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Relevant bibliographies by topics / Metal-to-ligand charge transfer

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Academic literature on the topic 'Metal-to-ligand charge transfer'

Author: Grafiati

Published: 4 June 2021

Last updated: 27 July 2025

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Journal articles on the topic "Metal-to-ligand charge transfer"

1

Ding, Yong, Jian-xiu Guo, Xiang-si Wang, Sha-sha Liu, and Feng-cai Ma. "Visualization of Metal-to-Ligand and Ligand-to-Ligand Charge Transfer in Metal-Ligand Complexes." Chinese Journal of Chemical Physics 22, no. 3 (2009): 269–74. http://dx.doi.org/10.1088/1674-0068/22/03/269-274.

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K., KALYANASUNDARAM. "Properties and Reactions of Charge Transfer Excited States in Mono/Polynuclear Polypyridyl Complexes of Ru, Os and Re." Journal of Indian Chemical Society Vol. 70, Apr-May 1993 (1993): 433–53. https://doi.org/10.5281/zenodo.5939921.

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Institute of Physical Chemistry, Swiss Federal Institute of Technology, CH-1015 Lausanne, Switzerland <em>Manuscript received 23 February 1993</em> Properties and reactions of different types of charge transfer excited states I metal-to-ligand (or MLCT), ligand-to-metal (or LMCT) and metal-to-metal (MMCT)] of mono- and polynuclear polypyridyl complexes of Ru, Os and Re are reviewed, with examples taken mostly from the work done in the authors' laboratory in the last decade. Properties and dynamical aspects of the CT transitions are deduced from ground state absorption, emission, trans

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Vogler, Arnd, and Horst Kunkely. "Outer-sphere ligand to ligand charge transfer of metal complexes." Journal of the Chemical Society, Chemical Communications, no. 21 (1986): 1616. http://dx.doi.org/10.1039/c39860001616.

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Han, Xue, Li-Zhu Wu, Gang Si, et al. "Switching between Ligand-to-Ligand Charge-Transfer, Intraligand Charge-Transfer, and Metal-to-Ligand Charge-Transfer Excited States in Platinum(II) Terpyridyl Acetylide Complexes Induced by pH Change and Metal Ions." Chemistry - A European Journal 13, no. 4 (2007): 1231–39. http://dx.doi.org/10.1002/chem.200600769.

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Li, Chenfei, Xin Ying Kong, Zheng Hao Tan, Crystal Ting Yang, and Han Sen Soo. "Emergence of ligand-to-metal charge transfer in homogeneous photocatalysis and photosensitization." Chemical Physics Reviews 3, no. 2 (2022): 021303. http://dx.doi.org/10.1063/5.0086718.

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Light energy can be harnessed by photosensitizers or photocatalysts so that some chemical reactions can be carried out under milder conditions compared to the traditional heat-driven processes. To facilitate the photo-driven reactions, a large variety of chromophores that are operated via charge transfer excitations have been reported because of their typically longer excited-state lifetimes, which are the key to the downstream photochemical processes. Although both metal-to-ligand charge transfers and ligand-to-metal charge transfers are well-established light absorption pathways; the former

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Ji, Zhiqiang, Yunjing Li, and Wenfang Sun. "Acid/base sensitive platinum terpyridyl complex: Switching between metal-to-ligand charge transfer (MLCT), ligand-to-ligand charge transfer (LLCT), and intraligand charge transfer (ILCT) states." Journal of Organometallic Chemistry 694, no. 26 (2009): 4140–45. http://dx.doi.org/10.1016/j.jorganchem.2009.09.015.

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Hush, N. "Solvent effects on metal to ligand charge transfer excitations." Coordination Chemistry Reviews 177, no. 1 (1998): 37–60. http://dx.doi.org/10.1016/s0010-8545(98)00100-3.

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Vogler, A. "Photoreactivity of metal-to-ligand charge transfer excited states." Coordination Chemistry Reviews 177, no. 1 (1998): 81–96. http://dx.doi.org/10.1016/s0010-8545(98)00131-3.

