Academic literature on the topic 'Methyl aniline'

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Journal articles on the topic "Methyl aniline"

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Ge, Hui Lin, Shu Shen Liu, Peng Zhou, Yao Wan, Yan Ling Zhang, and Ling Yun Mo. "Assessment and Prediction of Mixture Effects of Four Different Types of Organic Pollutants on Photobacterium." Applied Mechanics and Materials 448-453 (October 2013): 277–80. http://dx.doi.org/10.4028/www.scientific.net/amm.448-453.277.

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The low-dose and combined effects of aniline, 2-methyl-aniline, 3-methyl-aniline, 4-methyl-aniline, nitrobenzene, 4-methyl-nitrobenzene, phenol, 2-methyl-phenol, 3-methyl-phenol, 4-methyl-phenol, dimethyl phthalate, and diethyl phthalate on photobacterium Vibrio qinghaiensis were predicted and evaluated by using concentration addition and independent action models. The mixture effects can be predicted by concentration addition and independent action models. Combined effect of environmental pollutants should be considered in risk assessment practice.
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Sharma, V. K., Prem Paul Singh, Sanjeev Maken, and B. Singh. "Topological investigations of aniline and substituted anilines in binary solutions containing methylene bromide." Canadian Journal of Chemistry 71, no. 12 (1993): 2183–88. http://dx.doi.org/10.1139/v93-273.

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Molar excess volumes and molar excess enthalpies for various (i + j) binary methylene bromide (i) + aniline or N-methyl aniline and + N,N-dimethyl aniline (j) mixtures have been determined as a function of composition at 308.15 K. The data have been analysed in terms of the graph-theoretical approach and Sanchez and Lacombe theory. The graph-theoretical analyses of VE data suggest that aniline, N-methyl aniline, and N,N-dimethyl aniline exist as equilibrium mixtures of monomer and dimer and that these mixtures contain 1:1 molecular complexes. The IR studies lend further credence to the nature
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Kiricojevic, Vesna, Milovan Ivanovic, I. V. Micovic, J. B. Djordjevic, Goran Roglic, and Ljiljana Dosen-Micovic. "An optimized synthesis of a key pharmaceutical intermediate methyl 4-[(1-oxopropyl)phenylamino]piperidine-4-carboxylate." Journal of the Serbian Chemical Society 67, no. 12 (2002): 793–802. http://dx.doi.org/10.2298/jsc0212793k.

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An efficient synthesis of methyl 4-[(1-oxopropyl)phenylamino]piperidine-4-carboxylate (7) has been developed starting from 1-benzylpiperidin-4-one (1). The compound is a key intermediate in the synthesis of new generation, highly active narcotic analgesics, such as remifintanil, as well as the novel classes of fentanyl analogues. An optimized Strecker-type condensation of piperidone 1 with aniline and HCN yielded the anilino-nitrile 2(?90%) which, upon selective hydrolysis with conc. H2SO4, gave the anilino-amide 3.After vigorous basic hydrolysis of 3, followed by acidification and successive
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Yunnikova, Lidiya P., Yuliya E. Likhareva, and Svetlana Yu Balandina. "N-TROPYLATION OF ARYLAMINES." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 62, no. 2 (2019): 79–84. http://dx.doi.org/10.6060/ivkkt.20196202.5751.

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An efficient method for introduction of biogenic tropylium cycle into aromatic amines molecules is offered. Introduction is carried out in the presence of imidazole as a strong base. Interaction between tropylium salts (tetrafluoroborate or perchlorate) and aromatic amines with either nitro- or acetyl groups (meta-nitroaniline, para-nitroaniline, 2-methyl-4-nitroaniline and para-acetylaniline) as electron-acceptor substituents in the benzol ring results in stable products resulting from substitution of the hydrogen atom in the amino group of aromatic amines, namely: 4-nitro-N-(1'-cyclohepta-2'
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Kaválek, Jaromír, Ludmila Hejtmánková, and Vojeslav Štěrba. "Kinetics and mechanism of solvolysis of substituted phenyl N-phenylbenzimidoesters." Collection of Czechoslovak Chemical Communications 52, no. 5 (1987): 1285–97. http://dx.doi.org/10.1135/cccc19871285.

