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Relevant bibliographies by topics / Metal-oxo complexes

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Academic literature on the topic 'Metal-oxo complexes'

Author: Grafiati

Published: 4 June 2021

Last updated: 11 February 2022

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Journal articles on the topic "Metal-oxo complexes"

1

Mathur, Pradeep, and Saurav Chatterjee. "OXO INCORPORATED METAL ACETYLIDE COMPLEXES." Comments on Inorganic Chemistry 26, no. 5-6 (September 2005): 255–86. http://dx.doi.org/10.1080/02603590500403933.

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Yang, Yi, Visalakshi Ramamoorthy, and Paul R. Sharp. "Late transition metal oxo and imido complexes. 11. Gold(I) oxo complexes." Inorganic Chemistry 32, no. 10 (May 1993): 1946–50. http://dx.doi.org/10.1021/ic00062a012.

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3

Yang, Lili, Fang Wang, Jiali Gao, and Yong Wang. "What factors tune the chemical equilibrium between metal-iodosylarene oxidants and high-valent metal-oxo ones?" Physical Chemistry Chemical Physics 21, no. 3 (2019): 1271–76. http://dx.doi.org/10.1039/c8cp06117c.

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Kobayashi, Yusuke. "Reduction with Hydrosilanes Catalyzed by Metal-oxo Complexes." Journal of Synthetic Organic Chemistry, Japan 68, no. 8 (2010): 866–67. http://dx.doi.org/10.5059/yukigoseikyokaishi.68.866.

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Garden, J. A., and S. D. Pike. "Hydrolysis of organometallic and metal–amide precursors: synthesis routes to oxo-bridged heterometallic complexes, metal-oxo clusters and metal oxide nanoparticles." Dalton Transactions 47, no. 11 (2018): 3638–62. http://dx.doi.org/10.1039/c8dt00017d.

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Khosravi, Iman, and Mohammad Yazdanbakhsh. "Preparation and characterization of novel oxo-centered basic p-chlorobenzoic bridging trinuclear complexes." Journal of the Serbian Chemical Society 75, no. 7 (2010): 929–34. http://dx.doi.org/10.2298/jsc090825066k.

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Three new oxo-centered trinuclear complexes, one of them a mixed-valence complex [Mn3O(C7H4O2Cl)6(Py)3]Py (1) and the others, mixed-metal complexes of [Fe2MnO(C7H4O2Cl)6(Py)3]NO3 (2) and [Fe2CoO(C7H4O2Cl)6(Py)3] (3) were synthesized by the direct reaction between metal nitrates and p-chlorobenzoic acid. These complexes were characterized by elemental analyses (CHN), atomic absorption spectroscopy and spectral (IR, electronic) studies. These are new type of oxo-bridged mixed-metal complexes in which the carboxylate ligand is pchlorobenzoic acid. The UV spectra of the complexes exhibited a strong band in the region 42,500 cm-1 which is related to the (? ? ?*) transitions of the pyridine ligand. The IR spectra of these compounds showed two strong stretching vibrations bands, indicating a bridging coordination mode of the carboxylic group of the ligand in the complexes.

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Fukuzumi, Shunichi. "Electron transfer and catalysis with high-valent metal-oxo complexes." Dalton Transactions 44, no. 15 (2015): 6696–705. http://dx.doi.org/10.1039/c5dt00204d.

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8

O’Halloran, Kevin P., Chongchao Zhao, Nicole S. Ando, Arthur J. Schultz, Thomas F. Koetzle, Paula M. B. Piccoli, Britt Hedman, et al. "Revisiting the Polyoxometalate-Based Late-Transition-Metal-Oxo Complexes: The “Oxo Wall” Stands." Inorganic Chemistry 51, no. 13 (June 13, 2012): 7025–31. http://dx.doi.org/10.1021/ic2008914.

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9

Sharp, Paul R., and John R. Flynn. "Late-transition-metal .mu.-oxo and .mu.-imido complexes. 1. .mu.-Oxo complexes of rhodium and iridium." Inorganic Chemistry 26, no. 19 (September 1987): 3231–34. http://dx.doi.org/10.1021/ic00266a036.

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10

Fukuzumi, Shunichi. "Electron-transfer properties of high-valent metal-oxo complexes." Coordination Chemistry Reviews 257, no. 9-10 (May 2013): 1564–75. http://dx.doi.org/10.1016/j.ccr.2012.07.021.

