Academic literature on the topic 'Metal-support interactions'

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Journal articles on the topic "Metal-support interactions"

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Tauster, S. J. "Strong metal-support interactions." Accounts of Chemical Research 20, no. 11 (1987): 389–94. http://dx.doi.org/10.1021/ar00143a001.

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BURCH, R. "Metal sulfide-support interactions." Journal of Catalysis 97, no. 2 (1986): 385–89. http://dx.doi.org/10.1016/0021-9517(86)90010-2.

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Wang, Tairan, Jianyu Hu, Runhai Ouyang, et al. "Nature of metal-support interaction for metal catalysts on oxide supports." Science 386, no. 6724 (2024): 915–20. http://dx.doi.org/10.1126/science.adp6034.

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The metal-support interaction is one of the most important pillars in heterogeneous catalysis, but developing a fundamental theory has been challenging because of the intricate interfaces. Based on experimental ‎data, interpretable machine learning, theoretical derivation, and first-principles simulations, we established a ‎general theory of metal-oxide interactions grounded in ‎metal-metal and metal-oxygen interactions. The theory applies to metal nanoparticles and atoms on oxide supports and oxide films on metal supports. We found that for late-transition metal catalysts, metal-metal interac
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del Arco, M., and V. Rives. "Metal-support and metal oxide-support interactions in Cu/TiO2." Reaction Kinetics and Catalysis Letters 31, no. 1 (1986): 239–44. http://dx.doi.org/10.1007/bf02062539.

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Du, Xiaorui, Hailian Tang, and Botao Qiao. "Oxidative Strong Metal–Support Interactions." Catalysts 11, no. 8 (2021): 896. http://dx.doi.org/10.3390/catal11080896.

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The discoveries and development of the oxidative strong metal–support interaction (OMSI) phenomena in recent years not only promote new and deeper understanding of strong metal–support interaction (SMSI) but also open an alternative way to develop supported heterogeneous catalysts with better performance. In this review, the brief history as well as the definition of OMSI and its difference from classical SMSI are described. The identification of OMSI and the corresponding characterization methods are expounded. Furthermore, the application of OMSI in enhancing catalyst performance, and the in
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Guenin, M., P. N. Da Silva, and R. Frety. "Influence of chlorine towards metal-support and metal-sulphur support interactions." Applied Catalysis 27, no. 2 (1986): 313–23. http://dx.doi.org/10.1016/s0166-9834(00)82927-9.

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Douidah, A., P. Marécot, S. Szabo, and J. Barbier. "Evaluation of the metal–support interactions." Applied Catalysis A: General 225, no. 1-2 (2002): 21–31. http://dx.doi.org/10.1016/s0926-860x(01)00627-5.

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Nicole, J., D. Tsiplakides, C. Pliangos, X. E. Verykios, Ch Comninellis, and C. G. Vayenas. "Electrochemical Promotion and Metal–Support Interactions." Journal of Catalysis 204, no. 1 (2001): 23–34. http://dx.doi.org/10.1006/jcat.2001.3360.

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BADYAL, J. P. S. "ChemInform Abstract: Strong Metal-Support Interactions." ChemInform 25, no. 2 (2010): no. http://dx.doi.org/10.1002/chin.199402301.

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Li, Yangyang, Yunshang Zhang, Kun Qian, and Weixin Huang. "Metal–Support Interactions in Metal/Oxide Catalysts and Oxide–Metal Interactions in Oxide/Metal Inverse Catalysts." ACS Catalysis 12, no. 2 (2022): 1268–87. http://dx.doi.org/10.1021/acscatal.1c04854.

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Dissertations / Theses on the topic "Metal-support interactions"

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Anderson, J. B. F. "Strong metal-support interactions in titania-supported metal catalysts." Thesis, University of Reading, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.372539.

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Jungius, Hugo. "Model inverse electro-catalyst investigations of metal support interactions." Thesis, University of Southampton, 2017. https://eprints.soton.ac.uk/413849/.

