1627/jpi1958.36.268.

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11

Rimoldi, Martino, Akitake Nakamura, Nicolaas A. Vermeulen, et al. "A metal–organic framework immobilised iridium pincer complex." Chemical Science 7, no. 8 (2016): 4980–84. http://dx.doi.org/10.1039/c6sc01376g.

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An iridium pincer complex has been immobilised in the metal–organic framework NU-1000. The stable Ir-pincer modified NU-1000 is catalytically active in the hydrogenation of alkenes in condensed phase and under flow conditions.

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12

Ludvík, Jiří, and Bengt Nygård. "Electrochemistry and metal complex formation of organic diselenides." Journal of Electroanalytical Chemistry 423, no. 1-2 (1997): 1–11. http://dx.doi.org/10.1016/s0022-0728(96)04955-8.

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13

Santalo, N., J. Tarres, E. Espinosa, et al. "(BTDM-TTF)-TCNQ complex, a new organic metal." Synthetic Metals 56, no. 1 (1993): 2050–56. http://dx.doi.org/10.1016/0379-6779(93)90371-3.

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14

Wang, J. F., G. E. Jabbour, E. A. Mash, et al. "Oxadiazole Metal Complex for Organic Light-Emitting Diodes." Advanced Materials 11, no. 15 (1999): 1266–69. http://dx.doi.org/10.1002/(sici)1521-4095(199910)11:15<1266::aid-adma1266>3.0.co;2-h.

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15

Yang, Chen, Yan-Lung Wong, Ran Xiao, et al. "Complex Metal-Organic Frameworks from Symmetrically Backfolded Dendrimers." ChemistrySelect 1, no. 13 (2016): 4075–81. http://dx.doi.org/10.1002/slct.201601089.

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16

Budnikova, Yu H. "ChemInform Abstract: Metal Complex Catalysis in Organic Electrosynthesis." ChemInform 33, no. 31 (2010): no. http://dx.doi.org/10.1002/chin.200231279.

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17

Alenezi, Moneer, Bader Alarbeed, and Yousef Alqaheem. "METAL HYDRIDES AND METAL-ORGANIC FRAMEWORKS FOR HYDROGEN STORAGE IN AUTOMOTIVE APPLICATIONS: A REVIEW." Chemical Problems 22, no. 1 (2024): 76–94. http://dx.doi.org/10.32737/2221-8688-2024-1-76-94.

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Hydrogen is an attractive automotive fuel because it is carbon-free, abundantly available from water, and has an exceptional mass-energy density. Hydrogen storage has become a trendy topic in recent years with its ability to design low-cost, lightweight materials that can reversibly and rapidly store hydrogen near ambient conditions. Various materials-based systems, such as metal hydrides and metal-organic frameworks (MOFs), have been introduced. This paper discusses and compares each material in terms of hydrogen storage capacity, kinetics, and viability. Different types of metal hydrides, su

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18

Ivanova, Stefka. "Metal-based organic complexes with anticancer activity." Bulgarian Society of Medical Sciences Journal 6 (October 28, 2024): e136135. https://doi.org/10.3897/bsms.6.136135.

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The discovery of the mechanism of action and the main structure-activity dependencies of platinum complexes create opportunities for rational synthesis of new metal-based organic complexes as potential antitumor drugs with reduced resistance and toxicity and / or a wider spectrum of antitumor activity. In the field of targeted synthesis of antitumor complexes has been working hard for 40 years. Initial research focused on obtaining complexes with a structure similar to cisplatin, and later on the search for new "non-classical" antitumor complexes. Selection of a suitable ligand system, ensurin

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19

Kaur, Navjeet, Neha Ahlawat, Pooja Grewal, Pranshu Bhardwaj, and Yamini Verma. "Organo or Metal Complex Catalyzed Synthesis of Five-membered Oxygen Heterocycles." Current Organic Chemistry 23, no. 25 (2020): 2822–47. http://dx.doi.org/10.2174/1385272823666191122111351.

