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Journal articles on the topic 'Methanol-water'

Author: Grafiati

Published: 18 May 2024

Last updated: 31 July 2025

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1

Fileti, Eudes E., and Sylvio Canuto. "Calculated infrared spectra of hydrogen-bonded methanol-water, water-methanol, and methanol-methanol complexes." International Journal of Quantum Chemistry 104, no. 5 (2005): 808–15. http://dx.doi.org/10.1002/qua.20585.

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2

Barraclough, Colin G., Peter T. McTigue, and Y. Leung Ng. "Surface potentials of water, methanol and water + methanol mixtures." Journal of Electroanalytical Chemistry 329, no. 1-2 (1992): 9–24. http://dx.doi.org/10.1016/0022-0728(92)80205-i.

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3

Kurihara, Kiyofumi, Tsuyoshi Minoura, Kouichi Takeda, and Kazuo Kojima. "Isothermal Vapor-Liquid Equilibria for Methanol + Ethanol + Water, Methanol + Water, and Ethanol + Water." Journal of Chemical & Engineering Data 40, no. 3 (1995): 679–84. http://dx.doi.org/10.1021/je00019a033.

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4

Masella, Michel, and Jean Pierre Flament. "Relation between cooperative effects in cyclic water, methanol/water, and methanol trimers and hydrogen bonds in methanol/water, ethanol/water, and dimethylether/water heterodimers." Journal of Chemical Physics 108, no. 17 (1998): 7141–51. http://dx.doi.org/10.1063/1.476131.

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5

Ratanakandilok, S. "Coal desulfurization with methanol/water and methanol/KOH." Fuel and Energy Abstracts 43, no. 4 (2002): 236. http://dx.doi.org/10.1016/s0140-6701(02)86071-4.

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6

Ratanakandilok, S., S. Ngamprasertsith, and P. Prasassarakich. "Coal desulfurization with methanol/water and methanol/KOH." Fuel 80, no. 13 (2001): 1937–42. http://dx.doi.org/10.1016/s0016-2361(01)00047-3.

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7

Rived, Fernando, Immaculada Canals, Elisabeth Bosch, and Martı́ Rosés. "Acidity in methanol–water." Analytica Chimica Acta 439, no. 2 (2001): 315–33. http://dx.doi.org/10.1016/s0003-2670(01)01046-7.

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8

Tian, Gang, Cong Yang, Xiaoxia Li, et al. "Determination and correlation of refractive index of three binary and ternary systems containing hydroxyl ionic liquids/ water/methanol." Materials Express 10, no. 4 (2020): 469–78. http://dx.doi.org/10.1166/mex.2020.1667.

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In this paper, the refractive index of methanol + water, [HOEMIm]Cl + methanol, [HOEMMIm]Cl + methanol, [OHEN1,1,1]Cl + methanol, [HOEMIm]Cl + water, [OHEN1,1,1]Cl + water, [HOEMMIm]Cl + water, [OHEN1,1]Cl + water, [HOEMIm]Cl + methanol + water, [HOEMMIm]Cl + methanol + water and [OHEN1,1,1]Cl+methanol+water at different temperatures were determined by refractometer. The physical database of hydroxyl ionic liquids was enriched, and the excess refractive index of these systems was obtained by calculation. The relationship between the refractive index or the excess refractive index and the compo

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9

Sun, Tong, Gerald Wilemski, Barbara N. Hale, and Barbara E. Wyslouzil. "The effects of methanol clustering on methanol–water nucleation." Journal of Chemical Physics 157, no. 18 (2022): 184301. http://dx.doi.org/10.1063/5.0120876.

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The formation of subcritical methanol clusters in the vapor phase is known to complicate the analysis of nucleation measurements. Here, we investigate how this process affects the onset of binary nucleation as dilute water–methanol mixtures in nitrogen carrier gas expand in a supersonic nozzle. These are the first reported data for water–methanol nucleation in an expansion device. We start by extending an older monomer–dimer–tetramer equilibrium model to include larger clusters, relying on Helmholtz free energy differences derived from Monte Carlo simulations. The model is validated against th

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10

Buettner, Joerg, Maritza Gutierrez, and A. Henglein. "Sonolysis of water-methanol mixtures." Journal of Physical Chemistry 95, no. 4 (1991): 1528–30. http://dx.doi.org/10.1021/j100157a004.