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Gold supported titania nano-particle surfaces have been synthesised in order to understand supported electrochemical mechanisms through an inverse catalyst. The catalyst process investigated was the electro-oxidation of CO which is known to be promoted on Au nano-particles on a titania support. Synthesis proceeded via physical vapour deposition (PVD) of titanium onto a gold surface (both polycrystalline and 111 crystal), followed by alloying and oxidation to form discrete particles of titania on the surface, with variations in density of particles achieved by control of the initial titanium co
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Mogorosi, Ramoshibidu Patrick. "Metal-support interactions on Fe-based Fischer-Tropsch catalysts." Doctoral thesis, University of Cape Town, 2012. http://hdl.handle.net/11427/5438.

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Includes abstract.<br>Includes bibliographical references.<br>‘Metal support interactions’ is a term used to describe a phenomenon whereby the interaction between the active metal and the support material is strong enough to affect the catalytic activity and selectivity of the active phase. Primarily, there are two theories described in literature to explain the manner in which the development of these interactions alters catalytic behavior in supported catalysts. The first theory is ‘the contact affect’, which is generally associated with partially reducible supports such as TiO2 [Tauster et
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Venable, Margaret Hamm. "Syntheses, structures and support interactions of potential metal oxide catalyst precursors." Thesis, Georgia Institute of Technology, 1990. http://hdl.handle.net/1853/26940.

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DEMRI, HARIK OJAMILA, and J. P. HINDERMANN. "Etude des interactions metal-support et metal-promoteur sur des catalyseurs a base de rhodium." Université Louis Pasteur (Strasbourg) (1971-2008), 1992. http://www.theses.fr/1992STR13101.

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Le but du present travail est l'etude des interactions metal-support et metal-promoteur (th, zr, ce, y, na. . . ) dans la reaction co+h#2 sur des catalyseurs au rhodium. L'utilisation combinee de differentes methodes (adsorption, microscopie electronique a transmission (met)), spectroscopie infra-rouge a transformee de fourier (ir-tf), thermodesorption programmee (tpd) et thermoreaction programmee (tpsr) a permis de tirer les conclusions suivantes: la difference de taille des particules metalliques observee par les methodes d'adsorption et par la microscopie electronique montrent qu'une partie
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Macheli, Lebohang. "Inverse model systems to investigate metal-support interactions in Fischer-Tropsch catalysis." Doctoral thesis, Faculty of Engineering and the Built Environment, 2019. http://hdl.handle.net/11427/30921.

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This thesis aims to gain insight into the effects of metal-support interaction in Co/SiO2 catalysts using an inverse model system by modifying Co3O4 nanocrystallites with silanes (i.e. tetraethoxysilane, trimethyl chlorosilane, triphenyl ethoxysilane). It is postulated that the formation of Co-O-Si will alter the catalytic properties of the cobalt site to which silane is bonded and the adjacent ligand-free sites. The desire is to understand the effects of metal support interactions obtained after reduction of the model system on its performance in FischerTropsch synthesis, which was used as a
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Traversaz, Olivier. "Etude des interactions relatives metal-metal et metal-support mises en jeu lors de la preparation de catalyseurs bimetalliques supportes." Paris 6, 1992. http://www.theses.fr/1992PA066621.

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Ce travail a porte sur la preparation de catalyseurs bimetalliques supportes par depot selectif, en solution aqueuse, d'un deuxieme metal present sous forme de sel, sur un premier metal supporte. Les parametres (nature et composition du milieu d'impregnation, ph. . . ) regissant le depot, sur le support d'une part et sur le premier metal d'autre part, ont ete etudies. Les resultats nous ont permis de preparer des catalyseurs palladium-cuivre et platine-cuivre deposes sur des billes d'alumine, en operant en deux etapes : - penetration du cuivre au coeur du grain au moyen d'un agent complexant (
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Dyasi, Nontsikelelo. "Model systems for the investigation of metal-support interactions in cobalt based Fischer-Tropsch." Master's thesis, Faculty of Engineering and the Built Environment, 2021. http://hdl.handle.net/11427/33639.