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Kinetics of hydrochloric acid-catalyzed solvolysis of substituted phenyl and methyl N-phenylbenzimidoesters have been studied in methanol, 50 vol. % aqueous methanol, and 50 vol. % aqueous tetrahydrofurane, and the composition of the reaction products has been determined. The rate-limiting step consists in addition of water or methanol to the protonated substrate. The reaction of methyl N-phenylbenzimidoester with both water and methanol and that of substituted phenyl N-phenylbenzimidoesters with methanol produce aniline, the ester (or orthoester) and the corresponding phenol. The reaction of
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Garrison, Bradley B., Joseph E. Duhamel, Nehemiah Antoine, et al. "4-(Tris(4-methyl-1H-pyrazol-1-yl)methyl)aniline." Molbank 2024, no. 2 (2024): M1823. http://dx.doi.org/10.3390/m1823.

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4-(tris(4-methyl-1H-pyrazol-1-yl)methyl)aniline was prepared in a 63% yield utilizing a C–F activation strategy from a mixture of 4-(trifluoromethyl)aniline, 4-methylpyrazole, and KOH in dimethylsulfoxide (DMSO). The identity of the product was confirmed by nuclear magnetic resonance spectroscopy, infrared spectroscopy, mass spectrometry, and single-crystal analysis. An analysis of crystals grown from the layering method (CH2Cl2/acetone/pentane) indicated two distinct polymorphs of the title compound. Moreover, density functional theory calculations utilizing the MN15L density functional and t
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Solet, Sanwar Mal, Neetesh Kumar Sharma, and Raghvendra Singh Bhadauria. "Synthesis of 2, 5-disubstituted-1, 3, 4-oxadiazole derivatives." Journal of Drug Delivery and Therapeutics 9, no. 4-A (2019): 528–60. http://dx.doi.org/10.22270/jddt.v9i4-a.3514.

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Synthesis of a series of various 2, 5-disubstituted-1, 3, 4-oxadiazole derivatives (7a-7u) have been done. Synthesis of a series of intermediates (3a-3c and 5a-5c) have been also done, ethyl-2-phenoxyacetate (3a), ethyl 2-(2, 4-dichlorophenoxy)acetate (3b), ethyl 2-(4-nitrorophenoxy) acetate (3c), 2-phenoxyacetohydrazide (5a), 2-(2, 4-dichlorophenoxy) acetohydrazide (5b), 2-(4-nitrophenoxy)acetohydrazide (5c), and final product (7a-7u), 2-(phenoxymethyl)-5-phenyl-1, 3, 4-oxadiazole (7a), 4-(5-(phenoxymethyl)-1, 3, 4-oxadiazol-2-yl)aniline (7b), 3-(5-(phenoxymethyl)-1, 3, 4-oxadiazol-2-yl) anil
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Mini, R., T. Joselin Beaula, P. Muthuraja та V. Bena Jothy. "Supramolecular Assembly Interceded by C-H···O Hydrogen Bonds and Nitro···π(arene) Interactions of Antibacterial 4-Methyl-(2-nitro benzylidene)aniline using DFT and its Spectral Studies". Asian Journal of Chemistry 32, № 5 (2020): 1048–58. http://dx.doi.org/10.14233/ajchem.2020.22517.

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4-Methyl-(2-nitrobenzylidene)aniline (MNBA) was grown and its structural as well as spectral analyses (FT-IR, FT-Raman, UV and NMR) using experimental and DFT computations were performed to understand its biological applications. Stability of molecule, charge delocalization, charge analysis and charge transfer interactions had been explored to examine the structural analysis. Docking studies also suggested that 4-methyl-(2-nitrobenzylidene)aniline exhibit antibacterial activity. Supramolecular assembly of 4-methyl-(2-nitrobenzylidene)aniline molecule was interceded by C-H···O hydrogen bonds an
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Pande, Nishigandh, Adinath Jambhale, Dipika Jaspal, Jalinder Ambekar, and Himanshu Patil. "Poly (N-Methyl Aniline)-Li Nanocomposite as an Electrolyte for Rechargeable Battery: In-situ Recipe." E3S Web of Conferences 170 (2020): 01018. http://dx.doi.org/10.1051/e3sconf/202017001018.

