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Dissertations / Theses on the topic 'Metallic lithium'

Author: Grafiati

Published: 25 May 2024

Last updated: 31 July 2025

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1

Deavin, Oliver. "Thermodynamic tuning of lithium borohydride using various metallic sources." Thesis, University of Nottingham, 2018. http://eprints.nottingham.ac.uk/50398/.

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Lithium borohydride (LiBH4) has been shown great interest as a hydrogen storage material owing to its large hydrogen storage capacity of 18.5 wt%, but unfortunately to release the vast majority of the stored hydrogen requires temperatures in excess of 600 °c. To improve the temperature at which LiBH4 decomposes, and to improve its poor reversibility, a process known as thermodynamic tuning can be used. Thermodynamic tuning involves creating new, more favourable reaction pathways and in this work the addition of nickel, silicon, iron and cobalt were investigated. The addition of nickel in the L

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2

Ma, Miaomiao. "Layered LiMn0.4Ni0.4Co0.2O2 as cathode for lithium batteries." Diss., Online access via UMI:, 2005.

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Thesis (Ph. D.)--State University of New York at Binghamton, Materials Science, 2005.<br>Numerals in chemical formula in title are "subscript" in t.p. of printed version. Includes bibliographical references.

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3

Viik, Rickard. "Surface layer formation on the surfaces of metallic lithium, copper and iron." Thesis, Uppsala universitet, Molekyl- och kondenserade materiens fysik, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-257571.

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4

Drury, William James. "Quantitative microstructural and fractographic characterization of AE-Li/FP metal matrix composite." Thesis, Georgia Institute of Technology, 1988. http://hdl.handle.net/1853/19958.

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5

Bonatti, Colin. "Testing and modeling of the viscoplastic and fracture behavior of metallic foils used in lithium-ion batteries." Thesis, Massachusetts Institute of Technology, 2015. http://hdl.handle.net/1721.1/101332.

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Thesis: S.M., Massachusetts Institute of Technology, Department of Mechanical Engineering, 2015.<br>Cataloged from PDF version of thesis.<br>Includes bibliographical references (pages 37-39).<br>Aluminum 1235-H18 foils with sub-micron grain dimensions are often used as current collectors in Li-ion batteries. Due to their contribution to the structural integrity of batteries under impact loading, their plastic and fracture response is investigated in detail. Using a novel micro-tensile testing device with a piezoelectric actuator, dogbone specimens with a 1.25 mm wide and 5.7 mm long gage secti

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6

Cluzeau, Benoît. "Développement de batteries lithium-ion « Tout solide » pour véhicules électriques." Electronic Thesis or Diss., Pau, 2022. http://www.theses.fr/2022PAUU3071.

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L'amélioration continue des performances des batteries Li-ion au cours des deux dernières décennies a permis l'introduction de nombreuses automobiles électriques sur le marché. Cependant, les demandes concernant la sécurité, l'autonomie et la charge rapide des véhicules nécessitent le développement de nouvelles technologies plus performantes.C'est dans cette optique qu'a été fondé le projet RAISE 2024 dans lequel s'inscrit cette thèse. Cette collaboration entre SAFT, ARKEMA et l'université de Pau et des pays de l'Adour vise à développer une batterie à électrolyte solide. Le développement d'un

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7

Santoki, Jay [Verfasser], and B. [Akademischer Betreuer] Nestler. "Phase-field modeling on the diffusion-driven processes in metallic conductors and lithium-ion batteries / Jay Santoki ; Betreuer: B. Nestler." Karlsruhe : KIT-Bibliothek, 2021. http://d-nb.info/1225401070/34.

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8

Xu, Chunbao. "Continuous and batch hydrothermal synthesis of metal oxide nanoparticles and metal oxide-activated carbon nanocomposites." Diss., Available online, Georgia Institute of Technology, 2006, 2006. http://etd.gatech.edu/theses/available/etd-07302006-231517/.

