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Dissertations / Theses on the topic 'Methacrylate monomers'

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1

Yong, Tuck Mun. "Controlled polymerisation of methacrylate monomers." Thesis, University of Cambridge, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.627136.

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2

Zwolak, Grzegorz Chemical Sciences &amp Engineering Faculty of Engineering UNSW. "Catalytic chain transfer polymerisation in C02-expanded monomers." Awarded by:University of New South Wales. Chemical Sciences & Engineering, 2009. http://handle.unsw.edu.au/1959.4/43548.

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Experimental data on the solubility of CO2 in methyl methacrylate (MMA) and butyl methacrylate (BMA) are reported at temperatures from 308 to 333 K and pressures in the range of 1 to 10 MPa. The corresponding measurements of the volumetric expansion of the liquid phase are also presented. The solubility data are correlated with the Peng-Robinson equation of state using two interaction parameters. Solubilities of CO2 as high as 80 mol% can be attained in both monomers in the range of pressure considered. A near-linear relationship is observed between pressure and liquid-phase composition. The P
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3

Topping, Clare. "The synthesis and polymerization of methacrylate macronomers." Thesis, University of Warwick, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.481545.

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4

Sinnathamby, Prash. "Synthesis and polymerisation of isotopically labelled methacrylate based monomers." Thesis, Durham University, 2000. http://etheses.dur.ac.uk/4519/.

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This thesis is concerned with the synthesis and polymerisation of isotopically labelled methacrylate based monomers. Chapter 2 describes the preparation of methyl [2-(^13)C]-and [3-(^13)C]-methacrylate via a Wittig-Homer type reaction and a diethyl malonate route respectively. The results of the free radical polymerisation of these monomers are discussed in Chapter 4. The presence of (^13)C-isotope in the resultant polymer enhanced the low intensity signals from the end groups in the (^13)C-NMR. However, more importantly, this study allowed us to investigate the presence of head to head links
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5

Kimani, Solomon Mbuthia. "Ambient-temperature copper catalysed controlled radical polymerisation of methacrylate monomers." Thesis, University of Cambridge, 2005. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.615100.

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6

Long, Timothy E. "Anionic synthesis and characterization of alkyl methacrylate containing polymeric systems." Diss., Virginia Polytechnic Institute and State University, 1987. http://hdl.handle.net/10919/74767.

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The anionic synthesis of alkyl methacrylates has received sparse attention in comparison to the synthesis of nonpolar hydrocarbon monomers such as styrene or the dienes. The two major reasons for the sluggish synthetic development of this class of polar monomers are the protic impurities present in most commercially available grades of monomer and the inherent side reactions associated with the ester functionality during anionic polymerization. However, by very carefully controlling various synthetic parameters and utilizing rigorously purified monomers, one can take advantage of the "living"
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7

Ashford, Emma J. "Synthesis of water-soluble polymers via atom transfer radical polymerisation." Thesis, University of Sussex, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.341539.

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A study of the atom transfer radical polymerisation (ATRP) of water-soluble, acidic, monomers was carried out in aqueous media. The ATRP of sodium methacrylate (MAANa) produced polymers with controlled molecular weights and narrow polydispersities (Me/M, - 1.3) at 90°C. This is the first reported example of direct polymerisation of an acidic monomer via ATRP. Previously, such acidic polymers were produced by polymerisation of protected monomers. In this thesis, copper(l) bromide and iron(II) bromide were investigated as ATRP catalysts. Both were found to be effective when solubilised by 2,2'-b
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8

Chen, Lan. "Polymerization of monomers within hoop pine to enhance harness for appearance grade applications /." [St. Lucia, Qld], 2004. http://www.library.uq.edu.au/pdfserve.php?image=thesisabs/absthe18196.pdf.

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9

Ho, Sze Man. "Injectable biodegradable poly(ester-co-ether) methacrylate monomers for bone tissue engineering and drug delivery applications." Thesis, University College London (University of London), 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.497785.

