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Journal articles on the topic 'Metallo bis-ditiolene sulphur-based ligands'

Author: Grafiati

Published: 9 March 2023

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1

Hladysh, Sviatoslav, Daniela Václavková, David Vrbata, et al. "Synthesis and characterization of metallo-supramolecular polymers from thiophene-based unimers bearing pybox ligands." RSC Advances 7, no. 18 (2017): 10718–28. http://dx.doi.org/10.1039/c6ra26665g.

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A series of novel metallo-supramolecular polymers was prepared, based on 2,6-bis(2-oxazolinyl)pyridine chelating groups bridged with thiophene, bithiophene and thienothiophene as a linker, beginning from commercially available (chelidamic) acid.

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2

Xu, Xiaowen, Anne K. Seiffert, Ruben Lenaerts, et al. "[2 × 2] metallo-supramolecular grids based on 4,6-bis((1H-1,2,3-triazol-4-yl)-pyridin-2-yl)-2-phenylpyrimidine ligands: from discrete [2 × 2] grid structures to star-shaped supramolecular polymeric architectures." Dalton Transactions 50, no. 25 (2021): 8746–51. http://dx.doi.org/10.1039/d1dt01373d.

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[2 × 2] metallo-supramolecular grids were readily obtained by complexation of novel 4,6-bis(6-ethynylpyridin-2-yl)-2-phenylpyrimidine ligands with Fe<sup>2+</sup> or Zn<sup>2+</sup> in acetonitrile, allowing for constructing discrete grids and star-shaped polymers.

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3

Chaur Valencia, Manuel Noé, Héctor Fabio Zuluaga Corrales, and Gabriel Martínez. "Electronic and electrochemical properties of grid-type metal ion complexes (Fe+2 and Co2+) with a pyridine-pyrimidine-pyridine based bis(hydrazone)." Revista Colombiana de Química 47, no. 2 (2018): 45–53. http://dx.doi.org/10.15446/rev.colomb.quim.v47n2.66081.

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Se reporta la síntesis de nuevos complejos metálicos de Co2+ y Fe2+ tipo rejilla que contienen como ligando orgánico una doble hidrazona altamente soluble en solventes orgánicos. Los datos obtenidos de resonancia magnética nuclear (RMN 1H), espectroscopía infrarroja con transformada de Fourier (FT-IR) y análisis elemental indican que los complejos adoptaron una estructura de tipo rejilla. Las propiedades electrónicas de las metalo-rejillas fueron analizadas a través de espectroscopía UV-Vis en cloroformo, metanol y diclorometano. Adicionalmente, se realizaron medidas de voltamperometría cíclic

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4

Zhang, Ying-Ying, Yue-Jian Lin, and Guo-Xin Jin. "Nano-sized heterometallic macrocycles based on 4-pyridinylboron-capped iron(ii) clathrochelates: syntheses, structures and properties." Chem. Commun. 50, no. 18 (2014): 2327–29. http://dx.doi.org/10.1039/c3cc49038f.

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A series of nano-scaled Ir–Fe heterometallic rectangles were prepared from 4-pyridinylboron-capped iron(ii) clathrochelates and bis(amidine) ligands. The cavity size could be controlled easily by the length of the organic ligand.

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5

Satapathy, Rudrakanta, Mohan Ramesh, Harihara Padhy, et al. "Novel metallo-dendrimers containing various Ru core ligands and dendritic thiophene arms for photovoltaic applications." Polym. Chem. 5, no. 18 (2014): 5423–35. http://dx.doi.org/10.1039/c4py00444b.

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A polymer solar cell device containing an active layer of BTRu2G3 : PC70BM = 1 : 3 (by wt), i.e., the third generation of the bis-Ru-based dendritic complex BTRu2G3 showed the highest PCE value of 0.77%.

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6

Chagas, Rafael César Russo, José Roberto da Silveira Maia, and Vany P. Ferraz. "Synthesis and characterisation of organotin(IV) derivatives of ambidentate ligands containing nitrogen and sulphur donor atoms." Main Group Metal Chemistry 34, no. 5-6 (2011): 131–37. http://dx.doi.org/10.1515/mgmc-2012-0904.

