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Journal articles on the topic 'Methyl cyanide'

Author: Grafiati

Published: 4 June 2021

Last updated: 16 February 2022

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1

Schneider, J., V. Bürger, and F. Arnold. "Methyl cyanide and hydrogen cyanide measurements in the lower stratosphere: Implications for methyl cyanide sources and sinks." Journal of Geophysical Research: Atmospheres 102, no. D21 (1997): 25501–6. http://dx.doi.org/10.1029/97jd02364.

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2

Chen, You-Sheng, and Jian-Hong Zhang. "2-Methyl-3-nitrobenzyl cyanide." Acta Crystallographica Section E Structure Reports Online 65, no. 4 (2009): o767. http://dx.doi.org/10.1107/s1600536809008484.

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3

Dechamps, Noémie, Robert Flammang, Michaël Boulvin, et al. "Ion—Molecule Reactions Involving Methyl Isocyanide and Methyl Cyanide." European Journal of Mass Spectrometry 13, no. 6 (2007): 385–95. http://dx.doi.org/10.1255/ejms.896.

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4

de Meester, P., S. S. C. Chu, and J. E. Johnson. "(E)-O-Methyl-p-nitrobenzohydroximoyl cyanide." Acta Crystallographica Section C Crystal Structure Communications 42, no. 11 (1986): 1656–57. http://dx.doi.org/10.1107/s0108270186091084.

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5

Rosero, V., P. Hofner, S. Kurtz, J. Bieging, and E. D. Araya. "METHYL CYANIDE OBSERVATIONS TOWARD MASSIVE PROTOSTARS." Astrophysical Journal Supplement Series 207, no. 1 (2013): 12. http://dx.doi.org/10.1088/0067-0049/207/1/12.

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6

Green, Sheldon. "Collisional excitation of interstellar methyl cyanide." Astrophysical Journal 309 (October 1986): 331. http://dx.doi.org/10.1086/164605.

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7

Abd-Ei-Aziz, Alaa S., Debbie A. Armstrong, Shelly Bernardin, and Harold M. Hutton. "Nucleophilic addition to di- and poly-iron arene complex cations." Canadian Journal of Chemistry 74, no. 11 (1996): 2073–82. http://dx.doi.org/10.1139/v96-236.

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Hydride and cyanide addition to a series of di- and polycyclopentadienyliron arene complex cations with etheric bridges is described. Reaction of the di-iron complexes with sodium borohydride resulted in the formation of a number of adducts.p-Methyl- and o,o-dimethylphenoxybenzene cyclopentadienyliron complexes were used as models in this study to allow for the characterization of the analagous di-iron complexes. The use of HH COSY and CH COSY NMR techniques enabled us to identify the isomeric nature of these adducts. The hydride addition results indicated that the etheric substituent had the

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8

Arnold, Donald R., Kimberly A. McManus, and Mary S. W. Chan. "Photochemical nucleophile–olefin combination, aromatic substitution (photo-NOCAS) reaction, Part 13. The scope and limitations of the reaction with cyanide anion as the nucleophile." Canadian Journal of Chemistry 75, no. 8 (1997): 1055–75. http://dx.doi.org/10.1139/v97-126.

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The scope of the photochemical nucleophile–olefin combination, aromatic substitution (photo-NOCAS) reaction has been extended to include cyanide anion as the nucleophile. Highest yields of adducts were obtained when the alkene or diene has an oxidation potential less than ca. 1.5 V (SCE). No adducts were obtained from 2-methylpropene (9), oxidation potential 2.6 V. Oxidation of cyanide anion, by the radical cation of the alkene or diene, can compete with the combination. With the alkenes, 2,3-dimethyl-2-butene (2) and 2-methyl-2-butene (10), both nitriles and isonitriles were obtained; isonitr

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9

Noland, Wayland E., Ryan J. Herzig, Abigail J. Engwall, Renee C. Jensen, and Kenneth J. Tritch. "Crystal structures of methyl 3,5-dibromo-4-cyanobenzoate and methyl 3,5-dibromo-4-isocyanobenzoate." Acta Crystallographica Section E Crystallographic Communications 74, no. 3 (2018): 345–48. http://dx.doi.org/10.1107/s2056989018002256.