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10

Dove, Andrew Peter. "Novel-ß diketiminato compexes of tin, magnesium and zinc as initiators for the polymerisation of methyl methacrylate, lactide and other cyclic ester monomers." Thesis, Imperial College London, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.404562.

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11

Adhikari, Narendra M. "Sum Frequency Generation Vibrational Spectroscopic Study of Methacrylate-Based Monomers at the Solid-liquid Interface and Polymer Thin Films at Air-polymer and Polymer-liquid Interfaces." Ohio University / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1554387610814798.

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12

Söderqvist, Lindblad Margaretha. "Strategies for building polymers from renewable sources : Using prepolymers from steam treatment of wood and monomers from fermentation of agricultural products." Doctoral thesis, KTH, Fibre and Polymer Technology, 2003. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3554.

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<p>A strategic research area today is development of polymericproducts made from renewable sources. The ways of utilizingrenewable sources studied in this thesis are using 1)prepolymers obtained by steam treatment of wood and 2) monomersobtainable by fermentation of agricultural products.</p><p>Novel hemicellulose-based hydrogels were prepared by usingprepolymers obtained from steam treatment of spruce.Hemicellulose was first modified with well-defined amounts ofmethacrylic functions. Hydrogels were then prepared by radicalpolymerization with 2-hydroxyethyl methacrylate orpoly(ethylene glycol)
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13

Premadasa, Uvinduni I. "Insights into the Role of Structural Modification on the Surface Molecular Interactions Probed Using Sum Frequency Generation Spectroscopy." Ohio University / OhioLINK, 2020. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1578394424376667.

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14

Wang, Qian. "Effect of molecular order on photopolymerization behavior and polymer properties of liquid crystal monomers a dissertation /." San Antonio : UTHSC, 2008. http://proquest.umi.com.libproxy.uthscsa.edu/pqdweb?did=1594485671&sid=1&Fmt=2&clientId=70986&RQT=309&VName=PQD.

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15

Ono, Isamu. "Optimization of the Structure of Benzocyclobutene Containing Methacrylate Monomer for Controlled Radical Polymerization." University of Akron / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=akron1468500945.

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16

Lomege, Juliette. "Synthèse d'additifs améliorant d'indice de viscosité issus de poly(méthacrylate de n-alkyle)s d'acides gras et leur application dans des huiles lubrifiantes." Electronic Thesis or Diss., Montpellier, Ecole nationale supérieure de chimie, 2018. http://www.theses.fr/2018ENCM0008.

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Les huiles lubrifiantes actuelles sont formulées avec des additifs de type « Viscosity Index Improver » (VII) afin de limiter la variation de leur viscosité avec la montée en température et de conserver ainsi leurs propriétés lubrifiantes à chaud. Les VIIs sont des polymères de hautes masses molaires, disposant d’une faible solubilité dans les huiles à froid, qui ont la capacité d’augmenter davantage la viscosité d’une huile à haute qu’à basse températures via le mécanisme de « coil expansion ». Actuellement, les poly(méthacrylate de n-alkyle)s (PMA)s dominent le marché des additifs VII mais s
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17

Omosa, Haron Moeti. "Studies on Several Diacetone-Glucose-derived Esters." Youngstown State University / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1628676922903541.

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18

Applin, Samantha. "Surfactant Free Emulsion Polymerization of Poly(Styrene-Co-Methyl Methacrylate): Correlation of Microsphere Characteristics with Monomer Reactivity and Water Solubility." W&M ScholarWorks, 2017. https://scholarworks.wm.edu/etd/1530192354.

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Polymeric microspheres have been used in a broad range of applications from chromatographic separation techniques to analysis of air flow over aerodynamic surfaces. The preparation of microspheres from many polymer families has consequently been extensively studied using a variety of synthetic approaches. Although there are a myriad of polymeric microsphere synthesis methods, free-radical initiated emulsion polymerization is one of the most common techniques. In this work, poly(styrene-co-methyl methacrylate) microspheres were synthesized via surfactant-free emulsion polymerization. The effect
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19

Martins, Aurealice Rosa Maria 1986. "Influence of diluent isobornyl methacrylate monomer (IBOMA) on physico-mechanical properties of experimental resin = Influência do monômetro diluente isobornil metacrilato (IBOMA) em propriedades físico-mecânicas de resinas experimentais." [s.n.], 2013. http://repositorio.unicamp.br/jspui/handle/REPOSIP/290387.