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: The reactions involving the formation of C-O bond using metal as a catalyst have emerged to be one of the most influential reactions for the synthesis of heterocycles in modern organic chemistry. Catalysis by metals offers diverse opportunities to invent new organic reactions with a promising range of selectivities such as chemoselectivity, regioselectivity, diastereoselectivity, and enantioselectivity. The methodologies used earlier for synthesis were less approachable to the organic chemist because of their high cost, highly specified instrumentation and inconvenient methods. For both ster

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20

Gándara, Felipe, and Thomas D. Bennett. "Crystallography of metal–organic frameworks." IUCrJ 1, no. 6 (2014): 563–70. http://dx.doi.org/10.1107/s2052252514020351.

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Metal–organic frameworks (MOFs) are one of the most intensely studied material types in recent times. Their networks, resulting from the formation of strong bonds between inorganic and organic building units, offer unparalled chemical diversity and pore environments of growing complexity. Therefore, advances in single-crystal X-ray diffraction equipment and techniques are required to characterize materials with increasingly larger surface areas, and more complex linkers. In addition, whilst structure solution from powder diffraction data is possible, the area is much less populated and we deta

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21

Sacarescu, Liviu, Rodinel Ardeleanu, Gabriela Sacarescu, Mihaela Simionescu, and Ionel Mangalagiu. "Polysilane–Metal Complexes for Organic Semiconductors." High Performance Polymers 19, no. 5-6 (2007): 501–9. http://dx.doi.org/10.1177/0954008306081193.

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New polysilane-metal complexes structures were obtained by the polycondensation reaction of α,ω-bis(chloromethyl)-polymethylphenylsilane with the Ni (II) complex of bis(salicylidene)ethylenedia-mine (salen). The chloro-functionalized polysilane was obtained by a modified Wurtz coupling procedure at low temperatures. To obtain the polymer-metal complex the resulted macroligand was complexed with metal cations. This structure is characterized by a highly localized electroactivitry in the redox moiety combined with a specific σ conjugative effect in the polysilane chain. Infrared, 1H NMR and UV-v

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22

Li, Ying, Hua Xu, Shuxin Ouyang, and Jinhua Ye. "Metal–organic frameworks for photocatalysis." Physical Chemistry Chemical Physics 18, no. 11 (2016): 7563–72. http://dx.doi.org/10.1039/c5cp05885f.

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Metal–organic frameworks (MOFs) have emerged as novel photocatalysts owing to their inherent structural characteristics of a large surface area and a well-ordered porous structure. In this article, we summarize various strategies carried out over MOFs via either modification of the organic linker/metal clusters or incorporation with metal/complex catalysts to enhance the light absorption, charge separation, reactant adsorption/activation of MOF-based photocatalysis towards the superior photocatalytic performance.

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23

Tarabasanu Mihaila, Cornel, Lavinia G. Hinescu, Cristian Boscornea, Carmen Moldovan, and Mihai E. Hinescu. "METAL COMPLEX TETRAIZOINDOLES AS SENSOR MATERIALS." SOUTHERN BRAZILIAN JOURNAL OF CHEMISTRY 10, no. 11 (2002): 79–87. http://dx.doi.org/10.48141/sbjchem.v10.n11.2002.81_2002.pdf.

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The paper presents the synthetic routes for obtaining some organic semiconductors and their characterization in order to use in thin film deposition for gas sensing devices. An original technique was used to control the molecular weight of polymeric phthalocyanine. We have fabricated devices consisting of evaporated thin films of copper, nickel, and iron phthalocyanines onto interdigital electrodes and estimated the electrical conductivity by in-situ measurements. The films were evaporated onto substrates (gold or aluminum) which were entirely integrated in the standard CMOS (capacitor metal o

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24

Sajna, Kappamveettil, Alejandro M. Fracaroli, Omar M. Yaghi, and Kentaro Tashiro. "Modular Synthesis of Metal–Organic Complex Arrays Containing Precisely Designed Metal Sequences." Inorganic Chemistry 54, no. 4 (2015): 1197–99. http://dx.doi.org/10.1021/ic5025372.

