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Relevant bibliographies by topics / Metal thiolate chemistry

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Academic literature on the topic 'Metal thiolate chemistry'

Author: Grafiati

Published: 4 June 2021

Last updated: 7 February 2022

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Journal articles on the topic "Metal thiolate chemistry"

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Wark, Teresa A., та Douglas W. Stephan. "Rhodium induced titanium–sulfur bond cleavage: crystal and molecular structure of ((COD)Rh(μ-SMe))2". Canadian Journal of Chemistry 68, № 4 (1990): 565–69. http://dx.doi.org/10.1139/v90-086.

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Reactions of Ti(III) and Ti(IV) thiolates with Rh complexes have been investigated. In the reaction of Cp2Ti(SMe)2 and [(COD)2Rh]BF4 or [(COD)Rh(sol)2]PF6, thiolate abstraction yields ((COD)Rh(μ-SMe))2, 1. Reaction of (Cp2Ti(μ-SMe))2 with ((COD)Rh(μ-Cl))2 results in ligand exchange affording (Cp2Ti(μ-Cl))2 and 1. The complex 1 crystallizes in the monoclinic space group P21/n, with a = 8.551(2) Å, b = 10.058(3) Å, c = 22.187(4) Å, β = 92.54(1)°, Z = 4, and V = 1906(1) Å3. The structural data show a relatively short approach between the Rh centres (2.948 Å) and between the bridging sulfur atoms

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Dance, IanG. "Metal thiolate cluster chemistry." Journal of Inorganic Biochemistry 36, no. 3-4 (1989): 184. http://dx.doi.org/10.1016/0162-0134(89)84115-7.

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NAVID, ALI, EDUARD M. TYAPOCHKIN, CHARLES J. ARCHER, and EVGUENII I. KOZLIAK. "UV-vis and Binding Studies of Cobalt Tetrasulfophthalocyanine–Thiolate Complexes as Intermediates of the Merox Process." Journal of Porphyrins and Phthalocyanines 03, no. 07 (1999): 654–66. http://dx.doi.org/10.1002/(sici)1099-1409(199908/10)3:6/7<654::aid-jpp189>3.0.co;2-l.

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Intermediates of the cobalt tetrasulfophthalocyanine ( CoTSPc )-catalyzed thiol autoxidation were studied by UV-vis spectroscopy. All thiolates react with CoTSPc resulting in the formation of 1:1 complexes. Three major factors control both the stability and aggregation of the complexes: thiolate basicity, metal-to-ligand charge transfer (MLCT) and π stacking. Basic thiolates partially reduce C oII TSPc , whereas CoTSPc complexes with low-basicity aliphatic thiolates ( p K a < 4) do not exhibit Co (II) reduction, based on the absence of the characteristic Co (I) charge transfer band at 450 n

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TYAPOCHKIN, EDUARD M., and EVGUENII I. KOZLIAK. "Interactions of cobalt tetrasulfophthalocyanine with thiolate anions in dimethylformamide." Journal of Porphyrins and Phthalocyanines 05, no. 04 (2001): 405–14. http://dx.doi.org/10.1002/jpp.341.

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Thiolate complexes of cobalt tetrasulfophthalocyanine ( CoTSPc ), possible intermediates of the industrial removal of mercaptans from oil fractions (Merox process), were studied in dimethylformamide, dimethylsulfoxide, and other polar aprotic solvents by UV-vis, 1 H NMR, and ESR spectroscopy. All thiolates react with Co II TSPc under anaerobic conditions with 1:1 stoichiometry. All tested aliphatic thiolates, regardless of their basicity, reduce Co II TSPc to form Co I TSPc derivatives. Low-basicity thiolates also form unstable non-reduced ( RS -) Co II TSPc complexes as dead-end products. Ind

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Weigand, Wolfgang. "Metallkomplexe mit funktionalisierten Schwefelliganden, I / Metal Complexes of Functionalized Sulphur Containing Ligands, I." Zeitschrift für Naturforschung B 46, no. 10 (1991): 1333–37. http://dx.doi.org/10.1515/znb-1991-1010.