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Abstract A series of organotin(IV) derivatives of bis(pyrimidin-2-ylthio)methane (ptm), 1,2-bis(pyrimidin-2-ylthio)ethane (pte) and 1,6-bis(pyrimidin-2-ylthio)hexane (pth) have been prepared in dichloromethane at room temperature. The 2:1 (M/L) molar ratio compounds have a general formula of [Sn2ClxPh8-xL] (x=2, 4, 6, 8; L=ptm, pte and pth). A 1:1 complex was also obtained by reacting SnClPh3 with pth. The organotin derivatives were characterised by multinuclear NMR (1H, 13C and 119Sn) and infrared spectroscopy, gel permeation chromatography (GPC), microanalysis and melting point. In the triph

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7

Awal, Abdul, Shifa Sarker, Md Mia, Md Delwar Hossain, and A. J. Saleh Ahammad. "Fe(II)-Based Metallo-Supramolecular Polymer Film as a Sensing Material for the Detection of Nitrite." ECS Transactions 107, no. 1 (2022): 14783–90. http://dx.doi.org/10.1149/10701.14783ecst.

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In this work, we report the synthesis of a mono metallic supramolecular polymer for constructing a new nonenzymatic electrochemical nitrite sensor. Metallo supramolecular polymer have been prepared by the complexation reaction of a ligand bearing terpyridine moieties [4′,4′′′′-(1,4 Phenylene) bis (2,2′:6′,2′′-terpyridine] with Fe(II) salts (Fe salt: Ligand-1:1) (polyFe). The polyFe was characterized with the UV/Vis titration and FTIR. The glassy carbon electrode (GCE) was used for fabricating ployFe_GCE via a drop casting method that was used for detecting nitrite through the oxidation process

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8

Macedi, Eleonora, Daniele Paderni, Mauro Formica, et al. "Playing with Structural Parameters: Synthesis and Characterization of Two New Maltol-Based Ligands with Binding and Antineoplastic Properties." Molecules 25, no. 4 (2020): 943. http://dx.doi.org/10.3390/molecules25040943.

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Two maltol-based ligands, N,N′-bis((3-hydroxy-4-pyron-2-yl)methyl)-1,4-piperazine (L1) and N,N′,N′-tris((3-hydroxy-4-pyron-2-yl)methyl)-N-methylethylendiamine (L2), were synthesized and characterized. L1 and L2, containing, respectively, two and three maltol units spaced by a diamine fragment, were designed to evaluate how biological and binding features are affected by structural modifications of the parent compound malten. The acid-base behavior and the binding properties towards transition, alkaline-earth (AE) and rare-earth (RE) cations in aqueous solution, studied by potentiometric, UV-Vi

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9

Kanao, Miki, and Masayoshi Higuchi. "Synthesis of Ni-Based Metallo-Supramolecular Polymer with Bis-NNO-Tridentate Ligand for Electrochromic Devices." Journal of Photopolymer Science and Technology 29, no. 2 (2016): 295–300. http://dx.doi.org/10.2494/photopolymer.29.295.

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10

Feng, Tao, Li-Li Li, Ya-Juan Li, and Wen-Kui Dong. "A half-salamo-based pyridine-containing ligand and its novel NiII complexes including different auxiliary ligands: syntheses, structures, fluorescence properties, DFT calculations and Hirshfeld surface analysis." Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 77, no. 1 (2021): 168–81. http://dx.doi.org/10.1107/s2052520620016157.

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Three novel multinuclear NiII complexes, namely, bis{μ-2-methoxy-6-[8-(pyridin-2-yl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl]phenolato}bis[thiocyanatonickel(II)], [Ni2(L)2(NCS)2], 1, bis{μ-2-methoxy-6-[8-(pyridin-2-yl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl]phenolato}bis[azidonickel(II)], [Ni2(L)2(N3)2], 2, and catena-poly[[{2-methoxy-6-[8-(pyridin-2-yl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl]phenolato}nickel(II)]-μ-dicyanamidato], [Ni(L)(dca)] n , 3 {dca is dicyanamide, C2N3, and HL is 2-methoxy-6-[8-(pyridin-2-yl)-3,6-dioxa-2,7-diazaocta-1,7-dien-1-yl]phenol, C16H17N3O4}, with a half-salamo-base

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11

Fujii, Kazuko, Manas Kumar Bera, Dines Chandra Santra, and Masayoshi Higuchi. "Nanocomposites of Fe(II)-Based Metallo-Supramolecular Polymer and a Layered Inorganic–Organic Hybrid for Improved Electrochromic Materials." Polymers 14, no. 5 (2022): 915. http://dx.doi.org/10.3390/polym14050915.