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Thesis (Ph. D.)--Chemical and Biomolecular Engineering, Georgia Institute of Technology, 2007.<br>Teja, Amyn, Committee Chair ; Kohl, Paul, Committee Member ; Liu, Meilin, Committee Member ; Nair,Sankar, Committee Member ; Rousseau, Ronald, Committee Member.

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9

Chaumont-Olive, Pauline. "Synthèse et développement de la réactivité des triorganozincates de lithium chiraux en addition nucléophile énantiosélective et application à la synthèse de produits bioactifs." Thesis, Normandie, 2018. http://www.theses.fr/2018NORMR069/document.

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Le développement de méthodes de synthèse asymétriques a largement été exploré au cours des vingt dernières années et en particulier par le biais de réactifs organométalliques. Bien que ces processus mènent à d’excellents résultats en terme d’énantiodiscrimination, l’objectif de cette thèse a été de développer de nouveaux outils de synthèse peu onéreux, respectueux des fonctions sensibles environantes et permettant l’accès aux composés attendus avec de bons rendements et excès énantiomériques. Dans cet optique, des triorganozincates de lithium chiraux ont été étudiés. Des méthodes d’alkylation

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10

Ren, Yu. "Applications of ordered mesoporous metal oxides : energy storage, adsorption, and catalysis." Thesis, University of St Andrews, 2010. http://hdl.handle.net/10023/1705.

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The experimental data and results demonstrated here illustrate the preparation and application of mesoporous metal oxides in energy storage, adsorption, and catalysis. First, a new method of controlling the pore size and wall thickness of mesoporous silica was developed by controlling the calcination temperature. A series of such silica were used as hard templates to prepare the mesoporous metal oxide Co₃O₄. Using other methods, such as varying the silica template hydrothermal treatment temperature, using colloid silica, varying the materials ratio etc., a series of mesoporous β-MnO₂ with diff

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11

Liao, Feng. "Relation entre caractéristiques morphologiques et chimiques interfaciales et comportement électrochimique de couches minces de sulfures métalliques pour batteries li-ion : = Relation between morphological and chemical interfacial characteristics and electrochemical properties of metallic sulfides thin films for lithium ion batteries." Paris 6, 2013. http://www.theses.fr/2013PA066126.

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Les mécanismes de lithiation électrochimique, de passivation et de vieillissement de sulfures métalliques (Fe1-xS (0≤x≤0. 07), Ni3S2 et Cu2S) ont éte�� étudiés par spectroscopie de surface (XPS et ToF-SIMS) couplée à des mesures électrochimiques. Une approche modèle des matériaux d’électrode négative de type conversion pour les batteries Li-ion a été développée. Elle repose sur l’élaboration de films minces de sulfure par croissance en milieu H2S sur substrat métallique. Le substrat sert de collecteur de courant. Les résultats montrent que la conversion/déconversion avec le lithium est réversi

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12

Soulmi, Nadia. "Mise au point de nouveaux procédés d'élaboration en milieu liquide ionique de nanomatériaux à base d'étain en vue de leur utilisation comme électrode négative de batterie Li-ion." Thesis, Paris 6, 2017. http://www.theses.fr/2017PA066520/document.

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L’étain est une alternative privilégiée en remplacement du carbone graphite comme matériau d’électrode négative dans les batteries Li-ion en raison de son importante capacité théorique spécifique massique de 993 mAh.g-1. Toutefois son expansion volumique lors sa lithiation conduit à sa dégradation au cours du cyclage, diminuant la durée de vie du matériau. Pour pallier à sa pulvérisation, l’utilisation de l’espace inter-granulaire via la nanostructuration du matériau est complétée par l’adjonction d’une matrice carbonée ou d’un autre élément inactif vis-à-vis de la lithiation (utilisation d’al

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13

Raguž, Branimir [Verfasser]. "Synthese und Charakterisierung von Lithium-metall(I)-phosphaten / Branimir Raguž." Bonn : Universitäts- und Landesbibliothek Bonn, 2020. http://d-nb.info/1224270630/34.