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The synthesis of cost-effective and safe polymeric nanocomposite materials has been a subject of interest and study for material science researchers. Poly (N-Methyl Aniline) –Li nanocomposite has been synthesized by a one-pot in-situ method and has been explored as an electrolyte in the battery. Poly (N-Methyl Aniline)-Li nanocomposite prepared, has been characterized by UV-visible, FTIR, FE-SEM, X-ray diffraction techniques. A mechanism of interaction of lithiumion with nitrogen at the imine site has been proposed. The charge-discharge process of poly (N-Methyl Aniline) –Li nanocomposite, whe
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Luzina, Maria, and Aydar Minibaev. "Catalytic synthesis of N-substituted allylarylamines." IOP Conference Series: Earth and Environmental Science 1231, no. 1 (2023): 012081. http://dx.doi.org/10.1088/1755-1315/1231/1/012081.

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Abstract Some N-substituted allylarylamines, for example, N-(1-methyl-2-butenyl) aniline (N-MBA) form, upon isomerization, not only ortho-, but also para- and 2,6-disubstituted derivatives, which does not fit into generally accepted theory. The amino-Claisen rearrangement (ACR) of N-MBA is catalyzed by Lewis acids, cationites, and arylamine hydrochlorides. This work presents the results of studies of ACR N-MBA in solutions of mineral acids. It was found that the reaction must be carried out in dilute solutions. At H2SO4 concentrations of 0.5 mol/L and below, three parallel reactions are observ
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Dissertations / Theses on the topic "Methyl aniline"

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Platten, William E. III. "Anaerobic Treatment of Wastewaters Containing 2,4-dinitroanisole and N-methyl paranitro aniline from Munitions Handling and Production." University of Cincinnati / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1299010001.

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Lamas, Eugenia. "Modifications de l'expression génétique au cours de l'hépatocarcinogénèse chimique induite chez le rat par le 3'-methyl-4-dimethylaminoazobenzene." Paris 6, 1986. http://www.theses.fr/1986PA066316.

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Au cours de l'hépatocarcinogénèse induite par methyl-3'-dab, il y a réexpression précoce des ARN messagers de type fœtal et simultanément, blocage de l'expression de certains ARN messagers codant pour des marqueurs spécifiques du foie adulte.
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Karatay, Elif. "Effect Of Preparation And Operation Parameters On Performance Of Polyethersulfone Based Mixed Matrix Gas Separation Membranes." Master's thesis, METU, 2009. http://etd.lib.metu.edu.tr/upload/12610831/index.pdf.

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ABSTRACT EFFECT OF PREPARATION AND OPERATION PARAMETERS ON PERFORMANCE OF POLYETHERSULFONE BASED MIXED MATRIX GAS SEPARATION MEMBRANES Karatay, Elif M.Sc., Department of Chemical Engineering Supervisor : Prof. Dr. Levent Yilmaz Co-supervisor : Assoc. Prof. Dr. Halil Kalip&ccedil<br>ilar August 2009, 126 pages Membrane processes have been considered as promising alternatives to other competing technologies in gas separation industry. Developing new membrane morphologies are required to improve the gas permeation properties of the membranes. Mixed matrix membranes composing of polymer
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Biewer, Christian [Verfasser]. "Organometallische Nickel-Komplexe mit N-(Pyridin-2-yl-methylen)anilin-Liganden: Reaktivität und Elektronentransfer-Verhalten / Christian Biewer." München : Verlag Dr. Hut, 2013. http://d-nb.info/1045989207/34.

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Jonke, Alex P. "Atomic metal/polyaniline composites." Diss., Georgia Institute of Technology, 2013. http://hdl.handle.net/1853/49070.

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It is ideal to theoretically predict the activity of a catalyst. It has been recognized that not only the type of metal, but also its atomic size plays an important role in catalysis. In the past, atomic clusters have been created by sputtering from a sacrificial metal plate and then using a mass selector to choose cluster sizes from 1-233 atoms of gold. This approach has practical limitations. In this thesis, I describe a procedure by which atomic clusters of gold containing 1-8 atoms are deposited in polyaniline as an isolation matrix. My atomic deposition follows a cyclic pathway. Atom
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Costin-Hogan, Crissy. "Two particle studies 1) a microscopic evaluation of "clay mimics" + their intercalates, and 2) synthesis and characterization of metal halides with ammonium cations /." Master's thesis, Mississippi State : Mississippi State University, 2008. http://library.msstate.edu/etd/show.asp?etd=etd-07102008-121653.