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The catalyst used plays a pivotal role in the optimization of the Fischer Tropsch (FT) synthesis. Cobalt (Co)-based catalysts have been widely used in low temperature Fischer Tropsch synthesis for the production of longer chain olefins [1]. The interaction between the support and the active metal, Co, has been observed to affect the activity and selectivity of the FT synthesis [2]. In order to investigate metal support interactions independent of other support effects, the inverse method was used in the synthesis of model catalysts [3]. The inverse method mimics the interface bond between the
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Neumann, Sarah [Verfasser], Sebastian [Akademischer Betreuer] Kunz, Sebastian [Gutachter] Kunz, and Marcus [Gutachter] Bäumer. "Heterogeneous Catalysis with supported Nanoparticles : Particle Size Effects and Metal-Support Interactions / Sarah Neumann ; Gutachter: Sebastian Kunz, Marcus Bäumer ; Betreuer: Sebastian Kunz." Bremen : Staats- und Universitätsbibliothek Bremen, 2019. http://d-nb.info/1203298927/34.

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Spence, Stephanie L. "Tuning the Morphology and Electronic Properties of Single-Crystal LiNi0.5Mn1.5O4-δ". Thesis, Virginia Tech, 2020. http://hdl.handle.net/10919/100790.

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The commercialization of lithium-ion batteries has played a pivotal role in the development of consumer electronics and electric vehicles. In recent years, much research has focused on the development and modification of the active materials of electrodes to obtain higher energies for a broader range of applications. High voltage spinel materials including LiNi<sub>0.5</sub>Mn<sub>1.5</sub>O<sub>4-δ</sub> (LNMO) have been considered as promising cathode materials to address the increasing demands for improved battery performance due to their high operating potential, high energy density, and s
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Books on the topic "Metal-support interactions"

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Baker, R. T. K., S. J. Tauster, and J. A. Dumesic, eds. Strong Metal-Support Interactions. American Chemical Society, 1986. http://dx.doi.org/10.1021/bk-1986-0298.

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Baker, R. T. K., 1938-, Tauster S. J. 1935-, Dumesic J. A. 1949-, et al., eds. Strong metal-support interactions. The Society, 1986.

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A, Stevenson Scott, ed. Metal-support interactions in catalysis, sintering, and redispersion. Van Nostrand Reinhold Co., 1987.

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(Firm), Knovel, ed. Electrochemical activation of catalysis: Promotion, electrochemical promotion, and metal-support interactions. Kluwer Academic/Plenum Publishers, 2001.

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G, Vayenas C., ed. Electrochemical activation of catalysis: Promotion, electrochemical promotion, and metal-support interactions. Kluwer Academic/Plenum Publishers, 2001.

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Vayenas, Costas G., Symeon Bebelis, and Costas Pliangos. Electrochemical Activation of Catalysis: Promotion Electrochemical Promotion and Metal-Support Interactions. Kap/Plenum (E), 2002.

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Vayenas, Costas G., Symeon Bebelis, Costas Pliangos, Susanne Brosda, and Demetrios Tsiplakides. Electrochemical Activation of Catalysis: Promotion, Electrochemical Promotion, and Metal-Support Interactions. Springer, 2002.

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Vayenas, Costas G. Electrochemical Activation of Catalysis: "Promotion, Electrochemical Promotion, And Metal-Support Interactions". Springer, 2013.

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Cheng, Y. Frank, and Richard Norsworthy. Pipeline Coatings. NACE International, The Worldwide Corrosion Authority15835 Park Ten Place, Houston, TX 77084, 2017. https://doi.org/10.5006/37616.

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Pipeline Coatings begins with a review of coating fundamentals, including the evolution of coating technology and the principles for coating formulation. Guidelines for coating design, selection, and application are presented. The structure of a coating system and the high-performance coating’s essential properties and characteristics are covered in detail. Some standard testing methods for determining and evaluating coating properties are included. Coatings used in the oil/gas pipeline industry are then covered. Generally, pipeline coatings are divided into two categories (plant-applied and f
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Book chapters on the topic "Metal-support interactions"

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Tauster, S. J. "Strong Metal-Support Interactions." In ACS Symposium Series. American Chemical Society, 1986. http://dx.doi.org/10.1021/bk-1986-0298.ch001.

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Coq, B. "Metal-Support Interaction In Catalysis." In Metal-Ligand Interactions in Chemistry, Physics and Biology. Springer Netherlands, 2000. http://dx.doi.org/10.1007/978-94-011-4245-8_3.

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Ko, E. I., J. E. Lester, and G. Marcelin. "Metal-Support Interactions in Ni Catalysts." In ACS Symposium Series. American Chemical Society, 1986. http://dx.doi.org/10.1021/bk-1986-0298.ch013.