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14

Mogay-Batalla, Carlos. "Synthesis and characterisation of new metallo phthalocyanines and sub-phthalocyanines." Thesis, Imperial College London, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.368706.

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15

Metzger, Sebastian J. [Verfasser]. "Hochdruckmodifikationen von Oxoarsenaten(V) und Oxoarsenaten(III) der Selten-Erd-Metalle und Lithium-Mangan-Eisen-Oxophosphat(V) als Kathodenmaterial für Lithium-Akkumulatoren / Sebastian J. Metzger." München : Verlag Dr. Hut, 2013. http://d-nb.info/1037286952/34.

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16

Baburin, Igor A., Bassem Assfour, Gotthard Seifert, and Stefano Leoni. "Polymorphs of lithium-boron imidazolates: energy landscape and hydrogen storage properties." Saechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden, 2014. http://nbn-resolving.de/urn:nbn:de:bsz:14-qucosa-138700.

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The topological diversity of lithium-boron imidazolates LiB(imid)4 was studied by combining topological enumeration and ab initio DFT calculations. The structures based on zeolitic rho, gme and fau nets are shown to be stable and have high total hydrogen uptake (6.9–7.8 wt.%) comparable with that of MOF-177<br>Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich

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17

Baburin, Igor A., Bassem Assfour, Gotthard Seifert, and Stefano Leoni. "Polymorphs of lithium-boron imidazolates: energy landscape and hydrogen storage properties." Royal Society of Chemistry, 2011. https://tud.qucosa.de/id/qucosa%3A27772.

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The topological diversity of lithium-boron imidazolates LiB(imid)4 was studied by combining topological enumeration and ab initio DFT calculations. The structures based on zeolitic rho, gme and fau nets are shown to be stable and have high total hydrogen uptake (6.9–7.8 wt.%) comparable with that of MOF-177.<br>Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.

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18

Dittrich, Thomas. "Meso- to Neoarchean Lithium-Cesium-Tantalum- (LCT-) Pegmatites (Western Australia, Zimbabwe) and a Genetic Model for the Formation of Massive Pollucite Mineralisations." Doctoral thesis, Technische Universitaet Bergakademie Freiberg Universitaetsbibliothek "Georgius Agricola", 2017. http://nbn-resolving.de/urn:nbn:de:bsz:105-qucosa-228968.

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Lithium Cesium Tantalum (LCT) pegmatites are important resources for rare metals like Cesium, Lithium or Tantalum, whose demand increased markedly during the past decade. At present, Cs is known to occur in economic quantities only from the two LCT pegmatite deposits at Bikita located in Zimbabwe and Tanco in Canada. Host for this Cs mineralisation is the extreme rare zeolite group mineral pollucite. However, at Bikita and Tanco, pollucite forms huge massive, lensoid shaped and almost monomineralic pollucite mineralisations that occur within the upper portions of the pegmatite. In addition, bo

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19

Meng, Shirley Y., Yi Li, and Gerbrand Ceder. "Investigation on Aluminum-Based Amorphous Metallic Glass as New Anode Material in Lithium Ion Batteries." 2003. http://hdl.handle.net/1721.1/3725.

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Aluminum based amorphous metallic glass powders were produced and tested as the anode materials for the lithium ion rechargeable batteries. Ground Al₈₀Ni&#x2081₀La&#x2081₀ was found to have a low first cycle capacity of about 100 Ah/Kg. The considerable amount of intermetallic formed in the amorphous glass makes the aluminum inactive towards the lithium. The ball milled Al₈₈Ni₉Y₃ powders contain pure aluminum crystalline particles in the amorphous matrix and have first cycle capacity of about 500 Ah/Kg. Nevertheless, polarization was caused by oxidation introduced by the ball-milling process.