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Fe-based metallo-supramolecular polymer (polyFe), composed of Fe(II) ions and bis(terpyridyl)benzene, is known as a good electrochromic (EC) material. For the first time, to improve the EC properties, we prepared nanocomposites comprising polyFe and a layered inorganic–imidazoline covalently bonded hybrid (LIIm) by simply mixing them in methanol and then examined the effect of the nanocomposition on EC properties. The obtained blue/purple-colored composites (polyFe/LIIm composites) were demonstrated by scanning electron microscopy (SEM) to comprise a structure of LIIm nanoparticles coated with

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12

Lai, Po-Ni, Sungwon Yoon, and Thomas S. Teets. "Efficient near-infrared luminescence from bis-cyclometalated iridium(iii) complexes with rigid quinoline-derived ancillary ligands." Chemical Communications 56, no. 62 (2020): 8754–57. http://dx.doi.org/10.1039/d0cc02745f.

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13

Perdih, Franc. "CuIIand ZnIIβ-diketonate coordination polymers based on pyrimidin-2-amine, pyrazine and 1,2-bis(4-pyridyl)ethane". Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 72, № 6 (2016): 828–35. http://dx.doi.org/10.1107/s2052520616014566.

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Copper(II) and zinc(II) bis(4,4,4-trifluoro-1-phenylbutane-1,3-dionato) compounds with pyrimidin-2-amine (pyr2a), pyrazine (pyz) and 1,2-bis(4-pyridyl)ethane (dpet) were prepared and solid-state structures of coordination polymers [M(tfpb)2(pyr2a)]∞[M= Cu (1), Zn (2); tfpb = 4,4,4-trifluoro-1-phenylbutane-1,3-dionate], [M(tfpb)2(pyz)]∞[M= Cu (3), Zn (4a, 4b)] and [Cu(tfpb)2(dpet)]∞(5), respectively, were determined by single-crystal X-ray analysis. The coordination of metal centers in all compounds is octahedral with nitrogen ligands occupying the axial positions. Compound (1) crystallizes in

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14

Ding, Junqiao, Jia Gao, Qi Fu, Yanxiang Cheng, Dongge Ma, and Lixiang Wang. "Highly efficient phosphorescent bis-cyclometalated iridium complexes based on quinoline ligands." Synthetic Metals 155, no. 3 (2005): 539–48. http://dx.doi.org/10.1016/j.synthmet.2005.08.034.

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15

Wang, Xiuli, Xiang Pan, Xiang Wang, Guocheng Liu, Hongyan Lin, and Shan Zhang. "Polyoxometalate-based complexes with a flexible bis-imidazole-bis-amide ligand: structures, electrochemical and photocatalytic properties." Transition Metal Chemistry 44, no. 3 (2018): 207–17. http://dx.doi.org/10.1007/s11243-018-0284-7.

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16

Irmak, Mustafa, Annika Groschner, and Mike M. K. Boysen. "glucoBox ligand—a new carbohydrate-based bis(oxazoline) ligand. Synthesis and first application." Chem. Commun., no. 2 (2007): 177–79. http://dx.doi.org/10.1039/b612986b.

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17

Ligny, Romain, Mikko M. Hänninen, Sophie M. Guillaume та Jean-François Carpentier. "Steric vs. electronic stereocontrol in syndio- or iso-selective ROP of functional chiral β-lactones mediated by achiral yttrium-bisphenolate complexes". Chemical Communications 54, № 58 (2018): 8024–31. http://dx.doi.org/10.1039/c8cc03842b.

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18

Gun, Jenny, Irina Ekeltchik, Ovadia Lev, Rimma Shelkov, and Artem Melman. "Bis-(hydroxyamino)triazines: highly stable hydroxylamine-based ligands for iron(iii) cations." Chemical Communications, no. 42 (2005): 5319. http://dx.doi.org/10.1039/b508138f.