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The title crystals, C9H5Br2NO2, are the first reported 2,6-dihalophenyl cyanide–isocyanide pair that have neither three- nor two-dimensional isomorphism. Both crystals contain contacts between the carbonyl O atom and a Br atom. In the crystal of the cyanide,R22(10) inversion dimers form based on C[triple-bond]N...Br contacts, a common packing feature in this series of crystals. In the isocyanide, the corresponding N[triple-bond]C...Br contacts are not observed. Instead, the isocyano C atom forms contacts with the methoxy C atom. RNC was refined as a two-component pseudo-merohedral twin.

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10

French, Richard C., Peter T. Kujawski, and Gerald R. Leather. "Effect of Various Flavor-Related Compounds on Germination of Curly Dock Seed (Rumex crispus) and Curly Dock Rust (Uromyces rumicis)." Weed Science 34, no. 3 (1986): 398–402. http://dx.doi.org/10.1017/s0043174500067060.

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Chemicals that stimulate germination of curly dock seed (Rumex crispus L. # RUMCR) and urediniospores of curly dock rust [Uromyces rumicis Schum. (Wint.)], an obligate parasite of this weed, were studied and compared. Methyl salicylate, benzyl cyanide, and benzonitrile were the best stimulators of germination of curly dock seed. The compounds tested were most effective at concentrations ranging from 250 to 1000 μl/L. A 500 μl/L concentration of methyl salicylate caused 99% of the curly dock seed to germinate. Exposure to volatiles from 10 μl methyl salicylate or octyl cyanide for 16 to 24 h wa

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11

Sarkkinen, H., R. Paso, and R. Anttila. "Assignment of methyl cyanide FIR laser lines." Infrared Physics & Technology 37, no. 6 (1996): 643–53. http://dx.doi.org/10.1016/s1350-4495(96)00013-8.

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12

Koohestani, Hassan, and Amirabbas Kheilnejad. "Hydrogen Generation and Pollution Degradation from Wastewater Using TiO2–CuO Nanocomposite." Journal of Nanoscience and Nanotechnology 20, no. 9 (2020): 5970–75. http://dx.doi.org/10.1166/jnn.2020.18544.

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Simultaneous production of hydrogen and degradation of cyanide ion and methyl red dye were successfully accomplished by employing nano-particles of TiO2–CuO under the radiation of UV light. Exploiting composites improves the electron–hole separation and consequently optimizes photocatalytic processes. Furthermore, the simultaneity of several photocatalytic processes decreases the rate of electron–hole recombination. According to the results, more hydrogen was produced in lower pHs. Up to the initial concentration of 0.3 and 0.8 mol/L for methyl red and cyanide ion respectively, the presence of

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13

Calcutt, H., M. R. Fiechter, E. R. Willis, et al. "The ALMA-PILS survey: first detection of methyl isocyanide (CH3NC) in a solar-type protostar." Astronomy & Astrophysics 617 (September 2018): A95. http://dx.doi.org/10.1051/0004-6361/201833140.

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Context. Methyl isocyanide (CH3NC) is the isocyanide with the largest number of atoms confirmed in the interstellar medium (ISM), but it is not an abundant molecule, having only been detected towards a handful of objects. Conversely, its isomer, methyl cyanide (CH3CN), is one of the most abundant complex organic molecules detected in the ISM, with detections in a variety of low- and high-mass sources. Aims. The aims of this work are to determine the abundances of methyl isocyanide in the solar-type protostellar binary IRAS 16293–2422 and to understand the stark abundance differences observed b

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14

POULSEN, MATT, STEPHEN DUCHARME, A. V. SOROKIN, et al. "Investigation of Ferroelectricity in Poly(methyl vinylidene cyanide)." Ferroelectrics Letters Section 32, no. 3-4 (2005): 91–97. http://dx.doi.org/10.1080/07315170500311614.