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Vogler, Arnd, and Horst Kunkely. "Photochemistry induced by metal-to-ligand charge transfer excitation." Coordination Chemistry Reviews 208, no. 1 (2000): 321–29. http://dx.doi.org/10.1016/s0010-8545(99)00246-5.

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Nemykin, Viktor, and Brendon McNicholas. "Charge-Transfer Spectroscopy and Electrochemistry of Transition-Metal Phthalocyanines." ECS Meeting Abstracts MA2024-01, no. 14 (2024): 1154. http://dx.doi.org/10.1149/ma2024-01141154mtgabs.

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Charge-transfer spectroscopy of the selected transition-metal phthalocyanines will be discussed in conjunction with their electrochemical properties. Specifically, UV-Vis and magnetic circular dichroism (MCD) spectra of the PcFe(II)L2, PcRu(II)L2, PcMn(III)LX, and PcCr(III)LX (L is a neutral and X is a monoanionic ligand) will be discussed in terms of their metal-to-ligand (MLCT) and ligand-to-metal (LMCT) charge-transfer spectroscopy determined by the experimental UV-Vis and MCD as well as theoretical (time-dependent density functional theory) methods. Lever's EL scale was used to predict and

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Dissertations / Theses on the topic "Metal-to-ligand charge transfer"

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Smithback, Michael T. "Rhenium(I) metal-to-ligand charge-transfer excited states containing sigma-bonded closo-dicarbadodecaboranes." Laramie, Wyo. : University of Wyoming, 2006. http://proquest.umi.com/pqdweb?did=1212790661&sid=1&Fmt=2&clientId=18949&RQT=309&VName=PQD.

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陳容芳 and Yung-fong Yvonne Cheng. "Resonance raman investigation of metal to ligand charge transfer transitions in selected inorganic complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2001. http://hub.hku.hk/bib/B31224143.

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Cheng, Yung-fong Yvonne. "Resonance raman investigation of metal to ligand charge transfer transitions in selected inorganic complexes." Hong Kong : University of Hong Kong, 2001. http://sunzi.lib.hku.hk/hkuto/record.jsp?B22713359.

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Grisenti, David L. "The effect of bimolecular quenching reactions on energy transfer processes in oligometallic metal to ligand charge transfer excited states." Laramie, Wyo. : University of Wyoming, 2007. http://proquest.umi.com/pqdweb?did=1495960661&sid=1&Fmt=2&clientId=18949&RQT=309&VName=PQD.

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Hua, Fei. "Synthesis and Photophysics of Platinum (II) Diimine Acetylide Complexes." Bowling Green State University / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1187329346.

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Ko, Chi-chiu. "Design, synthesis and studies of novel classes of photochromic spirooxazine and diarylethene ligands and their metal-to-ligand charge transfer complexes." Click to view the E-thesis via HKUTO, 2003. http://sunzi.lib.hku.hk/hkuto/record/B43895311.

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Brown-Xu, Samantha E. "Photophysical and Photosensitizing Properties of Dimetal Quadruply Bonded Paddlewheel Complexes Probed Through Ultrafast Spectroscopy." The Ohio State University, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=osu1405491729.

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Reed, Carly R. "The Photophysical Properties of Multiply Bonded Metal Complexes of Molybdenum, Tungsten, and Rhenium." The Ohio State University, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=osu1309880937.

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Slageren, Joris van. "Sigma-bond-to-ligand charge transfer transitions and excited states of d6 metal-diimine complexes efficient radical formation and very long-lived excited states /." [S.l. : Amsterdam : s.n.] ; Universiteit van Amsterdam [Host], 2000. http://dare.uva.nl/document/57139.

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Loukova, G. V., V. V. Vasiliev, V. L. Ivanov, M. Ya Melnikov, V. A. Smirnov, and E. E. Melnichuk. "Two−photon Processes in Organometallic Molecules and Clusters: T−T Absorption of Group IV Metal Complexes." Thesis, Sumy State University, 2013. http://essuir.sumdu.edu.ua/handle/123456789/35395.