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20

"Synthesis and characterization of nanometer-sized β-LiAlO₂ network reinforced Al-based metal matrix composite". 2006. http://library.cuhk.edu.hk/record=b5896471.

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by Li, Tsui Kiu = 納米鋁酸鋰網絡增強的鋁基複合材料的製造和表徵 / 李翠翹.<br>Thesis (M.Phil.)--Chinese University of Hong Kong, 2006.<br>Includes bibliographical references.<br>Text in English; abstracts in English and Chinese.<br>by Li, Tsui Kiu = Na mi lü suan li wang luo zeng qiang de lü ji fu he cai liao de zhi zao he biao zheng / Li Cuiqiao.<br>Acknowledgement --- p.i<br>Abstract --- p.ii<br>摘要 --- p.iv<br>Table of contents --- p.vi<br>List of tables --- p.ix<br>List of figures --- p.xii<br>Chapter Chapter 1. --- Introduction<br>Chapter 1.1. --- Metal matrix composites (MMCs) --- p.1-2<br>Chapter 1.1.1. ---

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21

"Ferroelectric Lithium Niobate Surfaces for Depositions of Metallic Nanostructure and ZnO Semiconducting Thin Film." Doctoral diss., 2011. http://hdl.handle.net/2286/R.I.9290.

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abstract: A distinct characteristic of ferroelectric materials is the existence of a reversible spontaneous polarization with the application of an electric field. The relevant properties ferroelectric lithium niobate surfaces include a low density of defects and external screening of the bound polarization charge. These properties result in unique surface electric field distribution with a strong electric field in the vicinity of domain boundaries, while away from the boundaries, the field decreases rapidly. In this work, ferroelectric lithium niobate (LN) is used as a template to direct the

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22

Meng, Shirley Y., Yi Li, Elena M. Arroyo, and Gerbrand Ceder. "Amorphous Metallic Glass as New High Power and Energy Density Anodes For Lithium Ion Rechargeable Batteries." 2002. http://hdl.handle.net/1721.1/3966.

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We have investigated the use of aluminum based amorphous metallic glass as the anode in lithium ion rechargeable batteries. Amorphous metallic glasses have no long-range ordered microstructure; the atoms are less closely packed compared to the crystalline alloys of the same compositions; they usually have higher ionic conductivity than crystalline materials, which make rapid lithium diffusion possible. Many metallic systems have higher theoretical capacity for lithium than graphite/carbon; in addition irreversible capacity loss can be avoided in metallic systems. With careful processing, we ar

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23

Yang, Kai-Yun, and 楊開雲. "Studies on Mechanism and Suppression of Interfacial Reaction Between Perovskite La2/3−xLi3xTiO3 and Metallic Lithium." Thesis, 2007. http://ndltd.ncl.edu.tw/handle/88229826381407658549.

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博士<br>國立成功大學<br>材料科學及工程學系碩博士班<br>95<br>Li+ conductors are key materials for technological applications as all- solid-state lithium batteries. Unfortunately, many crystalline phases having high Li+ conductivity are unstable in the presence of a metallic lithium anode. Although interfacial reactions between such conductors and the lithium anode are always inferred, very little effort has been devoted to studying this interfacial instability, which is usually examined by observing the coloration of sample with the naked eye. The scope of our study is, therefore, focused on the detailed reaction m

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24

Kim, Hyun Woo. "Structure and properties of amorphous metallic alloys : a first principles study." Thesis, 2010. http://hdl.handle.net/2152/ETD-UT-2010-12-2328.