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15

Pearson, J. C., and H. S. P. Muller. "The Submillimeter Wave Spectrum of Isotopic Methyl Cyanide." Astrophysical Journal 471, no. 2 (1996): 1067–72. http://dx.doi.org/10.1086/178034.

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16

Carlotti, M., G. Di Lonardo, L. Fusina, and B. Carli. "The far-infrared spectrum of methyl cyanide, CH3CN." Journal of Molecular Spectroscopy 129, no. 2 (1988): 314–25. http://dx.doi.org/10.1016/0022-2852(88)90038-0.

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17

Marimuthu, Aravindh N., Frank Huis in’t Veld, Sven Thorwirth, Britta Redlich, and Sandra Brünken. "Infrared predissociation spectroscopy of protonated methyl cyanide, CH3CNH+." Journal of Molecular Spectroscopy 379 (May 2021): 111477. http://dx.doi.org/10.1016/j.jms.2021.111477.

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18

Szilágyi, Tibor. "Infrared spectra of methyl cyanide and methyl isocyanide adsorbed on Pt/SiO2." Applied Surface Science 35, no. 1 (1988): 19–26. http://dx.doi.org/10.1016/0169-4332(88)90034-7.

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19

Ben Khalifa, M., E. Quintas-Sánchez, R. Dawes, K. Hammami, and L. Wiesenfeld. "Rotational quenching of an interstellar gas thermometer: CH3CN⋯He collisions." Physical Chemistry Chemical Physics 22, no. 31 (2020): 17494–502. http://dx.doi.org/10.1039/d0cp02985h.

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20

RAHIMI, R., and P. HAMBRIGHT. "Anti-Cyanide Drugs: Kinetics of the Removal of Copper(II) and Nickel(II) from N-Methyl-tetra(4-sulfonatophenyl)porphyrins by Cyanide. LD50s of Common Metalloporphyrins and Metallophthalocyanines." Journal of Porphyrins and Phthalocyanines 02, no. 06 (1998): 493–99. http://dx.doi.org/10.1002/(sici)1099-1409(199811/12)2:6<493::aid-jpp88>3.0.co;2-y.

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The purpose of this project was to develop prophylactic water-soluble anti-cyanide drugs. The 24 h mean LD 50s in mice of 13 common metalloporphyrins and metallophthalocyanines are reported. At doses of 1/4, 1/16 and 1/64 of the LD 50 administered 15 or 60 min prior to a 2LD50 challenge of sodium cyanide, none of these compounds protected mice against cyanide. While Co ( H 2 O )6 Cl 2 and Ni ( H 2 O )6Cl2 were found to be effective, they are too toxic to be useful. A stable metalloporphyrin that could scavenge cyanide by donating metal ions to produce non-toxic polycyano species in the presenc

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21

Wehres, N., J. Maßen, K. Borisov, et al. "A laboratory heterodyne emission spectrometer at submillimeter wavelengths." Physical Chemistry Chemical Physics 20, no. 8 (2018): 5530–44. http://dx.doi.org/10.1039/c7cp06394f.

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22

Rachid, Leena N., та Peter W. R. Corfield. "Poly[3-methyl-1,3-oxazolidin-2-iminium[µ3-cyanido-tri-µ2-cyanido-κ9C:N-tricuprate(I)]]". Molbank 2021, № 3 (2021): M1259. http://dx.doi.org/10.3390/m1259.