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ATZORI, MATTEO. "Anilate-based Functional Molecular Materials with Conducting and Magnetic Properties." Doctoral thesis, Università degli Studi di Cagliari, 2015. http://hdl.handle.net/11584/266558.

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This work reports on the design, synthesis and characterization of novel anilate-based functional molecular materials showing magnetic and conducting properties. The family of anilate ligands comprises several derivatives obtained by introducing various substituents (H, F, Cl, Br, I, CN, Me, NO2, etc.) at the 3 and 6 positions of a common 2,5-dihyroxy- 1,4-benzoquinone framework. Their electronic/structural features, coordination modes and ability to mediate magnetic exchange interactions between coordinated metal centers make them suitable candidates for the preparation of the above-men
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HADDAD-FAHED, OMAIMA. "Catalyse micellaire de reactions de substitution nucleophile aromatique comportant des reactifs electriquement charges." Paris 6, 1987. http://www.theses.fr/1987PA066419.

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HUYNH, SYLVIE. "Microcalorimetrie de la protonation : application a l'etude du metabolisme des derives nitroses." Caen, 1985. http://www.theses.fr/1985CAEN2020.

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Application de la microcalorimetrie a l'etude des derives nitroses qui suscitent un interet toxicologique certain et servent de substrat a des systemes enzymatiques qui les degradent et modifient leur activite
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Fraysse, Jérôme. "Composites polyaniline/polyméthacrylate de méthyle : percolation, transport électronique et propriétés mécaniques." Université Joseph Fourier (Grenoble), 2000. http://www.theses.fr/2000GRE10201.

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Dans ce travail nous nous interessons aux composites constitues par la dispersion d'un polymere conducteur electronique intrinseque : la polyaniline (pani) dans une matrice polymere isolante : le polymethacrylate de methyle (pmma). Ces materiaux sont une realisation exemplaire de systemes a tres faible seuil de percolation electrique. La comprehension des proprietes de transport electronique au voisinage de ce seuil renvoie d'une part aux proprietes intrinseques de la phase percolante, et d'autre part au phenomene de percolation. Nous exposons donc tout d'abord differents modeles decrivant le
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Books on the topic "Methyl aniline"

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Panigrahi, Muktikanta, and Arpan Kumar Nayak. Polyaniline based Composite for Gas Sensors. IOR PRESS, 2021. http://dx.doi.org/10.34256/ioriip212.

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In this research work, we have demonstrated the synthesis, spectroscopic characteristics, thermal behaviour and DC conductivity of a few nanostructured composites, substituted conducting polymers (ICPs) and composites of ICPs. The physical properties of aforementioned composites are significantly changed by the doping with HCl, H2SO4, HNO3, H3PO4, or acrylic acid. The charge transport properties of these polymeric materials have been studied in detail because of their potential application in gas sensors. In the current work, varieties of conducting polymer based materials such as PANI-ES/Cloi
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Araújo, Ana Cláudia Vaz de. Síntese de nanopartículas de óxido de ferro e nanocompósitos com polianilina. Brazil Publishing, 2021. http://dx.doi.org/10.31012/978-65-5861-120-2.

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In this work magnetic Fe3O4 nanoparticles were synthesized through the precipitation method from an aqueous ferrous sulfate solution under ultrasound. A 23 factorial design in duplicate was carried out to determine the best synthesis conditions and to obtain the smallest crystallite sizes. Selected conditions were ultrasound frequency of 593 kHz for 40 min in 1.0 mol L-1 NaOH medium. Average crystallite sizes were of the order of 25 nm. The phase obtained was identified by X-ray diffractometry (XRD) as magnetite. Scanning electron microscopy (SEM) showed polydisperse particles with dimensions
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Book chapters on the topic "Methyl aniline"

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Winkelmann, Jochen. "Diffusion coefficient of methyl-cyclohexane in aniline." In Diffusion in Gases, Liquids and Electrolytes. Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-662-54089-3_707.

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Winkelmann, Jochen. "Diffusion coefficient of 2-methyl-aniline in water." In Diffusion in Gases, Liquids and Electrolytes. Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-662-54089-3_699.