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Dissertations / Theses on the topic "Metal-oxo complexes"

1

Green, G. "Transition metal oxo-complexes as organic oxidants." Thesis, Imperial College London, 1985. http://hdl.handle.net/10044/1/37711.

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2

Shan, Hui. "New late transition metal oxo and hydrazido complexes /." free to MU campus, to others for purchase, 1998. http://wwwlib.umi.com/cr/mo/fullcit?p9924922.

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3

Cecchini, Chiara. "Late Transition Metal-Oxo complexes: Synthesis, and Biorelevant Reactivity." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2016. http://amslaurea.unibo.it/11249/.

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High-valent terminal metal-oxygen adducts are supposed to be potent oxidising intermediates in enzymatic catalyses. In contrast to those from groups 6-8, oxidants that contain late transition metals (Co, Ni, Cu) are poorly understood. Because of their high reactivity, only a few examples of these compounds have been observed. The aim of this project was to investigate the reactivity of high-valent Ni(III) complexes, containing a monodentate oxygen-donor ligands, in hydrogen atom abstraction (HAA) and oxygen atom transfer (OAT) reactions which are typical of biological high-valent metal-oxygen species. Particularly, the Ni(III) complexes were generated in situ, at low temperature, from the oxidation of the Ni(II) species.The nickel complexes studied during this work were supported by tridentate ligands, with a strong σ-donating ability and exceedingly resistant to several common degradation pathways. These complexes vary based on the monodentate group in the fourth coordination position site, which can be neutral or anionic. In particular, we prepared four different Ni(III) complexes [NiIII(pyN2Me2)(OCO2H)] (12), [NiIII(pyN2Me2)(ONO2)] (14), [NiIII(pyN2Me2)(OC(O)CH3)] (18) and [NiIII(pyN2Me2)(OC(O)H)] (25). They feature a bicarbonate (-OCO2H), nitrate (-ONO2), acetate (-OC(O)CH3) and formate (-OC(O)H) group, respectively.HAA and OAT reactions were performed by adding 2,6-di-tert-butylphenol (2,6-DTBP) at -40°C, and triphenylphosphine (PPh3) at -80°C, to the in situ generated Ni(III) complexes, respectively. These reactions were carried out by adding 7 to 500 equivalents of substrate, in order to ensure pseudo-first order conditions. Since, the reactivity of the Ni(III) complex featured by the bicarbonate group has been studied in a previous work, we only investigated that of the species bearing the nitrate, acetate and formate ligand. Finally we compared the value of the reaction rate of all the four species in the HAA and OAT reactions.

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4

Ibrahim, Masooma [Verfasser]. "Polynuclear Transition Metal-Oxo Complexes Stabilized by Heteropolytungstates / Masooma Ibrahim." Bremen : IRC-Library, Information Resource Center der Jacobs University Bremen, 2012. http://d-nb.info/1035217686/34.

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林曉楓 and Hiu-fung Lam. "Photophysical and photochemical properties of oxo and nitrido complexes of osmium(VI)." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2001. http://hub.hku.hk/bib/B42576490.

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Lam, Hiu-fung. "Photophysical and photochemical properties of oxo and nitrido complexes of osmium(VI)." Click to view the E-thesis via HKUTO, 2001. http://sunzi.lib.hku.hk/hkuto/record/B42576490.

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Middleditch, Michael. "Towards a catalytic carbonyl olefination reaction using metal oxo complexes and ketenes." Thesis, University of Nottingham, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.430565.

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8

Broughton, Simon. "Progress toward a catalytic alkenation using transition metal alkylidene and oxo complexes." Thesis, University of Nottingham, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.251978.

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9

鄧煒堂 and Wai-tong Tang. "Homogeneous oxidation of organic substrates by ruthenium, iron and manganese tertiary amine complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1989. http://hub.hku.hk/bib/B31231706.

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Tang, Wai-tong. "Homogeneous oxidation of organic substrates by ruthenium, iron and manganese tertiary amine complexes /." [Hong Kong : University of Hong Kong], 1989. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12355203.

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Books on the topic "Metal-oxo complexes"

1

Nugent, William A. Metal-ligandmultiple bonds: The chemistry of transition metal complexes containing oxo, nitrido, imido, alkylidene, or alkylidyne ligands. New York: Wiley, 1988.