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11

Boukis, N., V. Diem, W. Habicht, and E. Dinjus. "Methanol Reforming in Supercritical Water." Industrial & Engineering Chemistry Research 42, no. 4 (2003): 728–35. http://dx.doi.org/10.1021/ie020557i.

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12

Kooi, J. "The system methylmethacrylate - methanol - water." Recueil des Travaux Chimiques des Pays-Bas 68, no. 1 (2010): 34–42. http://dx.doi.org/10.1002/recl.19490680103.

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13

Vaidya, Pravin S., and Raghavendra V. Naik. "Liquid−Liquid Equilibria for the Epichlorohydrin + Water + Methanol and Allyl Chloride + Water + Methanol Systems." Journal of Chemical & Engineering Data 48, no. 4 (2003): 1015–18. http://dx.doi.org/10.1021/je034018b.

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14

Wang, C. H., K. L. Pan, G. J. Ueng, L. J. Kung, and J. Y. Yang. "Burning behaviors of collision-merged water/diesel, methanol/diesel, and water+methanol/diesel droplets." Fuel 106 (April 2013): 204–11. http://dx.doi.org/10.1016/j.fuel.2012.12.022.

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15

Xu, Changchun, and Haengmuk Cho. "Effect of Methanol/Water Mixed Fuel Compound Injection on Engine Combustion and Emissions." Energies 14, no. 15 (2021): 4491. http://dx.doi.org/10.3390/en14154491.

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Due to the recent global increase in fuel prices, to reduce emissions from ground transportation and improve urban air quality, it is necessary to improve fuel efficiency and reduce emissions. Water, methanol, and a mixture of the two were added at the pre-intercooler position to keep the same charge and cooling of the original rich mixture, reduce BSFC and increase ITE, and promote combustion. The methanol/water mixing volume ratios of different fuel injection strategies were compared to find the best balance between fuel consumption, performance, and emission trends. By simulating the combus

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16

Zhai, Yanqin, Peng Luo, Jackson Waller, et al. "Dynamics of molecular associates in methanol/water mixtures." Physical Chemistry Chemical Physics 24, no. 4 (2022): 2287–99. http://dx.doi.org/10.1039/d1cp04726d.

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The nanoscopic mutual diffusion coefficient, DMn, of a methanol/water mixture is smaller than the single particle diffusion coefficient of either methanol or water, indicating the existence of dynamic associates of water and methanol molecules.

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17

Vašková, Hana, and Martin Tomeček. "Rapid spectroscopic measurement of methanol in water-ethanol-methanol mixtures." MATEC Web of Conferences 210 (2018): 02035. http://dx.doi.org/10.1051/matecconf/201821002035.

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The paper is focused on the Raman spectroscopic analysis of methanol content in water-ethanol-methanol mixtures as this kind of mixture chemically closely relates to alcoholic drinks. Counterfeit alcoholic drinks represent losses to the economy, but especially can cause serious health risks starting from nausea, to blindness, and even death. Extensive methanol poisonings were reported in last decades in number of countries worldwide. A set of water-ethanol-methanol mixtures with a range of concentrations of methanol from 0 % to 100 % was prepared to obtain the calibration dataset, needful for

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18

Isdale, J. D., A. J. Easteal, and L. A. Woolf. "Shear viscosity of methanol and methanol + water mixtures under pressure." International Journal of Thermophysics 6, no. 5 (1985): 439–50. http://dx.doi.org/10.1007/bf00508889.

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19

Alfenaar, M., and C. L. de Ligny. "The universal pH-scale in methanol and methanol-water mixtures." Recueil des Travaux Chimiques des Pays-Bas 86, no. 11 (2010): 1185–90. http://dx.doi.org/10.1002/recl.19670861104.