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25

Aljumaily, Mijbil Mohammad, and Hudhaifa Maan Al-Hamandi. "Organic Matter and Heavy Metals Sorption." Tikrit journal for agricultural sciences 22, no. 3 (2022): 158–65. http://dx.doi.org/10.25130/tjas.22.3.18.

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Organic matter content in soils is highly variable and includes dead and living organisms and their decomposition products. plant residue and humic substances. Thermodynamically, organic matter is unstable in soils and later will oxidize to Co2, and H2O. The effective substances of organic matter decomposition are fulvic and humic acids (FA+Hu) which contain Several functional groups that release electrons or protons during their decomposition leaving behind several radical groups that act as electron donner to ward heavy metal ions forming FA and Hu-metal soluble and insoluble complexes. Thos

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26

Krishnamurti, G. S. R., P. M. Huang, L. M. Kozak, H. P. W. Rostad, and K. C. J. Van Rees. "Distribution of cadmium in selected soil profiles of Saskatchewan, Canada: Speciation and availability." Canadian Journal of Soil Science 77, no. 4 (1997): 613–19. http://dx.doi.org/10.4141/s97-008.

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The distribution of Cd with depth, its particulate-bound speciation and availability index were studied in nine typical soil profiles of Saskatchewan, Canada. In the Ap horizons, Cd was predominantly in the metal-organic complex-bound form, accounting for about 38.8%, on average, of the total Cd present in the soils. The carbonate-bound Cd and the metal-organic complex-bound Cd accounted for 33.5 and 12.9%, respectively, on average, of the total Cd present in the B horizons. In the Ck horizons, Cd was predominantly in the carbonate-bound form, accounting for about 70.9%, on average, of the tot

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27

Akitsu, Takashiro. "Symmetry in Organic/Inorganic Hybrid Materials." Symmetry 14, no. 8 (2022): 1624. http://dx.doi.org/10.3390/sym14081624.

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The term “organic/inorganic hybrid materials” here refers to a metal complex consisting of an inorganic metal ion and an organic ligand, a metalloprotein, or a composite functional material in which an inorganic compound and an organic material are combined (Figure 1) [...]

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28

Ma, Yong, Hong-Xia Chen, Feng Zhou, et al. "Metal complex modified azo polymers for multilevel organic memories." Nanoscale 7, no. 17 (2015): 7659–64. http://dx.doi.org/10.1039/c5nr00871a.

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Our approach enables modulating energy levels of azo polymers by varying the coordination metal ions. The ability to tune the bandgap energy of azo polymers provides an opportunity to develop new materials for high density data storage.

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29

Kennedy, Robert D., Daniel J. Clingerman, William Morris, et al. "Metallacarborane-Based Metal–Organic Framework with a Complex Topology." Crystal Growth & Design 14, no. 3 (2014): 1324–30. http://dx.doi.org/10.1021/cg401817g.

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30

Xu, Hong, Vasiliki Kosma, Kazunori Sakai, Emmanuel P. Giannelis, and Christopher K. Ober. "EUV photolithography: resist progress in metal–organic complex photoresists." Journal of Micro/Nanolithography, MEMS, and MOEMS 18, no. 01 (2018): 1. http://dx.doi.org/10.1117/1.jmm.18.1.011007.

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31

Rani, Bina. "Coordination Chemistry of Cobalt Biguanide Complex: Ligand Interaction and Metal Complex Stability." International Journal for Research in Applied Science and Engineering Technology 13, no. 5 (2025): 7390–93. https://doi.org/10.22214/ijraset.2025.71822.