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19

Li, Peng, Ting Zhang, Li-Li Li, and Wen-Kui Dong. "Self-assembling of three rare structurally various homomultinuclear CuII complexes derived from a bis(salamo)-based multioxime ligand." Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 77, no. 5 (2021): 848–60. http://dx.doi.org/10.1107/s2052520621008441.

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A family of rare structurally different homometal multinuclear CuII bis(salamo)-based complexes, [Cu4(L)2(MeOH)2](ClO4)2·2MeOH (1), [Cu4(L)2(EtOH)2](NO3)2·2EtOH (2) and [Cu2(HL)(EtOH)Br2]·CHCl3 (3), has been successfully synthesized by the reactions of cupric salts with a bis(salamo)-based multidentate chelate ligand (H3 L). The salamo-based ligand [R-CH=N—O—(CH2) n —O—N=CH—R] is a new type of salen-based analog. Complexes (1) and (2) are isostructural structures, and crystallize in monoclinic space group P21/n with centrosymmetric spiral structures, where the main structures contain two fully

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20

Ying, Jun, Xiuyan Wang, and Yaguang Chen. "Four octamolybdate- and Keggin-based compounds constructed by flexible bis(triazole) ligands with different spacers." Transition Metal Chemistry 45, no. 5 (2020): 343–52. http://dx.doi.org/10.1007/s11243-020-00385-w.

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21

Wang, Xiu-Li, Jun-Jun Sun, Hong-Yan Lin, et al. "Effect of N-donor sites of bis-pyridyl-bis-amide ligands on the architectures of three Anderson-type polyoxometalate-based metal–organic complexes." Transition Metal Chemistry 42, no. 2 (2017): 145–52. http://dx.doi.org/10.1007/s11243-017-0119-y.

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22

Hao, Jin Ming, Yue Hua Li, Huan Huan Li, and Guang Hua Cui. "Erratum to: Two cobalt(II) metal–organic frameworks based on mixed 1,2,4,5-benzenetetracarboxylic acid and bis(benzimidazole) ligands." Transition Metal Chemistry 39, no. 1 (2013): 9. http://dx.doi.org/10.1007/s11243-013-9774-9.

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23

Grätz, Maik, Andreas Bäcker, Lisa Vondung, Leon Maser, Arian Reincke, and Robert Langer. "Donor ligands based on tricoordinate boron formed by B–H-activation of bis(phosphine)boronium salts." Chemical Communications 53, no. 53 (2017): 7230–33. http://dx.doi.org/10.1039/c7cc02335a.

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24

Bowlas, C. J., A. E. Underhill, and D. Thetford. "The synthesis and properties of metal bis-dithiolenes based on the new DMAD ligand." Synthetic Metals 56, no. 1 (1993): 2158–63. http://dx.doi.org/10.1016/0379-6779(93)90391-9.

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25

Yoshidomi, Tetsushi, Yasutomo Segawa, and Kenichiro Itami. "Pyridine-based dicarbene ligand: synthesis and structure of a bis-2-pyridylidene palladium complex." Chemical Communications 49, no. 50 (2013): 5648. http://dx.doi.org/10.1039/c3cc42655f.

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26

Zhu, Hui, Dong Liu, Yue-Hua Li, and Guang-Hua Cui. "Two silver(I) complexes based on dicarboxylate and flexible bis(benzimidazole) ligands: synthesis, crystal structures, sensing and photocatalytic properties." Transition Metal Chemistry 45, no. 1 (2019): 19–29. http://dx.doi.org/10.1007/s11243-019-00352-0.

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27

Singla, Manisha, Pavan Mathur, Manisha Gupta, and M. S. Hundal. "Oxidation of electron deficient olefins using a copper(II) complex based on a bis-benzimidazole diamide ligand." Transition Metal Chemistry 33, no. 2 (2007): 175–82. http://dx.doi.org/10.1007/s11243-007-9029-8.