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20

Cassone, Giuseppe, Adriano Sofia, Jiri Sponer, A. Marco Saitta, and Franz Saija. "Ab Initio Molecular Dynamics Study of Methanol-Water Mixtures under External Electric Fields." Molecules 25, no. 15 (2020): 3371. http://dx.doi.org/10.3390/molecules25153371.

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Intense electric fields applied on H-bonded systems are able to induce molecular dissociations, proton transfers, and complex chemical reactions. Nevertheless, the effects induced in heterogeneous molecular systems such as methanol-water mixtures are still elusive. Here we report on a series of state-of-the-art ab initio molecular dynamics simulations of liquid methanol-water mixtures at different molar ratios exposed to static electric fields. If, on the one hand, the presence of water increases the proton conductivity of methanol-water mixtures, on the other, it hinders the typical enhanceme

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21

Noskov, S. Y., M. G. Kiselev, A. M. Kolker, and B. M. Rode. "Structure of methanol-methanol associates in dilute methanol-water mixtures from molecular dynamics simulation." Journal of Molecular Liquids 91, no. 1-3 (2001): 157–65. http://dx.doi.org/10.1016/s0167-7322(01)00157-x.

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22

Pálinkás, G., and I. Bakó. "Excess Properties of Water-Methanol Mixtures as Studied by MD Simulations." Zeitschrift für Naturforschung A 46, no. 1-2 (1991): 95–99. http://dx.doi.org/10.1515/zna-1991-1-215.

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AbstractMolecular dynamics simulations with pair interactions reproduce experimental excess properties of methanol-water mixtures. Water molecules lose, and methanol molecules gain neighbours in the mixtures as compared to the solvents. The water-methanol mixture with 0.25 mole fraction of methanol, resulting in extreme values for different excess properties, is characterized by the highest number of molecules with maximal number of H-bonded neighbours.

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23

VIJAYALAKSHMI, S., C. P. VINOD, and G. U. KULKARNI. "A METHANOL–WATER COMPLEX STABILIZED ON A Zn(0001) SURFACE." Surface Review and Letters 10, no. 01 (2003): 87–94. http://dx.doi.org/10.1142/s0218625x0300469x.

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Coadsorption of water and methanol on a clean Zn(0001) surface has been investigated by employing X-ray photoelectron spectroscopy after exposing the surface at 80 K to the binary vapor from water–methanol liquid mixtures of varying compositions and subsequently warming the surface up to the room temperature. When the surface was exposed to the vapor from a mixture with water molefraction, xw, of 0.5, the proton abstraction and the C–O bond cleavage in methanol leading to methoxy (CH3O) and the hydrocarbon ( CH x) species respectively, occurs at a much higher temperature of 180 K, compared to

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24

Taghavi, Toktam, Hiral Patel, Omololu E. Akande, and Dominique Clark A. Galam. "Total Anthocyanin Content of Strawberry and the Profile Changes by Extraction Methods and Sample Processing." Foods 11, no. 8 (2022): 1072. http://dx.doi.org/10.3390/foods11081072.

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Anthocyanins are the primarily pigments in many flowers, vegetables, and fruits and play a critical role in human and plant health. They are polyphenolic pigments that are soluble in water and usually quantified by spectrophotometric methods. The two main methods that quantify anthocyanins are pH differential and organic solvent-based methods. Our hypothesis was that these methods extract different anthocyanin profiles. Therefore, this experiment was designed to identify anthocyanin profiles that are extracted by pH differential and organic solvent-based methods and observe their total anthocy

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25

Haniš, Tomáš, Miroslav Smrž, Pavel Klír, Karel Macek, and Zdeněk Deyl. "Improved separation of C12-C22 fatty acid phenacyl esters by reversed phase column liquid chromatography." Collection of Czechoslovak Chemical Communications 51, no. 12 (1986): 2722–26. http://dx.doi.org/10.1135/cccc19862722.