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Triplet – triplet absorption of d0 metal complexes was for the first time revealed and studied by means of pulse photolysis and electron-exchange (Dexter) resonant energy transfer energy transfer. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35395

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Books on the topic "Metal-to-ligand charge transfer"

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Bruce, Mitchell R. M. Ligand-to-metal charge-transfer photochemistry of high oxidation state organometallic complexes. 1985.

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Book chapters on the topic "Metal-to-ligand charge transfer"

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Loukova, Galina V. "Ligand-to-Metal Charge Transfer Excited States in Organometallic Compounds." In Springer Handbook of Inorganic Photochemistry. Springer International Publishing, 2022. http://dx.doi.org/10.1007/978-3-030-63713-2_19.

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Iwai, Shinichiro, Toshihide Kamata, Kaoru Yamamoto, Toshiaki Ohta, Toshio Fukaya, and Shigeo Murata. "Ultrafast Relaxation Processes of Metal-to-Ligand Charge Transfer Excited State in One-Dimensional Metal Complex." In Springer Series in Chemical Physics. Springer Berlin Heidelberg, 1998. http://dx.doi.org/10.1007/978-3-642-72289-9_150.

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Zhou, J. Y., T. Luo, W. L. She, et al. "Metal-to-Ligand Charge Transfer Spectra for Transition Metal Complexes of Chelated Aromatic Ligands: Theory and Experiment." In Laser in Forschung und Technik / Laser in Research and Engineering. Springer Berlin Heidelberg, 1996. http://dx.doi.org/10.1007/978-3-642-80263-8_38.

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Fukuzumi, Shunichi. "Photocatalytic Redox Reactions with Metal Complex Catalysts." In Redox-based Catalytic Chemistry of Transition Metal Complexes. Royal Society of Chemistry, 2024. https://doi.org/10.1039/9781837676484-00327.

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Metal-to-ligand charge-transfer (MLCT) and ligand-to-metal charge-transfer (LMCT) states are produced upon photoexcitation of metal complexes. The MLCT and LMCT states have strong reducing and oxidizing capabilities, respectively, exhibiting photoredox catalysis in various photocatalytic redox reactions including water oxidation, CO2 reduction and H2O2 production. By combining photoredox catalysis and thermal redox catalysis, molecular functions of photosynthesis have been achieved by constructing molecular models of PSI and PSII models, which are combined to achieve the stoichiometry of photo

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Bossert, Julien, Sébastien Villaume, Alain Strich, and Chantal Daniel. "From small organometallics to large metal-to-ligand-charge-transfer complexes." In Recent Progress in Computational Sciences and Engineering (2 vols). CRC Press, 2006. http://dx.doi.org/10.1201/b12066-135.

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Higuchi, M. "Metallosupramolecular Polymers as Display Materials." In Functional Macromolecular Complexes. Royal Society of Chemistry, 2024. http://dx.doi.org/10.1039/9781837675142-00238.

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This chapter introduces metallosupramolecular polymers (MSPs) as electrochromic (EC) display materials. MSPs are synthesized by the complexation of metal ions and multitopic organic ligands. MSPs with metal-to-ligand charge transfer (MLCT) absorption show reversible EC changes by electrochemical redox of the metal species. MSPs with one-, two- and three-dimensional structures show different EC properties. EC devices with MSPs have also been fabricated successfully by combination with an electrolyte layer and a counter material layer.

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Weller, Mark, Jonathan Rourke, Tina Overton, and Fraser Armstrong. "Coordination chemistry: reactions of complexes." In Inorganic Chemistry. Oxford University Press, 2018. http://dx.doi.org/10.1093/hesc/9780198768128.003.0023.

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This chapter discusses evidence and experiments that are used in the analysis of the reaction pathways of metal complexes. It considers ligand exchange reactions and describes how reaction mechanisms are classified. The discussion also covers ligand substitution in square planar complexes and octahedral complexes. The chapter explores the steps by which the reactions take place and the details of the formation of the transition state. These concepts are then used to describe the mechanisms of the redox reactions of complexes. The chapter explains the inner-sphere and outer-sphere mechanisms. L

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Kajiwara, T. "Optical Absorption and Emission of Metal Complexes." In Coordination Chemistry. Royal Society of Chemistry, 2024. http://dx.doi.org/10.1039/9781837673254-00088.