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Orientador: Mário Alexandre Coelho Sinhoreti<br>Texto em português e inglês<br>Dissertação (mestrado) - Universidade Estadual de Campinas, Faculdade de Odontologia de Piracicaba<br>Made available in DSpace on 2018-08-22T12:41:50Z (GMT). No. of bitstreams: 1 Martins_AurealiceRosaMaria_M.pdf: 1504844 bytes, checksum: 8845f1f591540a2f3ae0518e7fc047e2 (MD5) Previous issue date: 2013<br>Resumo: O objetivo neste estudo foi avaliar a utilização do isobornil metacrilato (IBOMA) como monômero diluente associado ou não ao TEGDMA, em resinas experimentais à base de Bis-GMA. No Capítulo 1, o grau de con
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20

Damay, Jérémie. "Développement de nouveaux traitements du bois basés sur le procédé d'imprégnation axiale." Thesis, Université de Lorraine, 2014. http://www.theses.fr/2014LORR0178/document.

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L’évolution des lois relatives à l’utilisation de produits biocides impose d’étudier des méthodes innovantes de traitement du bois. Dans ce contexte, les travaux de recherche présentés s’intéressent à une nouvelle alternative dite « non-biocide » impliquant la fabrication de composites bois massif / polymères obtenus par imprégnation de monomères et polymérisation in situ provoquée par chauffage. Le méthacrylate de méthyle, quatre acrylates organiques et trois acrylates hydrosolubles, ainsi que l’alcool furfurylique ont été testés. Les composites fabriqués ont été caractérisés : le polymère es
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21

Menard, Raphaël. "Synthèse de retardateurs de flamme phosphorés biosourcés pour résines époxy Synthesis of biobased phosphate flame retardants Synthesis of biobased phosphorus-containing flame retardants for epoxy thermosets Comparison of additive and reactive approaches From bio-based phosphorus-containing epoxy monomer to fully bio-based flame-retarded thermosets Synthesis of new flame-retardants by radical chain transfer copolymerization of glycidyl methacrylate and dimethoxy-phosphorylmethyl methacrylate." Thesis, Montpellier, Ecole nationale supérieure de chimie, 2015. http://www.theses.fr/2015ENCM0013.

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La toxicité avérée et le caractère bio-accumulatif des retardateurs de flamme halogénés usuels (PBDE) ont entrainé la mise en place de restrictions d'usage au sein de l'union européenne (REACH). Les retardateurs de flamme phosphorés (RFP) se sont imposés comme alternatives aux solutions halogénées pour leur moindre toxicité et leurs propriétés ignifugeantes adaptées à la composition chimique des résines époxy. Avec l'essor des résines époxy biosourcées, la dépendance aux ressources fossiles pour la synthèse des additifs en tout genre qui entre dans leur composition est devenue problématique. A
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22

Faria, Marisa Camacho Gonçalves. "New bacterial cellulose nanocomposites prepared by in situ radical polymerization of methacrylate monomers." Master's thesis, 2015. http://hdl.handle.net/10400.13/1151.

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Bacterial cellulose/polymethacrylate nanocomposites have received attention in numerous areas of study and in a variety of applications. The attractive properties of methacrylate polymers and bacterial cellulose, BC, allow the synthesis of new nanocomposites with distinct characteristics. In this study, BC/poly(glycidylmethacrylate) (BC/PGMA) and BC/poly(ethyleneglycol)methacrylate (BC/PPEGMA) nanocomposites were prepared through in situ free radical polymerization of GMA and PEGMA, respectively. Ammonium persulphate (APS) was used as an initiator and N,N’methylenebisacrilamide (MBA) was used
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23

Chen, Chia-Yin, and 陳佳吟. "Novel Multifunctional Methacrylate Monomers and Their Visible-light Cured Polymer/SiO2 Hybrids as Dental Restorative Materials." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/64540468596724519274.