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Winkelmann, Jochen. "Diffusion coefficient of 3-methyl-aniline in water." In Diffusion in Gases, Liquids and Electrolytes. Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-662-54089-3_700.

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Winkelmann, Jochen. "Diffusion coefficient of 4-methyl-aniline in water." In Diffusion in Gases, Liquids and Electrolytes. Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-662-54089-3_701.

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Winkelmann, Jochen. "Diffusion coefficient of 3-methyl-aniline in methanol at infinite dilution." In Diffusion in Gases, Liquids and Electrolytes. Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-662-54089-3_1987.

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Winkelmann, Jochen. "Diffusion coefficient of 4-methyl-aniline in methanol at infinite dilution." In Diffusion in Gases, Liquids and Electrolytes. Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-662-54089-3_1988.

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Winkelmann, Jochen. "Diffusion coefficient of 4-methyl-aniline in ethanol at infinite dilution." In Diffusion in Gases, Liquids and Electrolytes. Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-662-54089-3_1989.

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Winkelmann, Jochen. "Diffusion coefficient of 4-chloro-2-methyl-aniline in ethanol at infinite dilution." In Diffusion in Gases, Liquids and Electrolytes. Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-662-54089-3_1972.

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Winkelmann, Jochen. "Diffusion coefficient of 4-methyl-aniline in propan-2-one at infinite dilution." In Diffusion in Gases, Liquids and Electrolytes. Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-662-54089-3_1990.

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Winkelmann, Jochen. "Diffusion coefficient of 4-chloro-2-methyl-aniline in propan-2-one at infinite dilution." In Diffusion in Gases, Liquids and Electrolytes. Springer Berlin Heidelberg, 2018. http://dx.doi.org/10.1007/978-3-662-54089-3_1973.

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Conference papers on the topic "Methyl aniline"

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Haskaj, Adelina, Musaj Pacarizi, Sonja Lepitkova, Berat Sinan, Bahri Sinani, and Elida Dreshaj. "THE POTENTIAL COMPLEXING IMPACT OF SOME ORGANIC COMPOUNDS AMINE AND CARBOXYL GROUPS ON TRANSITION METALS." In 24th SGEM International Multidisciplinary Scientific GeoConference 24. STEF92 Technology, 2024. https://doi.org/10.5593/sgem2024/4.1/s18.42.

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Environmental water chemistry is substantially aided by modern electrochemical research. Sensitive voltammetric techniques are much more useful for metal species in natural waters, where complexation with organic molecules predominates. Many environmental electrochemists are still interested in determining the stability constants of metal ion complexes with various ionic species found in natural waterways. The aim of this work is to investigate the possible influence of complexation of amine and carboxyl groups of some organic molecules (with EDTA, NTA and aniline, using differential pulse pol
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Omotosho, Olugbenga Adeshola, Joshua Olusegun Okeniyi, and Abimbola Patricia Idowu Popoola. "Corrosion Inhibition of Stainless Steel in 0.5 M HCl by C6H5NH2." In CORROSION 2018. NACE International, 2018. https://doi.org/10.5006/c2018-10807.

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Abstract In this study, different concentrations of C6H5NH2 (Aniline) were employed for investigating its corrosion inhibition of stainless steel in 0.5 M HCl. Corrosion rate measurements at 28°C, 45°C and 60°C were obtained from a linear sweep voltametry instrument and analyzed for inhibition efficiency and apparent activation energy in the presence and absence of C6H5NH2. Results showed that C6H5NH2 generally exhibited excellent inhibition effects on stainless steel corrosion at the higher temperatures, i.e. the 45°C and 60°C, at which the self-protectiveness of the stainless steel metal app
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Marie, Herve, Hans Peter Deeg, Harald Philipp, Nicholas Marukos, and Chengrong Wang. "Study of Interaction of N-Methyl Aniline Octane Booster on Lubricating Oil." In International Powertrains, Fuels & Lubricants Meeting. SAE International, 2018. http://dx.doi.org/10.4271/2018-01-1809.

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Yan, Shuxin, Teresa Moore, and Lee H. Spangler. "Ring-mediated coupling of NH2 and CH3 modes in para-methylaniline." In OSA Annual Meeting. Optica Publishing Group, 1990. http://dx.doi.org/10.1364/oam.1990.tuy38.