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Nugent, William A. Metal-ligand multiple bonds: The chemistry of transition metal complexes containing oxo, nitrido, imido, alkylidene, or alkylidyne ligands. New York: Wiley, 1988.

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3

Cundari, Thomas R. Molecular orbital investigations of metal-oxo catalyzed oxidations. 1990.

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Book chapters on the topic "Metal-oxo complexes"

1

Meyer, Thomas J. "Metal Oxo Complexes and Oxygen Activation." In Oxygen Complexes and Oxygen Activation by Transition Metals, 33–47. Boston, MA: Springer US, 1988. http://dx.doi.org/10.1007/978-1-4613-0955-0_4.

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2

Winkler, Jay R., and Harry B. Gray. "Electronic Structures of Oxo-Metal Ions." In Molecular Electronic Structures of Transition Metal Complexes I, 17–28. Berlin, Heidelberg: Springer Berlin Heidelberg, 2011. http://dx.doi.org/10.1007/430_2011_55.

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3

Staemmler, V. "AB Initio Calculations of Electronic Surface States of Transition Metal Oxides and of the Superexchange Coupling in Oxo-bridged Transition Metal Complexes." In Metal-Ligand Interactions, 473–91. Dordrecht: Springer Netherlands, 1996. http://dx.doi.org/10.1007/978-94-009-0155-1_17.

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4

Wu, Pingsong, Gabriella Santoni, Cornelia Wikete, Falk Olbrich, and Dieter Rehder. "Biomimetic Vanadium Complexes and Oxo Transfer Catalysis." In Vanadium: The Versatile Metal, 61–69. Washington, DC: American Chemical Society, 2007. http://dx.doi.org/10.1021/bk-2007-0974.ch005.

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5

Jørgensen, Karl Anker. "On the Electronic Structure of Oxo-Metalloporphyrins and Mechanistic Aspects of Oxygen-Transfer Reactions." In Catalysis by Metal Complexes, 207–38. Dordrecht: Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-017-2247-6_7.

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6

Elias, Horst, Frank Stock, Waldemar Adam, Catherine Mitchell, Margareta Neuburger, and Markus Neuburger. "Salen-type Oxo Vanadium Complexes as Catalysts for Sulfoxidation and Epoxidation Reactions with Hydroperoxides." In Selective Reactions of Metal-Activated Molecules, 251–55. Berlin, Heidelberg: Springer Berlin Heidelberg, 1998. http://dx.doi.org/10.1007/978-3-662-00975-8_38.

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7

Bunker, Bruce C., and William H. Casey. "The Hydrolysis Products: Soluble Multi-cation Clusters." In The Aqueous Chemistry of Oxides. Oxford University Press, 2016. http://dx.doi.org/10.1093/oso/9780199384259.003.0010.

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The term hydrolysis describes the acid–base reactions that remove protons from hydrated metal cations. This word derives from two Greek words: hydro, meaning “water,” and lysis, meaning “to loosen.” Hydrolysis provides two mechanisms for converting one soluble metal complex into another. First, hydrolysis converts coordinated water molecules into coordinated hydroxo- and oxo-anions. For isolated monomers, the extent of hydrolysis depends on cation charge, cation coordination number, and pH (see Chapter 4). For example, as the cation charge increases, complexes can be generated that go from water rich to hydroxide rich to oxide rich, as exemplified by the sequence of species [Na(H2 O)6]+, [Mg(H2 O)5 (OH)]+, [Al(H2 O)4 (OH)2 ]+, [Si(OH)4 ]° , and finally [MnO4]−. Second, hydrolysis activates hydrated cations to participate in ligand-exchange reactions. When the entering ligand is not another isolated water molecule, but involves a hydroxo- or oxo-ligand that is bound to another dissolved metal complex, ligand- exchange reactions are called condensation reactions (or sometimes olation reactions) because they condense small oxide species into larger ones. In condensation reactions, hydroxo- or oxo-ligands form bridges between two or more cations. Species created via condensation range from dimers, trimers, and tetramers to larger species such as [Al13 O4 (OH)24 (H2 O)12]7+, enormous clusters such as the 2-nm-diameter Mo72 Fe30 Ox (OH)y species, and eventually to colloidal particles and extended oxide and hydroxide phases. The complete set of soluble metal-ion complexes containing only water molecules, hydroxide ions, and oxo-anions are called the hydrolysis products. The hydrolysis products represent the minimum basis set of complexes that must be taken into account to rationalize the aqueous chemistry of any oxide or hydroxide phase. The acid–base and ligand-exchange chemistry of monomeric hydrolysis products is described in Chapter 4. In this chapter, we emphasize the polymerization and depolymerization reactions that lead to the formation and disappearance of larger multi-cation clusters.