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Haberlandt, Helmut. "Theoretical Investigation of Metal-Support Interactions and Their Influence on Chemisorption." In Theoretical Aspects of Heterogeneous Catalysis. Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-010-9882-3_8.

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Panagiotopoulou, Paraskevi, and Xenophon E. Verykios. "Metal–support interactions of Ru-based catalysts under conditions of CO and CO2 hydrogenation." In Catalysis. Royal Society of Chemistry, 2020. http://dx.doi.org/10.1039/9781788019477-00001.

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Miura, H., S. S. Feng, R. Saymeh, and R. D. Gonzalez. "The Effect of Support-Metal Precursor Interactions on the Surface Composition of Supported Bimetallic Clusters." In Catalyst Characterization Science. American Chemical Society, 1985. http://dx.doi.org/10.1021/bk-1985-0288.ch025.

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Deo, Goutam, and Israel E. Wachs. "Surface Oxide—Support Interactions in the Molecular Design of Supported Metal Oxide Selective Oxidation Catalysts." In ACS Symposium Series. American Chemical Society, 1993. http://dx.doi.org/10.1021/bk-1993-0523.ch003.

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Horsley, J. A., and F. W. Lytle. "Information on Metal-Support Interactions from Near Edge X-ray Absorption Spectroscopy and Multiple Scattering Calculations." In ACS Symposium Series. American Chemical Society, 1986. http://dx.doi.org/10.1021/bk-1986-0298.ch002.

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Spencer, M. S. "Equilibrium and Kinetic Aspects of Strong Metal-Support Interactions in Pt-TiO2and Cobalt-Doped Cu-ZnO-Al2O3Catalysts." In ACS Symposium Series. American Chemical Society, 1986. http://dx.doi.org/10.1021/bk-1986-0298.ch009.

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Idzik, Christian, Daniel Hilger, Norbert Hosters, et al. "Decision Support for the Optimization of Continuous Processesusing Digital Shadows." In Internet of Production. Springer International Publishing, 2023. http://dx.doi.org/10.1007/978-3-031-44497-5_12.

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AbstractDecision support systems can provide real-time process information and correlations, which in turn assists process experts in making decisions and thus further increase productivity. This also applies to well-established and already highly automated processes in continuous production employed in various industrial sectors. Continuous production refers to processes in which the produced material, either fluid or solid form, is continuously in motion and processed. As a result, the process can usually not be stopped. It is only possible to influence the running process. However, the high
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Conference papers on the topic "Metal-support interactions"

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Natesan, K. "Role of FBC Deposits in the Corrosion of Heat Exchanger Materials." In CORROSION 1986. NACE International, 1986. https://doi.org/10.5006/c1986-86093.

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Abstract Metallic materials selected for the construction of in-bed heat exchangers and tube support structures in fluidized-bed combustion (FBC) systems must withstand the corrosive conditions prevalent in these systems. Oxidation/sulfidation interactions leading to accelerated metal wastage of in-bed materials can occur owing to the presence of sorbent deposits on the metal surfaces and/or the low oxygen partial pressures in the exposure environment. The present paper discusses the possible mechanisms of sulfidation of iron-base ferritic and austenitic alloys and the roles of key parameters
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Kumar, Dharmendr, Venkata Muralidhar K., Vinay Jain, Beena Rai, and Jeremy Moloney. "Mechanistic Insights into 2-Mercaptoethanol and Thioglycolic Acid Corrosion Inhibitor Chemistries for Mild Steel: DFT and Experimental Investigations." In CONFERENCE 2025. AMPP, 2025. https://doi.org/10.5006/c2025-00518.

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Abstract Sulfur-containing corrosion inhibitors (CIs), such as 2-mercaptoethanol (2ME), thioglycolic acid (TGA), and sodium thiosulfate (STS), are extensively used in oilfield formulations, often in conjunction with other chemistries like quaternary ammonium compounds, imidazolines, and aromatic amines, to mitigate steel corrosion in carbon dioxide environments. These sulfur-based CIs are favored for their effectiveness, low cost, and synergy with other chemistries. To optimize these formulations—by improving performance, reducing costs, and enhancing sustainability—there is a need to better u
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Lin, J. Y., F. C. Chiang, H. Chang, and C. C. Su. "The Field Measurement of Carburization and Oxidation of Ethylene Furnace Tubes by Multi-Technique Method." In CORROSION 1994. NACE International, 1994. https://doi.org/10.5006/c1994-94184.