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28

Leovac, Vukadin M., and Valerija I. Cešljević. "Transition metal complexes with thiosemicarbazide-based ligands, Part II, Synthesis and characterisation of nickel(II), cobalt(II), manganese(II) and zinc(II) complexes with the pentadentate ligand, 2,6-diacetylpyridine bis(S-methylisothiosemicarbazone)." Transition Metal Chemistry 12, no. 6 (1987): 504–7. http://dx.doi.org/10.1007/bf01023835.

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29

Qin, Li, Yu Gu, Guang Yue Li, Shu Lin Xiao, and Guang Hua Cui. "Preparation and crystal structure of a triple parallel interpenetrated copper coordination polymer based on a flexible bis(imidazole) ligand." Transition Metal Chemistry 38, no. 4 (2013): 407–12. http://dx.doi.org/10.1007/s11243-013-9705-9.

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30

Wang, Xiao Xiao, Ying Na Zhao, Guang Yue Li, and Guang Hua Cui. "Self-assembly of two 2D cobalt(II) coordination polymers constructed from 5-tert-butyl isophthalic acid and flexible bis(benzimidazole)-based ligands." Transition Metal Chemistry 39, no. 6 (2014): 653–60. http://dx.doi.org/10.1007/s11243-014-9846-5.

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31

Chen, Zhuo-Ling, Youzhen Dong, Qing-Wen Liu, et al. "Two coordination polymers based on mixed 1,4-bis(benzimidazo-1-yl)benzene and O-donor linker ligands: syntheses, crystal structures and properties." Transition Metal Chemistry 44, no. 5 (2019): 445–54. http://dx.doi.org/10.1007/s11243-019-00323-5.

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32

Zhang, Guo-Qi, Guo-Qiang Yang, Lin-Na Zhu, Qing-Qi Chen, and Jin-Shi Ma. "A potential fluorescent sensor for Zn2+ based on a selective bis-9-anthryldiamine ligand operating in buffer." Sensors and Actuators B: Chemical 114, no. 2 (2006): 995–1000. http://dx.doi.org/10.1016/j.snb.2005.08.014.

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33

Pan, Rong-Kai, Jiang-Li Song, Guo-Bi Li, San-Qing Lin, Sheng-Gui Liu, and Gui-Zhen Yang. "Copper(II), cobalt(II) and zinc(II) complexes based on a tridentate bis(benzimidazole)pyridine ligand: synthesis, crystal structures, electrochemical properties and antitumour activities." Transition Metal Chemistry 42, no. 3 (2017): 253–62. http://dx.doi.org/10.1007/s11243-017-0129-9.

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34

Tasada, Andres, Francisca M. Albertí, Antonio Bauzá, et al. "Metallomacrocycles as anion receptors: combining hydrogen bonding and ion pair based hosts formed from Ag(i) salts and flexible bis- and tris-pyrimidine ligands." Chemical Communications 49, no. 43 (2013): 4944. http://dx.doi.org/10.1039/c3cc40772a.

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35

Lin, Hong-Yan, Na Han, Xiu-Li Wang, Jian Luan, and Guo-Cheng Liu. "Two copper(II) complexes based on N,N′-bis(4-pyridinecarboxamide)-1,2-ethane and tricarboxylate ligands: a 5-fold interpenetrating 3 D network and a 1 D ribbon-like chain." Transition Metal Chemistry 39, no. 3 (2014): 343–51. http://dx.doi.org/10.1007/s11243-014-9807-z.

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36

Rodriguez-Zubiri, Mireia, Vito Gallo, Jacky Rosé, Richard Welter, and Pierre Braunstein. "Assembling metals and clusters around an octaphosphine ligand based on N-substituted bis(diphenylphosphanyl)amines: structural characterization of dendrimer-like Co12and Co16branched clusters." Chem. Commun., no. 1 (2008): 64–66. http://dx.doi.org/10.1039/b713540h.

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37

Braga, Dario, Marco Polito, Marco Bracaccini та ін. "Novel hetero-bimetallic metalla-macrocycles based on the bis-1-pyridyl ferrocene [Fe(η5-C5H4-1-C5H4N)2] ligand. Design, synthesis and structural characterization of the complexes [Fe(η5-C5H4-1-C5H4N)2](Agi)22+/(Cuii)24+/(Znii)24+". Chemical Communications, № 10 (18 квітня 2002): 1080–81. http://dx.doi.org/10.1039/b200344a.