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Utilization of amorphous metallic alloy has received much attention for use in numerous microelectronic and electrochemical devices since they provide unique electrical, thermal conductivity, and magnetic properties. To develop these functional properties, it is essential to understand the amorphous structure and the property relationships. First principles calculations provide insight into the structure, thermodynamic stability, electronic and magnetic properties of amorphous alloys. For Ru- and Co-based alloys, the thermodynamic stability was examined by calculating the mixing energy along w

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25

Wang, C. Y., Gerbrand Ceder, and Yi Li. "Amorphous Al-transition Metal Alloys as Anode Material for Lithium Ion Battery." 2005. http://hdl.handle.net/1721.1/29816.

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Al based alloy powders (Al₈₅Ni₅Y₆Co₂Fe₂) are produced by spray atomization method. High energy ball milling is done to modify the surface topology and particle size for better electrochemical performance. X ray diffraction (XRD), differential scanning calorimeter (DSC), scanning electron microscope (SEM) and transmission electron microscope (TEM) were conducted to characterize the microstructure of the alloys after ball milling. It is found that 5 hours ball milling gives the minimum crystallization and structure change. Thin film sample is also deposited on stainless steel substrate by pulsed

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26

Lai, Pei-Yu, and 賴姵宇. "Investigation of corrosion properties of thin film metallic glasses on cathodic aluminum current collectors in lithium ion batteries." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/877b2b.

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碩士<br>國立臺灣科技大學<br>材料科學與工程系<br>104<br>Lithium bis(trifluoromethane sulfonyl) imide (LiTFSI) salt is claimed to be a potential alternative to lithium hexafluorophosphate (LiPF6) since it has greater electrochemical properties such as chemical and thermal stability which may provide benefits of higher safety and longer lifetime of lithium ion batteries (LIBs).

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27

Carter, W. Craig. "Computation and Simulation of the Effect of Microstructures on Material Properties." 2003. http://hdl.handle.net/1721.1/3659.

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Many material properties depend on specific details of microstructure and both optimal material performance and material reliability often correlate directly to microstructure. In nano- and micro-systems, the material's microstructure has a characteristic length scale that approaches that of the device in which it is used. Fundamental understanding and prediction of material behavior in nano- and micro-systems depend critically on methods for computing the effect of microstructure. Methods for including the physics and spatial attributes of microstructures are presented for a number of materia

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28

Mason, James Derek. "Investigation of allenyl lithium species by lithium-metalloid exchange." 1988. http://catalog.hathitrust.org/api/volumes/oclc/19415066.html.

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Thesis (Ph. D.)--University of Wisconsin--Madison, 1988.<br>Typescript. Vita. 2. Investigation of chelation-controlled lithium-metalloid exchange. eContent provider-neutral record in process. Description based on print version record. Includes bibliographies.

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29

Phillips, Nancy Helen. "Mechanistic studies of the lithium-metalloid exchange reaction." 1988. http://catalog.hathitrust.org/api/volumes/oclc/18579107.html.

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30

Hoppe, Holger [Verfasser]. "Anwendung von Titannitridchlorid als Kathode in einer Lithium-Metall-Batterie und Synthese neuer TiCl4-Additionsverbindungen / vorgelegt von Holger Hoppe." 2002. http://d-nb.info/966015541/34.

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31

Dittrich, Thomas. "Meso- to Neoarchean Lithium-Cesium-Tantalum- (LCT-) Pegmatites (Western Australia, Zimbabwe) and a Genetic Model for the Formation of Massive Pollucite Mineralisations." Doctoral thesis, 2016. https://tubaf.qucosa.de/id/qucosa%3A23157.

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Lithium Cesium Tantalum (LCT) pegmatites are important resources for rare metals like Cesium, Lithium or Tantalum, whose demand increased markedly during the past decade. At present, Cs is known to occur in economic quantities only from the two LCT pegmatite deposits at Bikita located in Zimbabwe and Tanco in Canada. Host for this Cs mineralisation is the extreme rare zeolite group mineral pollucite. However, at Bikita and Tanco, pollucite forms huge massive, lensoid shaped and almost monomineralic pollucite mineralisations that occur within the upper portions of the pegmatite. In addition, bo

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