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Abstract A multi-coil electromagnetic induction type detector had been applied for in-field measurement of the depth of the carburized layer in ethylene furnace tubes. Laboratory tests showed that under conditions where the entire tube wall may be carburized, the technique can give erroneous indications. To identify the complex interaction of the inner and the external magnetic layers, a variable frequency metal sorting instrument was included in the field inspection procedures. Furthermore, dimension and thickness measurements, visual inspection and surface replica techneques also support thi
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Sharma, Ankit, Samit K. Ray, and K. V. Adarsh. "Breaking of Phonon Bottleneck In CsPbI3 Nanocrystals Due To Efficient Auger Recombination." In JSAP-Optica Joint Symposia. Optica Publishing Group, 2024. https://doi.org/10.1364/jsapo.2024.17a_a31_5.

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Inorganics lead halide perovskite (LHP) have been became appropriate system for demonstrating light-matter interaction due to their flexible bandgap tunability, defect tolerance and high photoluminescence quantum yield nature. Although, LHPs have many hallmark properties which can support highly efficient photovoltaic devices, but they lost lot of energy in carriers-phonon scattering which slow down the recombination process and decrease the efficiency. Faster thermalization time of hot carriers support electron-hole recombination at band-edge which can be exploited in optoelectronic devices e
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Janbi, Ayman S., and Husain M. Muslim. "Pipeline Lamination Assessment." In MECC 2023. AMPP, 2023. https://doi.org/10.5006/mecc2023-20025.

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Abstract This assessment addresses the reported lamination on NGL service pipeline. The 30/32” pipeline was built in 1974 transporting C3+ NGL with a total length of 13.82 kilometers. According to API 5791 “Laminations are a plane of non-fusion in the interior of a steel plate that results from the steel manufacturing process and exist on one or more planes in the equipment”. The pipeline was built with non-HIC resistant material which support the existence of the lamination in the pipeline. Recent conducted In-Line-Inspection (ILI) run reported high metal loss under identified lamination. Int
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Haxhimali, Tomorr, Marco Echeverria, Fady Najjar, et al. "Hydrodynamic and atomistic studies in support of high power laser experiments for metal ejecta recollection and interactions." In SHOCK COMPRESSION OF CONDENSED MATTER - 2019: Proceedings of the Conference of the American Physical Society Topical Group on Shock Compression of Condensed Matter. AIP Publishing, 2020. http://dx.doi.org/10.1063/12.0000824.

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"Syngas production via combined dry and steam reforming methane over Ni-based catalyst: A review." In Sustainable Processes and Clean Energy Transition. Materials Research Forum LLC, 2023. http://dx.doi.org/10.21741/9781644902516-3.

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Abstract. Global energy consumption has eventually increased as a result of the growing world population. Various problems arise as a result. The accumulation of greenhouse gases (GHGs), which led to a shift in the world's climate, is the most problematic. Combined dry and steam reforming of methane (CDRSM) is a highly advantageous method since it uses two of the most significant GHGs, CH4 and CO2, to produce syngas, an intermediate product to produce valuable fuels. Ni-based catalysts are inexpensive, compared to many noble metals, and exhibit good reaction activity. However, deactivation, co
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Dahlstro¨m, Stefan, S. Jack Hu, and Rikard So¨derberg. "Identifying Variable Effects on the Dimensional Quality of Compliant Assembly, Using Computer Experiments." In ASME 2002 International Design Engineering Technical Conferences and Computers and Information in Engineering Conference. ASMEDC, 2002. http://dx.doi.org/10.1115/detc2002/dac-34035.