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Phenacyl esters of C12-C22 fatty acids were separated on Separon SGX C18 column, using a gradient elution with methanol-acetonitrile-water. The proposed gradient showed better resolution of the critical pairs C18:3-C14:0, C16:1-C20:4, and C16:0-C18:1 than the gradient elution with methanol-water or acetonitrile-water, or than the isocratic elution with methanol-acetonitrile-water. The optimum volume concentration (83%) of the sum of both methanol and acetonitrile was maintained constant for 35 min; in this period the acetonitrile concentration decreased linearly from the initial 42-60% to 0% w

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26

Takamuku, Toshiyuki, Toshio Yamaguchia, Masaki Asato, Masaki Matsumoto, and Nobuyuki Nishi. "Structure of Clusters in Methanol-Water Binary Solutions Studied by Mass Spectrometry and X-ray Diffraction." Zeitschrift für Naturforschung A 55, no. 5 (2000): 513–25. http://dx.doi.org/10.1515/zna-2000-0507.

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Abstract The structure of clusters in methanol-water solutions in its dependence on the methanol mole fraction xM has been investigated by mass spectrometry on clusters isolated from submicron droplets by adiabatic expansion in vacuum and by X-ray diffraction on the bulk binary solutions. The mass spectra have shown that the average hydration number, (nm), of m-mer methanol clusters decreases with increasing xM , accompanied by two inflection points at xM = ~0.3 and ~0.7. The X-ray diffraction data have revealed a similar change in the number of hydrogen bonds per water and/or methanol oxygen

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27

AGUSTINA, EVA. "UJI AKTIVITAS SENYAWA ANTIOKSIDAN DARI EKSTRAK DAUN TIIN (Ficus Carica Linn) DENGAN PELARUT AIR, METANOL DAN CAMPURAN METANOL-AIR." KLOROFIL: Jurnal Ilmu Biologi dan Terapan 1, no. 1 (2017): 38. http://dx.doi.org/10.30821/kfl:jibt.v1i1.1240.

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<p>Antioxidants can ward off free radicals in the body to resist oxidative damage caused by free radicals. The aim of this research is to know the influence of water solvent, methanol and methanol-water mixture to antioxidant activity. The extraction is done by maceration method. The extraction results in the phytochemical test and functional group analysis to determine the compounds contained in Pig leaf extract. Further testing of antioxidant activity with DPPH method. Pig leaf extract with methanol solvent has antioxidant activity with IC50 3,3005 μg / ml value, Pig leaf extract with

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28

Pytela, Oldřich, Taťjana Nevěčná, and Jaromír Kaválek. "Reactivity of proton and general acid with 1,3-bis-(4-methylphenyl)triazene in aqueous methanol." Collection of Czechoslovak Chemical Communications 55, no. 11 (1990): 2701–6. http://dx.doi.org/10.1135/cccc19902701.

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The effect of concentration of benzoic acid and composition of the binary solvent water-methanol on the rate of decomposition of 1,3-bis(4-methylphenyl)triazene has been studied. It has been found that both general acid catalysis by undissociated benzoic acid and catalysis by the proton are significant. The rate constant kHA of general acid catalysis decreases monotonously with decreasing amount of water in the mixture due to preferred solvation of the activated complex as compared with the educts. The rate constant kH of the catalysis by proton in its dependence on methanol concentration exhi

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29

Marenco, Leonardo Fabio León, Luiza Pereira de Oliveira, Daniella Lopez Vale, and Maiara Oliveira Salles. "Predicting Vodka Adulteration: A Combination of Electronic Tongue and Artificial Neural Networks." Journal of The Electrochemical Society 168, no. 11 (2021): 117513. http://dx.doi.org/10.1149/1945-7111/ac393e.