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8

McLain, Jennifer L., Jinbo Lee, and John T. Groves. "Biomimetic Oxygenations Related to Cytochrome P450: Metal-Oxo and Metal-Peroxo Intermediates." In Biomimetic Oxidations Catalyzed by Transition Metal Complexes, 91–169. PUBLISHED BY IMPERIAL COLLEGE PRESS AND DISTRIBUTED BY WORLD SCIENTIFIC PUBLISHING CO., 2000. http://dx.doi.org/10.1142/9781848160699_0003.

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9

Roodt, Andreas, Amira Abou-Hamdan, Hendrik P. Engelbrecht, and Andre E. Merbach. "Substitution Studies of Second- and Third-Row Transition Metal OXO Complexes." In Advances in Inorganic Chemistry, 59–126. Elsevier, 1999. http://dx.doi.org/10.1016/s0898-8838(08)60269-x.

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10

Jolivet, Jean-Pierre. "Condensation in Solution: Polycations and Polyanions." In Metal Oxide Nanostructures Chemistry. Oxford University Press, 2019. http://dx.doi.org/10.1093/oso/9780190928117.003.0006.

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Condensation of metal complexes in solution forms entities in which the cations are linked by hydroxo (HO−) or oxo (O2−) bridges. The reaction is initiated by the addition of a base to an aquocomplex: . . . 2[Cr(OH2)6]3++ 2HO- → [Cr2(OH)2(OH2)8]4+ + 2 H2O . . . or by the addition of an acid to an anionic complex: . . . 2 [CrO4]2- + 2H+ → [Cr2O7]2- + H2O . . . Thus, purely aquo- and purely oxocomplexes are stable in solution, and the condensation of cations is initiated by hydroxylation. With regard to electrically charged hydroxylated complexes, the reaction forms discrete and soluble entities—polycations and polyanions with a molecular complexity which depends on acidity conditions. This chapter presents a detailed study of their formation and structure. With regard to noncharged hydroxylated complexes, the condensation reaction is no longer limited and leads to the formation of a solid (a subject that is examined in the following chapters). The hydroxylation reaction is the key stage to initiate the condensation of cations in solution. It is thus important to precise the mechanism of the successive steps of the process, in order to understand why the behavior of a cation is closely related to its oxidation state, and why the reaction product may be a discrete molecular species or a solid. As a cation generally exhibits its maximum coordination number in the initial monomeric complex and in condensed species, the condensation reaction is a substitution that proceeds according to one of three basic mechanisms: dissociation, association, and interchange or direct displacement [1, 2]. Dissociative substitution is a two-step process involving the formation of a reduced-coordination intermediate: In the first step, a labile ligand, the leaving group, breaks its bond in the starting complex before a nucleophilic entering group completes, in the second step, the cation coordination (Fig. 3.1 a). Associative substitution is also a two-step process in which the intermediate temporarily has increased coordination. The bond with the nucleophilic entering group (first step) occurs prior to the release of the leaving group (second step) (Fig. 3.1 b).

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Reports on the topic "Metal-oxo complexes"

1

Sharp, P. R. Late transition metal oxo and imido complexes. Office of Scientific and Technical Information (OSTI), December 1992. http://dx.doi.org/10.2172/7017245.

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Sharp, P. R. Late transition metal. mu. -oxo and. mu. -imido complexes. Office of Scientific and Technical Information (OSTI), January 1990. http://dx.doi.org/10.2172/6332549.

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Sharp, P. Late transition metal. mu. -oxo and. mu. -imido complexes. Office of Scientific and Technical Information (OSTI), January 1990. http://dx.doi.org/10.2172/7003275.

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4

Sharp, P. R. Late transition metal oxo and imido complexes. Progress report, May 15 1992--May 14, 1992. Office of Scientific and Technical Information (OSTI), December 1992. http://dx.doi.org/10.2172/10102788.

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5

Sharp, P. R. Late transition metal. mu. -oxo and. mu. -imido complexes: Progress report, May 15, 1988--May 14, 1989. Office of Scientific and Technical Information (OSTI), January 1989. http://dx.doi.org/10.2172/6262903.

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