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The unexpected formation of an oxazole ring has occurred during synthesis of a copper(I) cyanide network polymer as part of our ongoing studies of the structural chemistry of these networks. Crystals of the title compound were formed during the synthesis of a previously reported CuCN network solid containing protonated N-methylethanolamine and have been characterized by single crystal X-ray structure analysis. The structure shows well-defined oxazole-2-iminium cations sitting in continuous channels along the short a-axis of the crystal in a new three-dimensional copper(I) cyanide polymeric net

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23

Majewski, Marek, Marc DeCaire, Pawel Nowak, and Fan Wang. "Studies on enolate chemistry of 8-thiabicyclo[3.2.1]- octan-3-one: enantioselective deprotonation and synthesis of sulfur analogs of tropane alkaloids." Canadian Journal of Chemistry 79, no. 11 (2001): 1792–98. http://dx.doi.org/10.1139/v01-157.

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Enantioselective deprotonation of 8-thiabicyclo[3.2.1]octan-3-one (1) with chiral lithium amides, followed by reactions with electrophiles affords sulfur analogs of tropane alkaloids of pyranotropane family. Thus, deprotonation of 1 with (S)-N-(diphenyl)methyl-1-phenylethylamine (11d), followed by the reaction of the resulting nonracemic enolate with benzaldehyde gives the corresponding aldol product as one diastereoisomer (exo, threo) and in high enanatiomeric purity (95% ee). Trimethylsilyl chloride, acetic anhydride, and acyl cyanides react readily with the lithium enolate to give the corre

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24

Kemper, Paul R., Lewis M. Bass, and Michael T. Bowers. "A reexamination of the methyl + hydrogen cyanide association reaction including the methyl/methyl-d3 isotope effect." Journal of Physical Chemistry 89, no. 7 (1985): 1105–7. http://dx.doi.org/10.1021/j100253a012.

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25

Rye, R. R., J. T. Yatess, and M. R. Albert. "Functional group contributions to the auger spectra of methyl cyanide and methyl isocyanide." Journal of Electron Spectroscopy and Related Phenomena 40, no. 1 (1986): 69–83. http://dx.doi.org/10.1016/0368-2048(86)80007-x.

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26

Appleton, TG, JR Hall, and MA Williams. "Dimethylplatinum(IV) Complexes With Cyanide: Thermal and Photoassisted Substitution Reactions, and Characterization of Products by N.M.R." Australian Journal of Chemistry 40, no. 9 (1987): 1565. http://dx.doi.org/10.1071/ch9871565.

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Reactions of cyanide with the dimethylplatinum (IV) complexes, [PtMe2(OH) (H20)1.5 n, [PtMe2Br2]n and fac-PtMe2Br(H2O)3+, have been studied, principally by 1H, 13C and 195Pt n.m.r. Cyanide rapidly displaces the ligands trans to the methyl groups. Subsequent reactions cis to the methyl groups occur more slowly with heating, or, for bromo complexes, on ultraviolet irradiation. These substitution reactions compete with reductive elimination of groups from the platinum(IV) compounds to produce platinum(II) products. All attempts to prepare solutions of fac-PtMe2(CN)(H2O)3+ were unsuccessful. Oxida

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27

Green, Sheldon. "Rotational excitation in low-energy methyl cyanide-helium collisions." Journal of Physical Chemistry 89, no. 24 (1985): 5289–94. http://dx.doi.org/10.1021/j100270a034.

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28

Kalenskii, S. V., V. G. Promislov, A. V. Alakoz, A. Winnberg, and L. E. B. Johansson. "Determination of molecular gas properties using methyl cyanide lines." Astronomy Reports 44, no. 11 (2000): 725–37. http://dx.doi.org/10.1134/1.1320498.

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29

Le Guennec, M., G. Wlodarczak, J. Burie, and J. Demaison. "Rotational spectrum of CH2DCN and structure of methyl cyanide." Journal of Molecular Spectroscopy 154, no. 2 (1992): 305–23. http://dx.doi.org/10.1016/0022-2852(92)90210-f.

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30

van Driel, C. A. A., and W. L. Groeneveld. "The oxidation of methyl cyanide by vanadium(IV) chloride." Recueil des Travaux Chimiques des Pays-Bas 88, no. 8 (2010): 891–96. http://dx.doi.org/10.1002/recl.19690880802.