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An artificial neural network was used to build models caple of predicting and quantifying vodka adulteration with methanol and/or tap water. A voltammetric electronic tongue based on gold and copper microelectrodes was used, and 310 analyses were performed. Vodkas were adulterated with tap water (5 to 50% (v/v)), methanol (1 to 13% (v/v)), and with a fixed addition of 5% methanol and tap water varying from 5 to 50% (v/v). The classification model showed 99.5% precision, and it correctly predicted the type of adulterant in all samples. Regarding the regression model, the root mean squared error

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30

Feibert, E. B. G., S. R. James, K. A. Rykbost, A. R. Mitchell, and C. C. Shock. "Potato Yield and Quality Not Changed by Foliar-applied Methanol." HortScience 30, no. 3 (1995): 494–95. http://dx.doi.org/10.21273/hortsci.30.3.494.

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Previously published research suggests that the yield and water-use efficiency of C-3 plants can be enhanced through foliar-applied methanol. Potatoes (Solanum tuberosum L. cv. Russet Burbank) grown in Oregon at Klamath Falls, Madras, and Ontario were subjected to repeated foliar methanol treatments during the 1993 season. Methanol was applied at 20%, 40%, and 80% concentration with Triton X-100 sticker-spreader at 0.1%, and methanol was applied at 20% and 40% without Triton X-100. Methanol had no effect on tuber yield, size distribution, grade, or specific gravity at any location. Tuber stem-

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31

Inaba, Satoshi. "Acid–Base Catalytic Effects on Reduction of Methanol in Hot Water." Catalysts 9, no. 4 (2019): 373. http://dx.doi.org/10.3390/catal9040373.

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We have performed a number of quantum chemical simulations to examine the reduction process of methanol in hot water. Methanol is converted into a methane by capturing a hydrogen molecule and leaving a water molecule behind. The required energy for the reduction is too high to proceed in the gas phase. The energy barrier for the reduction of methanol is reduced by the catalytic effect of water molecules when we consider the reduction in aqueous solution. However, the calculated reduction rate is still much slower than that found experimentally. The ion product of water tends to increase in hot

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32

Kostko, Oleg, Leonid Belau, Kevin R. Wilson, and Musahid Ahmed. "Vacuum-Ultraviolet (VUV) Photoionization of Small Methanol and Methanol−Water Clusters†." Journal of Physical Chemistry A 112, no. 39 (2008): 9555–62. http://dx.doi.org/10.1021/jp8020479.

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33

You, Shujie, Junchun Yu, Bertil Sundqvist, et al. "Selective Intercalation of Graphite Oxide by Methanol in Water/Methanol Mixtures." Journal of Physical Chemistry C 117, no. 4 (2013): 1963–68. http://dx.doi.org/10.1021/jp312756w.

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34

Yang, Wenshao, Zhenhua Geng, Qing Guo, Dongxu Dai, and Xueming Yang. "Effect of Multilayer Methanol and Water in Methanol Photochemistry on TiO2." Journal of Physical Chemistry C 121, no. 32 (2017): 17244–50. http://dx.doi.org/10.1021/acs.jpcc.7b04224.

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35

Ullah, Aubaid, Nur Awanis Hashim, Mohamad Fairus Rabuni, and Mohd Usman Mohd Junaidi. "A Review on Methanol as a Clean Energy Carrier: Roles of Zeolite in Improving Production Efficiency." Energies 16, no. 3 (2023): 1482. http://dx.doi.org/10.3390/en16031482.

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Clean methanol can play an important role in achieving net zero emission targets by decarbonizing the energy and chemical sectors. Conventionally, methanol is produced by using fossil fuel as raw material, which releases a significant amount of greenhouse gases (GHGs) into the environment. Clean methanol, which is produced by hydrogen (H2) from renewable sources (green H2) and captured carbon dioxide (CO2), is totally free from the influence of fossil fuel. Due to its vast applications, clean methanol has potential to substitute for fossil fuels while preventing further GHGs emissions. This re

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36

Freakley, Simon J., Nikolaos Dimitratos, David J. Willock, Stuart H. Taylor, Christopher J. Kiely, and Graham J. Hutchings. "Methane Oxidation to Methanol in Water." Accounts of Chemical Research 54, no. 11 (2021): 2614–23. http://dx.doi.org/10.1021/acs.accounts.1c00129.