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Transition metal complexes often exhibit a variety of bright colours, which are due to the magnitude of the d–d splitting associated with complex formation corresponding to the visible region of the electronic absorption spectrum. This chapter discusses the electronic structures and photochemical properties of transition metal complexes based on the interaction between light and metal ions. First, the Franck–Condon principle is described, followed by the processes of light absorption and emission by metal complexes, and the photoreactions that occur upon photoexcitation. As the complexes conta

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Brisdon, Alan K. "UV-visible spectroscopy." In Inorganic Spectroscopic Methods. Oxford University Press, 1998. http://dx.doi.org/10.1093/hesc/9780198559498.003.0004.

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This chapter evaluates UV–visible spectroscopy. Within inorganic chemistry, the field of study often associated with UV–visible spectroscopy is that of the coloured transition metal complexes. The energies associated with transitions between different arrangements of valence electrons falls within the ultraviolet (UV) and visible region of the electromagnetic spectrum. Just as the most popular form of vibrational spectroscopy is usually referred to by the region it occurs in—the infrared—so the most popular form of electronic spectroscopy is usually known as UV-visible spectroscopy and is in e

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Bunker, Bruce C., and William H. Casey. "The Electrochemistry of Oxides." In The Aqueous Chemistry of Oxides. Oxford University Press, 2016. http://dx.doi.org/10.1093/oso/9780199384259.003.0018.

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Many of the critical reactions considered in this book involve the addition or subtraction of protons from oxides. In this chapter, we consider another species that can change oxide charge distributions and reactivity dramatically: the electron. Many oxides contain cations that have access to more than one oxidation state in water. Cations in these oxides can either donate or accept electrons to change their charge, or oxidation state. Oxidation reactions involve the loss of electrons as they are donated to other species, resulting in an increase in the cation charge or valence, whereas reduct

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Conference papers on the topic "Metal-to-ligand charge transfer"

1

Orman, L. K., D. R. Anderson, and J. B. Hopkins. "Direct structural characterization of charge localization in metal to ligand charge transfer complexes." In AIP Conference Proceedings Volume 172. AIP, 1988. http://dx.doi.org/10.1063/1.37523.

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Riesen, Hans, and Elmars Krausz. "Intramolecular energy transfer and excitation coupling in metal-to-ligand charge transfer (MLCT) excited states." In Excitonic Processes in Condensed Matter: International Conference, edited by Jai Singh. SPIE, 1995. http://dx.doi.org/10.1117/12.200972.

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Scherer, N. F., L. W. Ungar, D. C. Arnett, L. D. Book, H. Hu, and G. A. Voth. "Charge-Transfer Dynamics in Blue Copper Proteins: Experiment and Simulation." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 1996. http://dx.doi.org/10.1364/up.1996.fc.4.

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Blue copper proteins function as mobile electron carriers in biological systems by transfering electrons to and from their "type I" copper active sites liganded to the protein matrix.1 In reduced form, these active sites have a strong ligand-to-metal charge transfer transition between the copper atom and a cysteine sulfur ligand in the region of 595-630 nm, which gives the proteins their characterisitic blue color.2 This strong absorption makes blue copper proteins suitable for ultrafast spectroscopic studies of protein electron transfer. Elucidation of electronic and nuclear dynamics of these

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Rebane, Aleksander K., Charles Stark, Juri Pahapill, Alexander Mikhaylov, and Matt Rammo. "Probing metal-to-ligand charge transfer transitions in ruthenium complexes by quantitative two-photon absorption spectroscopy." In Organic Photonic Materials and Devices XX, edited by Christopher E. Tabor, François Kajzar, Toshikuni Kaino, and Yasuhiro Koike. SPIE, 2018. http://dx.doi.org/10.1117/12.2290363.

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Daniel, C., T. Matsubara, and G. Stor. "A CASSCF/MRCI study of the electronic spectrum of transition metal compounds with low-lying metal to ligand charge transfer states." In The first European conference on computational chemistry (E.C.C.C.1). AIP, 1995. http://dx.doi.org/10.1063/1.47862.