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碩士<br>國立臺灣大學<br>化學工程學研究所<br>94<br>The novel multifunctional methacrylates were prepared by the reaction between the hydroxyl groups of the epoxy-acrylate resin (EA) and the isocyanate groups of the diisocyanate, such as toluene-2, 4-diisocyanate (TDI), 1,6-Diisocyanatohexane (HDI) or isophorone diisocyanate (IPDI) , which were pre-reacted with 2-hydroxyethyl- methacrylate (HEMA) with 2:1 equivalent ratio, and utilized as the dental monomers. By varying the molar ratios between the hydroxyl groups of EA and the isocyanate groups of diisocyanate, the methacrylaes with three types of different f
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24

Lin, Yu Hsiang, and 林于翔. "Synthesis and characterization of phosphorous containing methacrylate monomers, curing with epoxy and studied their polymers properties." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/6pdk62.

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碩士<br>國立中興大學<br>化學工程學系所<br>106<br>In this experiment, two low-cost, higher phosphorus-containing bisphenol monomers were synthesized by a two-step reaction using low-cost DOPO, acetone, and resorcinol (or catechol). The hydroxyl structure in the monomer was modified with methacrylic anhydride and cured with commercially available epoxy resin, HP7200. At the same time of curing, the methacrylic group will also undergo self-crosslinking and solidification to achieve its higher crosslinking density, which gives the corresponding polymer the enhanced thermal properties. The cured polymers were tes
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25

Jayanthi, S. "Oxidative Copolymerization Of Vinylmonomers : Studies On The Microstructure And Reactivities Of The Copolyperoxides." Thesis, 1995. http://etd.iisc.ernet.in/handle/2005/1840.

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26

Bantshi, Minga Alain. "Gelcasting of alumina and alumina-cBN using 2-hydroxyethyl methacrylate as monomer." Thesis, 2009. http://hdl.handle.net/10539/7238.

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27

Chang, Yih-Her, and 張義和. "Sulfonated Tetracarboxylic Polyester (SMTAPE) Emulsifier:Synthesis, Surfactant Characteristics, and Studies on The Emulsion Polymerization of Butyl Methacrylate/Styrene Monomer." Thesis, 1999. http://ndltd.ncl.edu.tw/handle/02331666243821373135.

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博士<br>國立清華大學<br>化學工程學系<br>87<br>A novel polymeric emulsifier, SSIPM modified tetracarboxylic acid terminated polyester (SMTAPE)was prepared by end-capping sulfopolyester polyol with TMA in this study. The surface characteristics of SMTAPE, the optimum hydrophobic length of SMTAPE for the emulsion polymerization of PBMA, the nucleation mechanism and the surface area occupied by a SMTAPE molecule on a polymer latex particle at room temperatuve were studied by analyzing the surfactant characteristics, the reaction kinetic and the stability of the latices, the consumption of SMTAPE emulsifier duri
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28

Chen, Chi-Wei, and 陳紀瑋. "A Study on Effects of The Monomer Content, Photocuring Time and Visible-Light Intensity in Cured Resins of Bis-phenol A Diglycidyl Methacrylate and Triethylene Glycol Dimethacrylate." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/13178587503728868445.

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碩士<br>國立臺灣科技大學<br>材料科學與工程系<br>103<br>Adhesives were prepared by using various mole ratios of bis-phenol A diglycidyl methacrylate(BisGMA)(50~80 mol%) and triethylene glycol dimethacrylate (TEGDMA) (20~50 mol%) in feed, with camphorquinone (CQ) and diphenylphosphine oxide as the photoinitiators. We use the different photocuring times (2~6 mins) and different light intensities (600~1800 mW/cm2) of visible light. We examine the effects of BisGMA/TEGDMA mole ratios in feed, photocuring times and light intensities on conversion of reaction, and how crosslink density and conversion of reaction affec
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