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37

Bo, ZHENG, LI He-Xian, WANG Guo-Chang, et al. "Supramolecular Complexation in Water-Methanol Mixtures." Acta Physico-Chimica Sinica 24, no. 08 (2008): 1503–6. http://dx.doi.org/10.3866/pku.whxb20080830.

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38

Mallamace, Francesco, Carmelo Corsaro, Domenico Mallamace, Cirino Vasi, Sebastiano Vasi, and H. Eugene Stanley. "Dynamical properties of water-methanol solutions." Journal of Chemical Physics 144, no. 6 (2016): 064506. http://dx.doi.org/10.1063/1.4941414.

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39

Szuromi, Phil. "A water boost for methanol synthesis." Science 368, no. 6490 (2020): 484.5–485. http://dx.doi.org/10.1126/science.368.6490.484-e.

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40

Endo, Harumi, Kenji Saijou, and Gordon Atkinson. "Sound absorption in water-methanol mixtures." Journal of the Acoustical Society of Japan (E) 13, no. 2 (1992): 85–90. http://dx.doi.org/10.1250/ast.13.85.

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41

Yan, Hong-Lei, Zhi-Min Zong, Wei-Wei Zhu, et al. "Poplar Liquefaction in Water/Methanol Cosolvents." Energy & Fuels 29, no. 5 (2015): 3104–10. http://dx.doi.org/10.1021/ef502518n.

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42

Flörke, Ulrich, Wahyudi Priyono Suwarso, Ratna Layla Gani, Karsten Krohn, and Si Wang. "Dasypogalactone–methanol–water (1/2/1)." Acta Crystallographica Section E Structure Reports Online 59, no. 5 (2003): o638—o640. http://dx.doi.org/10.1107/s1600536803008055.

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43

Xu, Bei-Bei, Min Zhou, Ran Zhang, et al. "Solvent Water Controls Photocatalytic Methanol Reforming." Journal of Physical Chemistry Letters 11, no. 9 (2020): 3738–44. http://dx.doi.org/10.1021/acs.jpclett.0c00972.

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44

Savage, Phillip E., Ruokang Li, and John T. Santini. "Methane to methanol in supercritical water." Journal of Supercritical Fluids 7, no. 2 (1994): 135–44. http://dx.doi.org/10.1016/0896-8446(94)90050-7.

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45

Barylka, A. G., and R. M. Balabai. "Graphene Wetting by Methanol or Water." Ukrainian Journal of Physics 60, no. 10 (2015): 1049–54. http://dx.doi.org/10.15407/ujpe60.10.1049.

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46

Green, Gary J., and Tsoung Y. Yan. "Water tolerance of gasoline-methanol blends." Industrial & Engineering Chemistry Research 29, no. 8 (1990): 1630–35. http://dx.doi.org/10.1021/ie00104a009.

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47

Pestov, Dmitry, Miaochan Zhi, Zoe-Elizabeth Sariyanni, et al. "Femtosecond CARS of methanol-water mixtures." Journal of Raman Spectroscopy 37, no. 1-3 (2006): 392–96. http://dx.doi.org/10.1002/jrs.1482.

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48

Rao, R. Jagannadha, and C. Venkata Rao. "Ternary liquid equilibria: Methanol-water-esters." Journal of Applied Chemistry 7, no. 8 (2007): 435–39. http://dx.doi.org/10.1002/jctb.5010070804.

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49

Stouten, Pieter F. W., and J. Kroon. "Computation Confirms Contraction: A Molecular Dynamics Study of Liquid Methanol, Water and a Methanol-Water Mixture." Molecular Simulation 5, no. 3-4 (1990): 175–79. http://dx.doi.org/10.1080/08927029008022129.

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50

Schick, Bernhard, Pran N. Moza, Klaus Hustert, and Antonius Kettrup. "Photochemistry of vinclozolin in water and methanol-water solution." Pesticide Science 55, no. 11 (1999): 1116–22. http://dx.doi.org/10.1002/(sici)1096-9063(199911)55:11<1116::aid-ps65>3.0.co;2-y.

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