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Complexes of the types cis-L2PtCl2 (L = PPh3, 1/2 dppe) and cpRu(PPh3)2Cl react with 1-alkyne-1-thiolates to give the products trans-(Ph3P)2Pt(S–C≡C–Ph)2 (5), dppePt(S–C≡C–Ph)2 (6) and CpRu(PPh3)2(S–C≡C–Ph) (7), respectively. CpRu(PPh3)(CO)(S–C≡C–Ph) (8) is formed by reaction of 7 in an atmosphere of CO. The 2-propene-1-thiolato complexes dppePt(S–CH2–CH = CH2)2 (9), CpFe(CO)2(S–CH2–CH=CH2) (12) and CpFe(PPh3)(CO)(S–CH2–CH=CH2) (13) are obtained from dppePtCl2, CpFe(CO)2I, CpFe(PPh3)(CO)I and lithium or sodium 2-propene-1-thiolate. The complexes are characterized by IR and 1H,13C and 31P NMR s

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Solomon, Edward I., Serge I. Gorelsky, and Abhishek Dey. "Metal–thiolate bonds in bioinorganic chemistry." Journal of Computational Chemistry 27, no. 12 (2006): 1415–28. http://dx.doi.org/10.1002/jcc.20451.

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Dance, Ian G. "The structural chemistry of metal thiolate complexes." Polyhedron 5, no. 5 (1986): 1037–104. http://dx.doi.org/10.1016/s0277-5387(00)84307-7.

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8

Stillman, Martin J., Anthony Presta, Ziqi Gui, and De-Tong Jiang. "Spectroscopic Studies of Copper, Silver and Gold-Metallothioneins." Metal-Based Drugs 1, no. 5-6 (1994): 375–94. http://dx.doi.org/10.1155/mbd.1994.375.

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Metallothionein is a ubiquitous protein with a wide range of proposed physiological roles, including the transport, storage and detoxification of essential and nonessential trace metals. The amino acid sequence of isoform 2a of rabbit liver metallothionein, the isoform used in our spectroscopic studies, includes 20 cysteinyl groups out of 62 amino acids. Metallothioneins in general represent an impressive chelating agent for a wide range of metals. Structural studies carried out by a number of research groups (using H1 and Cd113 NMR, X-ray crystallography, more recently EXAFS, as well as optic

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Seela, Jeffrey L., Kirsten Folting, Ru Ji Wang, et al. "Manganese(III) thiolate chemistry: new structural types, including the first mixed-valence metal thiolate." Inorganic Chemistry 24, no. 26 (1985): 4454–56. http://dx.doi.org/10.1021/ic00220a005.

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Calvo, Jenifer S., Victor M. Lopez, and Gabriele Meloni. "Non-coordinative metal selectivity bias in human metallothioneins metal–thiolate clusters." Metallomics 10, no. 12 (2018): 1777–91. http://dx.doi.org/10.1039/c8mt00264a.

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Mammalian metallothioneins MT-2 and MT-3 contain two metal–thiolate clusters through cysteine coordination of d<sup>10</sup> metals, Cu(i) and Zn(ii), and isoform-specific non-coordinating residues control their respective zinc– and copper–thionein character.

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Dissertations / Theses on the topic "Metal thiolate chemistry"

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Abrahams, I. L. "Investigation of metallothioneins and related metal thiolate clusters." Thesis, University of Manchester, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.374556.

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Lu, Canzhong. "Novel transition metal complexes of sterically hindered silyl thiolate ligands." Thesis, University of Essex, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.307857.