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38

Leovac, Vukadin M., Vladimir Divjaković, Refik Fazlić, and Peter Engel. "Transition metal complexes with thiosemicarbazide-based ligands, Part IX. Cobalt(II) and nickel(II) complexes with 2-furaldehydeS-methylisothiosemicarbazone; crystal and molecular structure of aqua-bis(2-furaldehydeS-methylisothiosemicarbazone)cobalt(II)-diperchlorate." Transition Metal Chemistry 14, no. 2 (1989): 139–42. http://dx.doi.org/10.1007/bf01040609.

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39

Komuro, Takashi, та Hiromi Tobita. "Thermal reaction of a ruthenium bis(silyl) complex having a lutidine-based Si,N,Si ligand: formation of a μ-silyl(μ-silylene) diruthenium complex involving a 3c–2e Ru–Si–C interaction". Chemical Communications 46, № 7 (2010): 1136. http://dx.doi.org/10.1039/b915395k.

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40

Awal, Abdul, Md Mithu Mia, Shifa Sarkar, et al. "Fe(II)-Based Metallo-Supramolecular Polymer Film for Electrochemical Detection of Nitrite: Studies of Kinetics and Reaction Mechanisms." Journal of The Electrochemical Society, March 1, 2023. http://dx.doi.org/10.1149/1945-7111/acc01a.

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Abstract Here, a monometallic supramolecular polymer (SMP) was synthesized for the fabrication of an electrochemical nitrite sensor, and a mechanism for nitrite detection was proposed based on the experimental findings. The SMP (polyFe) was synthesized using a symmetrical ligand containing terpyridine moieties [4′,4′′′′-(1,4- Phenylene) bis(2,2′:6′,2′′-terpyridine)] and ferrous acetate. Various analytical methods, such as ultraviolet/visible titration, field-emission scanning electron microscopy, Fourier transform infrared spectroscopy, and energy dispersive X-ray spectroscopy, were used to ch

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41

Law, Wayne W. H., Voula Kanelis, and Deborah B. Zamble. "Biochemical studies highlight determinants for metal selectivity in the Escherichia coli periplasmic solute binding protein NikA." Metallomics, October 18, 2022. http://dx.doi.org/10.1093/mtomcs/mfac084.

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Abstract Nickel is an essential micronutrient for the survival of many microbes. On account of the toxicity of nickel and its scarcity in the environment, microbes have evolved specific systems for uptaking and delivering nickel to enzymes. NikA, the solute binding protein for the ATP binding cassette (ABC) importer NikABCDE, plays a vital role in the nickel homeostasis of Escherichia coli by selectively binding nickel over other metals in the metabolically complex periplasm. While the endogenous ligand for NikA is known to be the octahedral bis(L-histidinato)nickel(II) complex (Ni[II]-[L-His]

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42

Tobón Zapata, Gloria Elena, Dina Marcela Martínez Carmona, Gustavo Alberto Echeverría, and Oscar Enrique Piro. "Molecular structures of two copper complexes with the pharmaceuticals norfloxacin and tinidazole, when powder X-ray diffraction assists multi-domain single-crystal X-ray diffraction." Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 78, no. 3 (2022). http://dx.doi.org/10.1107/s2052520622003766.

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The crystal structures of bis[1-ethyl-6-fluoro-4-oxo-7-(piperazin-1-ium-4-yl)-1,4-dihydroquinoline-3-carboxylato]copper(II) sulfate heptahydrate, [Cu(C16H18FN3O3)2]SO4·7H2O or [Cu(nor)2]SO4·7H2O (nor is norfloxacin), and bis{1-[2-(ethylsulfonyl)ethyl]-2-methyl-5-nitroimide}dinitratocopper(II), [Cu(NO3)2(C8H13N3O4S)2] or [Cu(NO3)2(tnz)2] (tnz is tinidazole), were solved by X-ray diffraction. Both complexes crystallize in the space group P21/c, with Z = 4 (for nor) and Z = 2 (for ntz) molecules per unit cell. In [Cu(nor)2]SO4·7H2O, the CuII ion is at the centre of a square-planar environment, tr

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