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Biguanides are versatile organic compounds known for their broad applications in medicinal chemistry, coordination chemistry, and catalysis. Biguanide, C₂N₅H₇ is a nitrogen donor bidentate ligand. Structurally, they contain two linked guanidine moieties, which enable strong chelation with metal ions, forming stable complexes. The ability of biguanides to interact with transition metals has led to the development of metal-biguanide complexes with remarkable biological and catalytic properties. These complexes exhibit diverse coordination modes influenced by steric and electronic factors, result

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32

Hwang, Eunbin, and Hyo Sung Jung. "Metal–organic complex-based chemodynamic therapy agents for cancer therapy." Chemical Communications 56, no. 60 (2020): 8332–41. http://dx.doi.org/10.1039/d0cc03012k.

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33

Liyana Gunawardana, Vageesha W., and Gellert Mezei. "Amplification of impurity upon complex formation: how a 2% ligand impurity lowers the corresponding complex purity to 50%." New Journal of Chemistry 42, no. 21 (2018): 17195–202. http://dx.doi.org/10.1039/c8nj04176h.

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34

Manousi, Natalia, Dimitrios A. Giannakoudakis, Erwin Rosenberg, and George A. Zachariadis. "Extraction of Metal Ions with Metal–Organic Frameworks." Molecules 24, no. 24 (2019): 4605. http://dx.doi.org/10.3390/molecules24244605.

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Metal–organic frameworks (MOFs) are crystalline porous materials composed of metal ions or clusters coordinated with organic linkers. Due to their extraordinary properties such as high porosity with homogeneous and tunable in size pores/cages, as well as high thermal and chemical stability, MOFs have gained attention in diverse analytical applications. MOFs have been coupled with a wide variety of extraction techniques including solid-phase extraction (SPE), dispersive solid-phase extraction (d-SPE), and magnetic solid-phase extraction (MSPE) for the extraction and preconcentration of metal io

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35

Hu, Ding, Hongxia Xu, Bing Xiao, et al. "Albumin-Stabilized Metal–Organic Nanoparticles for Effective Delivery of Metal Complex Anticancer Drugs." ACS Applied Materials & Interfaces 10, no. 41 (2018): 34974–82. http://dx.doi.org/10.1021/acsami.8b12812.

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36

Abhervé, Alexandre, Thais Grancha, Jesús Ferrando-Soria, et al. "Spin-crossover complex encapsulation within a magnetic metal–organic framework." Chemical Communications 52, no. 46 (2016): 7360–63. http://dx.doi.org/10.1039/c6cc03667h.

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37

Morosanova, E. I. "Complex Formation in the Modified Xerogel Phase: Study and Application in Analysis." Координационная химия 49, no. 2 (2023): 73–88. http://dx.doi.org/10.31857/s0132344x22700098.

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The review summarizes the author’s results concerning the complex formation in the phase of modified xerogels synthesized by the sol–gel process for application as sensor materials. The results of studying the complex formation (pH ranges of reactions, light absorption maxima and compositions of complexes, and equilibrium constants) are presented and discussed for 87 systems of two types, that is, immobilized ligand (organic analytical reagent)–metal ion and immobilized metal ion–organic or inorganic compound. The approach proposed by the author to describe the complex formation in the modifie

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38

Yang, Ping, and Chengjia Tang. "Preparation of Indium Organic Frame Complex and Fluorescence Properties." Journal of Physics: Conference Series 2578, no. 1 (2023): 012023. http://dx.doi.org/10.1088/1742-6596/2578/1/012023.

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Abstract By varying the amounts of metal ions, ligands, and other reaction conditions, an organic complex with the central ion as indium metal was successfully synthesized through the solvothermal method and was characterized and analyzed. The fluorescence properties of the complexes were tested, which found that these compounds have good fluorescence properties. On this basis, we further applied the complex to fluorescence sensing and investigated its ion detection properties. It was found that the complex has high selectivity and sensitivity and can effectively detect Fe3+ ions.

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39

Li, Biao, Wan-Ting Zhang, Wen-Long Duan, Li-Li Zhang, and Jian Luan. "Fabrication of precursor-regulated derived materials from metal-organic complex and metal-organic salt for promoting photocatalytic properties." Inorganic Chemistry Communications 173 (March 2025): 113804. https://doi.org/10.1016/j.inoche.2024.113804.