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Lindle, J. R., James S. Shirk, F. J. Bartoli, C. A. Hoffman, Zakya H. Kafafi, and J. Young. "Degenerate four-wave mixing in metallophthalocyanines." In OSA Annual Meeting. Optica Publishing Group, 1989. http://dx.doi.org/10.1364/oam.1989.mm1.

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The metallophthalocyanines have recently received some attention as a new class of nonlinear optical (NLO) organometallic materials.1,2 In addition to the extensive delocalized π system, the presence of the metal introduces metal-to-ligand and ligand-to-metal charge transfer (MLCT and LMCT) states. While these properties are known to give rise to large third-order optical nonlinearities, the precise mechanism for the nonlinearities in transition-metal substituted phthalocyanines is not yet understood.

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Cannelli, O., S. Restelli, N. Ohannessian, et al. "Visualization of the Multi-Center Ultrafast Response in Photoexcited Spinel Co3O4." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 2022. http://dx.doi.org/10.1364/up.2022.th4a.35.

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Femtosecond optical and X-ray measurements show excitation-specific ultrafast relaxation processes in spinel Co3O4 thin films. Upon ligand-to-metal and metal-to-metal charge transfer, the system decays through different energy pathways characterized by different coherent and incoherent responses.

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Greve, Daniel R., Tommy Geisler, Thomas Bjørnholm, and Jan C. Petersen. "Third-Order Nonlinear Optical Effects in Organic Nickel Complexes and Triarylmethyl Cations." In Organic Thin Films for Photonic Applications. Optica Publishing Group, 1995. http://dx.doi.org/10.1364/otfa.1995.md.23.

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The second molecular hyperpolarizability, γ, has been determined at 1064 nm by Third- Harmonic Generation (THG) using the Maker fringe technique, for a family of triarylmethyl cations and for a familiy of organic Nickel complexes as guests in PMMA thin films. For the metal complexes it is a well established notion that the low-lying transition with ligand to metal charge transfer character is important for the nonlinear optical properties(1). However, ambiguity arises due to large discrepancies between different measurements(2-5), as well as difficulties in assessing the exact contribution to

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Eom, Hyo Soon, Cheon Min Kim, Sae Chae Jeoung, and Dongho Kim. "Ultrafast Vibrational Relaxation and Ligand Photodissociation/Photoassociation Processes of Nickel(II) Porphyrins." In International Conference on Ultrafast Phenomena. Optica Publishing Group, 1996. http://dx.doi.org/10.1364/up.1996.fe.54.

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The nickel(II) porphyrins have been well suited for an ideal system for investigating electronic decay, axial ligand photodissociation and photoassociation dynamics.1Of great significance in governing photophysics of the four- and six-coordinate nickel(II) complexes is the presence of a low-lying metal excited (dz2,dx2−y2) state having ~250 ps lifetme below porphyrin ring (π,π*) states.1 The (d,d) excited state shows characteristic sharply featured absorption difference spectra, compared to the broader featured more diffuse spectra of the ring (π,π*) and metal⇔ring charge transfer excited stat

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Akbar, Himyan, Salma Habib, Mohammed Mahroof Tahir, and Lakshmaiah Sreerama. "Synthesis and Characterization of Vanadium (IV)-Flavonoid Complexes and its Antioxidant ability toward Superoxide and Radical Scavenging." In Qatar University Annual Research Forum & Exhibition. Qatar University Press, 2020. http://dx.doi.org/10.29117/quarfe.2020.0109.

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In this project Vanadium complex -Vanadium (IV) - flavone was synthesized using vanadium (IV) acetylacetonate (VO(acac)2) complex and 3-hydroxy-6-methyl flavone ligand. The complex stability was checked using FTIR and UV-vis spectroscopies. Peackes around 990 cm-1 conforms the formation of (V=O) in the complex, as well as (V-O) around 790 cm-1. In UV-Vis spectrum peak around 400-450 nm was noticed, which conforms the formation of the vanadium complex that correspond to the ligand to metal charge transfer (LMCT) transition. The radical scavenging abilities of vanadium complex were investigated

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