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31

Spentzos, Ariana Z., Michael R. Gau, Patrick J. Carroll, and Neil C. Tomson. "Unusual cyanide and methyl binding modes at a dicobalt macrocycle following acetonitrile C–C bond activation." Chemical Communications 56, no. 67 (2020): 9675–78. http://dx.doi.org/10.1039/d0cc03521a.

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32

Gu, Lijun, Cheng Jin, Hongtao Zhang, Jiyan Liu, Ganpeng Li Ganpeng Li, and Zhi Yang. "An aerobic Cu-mediated practical approach to aromatic nitriles using cyanide anions as the nitrogen source." Organic & Biomolecular Chemistry 14, no. 28 (2016): 6687–90. http://dx.doi.org/10.1039/c6ob01269h.

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33

Burrow, P. D., A. E. Howard, A. R. Johnston, and K. D. Jordan. "Temporary anion states of hydrogen cyanide, methyl cyanide, and methylene dicyanide, selected cyanoethylenes, benzonitrile, and tetracyanoquinodimethane." Journal of Physical Chemistry 96, no. 19 (1992): 7570–78. http://dx.doi.org/10.1021/j100198a017.

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34

Tandon, Santokh S., and C. Robert Lucas. "Metal-induced facile synthesis of a tricyclic system — 10-Methyl-12-thia-2,9-diaza-tricyclo[8.3.1.03,8]tetradeca-3,5,7-triene-1-carbonitrile. Formation of an intramolecular carbon–carbon bond." Canadian Journal of Chemistry 86, no. 9 (2008): 912–17. http://dx.doi.org/10.1139/v08-100.

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The reaction between 4-thiaheptane-2,6-dione and 1,2-diaminobenzene in the presence of nickel(II) perchlorate results in the formation of a nickel(II) complex of a novel new heterotricyclic system: 1-methoxy-10-methyl-12-thia-2,9-diaza-tricyclo[8.3.1.03,8]tetradeca-3,5,7-triene, which on treatment with potassium cyanide gives 10-methy-12-thia-2,9-diaza-tricyclo[8.3.1.03,8]tetradeca-3,5,7-triene-1-carbonitrile, a case of metal-induced carbon–carbon bond formation.Key words: nickel-induced carbon–carbon bond formation, intramolecular cyclization, tricyclic formation.

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35

Edard, Florence, Adam P. Hitchcock, and Michel Tronc. "The .pi.* and .sigma.* shape resonances in the vibrational excitation of hydrogen cyanide, methyl cyanide, and methyl isocyanide by low-energy electron impact." Journal of Physical Chemistry 94, no. 7 (1990): 2768–74. http://dx.doi.org/10.1021/j100370a010.

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36

Kulkarni, S., MR Grimmett, LR Hanton, and J. Simpson. "Nucleophilic Displacements of Imidazoles. I. Oxygen, Nitrogen and Carbon Nucleophiles." Australian Journal of Chemistry 40, no. 8 (1987): 1399. http://dx.doi.org/10.1071/ch9871399.

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4(5)- Bromo - and - iodo-imidazoles, activated by an adjacent nitro substituent, undergo nucleophilic displacement with methoxide, phenoxide , cyclic secondary chines and cyanide. The regiochemistry of the reactions of 5-iodo-4-nitroimidazole with methoxide has been confirmed by spectroscopic and X-ray methods, and a number of erroneous structures from the literature have been revised. Some apparently anomalous reactions of methoxide with 5-halo-1,2-dimethyl-4- nitroimidazoles, and of cyanide with 4-halo-1-methyl-5-nitroimidazole have been noted. The crystal and molecular structure of 5-methox

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37

Hung, T., Sheng-Yuan Liu, Yu-Nung Su, et al. "A Mini Survey of Methyl Cyanide toward Extended Green Objects." Astrophysical Journal 872, no. 1 (2019): 61. http://dx.doi.org/10.3847/1538-4357/aafc23.