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Jet-cooled fluorescence-excitation spectra of aniline, aniline-ND2, p-methylaniline and p-methylaniline-ND2 will be presented. Two moderately intense peaks in the p-methylaniline spectrum show an unusual multiplet splitting that is not observed in the ring modes. These two transitions also show a large (100 cm−1) deuterium shift in the ND2 molecule and are thus assigned as evenquanta transitions involving the amine inversion and torsion. The corresponding peaks in aniline are not split, indicating that the splitting is due to the interaction of the CH3 torsion with large-amplitude amine motion
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Bailey, Raymond T., Grant Bourhill, Frank R. Cruickshank, et al. "Linear electro-optic properties of 4-nitro-4'-methyl benzylidene aniline single crystals." In Emerging OE Technologies, Bangalore, India, edited by Krishna Shenai, Ananth Selvarajan, C. K. N. Patel, C. N. R. Rao, B. S. Sonde, and Vijai K. Tripathi. SPIE, 1992. http://dx.doi.org/10.1117/12.637001.

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Julianto, Tatang Shabur, Jumina Jumina, Hardjono Sastrohamidjojo, and Mustofa Mustofa. "Synthesis and heme polymerization inhibitory assay of a new arylamino alcohol derivative compound from methyl eugenol and aniline." In 2ND INTERNATIONAL CONFERENCE ON CHEMISTRY, CHEMICAL PROCESS AND ENGINEERING (IC3PE). Author(s), 2018. http://dx.doi.org/10.1063/1.5065064.

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Song, Yujin, and Hyosun Lee. "Synthesis and structural characterisation of palladium(II) complexes containing N,N’-bidentate N-methyl-N-(pyridin-2-ylmethyl)aniline and its derivatives." In Annual International Conference on Chemistry, Chemical Engineering and Chemical Process. Global Science & Technology Forum (GSTF), 2015. http://dx.doi.org/10.5176/2301-3761_ccecp15.41.

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Tamilselvi, D., R. Nandhini, and K. Rathidevi. "A study of oxidation kinetics mechanism of maleic mono p-methyl aniline (MMMA) by N-chloro-3-methyl-2, 6 diphenyl piperidine-4-one (NCP) in the presence of ethanol medium." In THE 8TH ANNUAL INTERNATIONAL SEMINAR ON TRENDS IN SCIENCE AND SCIENCE EDUCATION (AISTSSE) 2021. AIP Publishing, 2022. http://dx.doi.org/10.1063/5.0108189.

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Graves, R. J., and H. W. White. "Tunneling Spectroscopy Study of Aniline Adsorbed on Aluminum Oxide." In Microphysics of Surfaces, Beams, and Adsorbates. Optica Publishing Group, 1987. http://dx.doi.org/10.1364/msba.1987.wc8.

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Information on the types and orientations of molecular species produced at the metal-adsorbate interface is generally very difficult to obtain since the thickness of the region is of the order of 5 to 10 angstroms. Tunneling spectroscopy can provide information on the bonding of these species and, to a limited extent, provide some information on their orientations with respect to the oxide.
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Mirea, Radu. "COMPARATIVE RESEARCH REGARDING HYDROGEN ADSORPTION CAPACITY OF METAL DOPED POLY-ANILINE." In 17th International Multidisciplinary Scientific GeoConference SGEM2017. Stef92 Technology, 2017. http://dx.doi.org/10.5593/sgem2017/42/s17.019.

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Reports on the topic "Methyl aniline"

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Ruangpornvisuti, Vithaya. Basicity investigation and structure optimization of polyaza-Calixarenes and stabilities of their complexes with metal cations. Chulalongkorn University, 2000. https://doi.org/10.58837/chula.res.2000.26.

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The structure of 25, 26, 27, 28-tetra(2-ethoxyaniline)calix[4]arene of cone (cL) and partial cone (pcL) conformations were optimized by PM3 of quantum chemical method. It has been found that cL structure is more stable than pcL conformation. The stabilization energies of protonation on four aniline-nitrogen atoms of both conformations of the ligand at 6-31G energy level, were obtained. The protonations process on the cL and pcL being 7 and 24 possible pathways, respectively, were evaluated. The basicity constants of partial cone conformation of 25, 26, 27, 28-tetra(2- ethoxyaniline)calix[4]are
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