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Compliant sheet metal assemblies are often used as support structures in automobiles, airplanes and appliances. These structures not only provide a metrology frame for other modules to be assembled, but also give the product its aesthetic form. For this reason, the dimension quality of the assemblies is a very important factor to control, in order to make sure that the product will function as planned and continuously keep the product cost low. The assembly is influenced by variations in the component parts and the assembly processes. Tolerance analysis, as conducted in most industries today,
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Klie, Robert F., Kai Sun, Mark M. Disko, J. Liu, and N. D. Browning. "Direct observation of metal support interaction in nano-scale systems." In International Symposium on Optical Science and Technology, edited by Jin Z. Zhang and Zhong L. Wang. SPIE, 2002. http://dx.doi.org/10.1117/12.450936.

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Cavallaro, Paul V., Christopher J. Hart, and Ali M. Sadegh. "Mechanics of Air-Inflated Drop-Stitch Fabric Panels Subject to Bending Loads." In ASME 2013 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/imece2013-63839.

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Rapid deployment and mobility of lightweight structures, namely inflatable structures, are of growing significance to the military and space communities. When deployment and rigidity are driven by pressure (for example, air or fluid) and materials such as textiles, elastomers and flexible composites are used, significant load carrying capacity per unit weight (or per-unit stowed volume) can be uniquely achieved. Specifically, the pressurized air directly provides the stiffness to support structural loads, thus eliminating the requirement for heavy metal stiffeners that are used in conventional
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Reports on the topic "Metal-support interactions"

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James M. Howe and Robert J. Davis. Understanding and Controlling Metal-Support Interactions in Nanocrystalline Bimetallic Catalysts. Office of Scientific and Technical Information (OSTI), 2005. http://dx.doi.org/10.2172/885190.

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Vannice, M. A. Enhancement of activity and selectivity by Metal-Support Interactions (MSI). Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/7281568.

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Vannice, M. A. The Influence of MSI (Metal-Support Interactions) and the Solvent in Liquid-Phase Reactions. Office of Scientific and Technical Information (OSTI), 2003. http://dx.doi.org/10.2172/824023.

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Gonzalez, R. D. The formation of supported bimetallic clusters: The effect of support-metal precursor interactions. Final report. Office of Scientific and Technical Information (OSTI), 1994. http://dx.doi.org/10.2172/10163134.

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Boszormenyi, Istvan. Model heterogeneous acid catalysts and metal-support interactions: A combined surface science and catalysis study. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/10115869.

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Boszormenyi, I. Model heterogeneous acid catalysts and metal-support interactions: A combined surface science and catalysis study. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/6827194.

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Henrich, V. Model catalyst studies of active sites and metal support interactions on vanadia and vanadia-supported catalysts. Office of Scientific and Technical Information (OSTI), 1989. http://dx.doi.org/10.2172/5484103.

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Vannice, M. A. Enhancement of activity and selectivity by Metal-Support Interactions (MSI). Progress report, September 1, 1988--June 30, 1991. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/10159594.

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Tiku, Sanjay, Amin Eshraghi, Aaron Dinovitzer, and Arnav Rana. PR-214-114500-R01 Fatigue Life Assessment of Dents with and without Interacting Features. Pipeline Research Council International, Inc. (PRCI), 2018. http://dx.doi.org/10.55274/r0011540.

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The long-term integrity of a dented pipeline segment is a complex function of a variety of parameters, including pipe geometry, indenter shape, dent depth, indenter support, pressure history at and following indentation. In order to estimate the safe remaining operational life of a dented pipeline, all of these factors must be accounted for in the assessment. The current project provides pipeline operators with a methodology for assessing and managing dent fatigue, thus making it possible to prioritize response and remedial action(s) in an informed manner. The methodology allows the users to c
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Tiku, Sanjay, Aaron Dinovitzer, Vlad Semiga, and Binoy John. PR-214-073510-Z01 FS Fatigue Testing Plain Dents+Dents Interacting with Welds and Metal Loss with Data. Pipeline Research Council International, Inc. (PRCI), 2018. http://dx.doi.org/10.55274/r0011514.

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Dents in buried pipelines occur due to a number of potential causes; the pipe resting on rock, third party machinery strike, rock strikes during backfilling, amongst others. The long-term integrity of a dented pipeline segment is a complex function of a variety of parameters, including pipe geom-etry, indenter shape, dent depth, indenter support, pressure history at and following indentation. In order to estimate the safe remaining operational life of a dented pipeline, all of these factors must be accounted for in the analysis. In order to characterize the severity of a dent on the integrity
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