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Tennyson, Andrew Gregory. "The detection of nitric oxide and its reactivity with transition metal thiolate complexes." Thesis, Massachusetts Institute of Technology, 2008. http://hdl.handle.net/1721.1/43767.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemistry, 2008.<br>Vita.<br>Includes bibliographical references.<br>Nitric oxide (NO) is a molecule that is essential for life and regulates both beneficial and harmful processes. Because this gaseous radical influences many aspects of health and disease, we wish to explore the relationship between NO and physiology/pathophysiology. To this end, we seek to create tools for the fluorescent imaging of NO in vivo. We have adapted an existing small molecule-based sensor for more biologically relevant applications by including it wit

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Law, Yuen-chi. "Platinum-ligand PI bonding interactions the ligand-to-ligand charge transfer transitions and supramolecular chemistry of platinum(II) acetylide and thiolate complexes /." Click to view the E-thesis via HKUTO, 2006. http://sunzi.lib.hku.hk/hkuto/record/B38746827.

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Law, Yuen-chi, and 羅婉芝. "Platinum-ligand PI bonding interactions: the ligand-to-ligand charge transfer transitions and supramolecularchemistry of platinum(II) acetylide and thiolate complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2006. http://hub.hku.hk/bib/B38746827.

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Hall, Nikita. "Synthèse, caractérisation et étude de la réactivité de complexes métalliques bio-inspirés à liaison Métal-Thiol." Thesis, Grenoble, 2013. http://www.theses.fr/2013GRENV073/document.

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Cette thèse présente la synthèse et la caractérisation de complexes moléculaires bio-inspirés àliaison métal-thiol avec l'objectif de modéliser le site actif de certaines métalloenzymes. Enparticulier, notre but était d'améliorer notre compréhension sur le rôle que joue cette liaisonmétal-thiol dans les métalloenzymes, notamment au niveau de ses propriétés structurales etélectroniques ainsi que sur la réactivité des sites actifs associés. Le thiol lié à un métal peut êtresujet à deux types de réaction dans métalloenzymes : les réaction de S- alkylation ou de Soxygénation.Il a été montré que la

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Zheng, Yifan. "Plantimum group metals and iron complexes of functionalised aromatic thiolates." Thesis, University of Essex, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.333549.

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Wilker, Jonathan J. (Jonathan James). "Alkyl transfer to metal thiolates and models for the repair of DNA aklylation damage." Thesis, Massachusetts Institute of Technology, 1997. http://hdl.handle.net/1721.1/42600.

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Britton, A. M. "Complexes of heterocyclic thiones and thiolates with nickel (II) and the platinum metals." Thesis, University of Newcastle Upon Tyne, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.383557.

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Savelieff, Masha Georges. "Metal thiolate and metal sulfide clusters in proteins /." 2008. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3337915.

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Thesis (Ph. D.)--University of Illinois at Urbana-Champaign, 2008.<br>Source: Dissertation Abstracts International, Volume: 69-11, Section: B, page: 6795. Adviser: Yi Lu. Includes bibliographical references. Available on microfilm from Pro Quest Information and Learning.

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Book chapters on the topic "Metal thiolate chemistry"

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Wright, Jeffrey G., Michael J. Natan, Frederick M. MacDonnel, Diana M. Ralston, and Thomas V. O'Halloran. "Mercury(II)-Thiolate Chemistry and the Mechanism of the Heavy Metal Biosensor MerR." In Progress in Inorganic Chemistry. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470166390.ch6.

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Kumar, Bharat, Yoshiki Niihori, Wataru Kurashige, and Yuichi Negishi. "Controlled Thiolate-Protected Gold and Alloy Clusters." In Descriptive Inorganic Chemistry Researches of Metal Compounds. InTech, 2017. http://dx.doi.org/10.5772/67833.

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3

Tonzetich, Zachary J. "Biomimetic Metal Thiolates." In Comprehensive Coordination Chemistry III. Elsevier, 2021. http://dx.doi.org/10.1016/b978-0-08-102688-5.00071-4.

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