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38

Rinsland, Curtis P., Steven W. Sharpe, and Robert L. Sams. "Temperature-dependent infrared absorption cross sections of methyl cyanide (acetonitrile)." Journal of Quantitative Spectroscopy and Radiative Transfer 96, no. 2 (2005): 271–80. http://dx.doi.org/10.1016/j.jqsrt.2005.03.004.

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39

Wilner, D. J., M. C. H. Wright, and R. L. Plambeck. "Maps of 92 GHz methyl cyanide emission in Orion-KL." Astrophysical Journal 422 (February 1994): 642. http://dx.doi.org/10.1086/173757.

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40

O'Leary, Deirdre M., Albert A. Ruth, Sophie Dixneuf, Johannes Orphal, and Ravi Varma. "The near infrared cavity-enhanced absorption spectrum of methyl cyanide." Journal of Quantitative Spectroscopy and Radiative Transfer 113, no. 11 (2012): 1138–47. http://dx.doi.org/10.1016/j.jqsrt.2012.02.022.

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41

Duthie, Andrew, Peter Scammells, Andrew Katsifis, and Edward R. T. Tiekink. "(1,3-Benzo[d]dioxol-5-yl)(2-pyridyl)methyl cyanide." Acta Crystallographica Section E Structure Reports Online 57, no. 2 (2001): o104—o105. http://dx.doi.org/10.1107/s1600536801000198.

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42

Codella, C., M. Benedettini, M. T. Beltrán, et al. "Methyl cyanide as tracer of bow shocks in L1157-B1." Astronomy & Astrophysics 507, no. 2 (2009): L25—L28. http://dx.doi.org/10.1051/0004-6361/200913340.

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43

Park, Min-Goo, Bo-Kyung Sung, and Jae-Young Cho. "Residual Characteristics of Methyl Bromide and Hydrogen Cyanide in Banana, Orange, and Pineapple." Journal of Applied Biological Chemistry 54, no. 3 (2011): 214–17. http://dx.doi.org/10.3839/jabc.2011.035.

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44

Díaz, C., and N. Yutronic. "Donor-Acceptor Properties of the Methyl Cyanide and Methyl Isocyanide Ligands Towards the Fragment CpFe(dppe)+." Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry 27, no. 1 (1997): 119–26. http://dx.doi.org/10.1080/00945719708000187.

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45

McEwan, Murray J., Arthur B. Denison, Wesley T. Huntress, Vincent G. Anicich, J. Snodgrass, and M. T. Bowers. "Association reactions at low pressure. 2. The methylium/methyl cyanide system." Journal of Physical Chemistry 93, no. 10 (1989): 4064–68. http://dx.doi.org/10.1021/j100347a039.

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46

Huet, T. R. "The ν 1 and ν 5 fundamental bands of methyl cyanide". Journal of Molecular Structure 517-518 (лютий 2000): 127–31. http://dx.doi.org/10.1016/s0022-2860(99)00243-4.

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47

Pankonin, V., E. Churchwell, C. Watson, and J. H. Bieging. "A Methyl Cyanide Search for the Earliest Stages of Massive Protostars." Astrophysical Journal 558, no. 1 (2001): 194–203. http://dx.doi.org/10.1086/322249.

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48

Bell, T. A., J. Cernicharo, S. Viti, et al. "Extended warm gas in Orion KL as probed by methyl cyanide." Astronomy & Astrophysics 564 (April 2014): A114. http://dx.doi.org/10.1051/0004-6361/201321872.

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49

Akeson, R. L., and J. E. Carlstrom. "Lifetimes of Ultracompact H II Regions: High-Resolution Methyl Cyanide Observations." Astrophysical Journal 470 (October 1996): 528. http://dx.doi.org/10.1086/177885.

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50

Sutton, E. C., Geoffrey A. Blake, R. Genzel, C. R. Masson, and T. G. Phillips. "Excitation of methyl cyanide in the hot core of the Orion." Astrophysical Journal 311 (December 1986): 921. http://dx.doi.org/10.1086/164829.

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