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40

Ameta, Rakesh Kumar. "Metal organic ionic framework based on the ionic metal complex and organic moiety as counter ion: A review." Hybrid Advances 1 (December 2022): 100012. http://dx.doi.org/10.1016/j.hybadv.2022.100012.

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41

Bao, Xuefei, Xu Li, Chunfeng Jiang, Wei Xiao, and Guoliang Chen. "Recent advances in catalysts for the Henry reaction." Australian Journal of Chemistry 75, no. 10 (2022): 806–19. http://dx.doi.org/10.1071/ch22136.

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The Henry reaction, the coupling of a nitro alkane and a carbonyl group, is an important C–C bond-forming reaction giving nitro alkanols, which are useful, versatile intermediates in synthetic organic chemistry and for the pharmaceutical industry. Among the catalysts employed in the Henry reaction, transition metal complex catalysts play an important role. Transition metal complexes, including small molecules and nanoparticles, catalyze the asymmetric Henry reaction efficiently and in most of the cases give chiral nitro alkanol products in good yield and enantiomeric excess. This review summar

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42

Xiao-shun, ZHOU, XU Xiaomi, ZHONG Hui-ping, et al. "Adsorption of Metal-Organic Complex Molecule on Au(111) Surface." Acta Physico-Chimica Sinica 21, no. 09 (2005): 949–51. http://dx.doi.org/10.3866/pku.whxb20050901.

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43

Ali, Mohamed A., Xiaofeng Liu, Hong-Tao Sun, Jinjun Ren, and Jianrong Qiu. "Metal Inorganic–Organic Complex Glass and Fiber for Photonic Applications." Chemistry of Materials 34, no. 5 (2022): 2476–83. http://dx.doi.org/10.1021/acs.chemmater.2c00240.

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44

Noack, Johannes, Katharina Teinz, Christian Schaumberg, Carsten Fritz, Stephan Rüdiger, and Erhard Kemnitz. "Metal fluoride materials with complex pore structure and organic functionality." J. Mater. Chem. 21, no. 2 (2011): 334–38. http://dx.doi.org/10.1039/c0jm02204g.

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45

Nguyen, Trang T. M., Hung M. Le, Yoshiyuki Kawazoe, and Ha L. Nguyen. "Reticular control of interpenetration in a complex metal–organic framework." Materials Chemistry Frontiers 2, no. 11 (2018): 2063–69. http://dx.doi.org/10.1039/c8qm00368h.

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46

Barlow, S. M., and R. Raval. "Complex organic molecules at metal surfaces: bonding, organisation and chirality." Surface Science Reports 50, no. 6-8 (2003): 201–341. http://dx.doi.org/10.1016/s0167-5729(03)00015-3.

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47

Dzhemilev, U. M., and R. V. Kunakova. "Metal complex catalysis in the synthesis of organic sulfur compounds." Journal of Organometallic Chemistry 455, no. 1-2 (1993): 1–27. http://dx.doi.org/10.1016/0022-328x(93)80375-l.

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48

Castillo-Blas, Celia, Víctor A. de la Peña-O’Shea, Inés Puente-Orench, et al. "Addressed realization of multication complex arrangements in metal-organic frameworks." Science Advances 3, no. 7 (2017): e1700773. http://dx.doi.org/10.1126/sciadv.1700773.

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49

Kim, Yumi, Heedong Jang, Yongjae Suh, and Yul Roh. "Characterization of Magnetite-Organic Complex Nanoparticles by Metal-Reducing Bacteria." Journal of Nanoscience and Nanotechnology 11, no. 8 (2011): 7242–45. http://dx.doi.org/10.1166/jnn.2011.4868.

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50

Bose, Purnandhu, Toshiaki Takei, Xianglan Li, et al. "A Glutathione-Responsive Short Sequence of Metal-Organic Complex Array." ChemBioChem 19, no. 16 (2018): 1706–10. http://dx.doi.org/10.1002/cbic.201800252.

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